Classifications

• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G18/00—Polymeric products of isocyanates or isothiocyanates
  • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
  • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
  • C08G18/30—Low-molecular-weight compounds
  • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
  • C08G18/3819—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen
  • C08G18/3821—Carboxylic acids; Esters thereof with monohydroxyl compounds
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
  • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
  • C09D175/04—Polyurethanes
  • C09D175/06—Polyurethanes from polyesters

Definitions

• the present invention relates generally to coating compositions, and more specifically to filled water-based polymeric coating compositions for substrates, such as mineral fiber boards.
• Aqueous coating compositions for substrates are becoming increasingly important for both economic and ecological reasons. It is desirable to reduce the use of volatile organic solvents, which can be harmful, resulting in an increased desire for waterborne (i.e., water-based) mixtures. There are, however, some disadvantages associated with the use of waterborne mixtures.
• aqueous solutions include the difficulty, in some cases, of effecting sufficient water dispersibility and solubility of the binder components of the coating composition in water. Where good dispersibility and solubility are achieved, one often encounters lowered resistance of the cured coatings to water. This is less of a problem with coating compositions that are soluble only in organic solvents.
• processing problems that result from the high viscosity of aqueous coating compositions. These problems have, in some situations, previously been overcome through the use of organic auxiliary solvents in conjunction with water. The use of these auxiliary solvents, however, dampens the economic and ecological advantages of using water in the first place.
• the present invention provides an aqueous system for coating a substrate.
• the system comprises two components.
• the first component contains a first polymer which has hydroxyl functional groups or amine functional groups and optionally a catalyst, preferably an organotin catalyst.
• the second component comprises a second polymer which is a polyisocyanate containing isocyanate functional groups.
• a filler i.e., an extender pigment
• at least one filler is incorporated in both the first component and the second component.
• the filler may only be present in one component. In the latter case the filler is present in an amount above about 50% by dry volume.
• the filler is selected from calcium carbonate, titanium dioxide, sand, clay, mica, dolomite, silica, talc, perlite, gypsum, wallastonite, aluminum trihydrate, zinc oxide, barium sulfate, zinc sulfate, and combinations thereof.
• the polymer of the first component is preferably selected from a polyester polyol, an acrylic polyol, a urethane polyol, a polyether polyol, a polyamine, an aldimine, a short oil alkyd, a silicone polyol, a cellulose ester, a vinyl polyol, and combinations thereof.
• a preferred polyamine is a polyaspartic ester.
• the present invention also provides methods of coating a substrate.
• the method comprises the steps of applying to the substrate a first component which contains the first polymer containing hydroxyl functional groups or amine functional groups and optionally a catalyst to form a partially coated substrate.
• a second component which contains a second polymer which is a polyisocyanate containing isocyanate functional groups
• the second component is applied to the substrate first.
• the two components can first be mixed and the mixture applied to the substrate.
• at least one filler is preferably incorporated in both the first component and the second component.
• the filler may only be present in one component. In the latter case, the filler is present at an amount above about 50% by dry volume.
• a third aspect to the present invention is the coating formed by applying to the substrate a coaling system of the present invention using the methods of the present invention.
• the present invention is an aqueous system for coating a substrate.
• the system comprises two components.
• the first component contains a first polymer which has hydroxyl functional groups or amine functional groups and optionally a catalyst.
• the second component comprises a second polymer which is a polyisocyanate containing isocyanate functional groups.
• at least one filler is incorporated in both the first component and the second component.
• the filler may only be present in one component. In the latter case, the filler is present at an amount above about 50% by dry volume of that component.
• the two polymer components serve as binders in known ways.
• the first polymer when the first polymer includes hydroxyl groups, the hydroxyl groups react with the isocyanate groups to form urethane groups in a crosslinked polymer.
• the first polymer when the first polymer includes amine groups, the amine groups react with the isocyanate groups to form urea groups in a crosslinked polymer.
• the first polymer can be any known compatible polymer, capable of being dispersed or dissolved in water, having hydroxyl groups or amine groups used to react with polyisocyanate to form a crosslinked polymer.
• the first polymer may be selected from, but not limited to, a polyester polyol, an acrylic polyol, a urethane polyol, a polyamine, an aldimine, a short oil alkyd, a silicone polyol, a cellulose ester, or a vinyl polyol.
• a preferred formula includes the use of a polyester polyol in the first component and a polyisocyanate in the second component.
• polymers contain minimum concentration of hydroxyl or amine functionality for sufficient cross-linking to occur.
• a preferred equivalent ratio of isocyanate functional groups to hydroxyl or amine functional groups is in the range of about 0.1:1 to about 10:1.
• a more preferred equivalent ratio of isocyanate functional groups to hydroxyl or amine functional groups is in the range of about 0.5:1 to about 5:1.
• the catalyst can preferably be an organo-metallic catalyst used to speed the overall curing rate. Catalysts are, of course, used in an effective amount to speed the overall curing rate.
• One suitable catalyst can be any long chain tertiary amine. Preferred catalysts include dibutyl-tin-laurate and zinc octoate.
• the filler may be a mixture or a single ingredient in both components; the fillers may also be the same or different in each component.
• a filler can be selected from the group consisting of calcium carbonate, titanium dioxide, sand, clay, mica, dolomite, silica, talc, perlite, gypsum, limestone, wallastonite, calcite, aluminum trihydrate, zinc oxide, barium sulfate, zinc sulfate and mixtures thereof.
• calcium carbonate is used, and it may either be prepared synthetically or derived from natural sources, such as from limestone or calcite. Mixtures of filler in each component will also work.
• the fillers should be included in both components in an amount of at least about 40% by dry volume of the total system after the two components are mixed or applied.
• each component contains at least about 40% filler by dry volume.
• the total system or both components individually) contain the filler in an amount of at least about 75% (and most preferably at least about 90%) by dry volume.
• the filler should be present in an amount of at least about 50% by dry volume of that component, with slightly higher preferable concentrations of at least about 85% and, most preferably, at least about 95% by dry volume. The concentrations are slightly higher for this embodiment because the filler is added to only one component.
• the coating composition of the present invention provides a highly accelerated cure time as compared to aqueous materials known in the prior art.
• the term "cure time” shall mean the time from applying either the mixture of the two components or the second of the two components until the coating is cured at ambient conditions. Curing is evidenced by a surface which is dry to the touch and is tack free. Cure times as low as about 5 minutes can be realized according to the present invention. Preferably, cure times as low as (or less than) about 2 minutes are achievable. Most preferably, cure times as low as (and less than) about 10 seconds are achieved. Such a short time provides advantages in manufacturing and production.
• the inventors believe that the improved cure times are a result of the adsorption of the active polymers of each component onto the surface of the filler (referred to as an "extender pigment" in the coating industry). It is believed that the accelerated cure times are thus created by an increased polymer surface area within the system.
• the increased polymer surface area allows easier and more extensive contact between the two polymers and subsequently, the rate of crosslinking, and ultimately curing, is enhanced. It has been found that by incorporating a filler in each component individually prior to combining the two components (either just prior to application or on a substrate by sequential application), the coating cures much faster. Alternatively, by elevating the content of filler in one component, the curing rate is increased in this way.
• Another way of determining the amount of filler which should be added is by adding a sufficient amount of filler to achieve a cure time at ambient conditions of less than about five minutes (preferably, ten seconds or less) after application of the mixture or second component.
• cure time can be decreased simply by increasing the amount of filler used (and/or decreasing the amount of water).
• a preferred polyester polyol is Bayhydrol XP-7093, provided by Bayer Corporation.
• BAYHYDROL XP-7093 is a registered trademark of Bayer Corporation for a waterborne polyester polyol at 30% solids.
• a preferred polyisocyanate is Bayhydur XP-7063, also provided by Bayer Corporation.
• BAYHYDUR XP 7063 is a registered trademark of Bayer Corporation for a polysocyanate.
• a preferred organotin catalyst is provided by Elf Atochem and is known as Fascat 4224.
• Fascat 4224 is a registered trademark of Elf Atochem for dibutyl-tin-dilaurate.
• the calcium carbonate is provided, preferably, by a material known as Omya Hydrocarb 60.
• OMYA HYDROCARB is a registered trademark of Pluess-Staufer for calcium carbonate.
• the system may also contain the known additives from coatings technology, such as softeners, high boiling liquids, UV stabilizers, anti-oxidants, microbiocides, algicides, dehydrators, thixotropic agents, wetting agents, flow enhancers, surfactants, matting agents, anti-slip agents, and aerators.
• the additives are chosen based on the requirements of the particular application and their compatibility with the necessary components as defined above, in a known manner.
• the first component is prepared by simply mixing the filler, the first polymer, the catalyst (if present), and water.
• the second component is also prepared by simply mixing the filler, the second polymer, and water.
• the water comes from a calcium carbonate slurry.
• the invention also includes a method of coating a substrate.
• the method comprises the steps of applying to the substrate a first component which contains a first polymer containing hydroxyl functional groups or amine functional groups and, optionally, a catalyst to form a partially coated substrate (i.e., coated with the first component).
• a second component comprising a second polymer, the second polymer being a polyisocyanate containing isocyanate functional groups, is applied to the partially coated substrate.
• the second coating should be applied promptly (preferably immediately) after application of the first coating and before any significant drying of the first coating occurs.
• Each of these two components is an aqueous mixture and their ease of application provides an effective, easy, and fast-curing coating.
• a preferred application is to ceiling tiles, such as those made from mineral fiber board.
• An alternative method is first separately preparing the first and second components of the present invention, then mixing the two components together, and then applying the mixture to the substrate.
• the mixture tends to gel quickly after mixing the two components, due to the rapid rate of crosslinking.
• Each of the two components, before they are mixed or applied, is in an aqueous bath.
• the water is typically present with the filler which is usually provided to the composition as a mixture. Additional water is provided through the polyol which is also typically an aqueous mixture.
• the preferred method of application of the two components is to spray one component onto the substrate fight before spaying the other.
• the order in which each component is sprayed is not critical.
• the two components are mixed fight on the substrate. Any overspray can be captured and recycled.
• This application does not require the use of a static mixer or the use of dual component spray guns.
• the first component could be applied with a roll coater or a curtain coater, followed by spraying the second component.
• substrates which can be coated by the present invention include wood, wood composite, gypsum board, scrim, cloth, glass and metal.
• the mineral fiber board of this example was coated by spraying the first component onto the board and then spraying the second component onto the sprayed board.
• the coating dried in about 10 seconds.
• All weight and volume percentages in the tables are dry weight and volume percentages.
• the first and second components were combined in amounts to provide a 1:1 stoichiometric ratio of hydroxyl to isocyanate functional groups.
• the final solids were 67% with the balance being water.
• the water in the coating comes from the Calcium Carbonate aqueous mixture which is 73.5% solids and from the Polyester Polyol aqueous mixture which is 30% solids.
• Fascat 4224 is an Organotin catalyst which helps provide a faster cure rate. The level of the catalyst can be used to control or modify the cure rate.
• This example is a higher solids formula of 71 % solids.

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• Chemical & Material Sciences (AREA)
• Organic Chemistry (AREA)
• Life Sciences & Earth Sciences (AREA)
• Engineering & Computer Science (AREA)
• Materials Engineering (AREA)
• Wood Science & Technology (AREA)
• Health & Medical Sciences (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Medicinal Chemistry (AREA)
• Polymers & Plastics (AREA)
• Application Of Or Painting With Fluid Materials (AREA)
• Paints Or Removers (AREA)

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• 1999
  • 1999-05-18 US US09/313,627 patent/US6316535B1/en not_active Expired - Fee Related
  • 1999-12-03 CA CA002291541A patent/CA2291541A1/fr not_active Abandoned
• 2000
  • 2000-05-04 AT AT00303731T patent/ATE309307T1/de not_active IP Right Cessation
  • 2000-05-04 DE DE60023787T patent/DE60023787T2/de not_active Expired - Lifetime
  • 2000-05-04 EP EP00303731A patent/EP1054046B1/fr not_active Expired - Lifetime

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