EP0980930A1 - Färbeverfahren für Textilmaterialien mit Indigo unter Benützung des Indoxyls und Vorrichtung zum Ausführen des Färbeverfahrens - Google Patents
Färbeverfahren für Textilmaterialien mit Indigo unter Benützung des Indoxyls und Vorrichtung zum Ausführen des Färbeverfahrens Download PDFInfo
- Publication number
- EP0980930A1 EP0980930A1 EP98630046A EP98630046A EP0980930A1 EP 0980930 A1 EP0980930 A1 EP 0980930A1 EP 98630046 A EP98630046 A EP 98630046A EP 98630046 A EP98630046 A EP 98630046A EP 0980930 A1 EP0980930 A1 EP 0980930A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- tank
- tanks
- installation
- wire
- rollers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000009434 installation Methods 0.000 title claims abstract description 46
- 238000000034 method Methods 0.000 title claims abstract description 43
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 title claims abstract description 35
- 235000000177 Indigofera tinctoria Nutrition 0.000 title claims abstract description 29
- 229940097275 indigo Drugs 0.000 title claims abstract description 29
- 238000004043 dyeing Methods 0.000 title claims abstract description 19
- 239000004753 textile Substances 0.000 title claims abstract description 10
- 239000000463 material Substances 0.000 title claims description 6
- PCKPVGOLPKLUHR-UHFFFAOYSA-N indoxyl Chemical group C1=CC=C2C(O)=CNC2=C1 PCKPVGOLPKLUHR-UHFFFAOYSA-N 0.000 claims abstract description 50
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract description 42
- 238000005406 washing Methods 0.000 claims abstract description 17
- 239000000203 mixture Substances 0.000 claims abstract description 11
- 229920005989 resin Polymers 0.000 claims abstract description 10
- 239000011347 resin Substances 0.000 claims abstract description 10
- 238000001035 drying Methods 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000000835 fiber Substances 0.000 claims abstract description 4
- COHYTHOBJLSHDF-BUHFOSPRSA-N indigo dye Chemical compound N\1C2=CC=CC=C2C(=O)C/1=C1/C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-BUHFOSPRSA-N 0.000 claims abstract description 4
- 230000001590 oxidative effect Effects 0.000 claims abstract 3
- 238000004804 winding Methods 0.000 claims abstract 2
- 238000007254 oxidation reaction Methods 0.000 claims description 46
- 230000003647 oxidation Effects 0.000 claims description 38
- 239000000975 dye Substances 0.000 claims description 19
- 238000004026 adhesive bonding Methods 0.000 claims description 5
- -1 polysiloxane Polymers 0.000 claims description 4
- 229920001296 polysiloxane Polymers 0.000 claims description 4
- 238000004513 sizing Methods 0.000 claims description 4
- 239000004925 Acrylic resin Substances 0.000 claims description 3
- 229920000178 Acrylic resin Polymers 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 229920005749 polyurethane resin Polymers 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 150000002191 fatty alcohols Chemical class 0.000 claims description 2
- 238000005470 impregnation Methods 0.000 claims description 2
- 239000000243 solution Substances 0.000 claims 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- 239000007864 aqueous solution Substances 0.000 claims 1
- 230000001131 transforming effect Effects 0.000 claims 1
- 239000004744 fabric Substances 0.000 abstract description 18
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 10
- 229920000742 Cotton Polymers 0.000 description 5
- 238000002845 discoloration Methods 0.000 description 4
- 230000035515 penetration Effects 0.000 description 4
- 239000011734 sodium Substances 0.000 description 3
- VIFKLIUAPGUEBV-UHFFFAOYSA-N 2-(3-hydroxy-1h-indol-2-yl)-1h-indol-3-ol Chemical compound N1C2=CC=CC=C2C(O)=C1C1=C(O)C2=CC=CC=C2N1 VIFKLIUAPGUEBV-UHFFFAOYSA-N 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 description 2
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000002605 large molecules Chemical class 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000005517 mercerization Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229940098465 tincture Drugs 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
Images
Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/22—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using vat dyestuffs including indigo
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B21/00—Successive treatments of textile materials by liquids, gases or vapours
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
- D06B3/10—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
- D06B3/12—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics in zig-zag manner over series of guiding means
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/0004—General aspects of dyeing
- D06P1/002—Processing by repeated dyeing, e.g. in different baths
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/0032—Determining dye recipes and dyeing parameters; Colour matching or monitoring
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/5214—Polymers of unsaturated compounds containing no COOH groups or functional derivatives thereof
- D06P1/5235—Polyalkenyl halides, e.g. PVC
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
- D06P1/5278—Polyamides; Polyimides; Polylactames; Polyalkyleneimines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
- D06P1/5285—Polyurethanes; Polyurea; Polyguanides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
- D06P1/5292—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds containing Si-atoms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/653—Nitrogen-free carboxylic acids or their salts
- D06P1/6533—Aliphatic, araliphatic or cycloaliphatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/667—Organo-phosphorus compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/916—Natural fiber dyeing
- Y10S8/918—Cellulose textile
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/93—Pretreatment before dyeing
- Y10S8/931—Washing or bleaching
Definitions
- the present invention relates to a dyeing process of a textile material with indigo using indoxyl and an installation for the implementation of process.
- a dyed textile yarn is made indigo then used to prepare a tissue called denim fabric with which we make items such as blue jeans, for example.
- Patent EP-B-0 692 042 describes a method of dyeing a textile material containing cellulose with indigo in which we use a solution aqueous leuco-indigo prepared by hydrogenation catalytic and we convert it to the form pigmented by air oxidation after its rise on the textile material.
- US-A-4,283,198 describes a continuous process for tincture of cellulose fibers with indigo where passes the fibers through a train of tanks soaking containing a liquor bath comprising leuco-indigo, sodium hydrosulfite and hydroxide sodium.
- US-A-3,457,022 describes a method of cotton fiber dye with indigo where applied indigo at a temperature between 65 ° C and 80 ° C on the wires and then we apply indigo at temperatures below 40 ° C.
- Indigo-dyed blue jeans have the disadvantage that it discolours on washing.
- the way of using the dye facilitated washing and aging. But all fashion is fleeting and does not last only a time.
- the patent application EP 98630005.1 describes a dyeing process with indigo during which makes a denim fabric that resists wear and discoloration. By this process indigo will penetrate more deep in the thread.
- the wire included a central core white and only the outer part was tinted to indigo. With the process according to the patent application EP 98 630 005.1 the white central core was much thinner.
- the object of the present invention is the realization denim fabric that resists wear and fade and the yarn obtained is dyed right through to the point that the white central soul is practically non-existent and has even disappeared.
- the operations usually performed to dye the yarn in indigo blue, adding additional operations, both in the baths and in the oxidation and prior mercerization to facilitate capacity absorption and impregnation of the wire.
- the wire is then vaporized under conditions of set temperature and pressure, before washing and mercerized again.
- the second phase of the process consists in constituting around the now dyed yarn, insulation for the make it immune to washing, and then it's ready to be used. To do this you must first make the wire neutral by successive passages in acid baths.
- the yarn is then completely dried and the indigo will be definitively fixed with the characteristics desired.
- the thread obtained by the methods known in the art consists of a white central core, i.e. undyed and by a part external impregnated with indigo dye. Thanks to process according to the invention, the central core will be tinted with right through indigo.
- prewash step passing the wire F coming from a starting roller on which it is wound through an installation of prewash 1 consisting of two or more tanks 2 containing a prewash solution 10.15.
- the wire is guided by rollers 3 and 4 in the first tank 2 containing the prewash solution and then leaving this solution it passes between two pressure rollers 5 to remove excess liquid then, guided by roller 6, plunges back in the prewash solution.
- the wire passes between two pressure rollers 7.
- the guide rollers 8 and 9 the wire plunges into the prewash solution 15 in the second tank 2.
- the wire will move in the second tank according to a identical route to that of the first tank passing successively between the two pressure rollers 12, below of the guide roller 11 then between the rollers pressers 13.
- the prewash solution contains a soaking product such as FINBIL AS (produced by the company Bozzetto) (trade designation) which is an ester derivative phosphoric fatty alcohol. It is used in the solution aqueous in a concentration of 5 to 8 gr / liter. This bath of prewash is used to impregnate the yarn in order to favor the subsequent penetration of indoxyl.
- FINBIL AS produced by the company Bozzetto
- Dye baths contain a solution aqueous indoxyl containing 6 to 8% by weight of indoxyl pure.
- the wires pass through the baths at a speed from 20 to 60 m / minute depending on the type and quality of the wire.
- the example shown in Figure 2 includes 8 tanks but it goes without saying that the operation can be repeated 2, 3 or more times using two, three or more sets of 8 tanks to obtain a increasing penetration of indoxyl in thread.
- the wire is passed successively through the tanks 41 to 45 by guiding it by means of the rollers 46, 47 and 48.
- the tank 41 contains water and in the tanks 42, 43 and 44, water is introduced.
- acetic acid (CH 3 -COOH) at 50% so that the tank 42 contains a proportion of 20 cc / l, the tank 43 contains 10 cc / l and the tank 44 contains 5 cc / l.
- the tank 45 again contains water, the final pH being between 6 and 7, preferably 6.7.
- the pre-wiping is carried out wire passing it around the rollers 50 as we can see it in figure 3.
- the wire passes through a tank 62 containing a mixture of 63 resins and is guided through of the tank by means of guide rollers 64 and pressure rollers 61.
- the method according to the invention can be implemented with various types of yarn, for example cotton, cotton and nylon, cotton and polyester etc ....
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Coloring (AREA)
- Treatment Of Fiber Materials (AREA)
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT98630046T ATE287984T1 (de) | 1998-08-18 | 1998-08-18 | Färbeverfahren für textilmaterialien mit indigo unter benützung des indoxyls und vorrichtung zum ausführen des färbeverfahrens |
| DE69828781T DE69828781T2 (de) | 1998-08-18 | 1998-08-18 | Färbeverfahren für Textilmaterialien mit Indigo unter Benützung des Indoxyls und Vorrichtung zum Ausführen des Färbeverfahrens |
| ES98630046T ES2235306T3 (es) | 1998-08-18 | 1998-08-18 | Procedimiento de tinte de una materia textil con indigo utilizando indoxilo e instalacion para la puesta en practica del procedimiento. |
| DK98630046T DK0980930T3 (da) | 1998-08-18 | 1998-08-18 | Fremgangsmåde til farvning af tekstilstoffer med indigo under anvendelse af indoxyl samt anordning til udförelse af fremgangsmåden |
| EP98630046A EP0980930B1 (de) | 1998-08-18 | 1998-08-18 | Färbeverfahren für Textilmaterialien mit Indigo unter Benützung des Indoxyls und Vorrichtung zum Ausführen des Färbeverfahrens |
| SI9830742T SI0980930T1 (en) | 1998-08-18 | 1998-08-18 | Process for dyeing of textile materials with indigo using the indoxyle and installation for carrying out the method |
| PT98630046T PT980930E (pt) | 1998-08-18 | 1998-08-18 | Processo de tingimento de um material textil com anil utilizando indoxilo e instalacao para a realizacao do processo |
| US09/349,692 US6090166A (en) | 1998-08-18 | 1999-07-08 | Process for dyeing a textile material with indigo using indoxyl, and system for exploiting the process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP98630046A EP0980930B1 (de) | 1998-08-18 | 1998-08-18 | Färbeverfahren für Textilmaterialien mit Indigo unter Benützung des Indoxyls und Vorrichtung zum Ausführen des Färbeverfahrens |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0980930A1 true EP0980930A1 (de) | 2000-02-23 |
| EP0980930B1 EP0980930B1 (de) | 2005-01-26 |
Family
ID=8235862
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP98630046A Revoked EP0980930B1 (de) | 1998-08-18 | 1998-08-18 | Färbeverfahren für Textilmaterialien mit Indigo unter Benützung des Indoxyls und Vorrichtung zum Ausführen des Färbeverfahrens |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US6090166A (de) |
| EP (1) | EP0980930B1 (de) |
| AT (1) | ATE287984T1 (de) |
| DE (1) | DE69828781T2 (de) |
| DK (1) | DK0980930T3 (de) |
| ES (1) | ES2235306T3 (de) |
| PT (1) | PT980930E (de) |
| SI (1) | SI0980930T1 (de) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ITUD20010111A1 (it) * | 2001-06-19 | 2002-12-19 | Jaeggli Meccanotessile Srl | Apparecchiatura e procedimento per la tintura e la mercerizzazione difili o filati |
| WO2004058898A1 (fr) * | 2002-12-25 | 2004-07-15 | Beijing Wisdom Yingli Pharmaceutical Technology Developing Co., Ltd. | Procede de teinture directe d'une structure textile in situ |
| DE102008039500A1 (de) * | 2008-08-23 | 2010-02-25 | Dystar Textilfarben Gmbh & Co. Deutschland Kg | Verfahren zum Färben von textilen Materialien |
| CN104562673A (zh) * | 2015-01-22 | 2015-04-29 | 吴照宇 | 用于片染、绳染的浆染联合机生产工艺 |
| TR201907245A2 (tr) * | 2019-05-14 | 2019-06-21 | Maritas Denim Sanayi Ve Ticaret A S | İndi̇go çözgü boyama prosesi̇nde ayri ayri gerçekleşti̇ri̇len ön i̇şlem ve boyama i̇şlemi̇ni̇n tek bi̇r adimda gerçekleşti̇ri̇lmesi̇ i̇le su sarfi̇yatinin azaltilmasi |
| US12297591B1 (en) * | 2021-02-17 | 2025-05-13 | Elcatex, S De R.L. De C.V. | Direct-to-garment printing |
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| US2920932A (en) * | 1955-11-08 | 1960-01-12 | Avondale Mills Inc | Dyed textile fiber and process for producing the same |
| US3457022A (en) * | 1964-12-02 | 1969-07-22 | Cone Mills Corp | Process of dyeing cotton fibers with indigo vat dyes |
| DE2544613A1 (de) * | 1975-10-06 | 1977-04-07 | Krueckels Maschf Zell J | Faerbeverfahren fuer webketten |
| US4118183A (en) * | 1976-04-09 | 1978-10-03 | Quikoton Ag | Process for the treatment of warp yarns |
| CH614339GA3 (en) * | 1975-09-01 | 1979-11-30 | Process for producing finished, wash-fast indigo-dyed textile sheet materials | |
| US4313235A (en) * | 1980-05-27 | 1982-02-02 | Gotovtseva Ljubov A | Method of treating cotton cloth of twisted yarn in loom state |
| US4416124A (en) * | 1979-12-21 | 1983-11-22 | Godau Eckhardt | Sheet-dyeing apparatus |
| EP0246933A1 (de) * | 1986-04-10 | 1987-11-25 | Societe Nouvelle Des Etablissements Faucheur (S.A.R.L.) | Verfahren und Vorrichtung zum kontinuierlichen Nassbehandeln von textilen Flächengebilden |
| DE4007504A1 (de) * | 1989-03-13 | 1990-09-27 | Gottlieb Benz | Einrichtung zur nass- und/oder trockenbehandlung von bahn-, garn-, strang- oder fadenfoermigem textilgut |
| DE4223556A1 (de) * | 1992-07-19 | 1994-01-20 | Sucker & Franz Mueller Gmbh | Oxidationsstrecke beim Indigofärben und Verfahren zum Betrieb der Strecke |
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| US4283198A (en) * | 1980-01-11 | 1981-08-11 | Fletcher John M | Inert atmosphere indigo dyeing |
| EP0387716A3 (de) * | 1989-03-13 | 1991-12-27 | Gottlieb Benz | Einrichtung zur Nass - und/oder Trockenbehandlung von bahn-, garn-, strang- oder fadenförmigen Textilgut |
| TW251325B (de) * | 1993-03-30 | 1995-07-11 | Basf Ag |
-
1998
- 1998-08-18 EP EP98630046A patent/EP0980930B1/de not_active Revoked
- 1998-08-18 PT PT98630046T patent/PT980930E/pt unknown
- 1998-08-18 AT AT98630046T patent/ATE287984T1/de not_active IP Right Cessation
- 1998-08-18 SI SI9830742T patent/SI0980930T1/xx unknown
- 1998-08-18 DK DK98630046T patent/DK0980930T3/da active
- 1998-08-18 ES ES98630046T patent/ES2235306T3/es not_active Expired - Lifetime
- 1998-08-18 DE DE69828781T patent/DE69828781T2/de not_active Expired - Fee Related
-
1999
- 1999-07-08 US US09/349,692 patent/US6090166A/en not_active Expired - Lifetime
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2920932A (en) * | 1955-11-08 | 1960-01-12 | Avondale Mills Inc | Dyed textile fiber and process for producing the same |
| US3457022A (en) * | 1964-12-02 | 1969-07-22 | Cone Mills Corp | Process of dyeing cotton fibers with indigo vat dyes |
| CH614339GA3 (en) * | 1975-09-01 | 1979-11-30 | Process for producing finished, wash-fast indigo-dyed textile sheet materials | |
| DE2544613A1 (de) * | 1975-10-06 | 1977-04-07 | Krueckels Maschf Zell J | Faerbeverfahren fuer webketten |
| US4118183A (en) * | 1976-04-09 | 1978-10-03 | Quikoton Ag | Process for the treatment of warp yarns |
| US4416124A (en) * | 1979-12-21 | 1983-11-22 | Godau Eckhardt | Sheet-dyeing apparatus |
| US4313235A (en) * | 1980-05-27 | 1982-02-02 | Gotovtseva Ljubov A | Method of treating cotton cloth of twisted yarn in loom state |
| EP0246933A1 (de) * | 1986-04-10 | 1987-11-25 | Societe Nouvelle Des Etablissements Faucheur (S.A.R.L.) | Verfahren und Vorrichtung zum kontinuierlichen Nassbehandeln von textilen Flächengebilden |
| DE4007504A1 (de) * | 1989-03-13 | 1990-09-27 | Gottlieb Benz | Einrichtung zur nass- und/oder trockenbehandlung von bahn-, garn-, strang- oder fadenfoermigem textilgut |
| DE4223556A1 (de) * | 1992-07-19 | 1994-01-20 | Sucker & Franz Mueller Gmbh | Oxidationsstrecke beim Indigofärben und Verfahren zum Betrieb der Strecke |
Also Published As
| Publication number | Publication date |
|---|---|
| ATE287984T1 (de) | 2005-02-15 |
| DK0980930T3 (da) | 2005-05-30 |
| EP0980930B1 (de) | 2005-01-26 |
| PT980930E (pt) | 2005-06-30 |
| ES2235306T3 (es) | 2005-07-01 |
| SI0980930T1 (en) | 2005-10-31 |
| DE69828781T2 (de) | 2005-12-22 |
| US6090166A (en) | 2000-07-18 |
| DE69828781D1 (de) | 2005-03-03 |
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