EP1056801A1 - Procede et dispositif pour le traitement de pneumatiques de vehicules automobiles - Google Patents

Procede et dispositif pour le traitement de pneumatiques de vehicules automobiles

Info

Publication number
EP1056801A1
EP1056801A1 EP98965112A EP98965112A EP1056801A1 EP 1056801 A1 EP1056801 A1 EP 1056801A1 EP 98965112 A EP98965112 A EP 98965112A EP 98965112 A EP98965112 A EP 98965112A EP 1056801 A1 EP1056801 A1 EP 1056801A1
Authority
EP
European Patent Office
Prior art keywords
product pieces
heated
interior
product
composite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP98965112A
Other languages
German (de)
English (en)
Other versions
EP1056801B1 (fr
Inventor
Reiner Numrich
Gerhard Tewes
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Gebrueder Loedige Maschinenbau GmbH
Original Assignee
Gebrueder Loedige Maschinenbau GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gebrueder Loedige Maschinenbau GmbH filed Critical Gebrueder Loedige Maschinenbau GmbH
Publication of EP1056801A1 publication Critical patent/EP1056801A1/fr
Application granted granted Critical
Publication of EP1056801B1 publication Critical patent/EP1056801B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/07Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of solid raw materials consisting of synthetic polymeric materials, e.g. tyres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00Recovery of plastics or other constituents of waste material containing plastics
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/02Separating plastics from other materials
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/44Carbon
    • C09C1/48Carbon black
    • C09C1/482Preparation from used rubber products, e.g. tyres
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B7/00Coke ovens with mechanical conveying means for the raw material inside the oven
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/10Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal from rubber or rubber waste
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0006Controlling or regulating processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/04Disintegrating plastics, e.g. by milling
    • B29B2017/0424Specific disintegrating techniques; devices therefor
    • B29B2017/0496Pyrolysing the materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2021/00Use of unspecified rubbers as moulding material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/06Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
    • B29K2105/065Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts containing impurities
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2705/00Use of metals, their alloys or their compounds, for preformed parts, e.g. for inserts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2705/00Use of metals, their alloys or their compounds, for preformed parts, e.g. for inserts
    • B29K2705/08Transition metals
    • B29K2705/12Iron
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2030/00Pneumatic or solid tyres or parts thereof
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2900/00Special features of, or arrangements for incinerators
    • F23G2900/50203Waste pyrolysis, gasification or cracking in a mechanically fluidised bed, e.g. obtained by a centrifugal force
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/141Feedstock
    • Y02P20/143Feedstock the feedstock being recycled material, e.g. plastics
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/62Plastics recycling; Rubber recycling

Definitions

  • the invention relates to a method and a device for processing motor vehicle tires, in particular used tires and damaged tires for trucks, passenger cars, motorcycles, airplanes, bicycles, etc.
  • the old tires or old tire parts are processed by pyrolysis and / or depolymerization.
  • the known preparation processes generally require a very high amount of energy, the throughput quantity per unit of time is limited and the wear of the processing tools is high in mechanical processes, because in tire manufacture a wide variety of components are processed into a composite material that is intended to withstand extremely high loads.
  • the object of the invention is therefore to develop a method and a device which make it possible to largely avoid individual component separation and environmental pollution.
  • product pieces made from used tires consist of a material composite that has at least one material component that decomposes when heated by mechanically moving and / or fluidizing the product pieces in a discontinuously operated device and via heated contact surfaces of the device are heated to a material decomposition temperature at which the material composite is broken down into one or more solid material components and fluids which can be removed from the device separately and the product pieces are introduced into a material template in the interior of the device.
  • Half of the starting material of the supplied product pieces can be converted into gases or oil vapors.
  • the other half of the treated raw material can be separated into inferior carbon black (carbon, sulfur) and steel wires.
  • the resulting gases can be used to generate energy.
  • the condensed, relatively homogeneous oil can still be used as a raw material.
  • the soot which has a high carbon content, can be used for energy generation due to its calorific value.
  • the steel recovered from the vehicle tires can be reintegrated into a product cycle as a raw material.
  • the material template can consist of material components that are formed during the decomposition of the composite material of the duct pieces result.
  • the supplied starting material is mixed, for example, with soot that is still warm.
  • the device is not cooled down too much.
  • the raw material is preheated by contacting the soot. Caking or clumping in the area of the interior walls of the device is prevented.
  • the efficiency of the process can be increased in that the thermal processing of the product pieces takes place under a vacuum in the device.
  • the purity of the end products produced can be improved if the thermal processing of the product pieces takes place in the absence of oxygen.
  • the object is also achieved by using a discontinuously operated device which has internals and surfaces provided in a device interior for mechanical fluidization and / or movement and thermal treatment of product parts which are produced from used tires from, for example, motor vehicles, by shredding the used tires, wherein the product pieces consist of a material composite that has at least one material component that decomposes when heated, with heatable product contact surfaces of the device for heating the product pieces to a material decomposition temperature, with a connection or connections of the device for maintaining a vacuum in the interior of the device, with a connection or connections of the device for introducing the product pieces into the interior of the device, with a connection or connections of the device for introducing a gas into the product interior and with a connection or connections of the device for discharging a fluid or fluids and a solid component or of Solid components that result from the thermal treatment of the product pieces.
  • the mixing and comminution of the product pieces can be achieved by installing the device, which are designed to be movable in a fixed housing of the device.
  • the internals of mixing elements can be arranged on a rotatable shaft which is mounted in end faces of the device, the shaft passing through the device and the mixing elements sweeping over the heated surfaces of the device.
  • the aforementioned method and the associated device can also be used for processing thermally decomposable rubber and / or plastic waste from the manufacture of motor vehicles.
  • Mixing elements 6 are provided within the device 1 and are fastened to a shaft 7.
  • the shaft 7 is rotatably supported on end faces 8 and 9 of the device 1. Therefore, the mixing elements 6 using mixing tools
  • (Mixing blades) 10 are provided, rotate in the direction of rotation 11.
  • a mechanical fluidized bed is generated during the treatment process, so that as many product pieces 2 as possible come into contact with the heated inner wall 5 of the device.
  • the mechanical fluidized bed produces soot in the form of fine microgranules made of carbon that does not dissolve in the condensed oil phase and can easily be removed, for example, by centrifugation.
  • Special mixing tools 10 prevent tangling of the exposed steel threads from the product pieces 2.
  • the mixing tools 10 have round surfaces, so that the steel threads slip off and cannot adhere to the surfaces of the mixing tools 10.
  • the material components produced during the thermal processing of the product pieces 2 can be removed in a weight-dosed manner from the device 1 via a raw material outlet 14 in the outlet direction 15.
  • Second additional units can be provided on the device 1, by means of which material components (weighing cells), which are produced during the thermal treatment of the product pieces 2, can be removed in a weight-dosed manner from the interior of the device.
  • the device 1 After the thermal treatment of a first batch of product pieces 2 has ended, the device 1 is only partially emptied. New product pieces 2 are mixed when the soot is still warm. The device 2 does not cool down too much. The new product pieces 2 are preheated by contact with the soot. The product pieces 2 are powdered with soot and cannot adhere or stick to the inside of the device 5 and / or the mixing tools 10. Sticking is avoided. A good separation into the individual raw materials is made possible. Alternatively, in a first mode of operation, carbon in dust form can be introduced into the interior of the device so that the product pieces 2 are mixed with the carbon when heated.
  • Product pieces 2 made from used tires are thermally processed in a discontinuously operated device 1.
  • the product pieces 2 consist of a material composite that has at least one material component that decomposes when heated by mechanically moving and / or fluidizing the product pieces 2 in the device 1 and heating them to a material decomposition temperature via heated contact surfaces of the device 2. At this temperature, the composite material decomposes into one or more solid material components and fluids, which can be removed separately from the device 1. Individual method separation is made possible by the method and the use of the device. Environmental pollution is largely avoided.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

Selon l'invention, des morceaux (2) produits à partir de vieux pneumatiques sont traités thermiquement dans un dispositif (1) à fonctionnement discontinu. Les morceaux (2) sont constitués d'un matériau composite comportant au moins un composant qui se décompose lors du chauffage, les morceaux (2) de produit étant déplacés mécaniquement et/ou fluidisés dans le dispositif (1) et chauffés de façon à atteindre la température de décomposition dudit composant, par l'intermédiaire de surfaces de contact chauffées du dispositif (2). A cette température, le matériau composite se décompose en un ou plusieurs composants solides et fluides qui sont retirés du dispositif (1) séparément. Le procédé présenté et l'utilisation de ce dispositif permettent une séparation des composants individuels. Les incidences nuisibles sur l'environnement sont évitées au maximum.
EP98965112A 1997-12-29 1998-12-12 Procede pour le traitement de pneumatiques de vehicules automobiles Expired - Lifetime EP1056801B1 (fr)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
DE19757794 1997-12-29
DE19757794 1997-12-29
DE19800567 1998-01-09
DE1998100567 DE19800567A1 (de) 1997-12-29 1998-01-09 Verfahren und Vorrichtung zur Aufbereitung von Kraftfahrzeugreifen
PCT/DE1998/003653 WO1999033907A1 (fr) 1997-12-29 1998-12-12 Procede et dispositif pour le traitement de pneumatiques de vehicules automobiles

Publications (2)

Publication Number Publication Date
EP1056801A1 true EP1056801A1 (fr) 2000-12-06
EP1056801B1 EP1056801B1 (fr) 2003-03-19

Family

ID=26042825

Family Applications (1)

Application Number Title Priority Date Filing Date
EP98965112A Expired - Lifetime EP1056801B1 (fr) 1997-12-29 1998-12-12 Procede pour le traitement de pneumatiques de vehicules automobiles

Country Status (6)

Country Link
US (1) US6364225B1 (fr)
EP (1) EP1056801B1 (fr)
AU (1) AU2045999A (fr)
DE (2) DE19800567A1 (fr)
ES (1) ES2192348T3 (fr)
WO (1) WO1999033907A1 (fr)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1314770B1 (fr) * 2001-11-27 2004-01-02 Jean Affolter Procédé en discontinu pour la pyrolyse de matière organique coupée et réacteur à lit fluidisé pour ce procédé
CA2552246A1 (fr) * 2004-01-14 2005-07-28 Invacare Corporation Fauteuil roulant reglable
LT5422B (lt) 2005-09-08 2007-05-25 Uždaroji akcinė bendrovė OSTRIO Transporto priemonių susidėvėjusių padangų perdirbimo būdas ir įrenginys
DE102008040850B3 (de) * 2008-07-30 2010-04-08 Gebrüder Lödige Maschinenbaugesellschaft mbH Schwimmend gelagerter Mischer nebst Verfahren
CN110000197A (zh) * 2019-04-29 2019-07-12 秦华 新型酸解还原剂的制备方法及其在硫酸法钛白粉生产中的应用
US11999920B2 (en) 2020-09-14 2024-06-04 Ecolab Usa Inc. Cold flow additives for plastic-derived synthetic feedstock
CA3209451A1 (fr) 2021-03-10 2022-09-15 Theodore C. Arnst Additifs stabilisants pour charge d'alimentation synthetique derivee de plastique
EP4416248A1 (fr) 2021-10-14 2024-08-21 Ecolab Usa Inc. Agents antisalissure pour matières premières synthétiques dérivées du plastique

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DE2724813C3 (de) 1977-06-02 1981-08-06 Walter 7470 Albstadt Letsch Anlage zum Aufbereiten von Altreifen und ähnlichen Gummiverbundstoffen
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JPS60130678A (ja) * 1983-12-15 1985-07-12 Mamoru Sano 熱分解乾溜機
GB8726397D0 (en) * 1987-11-11 1987-12-16 Holland K M Processing of organic material
US5157176A (en) * 1990-07-26 1992-10-20 Munger Joseph H Recycling process, apparatus and product produced by such process for producing a rubber extender/plasticizing agent from used automobile rubber tires
DE4034985A1 (de) * 1990-08-28 1992-05-14 Artur Richard Greul Verfahren zur gesteuerten tieftemperaturentgasung von organischen stoffen mit der elektrisch beheizten bandschnecke
US5411213A (en) * 1990-09-12 1995-05-02 Just; Arden L. Method for treatment of solid materials
US5264640A (en) * 1992-04-06 1993-11-23 S-P Reclamation, Inc. Depolymerization method for resource recovery from polymeric wastes
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US5504267A (en) * 1992-04-06 1996-04-02 S-P Reclamation, Inc. Resource recovery by catalytic conversion of polymers
DE4234385A1 (de) * 1992-10-06 1994-04-07 Formex Trading Gmbh Verfahren zur Pyrolyse von organischen Stoffen
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DE4416155A1 (de) * 1994-05-09 1995-11-16 Peter Hollaus Verfahren zur Verarbeitung von Altreifen von Kraftfahrzeugen zum Zweck der Weiterverwendung des Reifenmaterials insbesondere des Materials der Gummiauflage sowie Vorrichtung zur Durchführung des Verfahrens
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Also Published As

Publication number Publication date
WO1999033907A1 (fr) 1999-07-08
ES2192348T3 (es) 2003-10-01
US6364225B1 (en) 2002-04-02
DE19800567A1 (de) 1999-07-08
AU2045999A (en) 1999-07-19
DE59807590D1 (de) 2003-04-24
EP1056801B1 (fr) 2003-03-19

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