EP1050195A1 - Dispositif photoemetteur - Google Patents

Dispositif photoemetteur

Info

Publication number
EP1050195A1
EP1050195A1 EP99901768A EP99901768A EP1050195A1 EP 1050195 A1 EP1050195 A1 EP 1050195A1 EP 99901768 A EP99901768 A EP 99901768A EP 99901768 A EP99901768 A EP 99901768A EP 1050195 A1 EP1050195 A1 EP 1050195A1
Authority
EP
European Patent Office
Prior art keywords
layer
bonded carbon
tetrahedrally bonded
electrode
electrodes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP99901768A
Other languages
German (de)
English (en)
Inventor
Alan Moseley
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Central Research Laboratories Ltd
Original Assignee
Central Research Laboratories Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Central Research Laboratories Ltd filed Critical Central Research Laboratories Ltd
Publication of EP1050195A1 publication Critical patent/EP1050195A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B33/00—Electroluminescent light sources
    • H05B33/12—Light sources with substantially two-dimensional [2D] radiating surfaces
    • H05B33/26—Light sources with substantially two-dimensional [2D] radiating surfaces characterised by the composition or arrangement of the conductive material used as an electrode
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00—Organic light-emitting devices
    • H10K50/10—OLEDs or polymer light-emitting diodes [PLED]
    • H10K50/17—Carrier injection layers
    • H10K50/171—Electron injection layers

Definitions

  • This invention relates to a device for emitting light, comprising a body consisting of a light-emissive polymeric or organic material, and a plurality of electrodes electrically coupled to the body.
  • a layer of sputtered carbon is provided between the body and the anode (hole injection electrode) to improve adhesion between the body and the anode.
  • a device for emitting light as specified in claims 1 - 7.
  • a display unit as specified in claims 8 and 9.
  • Light emitting materials which are polymeric or organic are currently being developed for use in displays. Two types of display are presently under development, one type is based on light emitting polymers, and the other is based on organic electroluminescent materials which need not be polymers. The structures used for these two types of known display device are very similar and are shown in Figure 1.
  • the light emissive body (3) comprises a layer of either a polymer which emits light in response to an electrical impulse, or an organic electroluminescent material. This layer is sandwiched between a pair of electrodes, namely an anode (4) and a cathode (2), which are carried by a substrate (1). Hole carriers are injected from the anode into the body, whilst electrons are injected from the cathode into the body.
  • the anode in such prior art devices is generally made from a layer of a high work function material such as a metal or indium tin oxide (which is light transmissive).
  • the anode may also be supplied with other layers to aid hole transport such as CN X , or a conductive polymer such as polyaniline.
  • the cathode is usually made from a material having a low electron affinity such as a low work function metal or alloy such as Mg:Ag, Li:Al, CaOx, or LiF:Al. 2
  • the use of lithium or its alloys as a cathode can provide a number of disadvantages.
  • the cathode surface is susceptible to chemical reactions with water and/or oxygen which impairs its electron injection properties. Lithium also reacts with some organic layers. These problems are mitigated in the present invention by the provision of a tetrahedrally bonded carbon layer between the cathode electrode and the polymeric or organic body.
  • This feature can provide the advantage that reactive metals such as lithium or its alloys (which are commonly used for this electrode because of the low electron affinity required) may be substituted by less reactive conductors, thereby improving reliability of operation.
  • Figure 2 shows a device according to the present invention for emitting light, comprising a body (3) consisting of a light-emissive material which is polymeric and/or organic, a plurality of electrodes (2, 4) which are electrically coupled to the body, and a layer of tetrahedrally bonded carbon (6), which layer is located between the body and at least one electrode (2) and which is in electrical contact with both the body and the at least one electrode.
  • tetrahedrally bonded material has been disclosed in EP-A-0 175 980.
  • the layer of tetrahedrally bonded carbon is adapted to have an electron affinity sufficiently low such as to promote the emission of electrons into the body from the layer adjacent the said at least one electrode in use.
  • the work function of the tetrahedrally bonded carbon layer is preferably less than that of magnesium, i.e. less than about 3.5 eV.
  • Such layers can be produced by laser ablation (as described by N Kumar et al., in Society for Information Display SID 94 Digest p43 et seq. 1994 (ISSN 1083-1312/97/1701) or using a filtered cathodic vacuum arc (FCVA) as described by W Milne in J. Non-Cryst. Solids, vol 198 - 200, p605 (1996).
  • the work function of the material may be reduced by the addition of n-type dopants such as nitrogen or phosphorus.
  • a Corning 7059 glass substrate (1) has a patterned layer of ITO (4) deposited thereon by vapour deposition and subsequent photolithography and wet etching.
  • the organic or polymer layer (3) is then spin coated to a thickness of 100 nm.
  • a layer of undoped tetrahedrally bonded non-crystalline carbon 100 nm to 2 microns thick is then deposited thereon using a filtered cathodic vacuum arc (FCVA).
  • FCVA filtered cathodic vacuum arc
  • An aluminium cathode is then evaporated onto the carbon layer. This aluminium layer is patterned by photolithography and wet etching.
  • the whole device is 3 then encapsulated using an encapsulant (7) in the usual way to passivate the device.
  • the light emissive material in the embodiment shown in Figure 2 may comprise, for example, an organic electroluminescent material such as tris (8- quinolinolato) aluminium (known as Alq), or a light emitting polymer such as for example polyphenylenevin lene (known as PPV).
  • Alq organic electroluminescent material
  • PPV polyphenylenevin lene
  • the peak emission wavelengths of both materials can be controlled by adding suitable dopants or modifier compounds, or through modification of their structure.
  • the organic or polymeric layer may be produced by spin coating, or spreading on the surface of a substrate using a doctor blade.
  • Devices having a high quantum efficiency in practice usually have a body comprising a plurality of organic and /or polymeric layers, selected layers being doped to promote carrier transport or luminescence (as described for example in the paper by C W Tang, Society for Information Display - Seminar Lecture Notes 1997, volume 2, pF4/3 et seq.(ISSN 0887-915X).
  • the body (3) may therefore comprise a plurality of such layers.
  • the carbon layer (6) also promotes adhesion between the electrodes (2, 4) and the body (3).
  • the carbon layer is a poor electrical conductor, and need not be removed between adjacent electrodes.

Landscapes

  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Electroluminescent Light Sources (AREA)

Abstract

Ce dispositif photoémetteur comprend un corps (3) constitué par un polymère photoémetteur ou par un matériau organique électroluminescent, ainsi que plusieurs électrodes (2, 4) couplées électriquement audit corps. Une couche de carbone non cristallin à liaison tétraédrique (6) est placée entre ledit corps et au moins l'une desdites électrodes (2). Cette couche de carbone à liaison tétraédrique possède une affinité des électrons suffisamment basse pour favoriser l'émission des électrons dans le corps, pendant l'utilisation. La couche de carbone favorise également l'adhérence entre les électrodes et le corps. Cette couche de carbone est un faible conducteur électrique et il n'est pas nécessaire de la retirer entre les électrodes adjacentes.
EP99901768A 1998-01-23 1999-01-21 Dispositif photoemetteur Withdrawn EP1050195A1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GBGB9801316.2A GB9801316D0 (en) 1998-01-23 1998-01-23 A device for emitting light
GB9801316 1998-01-23
PCT/GB1999/000206 WO1999038362A1 (fr) 1998-01-23 1999-01-21 Dispositif photoemetteur

Publications (1)

Publication Number Publication Date
EP1050195A1 true EP1050195A1 (fr) 2000-11-08

Family

ID=10825671

Family Applications (1)

Application Number Title Priority Date Filing Date
EP99901768A Withdrawn EP1050195A1 (fr) 1998-01-23 1999-01-21 Dispositif photoemetteur

Country Status (6)

Country Link
EP (1) EP1050195A1 (fr)
JP (1) JP2002502090A (fr)
KR (1) KR20010034324A (fr)
GB (1) GB9801316D0 (fr)
TW (1) TW431121B (fr)
WO (1) WO1999038362A1 (fr)

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0393191A (ja) * 1989-09-04 1991-04-18 Nippon Sheet Glass Co Ltd エレクトロルミネッセンス素子
JP3428152B2 (ja) * 1994-07-13 2003-07-22 松下電器産業株式会社 有機ｅｌ素子の製造方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO9938362A1 *

Also Published As

Publication number Publication date
JP2002502090A (ja) 2002-01-22
KR20010034324A (ko) 2001-04-25
GB9801316D0 (en) 1998-03-18
WO1999038362A1 (fr) 1999-07-29
TW431121B (en) 2001-04-21

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