EP0993876A1 - Procédé d'application d'un décor coloré sur un substrat - Google Patents

Procédé d'application d'un décor coloré sur un substrat Download PDF

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Publication number
EP0993876A1
EP0993876A1 EP98119331A EP98119331A EP0993876A1 EP 0993876 A1 EP0993876 A1 EP 0993876A1 EP 98119331 A EP98119331 A EP 98119331A EP 98119331 A EP98119331 A EP 98119331A EP 0993876 A1 EP0993876 A1 EP 0993876A1
Authority
EP
European Patent Office
Prior art keywords
substrate
lacquer
layer
color
decor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP98119331A
Other languages
German (de)
English (en)
Other versions
EP0993876B1 (fr
Inventor
Thomas Dr. Walter
Maximilian Zaher
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bush Industries Inc
Original Assignee
Bush Industries Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bush Industries Inc filed Critical Bush Industries Inc
Priority to DE59810918T priority Critical patent/DE59810918D1/de
Priority to EP19980119331 priority patent/EP0993876B1/fr
Priority to ES98119331T priority patent/ES2213248T3/es
Publication of EP0993876A1 publication Critical patent/EP0993876A1/fr
Application granted granted Critical
Publication of EP0993876B1 publication Critical patent/EP0993876B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
    • B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
    • B44C1/17—Dry transfer
    • B44C1/1733—Decalcomanias applied under pressure only, e.g. provided with a pressure sensitive adhesive
    • B44C1/1745—Decalcomanias applied under pressure only, e.g. provided with a pressure sensitive adhesive using an intermediate support
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00—Processes for applying liquids or other fluent materials
    • B05D1/28—Processes for applying liquids or other fluent materials performed by transfer from the surfaces of elements carrying the liquid or other fluent material, e.g. brushes, pads, rollers
    • B05D1/286—Processes for applying liquids or other fluent materials performed by transfer from the surfaces of elements carrying the liquid or other fluent material, e.g. brushes, pads, rollers using a temporary backing to which the coating has been applied

Definitions

  • the invention relates to a method for applying a color decoration on a substrate using a carrier with so-called "Release” properties.
  • Carriers with "release” properties are known as such (cf. EP 0 573 676 A1).
  • certain papers are particularly considered or also plastic films that are designed on their surface or are prepared that applied under certain conditions Layers of paint or varnish in the manner of a "Peeling off” (like a decal) transferable to a substrate are.
  • Carrier with "release” property plastic films such as in particular Polyester films, which have a suitable release layer to achieve the "Release” (Abpell) property.
  • the present invention aims to provide a method of application a color decor on a substrate of the aforementioned Kind so that a primer of the substrate with very good adhesive and masking effect is achieved. Furthermore should the process provides decorated substrates (items) that show a very good visual impression of the decoration, in particular a deep effect of the coloring, good adhesion the applied layers of paint or varnish with each other and also a high scratch and abrasion resistance of the color decoration covering lacquer layer.
  • the color decor is preferred in all variants of the invention diffusible disperse dyes used, i.e. the Color decor has such disperse dyes.
  • the top layer of paint is heated, especially with a hot gas.
  • the hot gas is preferably in the form of a hot gas meter passed over the top layer of paint, in such a way that the gas temperature of the hot gas and a relative movement between the Hot gas and the substrate can be controlled so that essentially only the top layer of paint is heated effectively.
  • Another preferred embodiment of the invention provides that radiation curing is done with electron beam becomes.
  • the invention preferably provides that the first lacquer layer is a primer paint.
  • the partial crosslinking of the first lacquer layer according to step (c) is carried out preferably carried out with UV radiation.
  • the heating of the top coat of paint is carried out with a hot gas jet, which has a dimension (width) at least in one direction, the is small compared to the dimensions of the color decor and the Layers of paint in this direction.
  • the hot gas jet on a Temperature at which it causes or at least promotes, that the dye in the paint layer above it diffuses. This makes it a very good aesthetic Effect of the decorated product achieved, in particular a certain depth effect of the coloring.
  • the dye molecules diffuse different distances, depending on the molecular weight, in the paint above, what the visual impression the decoration is positively influenced.
  • the adhesion of the layers to each other and also the mechanical Properties of the applied lacquer and dye layers can according to a further preferred embodiment of the Invention are promoted in that the gas jet on impact has the shape of a knife on the top layer of lacquer and is guided in a line over the lacquer layer.
  • the gas jet on impact has the shape of a knife on the top layer of lacquer and is guided in a line over the lacquer layer.
  • this technology can use this technology to precisely increase the temperature for a certain period of time to a certain depth of Layers can be reached without the bottom layer of paint on the same temperature is raised as the top layer of lacquer on the substrate.
  • the diffusion of the dye molecules can be controlled in the desired manner, namely in particular in the lacquer layer above the dye light, for which is why in particular a transparent lacquer or at least one largely transparent or white lacquer is provided.
  • the edge and edge areas of the product are critical.
  • quality the lacquered decoration especially in the edge area promoted by the linear hot gas jet (especially hot air jet) is guided so that it affected Edge or the edge of the substrate with the covering the edge covering paint and varnish layers, so z. B. with a right-angled edge on both surfaces acts equally.
  • Figure 1 shows a carrier 10 with "release” properties.
  • the illustrated embodiment is a polyester film.
  • a color decor 12 is printed on the carrier 10, e.g. B. with Rotary printing or digital printing.
  • Rotary printing or digital printing are available ones As such, printing techniques are known to those skilled in the art.
  • a first lacquer layer 14 is applied to the color decor 12.
  • a lacquer is chosen which is used as the base lacquer is suitable for the substrate that is ultimately to be decorated, thus the surface structure of the substrate in the desired Way so that good adhesion of all applied Paint and color layers on the substrate is reached.
  • the paint layer can be transparent or colored.
  • the layer of varnish applied to the bottom of the substrate prefers a base color for the overlying decor his. If e.g. the decor should be walnut-like, the Basic color of one of the lacquer layers or both lacquer layers be brown.
  • the lacquer layers, especially the lower lacquer layer on the substrate which promotes adhesion Has properties.
  • the base coat of paint can also be used with regard to the application weight so that unevenness, Cracks, holes etc. in the substrate can be compensated.
  • the base lacquer layer can have adhesive properties, in particular, the base lacquer layer as a whole can be trade a glue.
  • Acrylic lacquer polyurethane lacquer, Polyester paint and the like.
  • be water-soluble paints used preferably no paints with Solvent.
  • the paint 14 applied to the color decor 12 is a so-called. Partially crosslinked.
  • a "partial networking" means that the paint has not yet been completely crosslinked will, but only partially, so that later a complete Networking is possible.
  • the networking of paints is that Known to those skilled in the art as such. Networking can e.g. B. with increased Temperatures, especially using infrared radiators be performed. Networking is promoted by so-called hardeners. In the illustrated embodiment, the achievement a subsequent good primer of the to be decorated Substrate and good adhesion of the layers the partial crosslinking the first lacquer layer 14 with UV radiation 16.
  • the system prepared in this way becomes a carrier 10, color decor layer 12 lying thereon and lying thereon partially cross-linked first lacquer layer 14 on a to be decorated Substrate 18 laid around the lacquer layer 14 and the color decor 12 to transfer to the substrate 18.
  • the paint layer is there 14 directly below on the substrate 18, as shown in FIG. 2 is.
  • the transmission takes place with the one explained at the beginning "Release" technique.
  • the first lacquer layer 14 serves as a primer of the substrate 18.
  • a second lacquer layer 20 is applied.
  • Paint layer 20 can use the types of paint mentioned above find, especially a transparent lacquer or a (light) white colored lacquer.
  • the top coat layer 20 is selected to be relatively thick, in particular in the range from 40 to 120 ⁇ m, particularly preferably in the range from 60 to 100 ⁇ m. These strengths of the lacquer layer 20 are important for the diffusion of the dye molecules described below.
  • the paint curing is carried out so that essentially both Lacquer layers 14, 20 are fully hardened.
  • the paints can also in aqueous, solvent-based or in 100% form the paint can be applied.
  • Hot air knife used. It is a Hot air jet coming from a nozzle 24 directly onto the top one Lacquer layer 20 is applied. For this purpose, hot air 26 flows through the nozzle 24.
  • the Hot air jet "knife-shaped", d. H. it has the shape of a line, which is perpendicular to the plane of the drawing and is preferred over the entire width of the paint and dye layers as well of the substrate 18 extends.
  • Such a "hot air knife” can corresponding to arrow 28 relative to substrate 18 with those lying thereon Paint and dye layers are moved.
  • Such a "hot air knife" 24, 26 can be used here Process can be used in various ways.
  • First the hot air knife can serve to transfer the Color decorations 12 with the partially crosslinked lacquer layer 14 from the carrier 10 onto the substrate 18 (i.e. the transition from FIG. 1 to FIG 2) to promote.
  • You can use the hot air knife to start with in this process the support 10 lying on top with the underlying ones Paint and varnish layers 12, 14 against the substrate 18 be pressed. Strokes the hot air knife over the carrier 10, there is a full-area, even system and the partially networked Lacquer is pressed against the substrate 10 and its adhesive effect promoted on the substrate. This makes peeling easier ("Peeling") of the carrier 10.
  • the hot air knife 24, 26 after the electron beam hardening the layers of paint 14, 20 is particularly beneficial for the decoration technology used here.
  • the hot air knife can the temperature of the upper layer of lacquer 20 and the underlying Dye layer 12 can be increased briefly in such a way that a clear temperature gradient from top to bottom is given, d. H. the top layer of lacquer 20 is hotter than that bottom paint layer 14. This causes the dye molecules diffuse from the color decor layer 12 into the upper lacquer layer 20.
  • diffusible disperse dyes that depends Color and thus the diffusion rate of the dye in usually depending on the molecular weight. Roughly said z. B.
  • yellow Colors have a typical molecular weight of 200 to 300, red of 250 to 350, blue from 300 to 400 and black from 350 to 500. This has the consequence that in the thermal diffusion described above the light dyes, such as yellow, continue to diffuse than the darker dyes, such as. B. blue or black. Hereby becomes a 3-dimensional depth effect of the color decoration reached.
  • the above strengths for the top coat 20 enable this depth effect due to different diffusion distances of the individual dye molecules.
  • the hot air knife mentioned is particularly suitable for this process, because it's a short-term very targeted temperature increase with the temperature gradient mentioned.
  • the temperature the hot air 26 and the speed of the relative movement between nozzle 24 and substrate 18 with those lying thereon Lacquer and dye layers are adjusted so that the above explained effect is achieved.
  • the locally limited Hot air knife enables a brief temperature increase with temperature gradients without immediately being complete uniform distribution of heating occurs, d. H. without a uniform temperature distribution in the paint and Dye layers sets before the targeted described above Diffusion of the dye molecules into the top layer of lacquer 20 is essentially reached.
  • the nozzle 24 is shaped so that the hot air jet in the form of an elongated line on the top layer of lacquer 20 hits. This enables in particular a good quality decoration of the substrate 18 in the particularly critical edge area 30.
  • the line-shaped hot air jet (the "Hot air knife”) passed obliquely over the edge area 30, see above that a uniform pressure and temperature influence on both edge surfaces is given by the gas jet. It can too several hot air knives at different angles at the same time be used.
  • Figure 3 shows a modification of the embodiment described above of the invention, being instead of the first a layer of adhesive now lying on the substrate 14a is used.
  • It can e.g. B.
  • Glue on water or solvent base can be used.
  • FIG. 4 shows a further exemplary embodiment of the invention, in that between the carrier 10a with "release” property and the curtain 12 is provided with a curable lacquer layer 20a.
  • the curable lacquer layer 20a consists in particular of UV radiation curable paint.
  • This UV-curable lacquer layer 20a has in particular the purpose of facilitating the detachment of the carrier 10a.
  • the carrier 10a can be removed more easily from the lacquer layer 20a are considered from a color decor layer 12. Between the Color decor 12 and the substrate to be decorated 18 is, as with 3, an adhesive layer 14a is arranged.
  • the layer 20a made of UV-curable lacquer is preferably stretchable and flexible.
  • the following mixture can be used: 40 to 60% by weight aliphatic urethane acrylate; 20 to 40% by weight polyether acrylate; 10 to 30% by weight of monoacrylate and 2 to 5% by weight of photoinitiator.
  • the process for the decoration according to FIG. 4 essentially runs as follows: First, the carrier 10a with "release” property, e.g. B. a PVA carrier, with a layer 20a of UV-curable Lacquer coated. The paint is hardened, at least partially, so that on him the color decor 12 of the above type can be applied. An adhesive layer is applied to the color decor 12 14a of the type mentioned above and the whole is placed on the substrate 18 to be decorated using activation of the pressure and / or elevated temperature Adhesive 14a and then the carrier 10a from the top Paint layer 20a can be peeled off in a simple manner.
  • the carrier 10a with "release” property e.g. B. a PVA carrier
  • the paint is hardened, at least partially, so that on him the color decor 12 of the above type can be applied.
  • An adhesive layer is applied to the color decor 12 14a of the type mentioned above and the whole is placed on the substrate 18 to be decorated using activation of the pressure and / or elevated temperature Adhesive 14

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  • Application Of Or Painting With Fluid Materials (AREA)
EP19980119331 1998-10-13 1998-10-13 Procédé d'application d'un décor coloré sur un substrat Expired - Lifetime EP0993876B1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
DE59810918T DE59810918D1 (de) 1998-10-13 1998-10-13 Verfahren zum Aufbringen eines Farbdekors auf ein Substrat
EP19980119331 EP0993876B1 (fr) 1998-10-13 1998-10-13 Procédé d'application d'un décor coloré sur un substrat
ES98119331T ES2213248T3 (es) 1998-10-13 1998-10-13 Procedimiento para aplicar una decoracion de color sobre un sustrato.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP19980119331 EP0993876B1 (fr) 1998-10-13 1998-10-13 Procédé d'application d'un décor coloré sur un substrat

Publications (2)

Publication Number Publication Date
EP0993876A1 true EP0993876A1 (fr) 2000-04-19
EP0993876B1 EP0993876B1 (fr) 2004-03-03

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Family Applications (1)

Application Number Title Priority Date Filing Date
EP19980119331 Expired - Lifetime EP0993876B1 (fr) 1998-10-13 1998-10-13 Procédé d'application d'un décor coloré sur un substrat

Country Status (3)

Country Link
EP (1) EP0993876B1 (fr)
DE (1) DE59810918D1 (fr)
ES (1) ES2213248T3 (fr)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004074009A3 (fr) * 2003-02-14 2004-11-18 Procter & Gamble Article destine a etre applique a une surface et procede associe
EP1619022A1 (fr) * 2004-02-23 2006-01-25 DeMaxz Deutschland GmbH Procédé de fabrication d'un film qui peut être employé pour appliquer un vernis et une couleur sur un objet
EP1618967A1 (fr) * 2004-02-23 2006-01-25 DeMaxz Deutschland GmbH Appareil pour appliquer un vernis sur un film
EP1470933A3 (fr) * 2003-04-24 2006-04-05 Aluminium Féron GmbH & Co. KG Couche protectrice comprenant de vernis
US7132142B2 (en) 2003-02-14 2006-11-07 Avery Dennison Corporation Dry paint transfer laminate for use as wall covering
EP2048001A1 (fr) 2007-10-11 2009-04-15 DeMaxZ AG Application d'un décor sur un objet à l'aide d'une feuille de collage, sur laquelle le décor a été préalablement appliqué selon le procédé de décollement
EP1732769A4 (fr) * 2004-02-23 2009-07-01 Demaxz Ag Appareil et procede de fabrication d'un film pouvant etre utilise pour appliquer du vernis et de la couleur sur un objet
US7703392B2 (en) 2004-11-22 2010-04-27 Demaxz Ag Pressure based method and apparatus for applying a decoration onto an object
WO2011120940A1 (fr) * 2010-04-01 2011-10-06 Karl Wörwag Lack- Und Farbenfabrik Gmbh & Co. Kg Substrat pourvu d'une peinture multicolore et sa fabrication
US8747487B2 (en) 2005-06-07 2014-06-10 S.C. Johnson & Son, Inc. Composition for application to a surface
US8846154B2 (en) 2005-06-07 2014-09-30 S.C. Johnson & Son, Inc. Carpet décor and setting solution compositions

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7316832B2 (en) 2001-12-20 2008-01-08 The Procter & Gamble Company Articles and methods for applying color on surfaces
US7709070B2 (en) 2001-12-20 2010-05-04 The Procter & Gamble Company Articles and methods for applying color on surfaces
US20050196607A1 (en) 2003-06-09 2005-09-08 Shih Frank Y. Multi-layer dry paint decorative laminate having discoloration prevention barrier
US7727289B2 (en) 2005-06-07 2010-06-01 S.C. Johnson & Son, Inc. Composition for application to a surface
US8061269B2 (en) 2008-05-14 2011-11-22 S.C. Johnson & Son, Inc. Multilayer stencils for applying a design to a surface
US8557758B2 (en) 2005-06-07 2013-10-15 S.C. Johnson & Son, Inc. Devices for applying a colorant to a surface

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DE2301584A1 (de) * 1972-01-14 1973-07-19 Cartiere Ambrogio Binda Spa Verfahren zur verguetung von oberflaechen sowie abgabetraeger zur durchfuehrung des verfahrens
US4058644A (en) * 1974-12-04 1977-11-15 Devries Roy F Sublimation transfer and method
DE2627860A1 (de) * 1976-06-22 1977-12-29 Rabit Bautenschutzmittel Gmbh Verfahren zum beschichten von gekruemmten flaechen, insbesondere von rohren mit einem erhaertenden kunstharz
DE2710900A1 (de) * 1977-03-12 1978-09-14 Horst Schucht Verfahren zum aufbringen von farbmittelschichten auf einen traeger
JPS54108704A (en) * 1978-02-10 1979-08-25 Nissha Printing Chinaapainting material
EP0276965A1 (fr) * 1987-01-30 1988-08-03 Johnson Matthey Public Limited Company Décalcomanie pour application automatique
US4903254A (en) * 1989-08-31 1990-02-20 Haas David J Time indicator enhancement method
EP0451888A2 (fr) * 1990-03-12 1991-10-16 Note/Worthy Products, Inc. Dispositif amélioré d'indication d'écoulement du temps par changement de couleur
EP0573676A1 (fr) * 1992-05-19 1993-12-15 General Electric Plastics B.V. Utilisation d'une bande de support ayant des propriétés de décollage pour l'application de laque et de teinture sur un substrat

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* Cited by examiner, † Cited by third party
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DE2301584A1 (de) * 1972-01-14 1973-07-19 Cartiere Ambrogio Binda Spa Verfahren zur verguetung von oberflaechen sowie abgabetraeger zur durchfuehrung des verfahrens
US4058644A (en) * 1974-12-04 1977-11-15 Devries Roy F Sublimation transfer and method
DE2627860A1 (de) * 1976-06-22 1977-12-29 Rabit Bautenschutzmittel Gmbh Verfahren zum beschichten von gekruemmten flaechen, insbesondere von rohren mit einem erhaertenden kunstharz
DE2710900A1 (de) * 1977-03-12 1978-09-14 Horst Schucht Verfahren zum aufbringen von farbmittelschichten auf einen traeger
JPS54108704A (en) * 1978-02-10 1979-08-25 Nissha Printing Chinaapainting material
EP0276965A1 (fr) * 1987-01-30 1988-08-03 Johnson Matthey Public Limited Company Décalcomanie pour application automatique
US4903254A (en) * 1989-08-31 1990-02-20 Haas David J Time indicator enhancement method
EP0451888A2 (fr) * 1990-03-12 1991-10-16 Note/Worthy Products, Inc. Dispositif amélioré d'indication d'écoulement du temps par changement de couleur
EP0573676A1 (fr) * 1992-05-19 1993-12-15 General Electric Plastics B.V. Utilisation d'une bande de support ayant des propriétés de décollage pour l'application de laque et de teinture sur un substrat

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DATABASE WPI Section Ch Week 7940, Derwent World Patents Index; Class A97, AN 79-72704B, XP002098500 *

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7132142B2 (en) 2003-02-14 2006-11-07 Avery Dennison Corporation Dry paint transfer laminate for use as wall covering
US7905981B2 (en) 2003-02-14 2011-03-15 The Procter & Gamble Company Method of making a dry paint transfer laminate
US7807246B2 (en) 2003-02-14 2010-10-05 The Procter & Gamble Company Dry paint transfer laminate
US7722938B2 (en) 2003-02-14 2010-05-25 The Procter & Gamble Company Dry paint transfer laminate
WO2004074009A3 (fr) * 2003-02-14 2004-11-18 Procter & Gamble Article destine a etre applique a une surface et procede associe
EP1470933A3 (fr) * 2003-04-24 2006-04-05 Aluminium Féron GmbH & Co. KG Couche protectrice comprenant de vernis
EP1732769A4 (fr) * 2004-02-23 2009-07-01 Demaxz Ag Appareil et procede de fabrication d'un film pouvant etre utilise pour appliquer du vernis et de la couleur sur un objet
EP1729977A4 (fr) * 2004-02-23 2009-07-01 Demaxz Ag Appareil et procede de fabrication d'un film a utiliser pour l'application de vernis et de couleur sur objet
EP1618967A1 (fr) * 2004-02-23 2006-01-25 DeMaxz Deutschland GmbH Appareil pour appliquer un vernis sur un film
EP1618966A1 (fr) * 2004-02-23 2006-01-25 DeMaxz Deutschland GmbH Appareil pour fabriquer un film qui peut être employé pour appliquer un vernis et une couleur sur un objet
EP1619022A1 (fr) * 2004-02-23 2006-01-25 DeMaxz Deutschland GmbH Procédé de fabrication d'un film qui peut être employé pour appliquer un vernis et une couleur sur un objet
US7703392B2 (en) 2004-11-22 2010-04-27 Demaxz Ag Pressure based method and apparatus for applying a decoration onto an object
US8747487B2 (en) 2005-06-07 2014-06-10 S.C. Johnson & Son, Inc. Composition for application to a surface
US8846154B2 (en) 2005-06-07 2014-09-30 S.C. Johnson & Son, Inc. Carpet décor and setting solution compositions
EP2048001A1 (fr) 2007-10-11 2009-04-15 DeMaxZ AG Application d'un décor sur un objet à l'aide d'une feuille de collage, sur laquelle le décor a été préalablement appliqué selon le procédé de décollement
WO2011120940A1 (fr) * 2010-04-01 2011-10-06 Karl Wörwag Lack- Und Farbenfabrik Gmbh & Co. Kg Substrat pourvu d'une peinture multicolore et sa fabrication
CN103025440A (zh) * 2010-04-01 2013-04-03 卡尔·沃瓦格漆料和颜料制造有限责任两合公司 具有多色漆的基材及其制造
CN103025440B (zh) * 2010-04-01 2015-09-30 卡尔·沃瓦格漆料和颜料制造有限责任两合公司 具有多色漆的基材及其制造

Also Published As

Publication number Publication date
EP0993876B1 (fr) 2004-03-03
ES2213248T3 (es) 2004-08-16
DE59810918D1 (de) 2004-04-08

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