EP1077250A1 - Wässrige Formulierungen - Google Patents

Wässrige Formulierungen Download PDF

Info

Publication number: EP1077250A1
Authority: EP; European Patent Office
Prior art keywords: composition; surfactant; weight; sodium; agent
Prior art date: 1999-08-16
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

EP00305606A

Other languages

English (en)

French (fr)

Other versions

EP1077250B1 (de

Inventor

Colin C.W. c/o Agroserve Ltd. Milne

Giacinto Giovanni c/o Agroserve Ltd. Barberio

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Agroserve Ltd

Original Assignee

Agroserve Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1999-08-16

Filing date

2000-07-03

Publication date

2001-02-21

2000-07-03 Application filed by Agroserve Ltd filed Critical Agroserve Ltd

2001-02-21 Publication of EP1077250A1 publication Critical patent/EP1077250A1/de

2005-01-26 Application granted granted Critical

2005-01-26 Publication of EP1077250B1 publication Critical patent/EP1077250B1/de

2020-07-03 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

239000013011 aqueous formulation Substances 0.000 title 1
239000000203 mixture Substances 0.000 claims abstract description 40
239000003795 chemical substances by application Substances 0.000 claims abstract description 15
239000004094 surface-active agent Substances 0.000 claims abstract description 15
239000000645 desinfectant Substances 0.000 claims abstract description 14
125000001453 quaternary ammonium group Chemical group 0.000 claims abstract description 10
-1 alkyl glucoside Chemical class 0.000 claims abstract description 7
239000002738 chelating agent Substances 0.000 claims abstract description 7
229930182478 glucoside Natural products 0.000 claims abstract description 7
229910000000 metal hydroxide Inorganic materials 0.000 claims abstract description 7
150000004692 metal hydroxides Chemical class 0.000 claims abstract description 7
229910052914 metal silicate Inorganic materials 0.000 claims abstract description 7
239000002736 nonionic surfactant Substances 0.000 claims abstract description 6
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 18
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical group [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 9
125000000217 alkyl group Chemical group 0.000 claims description 8
239000004115 Sodium Silicate Substances 0.000 claims description 3
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 3
229910052911 sodium silicate Inorganic materials 0.000 claims description 3
DHMQDGOQFOQNFH-UHFFFAOYSA-M Aminoacetate Chemical compound NCC([O-])=O DHMQDGOQFOQNFH-UHFFFAOYSA-M 0.000 claims description 2
KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 2
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 claims description 2
239000002280 amphoteric surfactant Substances 0.000 claims description 2
229960003237 betaine Drugs 0.000 claims description 2
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
229910052708 sodium Inorganic materials 0.000 claims description 2
239000011734 sodium Substances 0.000 claims description 2
235000013336 milk Nutrition 0.000 abstract description 10
239000008267 milk Substances 0.000 abstract description 10
210000004080 milk Anatomy 0.000 abstract description 10
238000004140 cleaning Methods 0.000 abstract description 6
238000009472 formulation Methods 0.000 description 22
239000005708 Sodium hypochlorite Substances 0.000 description 12
SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 12
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
241000193755 Bacillus cereus Species 0.000 description 6
239000000243 solution Substances 0.000 description 6
229910052751 metal Inorganic materials 0.000 description 5
239000002184 metal Substances 0.000 description 5
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
239000010941 cobalt Substances 0.000 description 4
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 4
150000002739 metals Chemical class 0.000 description 4
ZBJVLWIYKOAYQH-UHFFFAOYSA-N naphthalen-2-yl 2-hydroxybenzoate Chemical compound OC1=CC=CC=C1C(=O)OC1=CC=C(C=CC=C2)C2=C1 ZBJVLWIYKOAYQH-UHFFFAOYSA-N 0.000 description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
230000015556 catabolic process Effects 0.000 description 3
229910017052 cobalt Inorganic materials 0.000 description 3
238000010790 dilution Methods 0.000 description 3
239000012895 dilution Substances 0.000 description 3
238000005187 foaming Methods 0.000 description 3
229910052759 nickel Inorganic materials 0.000 description 3
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 2
239000010949 copper Substances 0.000 description 2
230000007797 corrosion Effects 0.000 description 2
238000005260 corrosion Methods 0.000 description 2
229910052742 iron Inorganic materials 0.000 description 2
ZAWGLAXBGYSUHN-UHFFFAOYSA-M sodium;2-[bis(carboxymethyl)amino]acetate Chemical compound [Na+].OC(=O)CN(CC(O)=O)CC([O-])=O ZAWGLAXBGYSUHN-UHFFFAOYSA-M 0.000 description 2
239000010935 stainless steel Substances 0.000 description 2
229910001220 stainless steel Inorganic materials 0.000 description 2
239000008399 tap water Substances 0.000 description 2
235000020679 tap water Nutrition 0.000 description 2
238000009736 wetting Methods 0.000 description 2
241000894006 Bacteria Species 0.000 description 1
JMHWNJGXUIJPKG-UHFFFAOYSA-N CC(=O)O[SiH](CC=C)OC(C)=O Chemical group CC(=O)O[SiH](CC=C)OC(C)=O JMHWNJGXUIJPKG-UHFFFAOYSA-N 0.000 description 1
KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
229910000531 Co alloy Inorganic materials 0.000 description 1
229910000881 Cu alloy Inorganic materials 0.000 description 1
FARBQUXLIQOIDY-UHFFFAOYSA-M Dioctyldimethylammonium chloride Chemical compound [Cl-].CCCCCCCC[N+](C)(C)CCCCCCCC FARBQUXLIQOIDY-UHFFFAOYSA-M 0.000 description 1
241000588724 Escherichia coli Species 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
229910000640 Fe alloy Inorganic materials 0.000 description 1
WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
229910000990 Ni alloy Inorganic materials 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
239000002253 acid Substances 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
239000004411 aluminium Substances 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
230000003466 anti-cipated effect Effects 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
239000000460 chlorine Substances 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
235000014113 dietary fatty acids Nutrition 0.000 description 1
230000000694 effects Effects 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
239000003925 fat Substances 0.000 description 1
239000000194 fatty acid Substances 0.000 description 1
229930195729 fatty acid Natural products 0.000 description 1
150000004665 fatty acids Chemical class 0.000 description 1
239000006260 foam Substances 0.000 description 1
235000013305 food Nutrition 0.000 description 1
239000008103 glucose Substances 0.000 description 1
239000008233 hard water Substances 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
150000002497 iodine compounds Chemical class 0.000 description 1
150000002632 lipids Chemical class 0.000 description 1
229910001092 metal group alloy Inorganic materials 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
230000002035 prolonged effect Effects 0.000 description 1
125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
102000004169 proteins and genes Human genes 0.000 description 1
108090000623 proteins and genes Proteins 0.000 description 1
150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
235000019795 sodium metasilicate Nutrition 0.000 description 1
DZCAZXAJPZCSCU-UHFFFAOYSA-K sodium nitrilotriacetate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CC([O-])=O DZCAZXAJPZCSCU-UHFFFAOYSA-K 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/883—Aminimide, i.e. ammonioamidates
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines

Definitions

This invention relates to cleaning formulations and in particular to formulations for use in the cleaning of milking and milk storage equipment such as bulk milk tanks, milk pipelines etc.
cleaning formulations for milking and milk storage equipment have been based on combinations of alkaline compounds (sodium hydroxide, potassium hydroxide, sodium carbonate) in solution with sodium hypochlorite for sanitising.
alkaline compounds sodium hydroxide, potassium hydroxide, sodium carbonate
sodium hypochlorite is a very effective sanitising agent
its solutions do not wet surfaces very effectively and hence products have been developed to overcome this wetting problem.
Surfactants have been found to increase wetting power and hence may be added to sodium hypochlorite formulations.
only a limited number of surfactants are compatible with sodium hypochlorite and these surfactants are usually high foaming.
Such high foaming formulations do not work well in certain environments such as cleaning in place (CIP) in milk and food pipeline systems.
Sodium hypochlorite solutions containing sodium hydroxide are alkaline and corrosive and hence are not suitable for use with milking equipment or milk storage systems comprising metals such as aluminium or zinc or soft metal alloys.
the reaction between the formulation and metal may also produce hydrogen which may have a corrosive effect on equipment structures.
a range of alternative products have been developed which have disinfectant properties, for example products comprising quaternary ammonium compounds (cationics), amphoterics, iodine compounds, etc. None of these products are as efficient as formulations comprising sodium hypochlorite and most cannot be used in alkaline mixtures. Since a level of causticity is required to emulsify fats and ensure successful removal of protein deposits from milking equipment, such as bulk storage tanks, such alternative products are also not favoured.
an alkaline formulation including surfactants, disinfectants, a hydrotroping agent and optionally a scale build-up retardant can provide efficacious sanitising with low foaming properties which is a real alternative to alkaline formulations containing sodium hypochlorite.
the invention thus provides an aqueous composition
an aqueous composition comprising
Preferred metal hydroxides are potassium hydroxide and especially sodium hydroxide.
Preferred metal silicates are sodium silicate, especially sodium metasilicate.
the alkalinity is provided by sodium hydroxide alone.
the formulation contains 2 to 25%, preferably 5 to 15%, more preferably 6 to 10% by weight of the metal hydroxide and/or metal silicate component.
the surfactant mixture comprises both an alkyl glucoside and a nonionic surfactant.
Alkyl glucosides also known as sugar lipids, are commercially available from a variety of suppliers and have a range of applications and properties. Alkyl glucosides are derived from glucose and possess alkyl substituents of differing chain length, for example C 3-14 .
Nonionic surfactants are also widely available commercially.
alkoxylate surfactants of general formula R(O(CH 2 ) m ) n OH where R is an alkyl group with an active hydrogen atom, e.g. an amine, alcohol, fatty acid, ester; m is 2 or 3, preferably 2; and n is 4 to 20 are commercially available.
Mixed ethoxy and propoxy alkoxylates are also readily available.
a particularly useful combination of alkyl glucoside and ethoxylate surfactant is sold under the trade name Berol by Akzo-Nobel, specifically Berol LFG 61 or Berol DGR 81.
the formulation of the invention contains 2 to 15%, preferably 5 to 9%, especially 5 to 7% by weight of the surfactant component.
Other suitable surfactant mixtures will of course be readily determined by the person skilled in the art.
the hydrotroping agent may be a proprionate, betaine or glycinate type of amphoteric surfactant and a range of such hydrotroping agents are again readily available in the market place.
Particularly preferred hydrotroping agents include octylimino-diproprionate and sodium capryloimino-diproprionate.
a particularly useful hydrotroping agent is that sold under the trade name Ampholak YJH-40 by Akzo-Nobel.
the formulation contains 1 to 10%, preferably 2 to 8%, especially 3 to 7% by weight of the hydrotroping agent.
Other suitable hydrotroping agents will of course be readily determined by the person skilled in the art.
a chelating agent in the formulations of the invention, especially in areas of hard water.
a chelating agent this may conveniently be trisodium nitrilotriacetate (sodium NTA) or 2-phosphonobutane-1,2,4-tricarboxylic acid (PBTC) or its sodium salts.
the formulation of the invention contains 1 to 10%, preferably 2 to 8%, especially 3 to 5% by weight of the chelating agent.
Other suitable chelating agents will of course be readily determined by the person skilled in the art.
the balance of the cleaning formulation of the invention is water.
the formulation is further diluted with water at a ratio of 200-300:1 water/cleaner.
sanitisation occurs at elevated temperature, e.g. 30°C, especially 75°C. This has been found to enhance the effectiveness of the sanitising formulation to bacteria.
a tap water sample was inoculated with high numbers (10 6 ) of Bacillus cereus .
Another tap water sample was injected with high numbers of E.Coli .
Both samples were divided into four separate tubes and a formulation comprising 7.5% by weight sodium hydroxide, 6.0% by weight Berol LFG61, 3.0% by weight Bardac LF, 4.5% by weight Ampholak YJH-40, 4% sodium NTA and 75% by weight water was added to a tube from each set to give a final dilution of 1:300, 1:250 and 1:200 respectively.
the remaining two tubes were kept as controls. All the tubes were incubated at 30°C for 10 minutes. The results are displayed in Table 1 below.

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Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Detergent Compositions (AREA)
Agricultural Chemicals And Associated Chemicals (AREA)
Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

EP00305606A 1999-08-16 2000-07-03 Wässrige Reinigungsformulierungen Expired - Lifetime EP1077250B1 (de)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
GB9919324		1999-08-16
GBGB9919324.5A GB9919324D0 (en)	1999-08-16	1999-08-16	Formulations

Publications (2)

Publication Number	Publication Date
EP1077250A1 true EP1077250A1 (de)	2001-02-21
EP1077250B1 EP1077250B1 (de)	2005-01-26

Family

ID=10859219

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
EP00305606A Expired - Lifetime EP1077250B1 (de)	1999-08-16	2000-07-03	Wässrige Reinigungsformulierungen

Country Status (5)

Country	Link
EP (1)	EP1077250B1 (de)
AT (1)	ATE287941T1 (de)
DE (1)	DE60017648T2 (de)
DK (1)	DK1077250T3 (de)
GB (1)	GB9919324D0 (de)

Cited By (4)

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EP1290943A1 (de) *	2001-09-07	2003-03-12	Air Liquide Santé (International)	Konservierungsmittel für Beschichtungszusammensetzungen
US8232239B2 (en)	2010-03-09	2012-07-31	Ecolab Usa Inc.	Liquid concentrated fabric softener composition
US8460477B2 (en)	2010-08-23	2013-06-11	Ecolab Usa Inc.	Ethoxylated alcohol and monoethoxylated quaternary amines for enhanced food soil removal
US9089251B2 (en)	2011-10-14	2015-07-28	Ecolab Usa Inc.	Method of removing and preventing redeposition of protein soils using sugar esters

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US20120046208A1 (en)	2010-08-23	2012-02-23	Ecolab Usa Inc.	Poly phosphate functionalized alkyl polyglucosides for enhanced food soil removal
US8329633B2 (en)	2010-09-22	2012-12-11	Ecolab Usa Inc.	Poly quaternary functionalized alkyl polyglucosides for enhanced food soil removal
US20110312867A1 (en)	2010-06-21	2011-12-22	Ecolab Usa Inc.	Betaine functionalized alkyl polyglucosides for enhanced food soil removal
US20110312866A1 (en)	2010-06-21	2011-12-22	Ecolab Usa Inc.	Alkyl polypentosides and alkyl polyglucosides (c8-c11) used for enhanced food soil removal
US20120046215A1 (en)	2010-08-23	2012-02-23	Ecolab Usa Inc.	Poly sulfonate functionalized alkyl polyglucosides for enhanced food soil removal
US8658584B2 (en)	2010-06-21	2014-02-25	Ecolab Usa Inc.	Sulfosuccinate functionalized alkyl polyglucosides for enhanced food and oily soil removal
US8389457B2 (en)	2010-09-22	2013-03-05	Ecolab Usa Inc.	Quaternary functionalized alkyl polyglucosides for enhanced food soil removal
US8877703B2 (en)	2010-09-22	2014-11-04	Ecolab Usa Inc.	Stearyl and lauryl dimoniumhydroxy alkyl polyglucosides for enhanced food soil removal
US20150252310A1 (en)	2014-03-07	2015-09-10	Ecolab Usa Inc.	Alkyl amides for enhanced food soil removal and asphalt dissolution
WO2023275269A1 (en) *	2021-06-30	2023-01-05	Nouryon Chemicals International B.V.	Chelate-amphoteric surfactant liquid concentrates and use thereof in cleaning applications

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US8367601B2 (en)	2010-03-09	2013-02-05	Ecolab Usa Inc.	Liquid concentrated fabric softener composition
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US9089251B2 (en)	2011-10-14	2015-07-28	Ecolab Usa Inc.	Method of removing and preventing redeposition of protein soils using sugar esters

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Publication number	Publication date
GB9919324D0 (en)	1999-10-20
DE60017648D1 (de)	2005-03-03
DE60017648T2 (de)	2006-03-30
EP1077250B1 (de)	2005-01-26
DK1077250T3 (da)	2005-05-30
ATE287941T1 (de)	2005-02-15

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