EP1189695A1 - Suspensions de composes cyanure polymetallique sous forme de plaquettes, leur preparation et leur utilisation pour produire des alcools de polyether - Google Patents

Suspensions de composes cyanure polymetallique sous forme de plaquettes, leur preparation et leur utilisation pour produire des alcools de polyether

Info

Publication number
EP1189695A1
EP1189695A1 EP00938659A EP00938659A EP1189695A1 EP 1189695 A1 EP1189695 A1 EP 1189695A1 EP 00938659 A EP00938659 A EP 00938659A EP 00938659 A EP00938659 A EP 00938659A EP 1189695 A1 EP1189695 A1 EP 1189695A1
Authority
EP
European Patent Office
Prior art keywords
multimetal cyanide
catalyst
polyether
catalyst suspension
cyanide compounds
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
EP00938659A
Other languages
German (de)
English (en)
Inventor
Georg Heinrich Grosch
Kathrin Harre
Jörg Erbes
Reinhard Lorenz
Stephan Bauer
Thomas Ostrowski
Eva Baum
Dieter Junge
Edward Michael Dexheimer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of EP1189695A1 publication Critical patent/EP1189695A1/fr
Ceased legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/24—Nitrogen compounds
    • B01J27/26—Cyanides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645—Metals or compounds thereof, e.g. salts
    • C08G65/2663—Metal cyanide catalysts, i.e. DMC's

Definitions

  • the invention relates to suspensions of multimetal cyanide compounds, their preparation and their use.
  • Polyether alcohols are used in large quantities for the production of polyurethanes. They are usually produced by catalytic addition of lower alkylene oxides, in particular ethylene oxide and propylene oxide, onto H-functional starter substances. Usually basic metal hydroxides or salts are used as catalysts, the potassium hydroxide being of the greatest practical importance.
  • multimetal cyanide complex compounds mostly zinc hexacyanometalates
  • DD-A-203 735 and DD-A-203 734 describe the preparation of polyetherols using zinc hexacyano cobaltate.
  • Alkali or alkaline earth metal cyanometalates such as potassium hexacyano cobaltate, are implemented.
  • the resulting precipitation suspension As a rule, a water-miscible component containing heteroatoms is added immediately after the precipitation process. This component can also already be present in one or in both educt solutions.
  • This water-miscible component containing heteroatoms can be, for example, an ether, polyether, alcohol, ketone or a mixture thereof.
  • This component is also referred to as an organic complexing agent or organic ligand.
  • Such methods are described, for example, in US 3,278,457, US 3,278,458, US 3,278,459, US 3,427,256, US 3,427,334, US 3,404,109, US 3,829,505, US 3,941,849,
  • DD-A-148 957 describes the production of zinc hexacyanoiridate and its use as a catalyst in the production of polyether alcohol.
  • Hexacanoiridic acid is used as a starting material. This acid is isolated as a solid and used in this form.
  • EP 862,947 describes the preparation of double metal cyanide complex compounds using hexacyanometal acids, in particular hexacyanocobaltoic acid or the aqueous solutions thereof as starting material.
  • the double metal cyanides produced according to EP 862,947 have a high reactivity for the ring-opening polymerization of alkylene oxides.
  • multimetal cyanide catalysts have high polymerization rates, there has been no lack of attempts to further increase the catalytic activity of the multimetal cyanide compounds.
  • One focus of the work in this area focuses on multimetal cyanide compounds that are amorphous.
  • the preparation of such multimetal cyanide compounds is disclosed, inter alia, in EP 654,302.
  • the activity of these catalysts can be increased further by incorporating polymers.
  • EP 700,949 describes double metal cyanide complexes with increased reactivity which contain between 5 and 80 percent by weight, based on the catalyst, of polyethers with a molecular weight greater than 500 daltons.
  • WO 97 / 40,086 describes double metal cyanide catalysts with increased reactivity which contain between 5 and 80% by weight of polyethers with molar masses of less than 500 daltons.
  • WO 98/16310 discloses double metal cyanides which contain between 2 and 80% by weight of functionalized polymers, but no polyethers.
  • the in EP-A-700, 949, WO-A-97/40, 086 and Double metal cyanide catalysts disclosed in WO-A-98/16, 310 are generally amorphous. According to the teaching of WO 98/16,310 (page 2, lines 16-22), the best currently known double metal cyanide catalysts have a low degree of crystallinity. The preferred catalysts are essentially non-crystalline (page 3, lines 10-11).
  • Multimetal cyanide catalysts are mostly used in the form of powder for the production of polyether alcohols.
  • US 4,477,589 and US 4,472,560 describe suspensions of multimetal cyanide compounds in propoxylated glycerol with contents of less than 5% by weight of multimetal cyanide compound.
  • US Pat. No. 5,639,705 and US Pat. No. 5,714,639 describe paste-shaped catalysts which consist of 10 to 60% by weight of multimetal cyanide compound, 40 to 90% by weight of organic complexing agent and 1 to 20% by weight of water.
  • the task was surprisingly achieved by suspending crystalline multimetal cyanide compounds in organic or inorganic liquids and using them in this form as catalysts. It is particularly advantageous if the suspended multimetal cyanide compound has a platelet-shaped morphology.
  • the invention therefore relates to a catalyst suspension for the ring-opening polymerization of alkylene oxides
  • the organic complexing agent b) is selected in particular from the group comprising alcohols, ethers, esters, ketones, aldehydes, carboxylic acids, amides, nitriles, sulfides and mixtures thereof.
  • Polyether alcohols in particular polyether alcohols, preferably hydroxyl-containing polyadducts of ethylene oxide, propylene oxide, butylene oxide, vinyloxirane, tetrahydrofuran, 1,1, 2-trimethylethylene oxide, 1,1,2, 2-tetramethylethylene oxide, 2, 2-dimethyloxetane, diisobutylene oxide, ⁇ -methyl styrene oxide and mixtures thereof are used.
  • Compounds selected from the group consisting of C 4 -C 6 alcohol alkoxylates, block copolymers of alkylene oxides of different hydrophilicity, alkoxylates of fatty acids and fatty acid glycerides, block copolymers of alkylene oxides and polymerizable acids and esters, in particular, are selected as surface-active substances e) used.
  • the crystalline multimetal cyanide compounds used according to the invention are preferably produced by the following process:
  • M 1 contains at least one metal ion selected from the group comprising Zn 2+ , Fe 2+ , Co 3+ , Ni 2+ , Mn 2+ , Co 2+ , Sn 2+ , Pb 2+ , Fe 3+ , Mo 4+ , Mo 6+ , Al 3+ , V 5+ , Sr 2+ , W + , W 6+ , Cu 2+ , Cr 2+ , Cr 3+ , Cd + , Hg 2+ , Pd 2+ , Pt 2+ , V 2+ , Mg 2+ , Ca 2+ , Ba 2+ and mixtures thereof,
  • X is at least one anion selected from the group consisting of halide, hydroxide, sulfate, carbonate, cyanide, thiocyanate, isocyanate, carboxylate, in particular formate, acetate, propionate, oxalate, nitrate and m and n are integers which represent the Values of M 1 and X are sufficient,
  • M 2 contains at least one metal ion selected from the group comprising Fe 2+ , Fe 3+ , Co 3+ , Cr 3+ , Mn 2+ , Mn 3+ , Rh 3+ , Ru 2+ , Ru 3+ , V 4+ , V 5+ , Co 2+ , Ir 3+ and Cr + and M 2 are identical or different M 1 can be,
  • H denotes hydrogen or a metal ion, usually an alkali metal, alkaline earth metal or an ammonium ion,
  • A is at least one anion selected from the group comprising halide, hydroxide, sulfate, carbonate, cyanate, thiocyanate, isocyanate, carboxylate or nitrate, in particular cyanide, where A can be the same or different X, and b is an integer greater than zero and a and c are integers larger or are zero, selected so that the
  • one or both solutions may optionally contain at least one water-containing, heteroatom-containing ligand which is selected from the group consisting of alcohols, ethers, esters, ketones, aldehydes, carboxylic acids, amides, sulfides or mixtures of at least two of the compounds mentioned,
  • step b) optionally combining the aqueous suspension formed in step a) with a ligand containing water-miscible heteroatoms, selected from the group described, which may be the same or different from the ligand from step a),
  • the platelet-shaped multimetal cyanide compounds used according to the invention are crystalline and can have a cubic, tetragonal, trigonal, orthorhombic, hexagonal, monoclinic or triclinic crystal system.
  • the definition of crystal systems and the space groups belonging to the aforementioned crystal systems can be found in "International tables for crystallography", Volume A, ed .: Theo Hahn, (1995).
  • the cyanometalate compound for the preparation of the multimetal cyanide compounds which are used for the suspensions according to the invention, it is advantageous, but not necessary, to use the cyanometalate compound as the cyanometalate acid, since this does not lead to the inevitable formation of a salt as a by-product.
  • cyanometalate hydrogen acids which can preferably be used, are stable in aqueous solution and easy to handle. Their production can, for example, as in W. Klemm, W. Brandt, R. Hoppe, Z. Anorg. General Chem. 308, 179 (1961), starting from the alkali metal cyanometalate via the silver cyanometalate to cyanometalate hydrochloric acid.
  • Another possibility is to convert an alkali metal or alkaline earth metal cyanometalate into a cyanometalate hydrogen acid using an acidic ion exchanger, as described, for example, in F. Hein, H. Lilie, Z. Anorg. General Chem. 270, 45 (1952), or A. Ludi, HU Güdel, V.
  • the proportion of acid in the solution should be greater than 80% by weight, based on the total mass of cyanometalate complexes, preferably greater than 90% by weight, in particular greater than 95% by weight.
  • the organic substances described above are used as ligands containing heteroatoms.
  • the ligand containing no hetero atom-containing ligand is added to the solutions, and step b), the addition of ligand containing hetero atoms to the precipitation suspension, is also omitted.
  • only at least one surface-active compound is added to one or the two solutions in step a).
  • the surface-active compounds used according to the invention can be anionic, cationic, nonionic and / or polymeric surfactants.
  • nonionic and / or polymeric surfactants are used.
  • fatty alcohol alkoxylates, coblock polymers of various epoxies with different hydrophilicity, castor oil alkoxylates or coblock polymers of epoxides and other monomers, such as acrylic acid or methacrylic acid, are selected from this group.
  • Fatty alcohol alkoxylates according to the invention have a fatty alcohol consisting of 8-36 carbons, in particular 10-18 carbons. This is alkoxylated with ethylene oxide, propylene oxide and / or butylene oxide.
  • the polyether part of the fatty alcohol alkoxylate according to the invention can consist of pure ethylene oxide, propylene oxide or butylene oxide polyethers. Copolymers of two or three different alkylene oxides are also possible, or coblock polymers of two or three different alkylene oxides.
  • Fatty alcohol alkoxylates, the Pure polyether chains are, for example, Lutensol AO brands
  • the polyether chains particularly preferably consist of 2 to 50, in particular 3 to 15, alkylene oxide units.
  • Coblock polymers as surfactants contain two different polyether blocks, which differ in their hydrophilicity.
  • Coblock polymers according to the invention can consist of ethylene oxide and propylene oxide (Pluronic brands, BASF Aktiengesellschaft). The water solubility is controlled by the lengths of the different blocks.
  • the molecular weights are in the range from 500 Da to 20,000 Da, preferably from 1000 Da to 6000 Da, and in particular 1500-4000.
  • the ethylene oxide content is from 5 to 50% by weight and the propylene oxide Proportion of 50 to 95 wt .-%.
  • Invention copolymers of alkylene oxide with other monomers preferably have ethylene oxide blocks.
  • Other monomers that may be used include butyl methacrylate (PBMA / PEO BE1010 / BE1030, Th. Goldschmidt), methyl methacrylate (PMMA / PEO ME1010 / ME1030, Th. Goldschmidt) or methacrylic acid (EA-3007, Th. Goldschmidt ).
  • the surface-active substances used should have a moderate to good water solubility.
  • an aqueous solution of a cyanometalate-hydrogen acid or a cyanometalate salt is combined with the aqueous solution of a metal salt of the general formula M 1 m ( ⁇ ) n / where the symbols have the meaning explained above.
  • a stoichiometric excess of the metal salt is used.
  • the molar ratio of the metal ion to the cyanometalate component is preferably from 1.1 to 7.0, preferably from 1.2 to 5.0 and particularly preferably from 1.3 to 3.0. It is advantageous to add the metal salt solution and add the cyanometalate compound, but the reverse can also be used. Thorough mixing, for example by stirring, is required during and after the starting material solutions have been combined.
  • the content of the cyanometalate compound in the cyanometalate reactant solution based on the mass of cyanometalate reactant solution is 0.1 to 30% by weight, preferably 0.1 to 20% by weight, in particular 0.2 to 10% by weight. -%.
  • the content of the metal salt component in the metal salt solution based on the mass of the metal salt solution is 0.1 to 50% by weight, preferably 0.2 to 40% by weight, in particular 0.5 to 30% by weight.
  • the surface-active substances are already introduced in at least one of the two solutions.
  • the surface-active substances are preferably added to the solution which is initially introduced during the precipitation.
  • the content of surface-active substances in the precipitation solution based on the total mass of the precipitation suspension, is between 0.01 and 40% by weight. A content of 0.05 to 30% by weight is preferred.
  • a further preferred embodiment provides for the surface-active substances to be distributed proportionally over both educt solutions.
  • the ligands containing heteroatoms are added to the resulting suspension, in particular after the two starting material solutions have been combined, and here too thorough mixing must be ensured.
  • the ligand should preferably be added to the solution of the cyanometalate compound.
  • Suspension should be 1 to 60% by weight, preferably 5 to 40% by weight, in particular 10 to 30% by weight.
  • the multimetal cyanide compounds used according to the invention can preferably have X-ray diffraction patterns, as shown in DE 197 42 978 FIGS. 3 and 4.
  • the multimetal cyanide compounds used to prepare the suspensions according to the invention preferably have primary crystals with a platelet-shaped habit.
  • Platelet-shaped particles are to be understood as meaning particles whose thickness is three times, preferably five times, particularly preferably ten times smaller than their length and width.
  • the preferred catalyst according to the invention contains more than
  • multimetal cyanide compounds according to the invention are visible in scanning electron microscope images. Multimetal cyanide compounds which are less preferred according to the invention are often either in the form of rods or in the form of small cube-shaped or spherical crystals.
  • the multimetal cyanide compounds produced by precipitation according to the process described above can then be separated from the precipitation suspension by filtration or centrifugation. The separation can then be followed by one or more washes of the multimetal cyanide compounds.
  • Washes can be performed with water, the ligands containing heteroatoms mentioned above, or mixtures thereof.
  • the washings can be carried out on the separation device (e.g. filter device) itself or in separate apparatus by e.g. Resuspend the multimetal cyanide compound in washing liquid and separate again from the liquid.
  • This washing can be carried out at temperatures from 10 ° C to 150 ° C, preferably 15 to 60 ° C.
  • the multimetal cyanide compound can then be dried at temperatures from 30 ° C. to 180 ° C. and pressures from 0.001 bar to 2 bar, preferably 30 ° C. to 100 ° C. and pressures from 0.002 bar to 1 bar.
  • a preferred embodiment of the production process of the multimetal cyanide compound used according to the invention provides that, apart from the surface-active substance, no organic, heteroatom-containing ligands, as defined above, are added before, during or after the precipitation.
  • the multimetal cyanide compound is washed with water after separation from the precipitation suspension.
  • the multi-metal cyanide compounds prepared as described above are used for the production of polyether alcohols in the form of the suspensions according to the invention. Both the moist and the dried multimetal cyanide compounds can be used as the starting material for the suspensions according to the invention.
  • the powdery, dried multimetal cyanide compounds are dispersed as finely as possible in the suspension liquid by efficient dispersing in order to achieve the highest possible activity of the multimetal cyanide catalyst.
  • the suspension takes place in suitable apparatus with the input of high shear energy.
  • Apparatus that allow a high input of shear energy have shear gradients between lxlO 2 s _1 to lxlO 7 s -1 , preferably lxlO 3 s " 1 to lxlO 6 s _1 , particularly preferably lxlO 4 s _1 to lxlO 6 s _1
  • the risk of agglomeration is particularly great due to the large contact surfaces in the case of platelet-shaped particles.
  • Such methods for the efficient production of a suspension which is as finely divided as possible include stirring under high shear forces, such as in homogenizers or Ultraturrax devices, and the use of dispersing machines, in particular pot and agitator ball mills, such as bead mills in general and those with small grinding beads (with, for example, 0.3 mm diameter), such as the double cylinder bead mills (DCP-Super Flow ® ) from Draiswerken GmbH, Mannheim, or the centrifugal fluidized bed mills (ZWM) from Netzsch Manbau GmbH, Selb. If necessary, dissolvers can be used for the pre-dispersion.
  • DCP-Super Flow ® the double cylinder bead mills
  • ZWM centrifugal fluidized bed mills
  • dissolvers can be used for the pre-dispersion.
  • Dispersants known to those skilled in the art such as, for example, lecithin, Zn oleate, Zn stearate, can also be used in small amounts. Furthermore, all methods are suitable which allow powder to be dispersed as finely as possible in liquids.
  • the dispersion can take place at temperatures from 10 ° C. to 150 ° C., preferably 30 ° C. to 120 ° C.
  • Dispersing liquids can be polyethers, organic liquids or water, and mixtures thereof.
  • Polyethers with molecular weights from 150 to 6000 daltons and functionalities from 1 to 8 can be used as the polyether.
  • Polyethers with molecular weights of 150 to 2000 daltons and functionalities of 1 to 3, in particular molecular weights of 150 to 800 daltons are preferably used.
  • suspensions with solids contents of less than 10% by weight are preferred. Solids contents of less than 5% by weight are particularly preferred.
  • Compounds containing heteroatoms and hydrocarbons or mixtures thereof can be used as organic liquids. Compounds that have a vapor pressure greater than 0.005 bar at 100 ° C.
  • predried multimetal cyanide compound is suspended in water, suspensions with solids contents of less than 20% by weight and pastes with solids contents of less than 60% by weight are preferred.
  • the water content in the pastes and suspensions should then be above 20% by weight.
  • Drying is preferably dispensed with.
  • the moist multimetal cyanide compounds are then used to prepare the suspensions according to the invention.
  • a suspension is produced from the multimetal cyanide compound after the precipitation and separation from the precipitation suspension, as well as after washing the multimetal cyanide compound, either on the filtering device or externally with subsequent filtration, without drying, from the moist multimetal cyanide compound.
  • the multimetal cyanide compound like the dried multimetal cyanide compounds, can be suspended in the above-mentioned dispersing media.
  • the methods which have been described for producing a suspension which is as finely divided as possible in the dried multimetal cyanide compounds can also be used in the dispersion of the undried multimetal cyanide compounds.
  • temperature and vacuum can be applied simultaneously during the dispersion in order to remove volatile constituents, e.g. Water or organic ligands to remove.
  • Vacuum is understood to mean both normal vacuum stripping up to pressures of 0.001 bar and the combination of vacuum treatment and stripping with inert gases such as nitrogen, argon, helium etc.
  • the temperature can be between 10 ° C and 150 ° C, preferably 30 ° C and 120 ° C.
  • suspensions with solids contents of less than 20% by weight are preferred. Solids contents of less than 10% by weight and particularly preferably less than 5% by weight are particularly preferred. If you suspend the undried one Multimetal cyanide compound in organic liquids, as described above, suspensions with solids contents of less than 10% by weight are preferred. Solids contents of less than 5% by weight are particularly preferred. If the undried multimetal cyanide compound is suspended in water, suspensions with solids contents of less than 20% by weight and pastes with solids contents of less than 60% by weight are preferred. The water content in the pastes and suspensions should then be above 20% by weight.
  • the suspensions according to the invention can be prepared according to the following advantageous embodiment.
  • the precipitation is carried out in the presence of the surface-active agent and optionally the organic ligand. If an organic ligand is used, the organic ligand should also have a vapor pressure greater than 0.005 bar at 100 ° C.
  • polyether is added to the precipitation suspension and, if appropriate, the acid formed during the precipitation, the water and at least some of the organic ligands are distilled off under vacuum.
  • the remaining suspension has a solids content of less than 20% by weight and a polyether content of more than 80% by weight.
  • the possible polyethers are defined above. Polyether alcohols with molecular weights of 150 to 2000 daltons are preferred, so that the resulting suspension can be used directly as a catalyst for the preparation of polyether alcohols.
  • the multimetal cyanide suspensions produced by the process according to the invention are outstandingly suitable as catalysts for the synthesis of polyetherols with functionalities from 1 to 8, preferably 1 to 6 and molar masses from 500 to 50,000, preferably 800 to 15,000, by addition of alkylene oxides onto H-functional ones Starter substances.
  • Catalyst concentrations used are smaller than 1 wt .-%, preferably less than 0.5 wt .-%, particularly preferably less than 1000 ppm, particularly preferably less than 500 ppm, especially preferably less than 100 ppm ⁇ be subjected to the total weight of the polyetherol.
  • the polyetherols can be prepared either continuously or batchwise. The synthesis takes place in the suspension procedure.
  • the temperatures used in the synthesis are between 50 ° C and 200 ° C, with temperatures between 90 ° C and 150 ° C being preferred.
  • compounds having at least one alkyl oxide group such as, for example, ethylene oxide, 1,2-epoxypropane, 1,2-methyl-2-methylpropane, 1,2-epoxybutane, 2,3-epoxybutane, can be used , 1, 2-methyl-3-methylbutane, 1, 2-epoxypentane, 1, 2-methyl-3-methylpentane, 1, 2-epoxyhexane, 1, 2-epoxyheptane, 1, 2-epoxyoctane, 1, 2 -Epoxynonan, 1, 2-Epoxydecan, 1, 2-Epoxyundecan, 1,2-Epoxydodecan, styrene oxide, 1, 2-Epoxycyclopentan, 1, 2-Epoxycyclohexan, (2, 3-Epoxypropyl Jbenzo
  • the regenerated ion exchanger was now used to produce a substantially alkali-free hexacyanocobaltic acid.
  • a 0.24 molar solution of potassium potassium hexacyanocobaltate in water was passed over the exchanger at a rate of one bed volume per hour. After 2.5 bed volume, the potassium hexacyanocobaltate solution was changed to water.
  • the 2.5 bed volumes obtained had an average content of
  • the X-ray diffractogram of the double metal cyanide obtained in this way could be indicated monoclinically, the images on the scanning electron microscope showed rod-shaped particles.
  • the solid was then filtered off and tert with 200 ml on the filter. -Butanol washed.
  • the solid thus treated was dried in vacuo at 50 ° C. for 16 h. 35
  • the X-ray diffractogram of the double metal cyanide obtained in this way showed two phases, one of which could be indicated monoclinically and the other cubically, the images on the scanning electron microscope showed larger platelet-shaped particles and traces of small cubic particles.
  • the suspension was stirred at 40 ° C for a further 30 min.
  • the solid was then filtered off and tert on the filter with 200 ml. -Butanol washed.
  • the solid thus treated was dried in vacuo at 50 ° C. for 16 h.
  • the X-ray diffractogram of the double metal cyanide obtained in this way showed two phases, one of which could be indicated monoclinically and the other cubically, the images on the scanning electron microscope showed larger platelet-shaped particles and traces of small cubic particles.
  • the X-ray diffractogram of the double metal cyanide obtained in this way showed a crystalline phase that could be indicated monoclinically, the images on the scanning electron microscope showed platelet-shaped particles.
  • the solid was then filtered off and washed on the filter with 200 ml of dipropylene glycol.
  • the moist solid was treated in vacuo at 50 ° C. for 16 h, then wet dispersed in dipropylene glycol, so that a 20% suspension was obtained.
  • the X-ray diffractogram of the double metal cyanide obtained in this way showed a crystalline phase that could be indicated monoclinically, the images on the scanning electron microscope showed platelet-shaped particles.
  • the X-ray diffractogram of the double metal cyanide obtained in this way showed a crystalline phase that could be indicated monoclinically, the images on the scanning electron microscope showed platelet-shaped particles.
  • the synthesis was carried out in a cleaned and dried 1 l stirred autoclave. 150 g of polypropylene glycol were added to the stirred tank and 80 ppm of multimetal cyanide catalyst from Example 2 (solids content of multimetal cyanide compound, based on the mass of the end product) were added. The contents of the kettle were rendered inert with nitrogen and treated in vacuo at 127 ° C. for 1.25 h.
  • the synthesis was carried out in a cleaned and dried 1 l stirred autoclave. 200 g of polypropylene glycol were added to the stirred tank and 250 ppm of catalyst from comparative example 1 were added. The kettle contents were rendered inert with nitrogen and treated in vacuo at 108 ° C. for 1 h.
  • the synthesis was carried out in a cleaned and dried 1 l stirred autoclave. 200 g of polypropylene glycol were added to the stirred tank and 100 ppm of catalyst from Example 1 were added. The contents of the kettle were rendered inert with nitrogen and treated in vacuo at 105 ° C. for 1 h. 1 mol of propylene oxide was then metered in at 110 ° C. and that
  • the synthesis was carried out in a cleaned and dried 1 l stirred autoclave. 200 g of polypropylene glycol were added to the stirred tank and 125 ppm of catalyst from Comparative Example 2 were added. The contents of the kettle were rendered inert with nitrogen and treated in vacuo at 105 ° C. for 1 h.
  • the synthesis was carried out in a cleaned and dried 1 l stirred autoclave. 200 g of polypropylene glycol were added to the stirred tank and 125 ppm of catalyst from Comparative Example 3 were added. The contents of the kettle were rendered inert with nitrogen and treated in vacuo at 105 ° C. for 1 h.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Toxicology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Polyethers (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

L'invention concerne des suspensions catalytiques utilisées pour la polymérisation d'oxydes d'alkylène à ouverture du cycle, qui contiennent: a) au moins un composé cyanure polymétallique de structure cristalline et à teneur en particules sous forme de plaquettes d'au moins 30 % en poids, par rapport au composé cyanure polymétallique, b) ainsi qu'au moins un agent complexant et/ou c) de l'eau et/ou d) au moins un polyéther et/ou e) au moins une substance tensioactive, sous réserve qu'au moins le constituant a) et au moins deux des constituants b) à e) soient présents.
EP00938659A 1999-06-02 2000-05-19 Suspensions de composes cyanure polymetallique sous forme de plaquettes, leur preparation et leur utilisation pour produire des alcools de polyether Ceased EP1189695A1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US09/324,271 US6800583B2 (en) 1999-06-02 1999-06-02 Suspension of multimetal cyanide compounds, their preparation and their use
US324271 1999-06-02
PCT/EP2000/004569 WO2000074843A1 (fr) 1999-06-02 2000-05-19 Suspensions de composes cyanure polymetallique sous forme de plaquettes, leur preparation et leur utilisation pour produire des alcools de polyether

Publications (1)

Publication Number Publication Date
EP1189695A1 true EP1189695A1 (fr) 2002-03-27

Family

ID=23262855

Family Applications (1)

Application Number Title Priority Date Filing Date
EP00938659A Ceased EP1189695A1 (fr) 1999-06-02 2000-05-19 Suspensions de composes cyanure polymetallique sous forme de plaquettes, leur preparation et leur utilisation pour produire des alcools de polyether

Country Status (6)

Country Link
US (2) US6800583B2 (fr)
EP (1) EP1189695A1 (fr)
AR (1) AR024177A1 (fr)
AU (1) AU5395800A (fr)
MX (1) MXPA01011992A (fr)
WO (1) WO2000074843A1 (fr)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6429166B1 (en) * 2000-05-19 2002-08-06 Dow Global Technologies Inc. Method for preparing metal cyanide catalyst/polyol initiator slurries
CN1215091C (zh) * 2001-03-09 2005-08-17 和光纯药工业株式会社 亲水性聚合物载体承载的氧化锇
US6764978B2 (en) * 2002-08-28 2004-07-20 Basf Aktiengesellschaft Multimetal cyanide compounds
DE10240186A1 (de) * 2002-08-28 2004-03-11 Basf Ag Verfahren zur Herstellung von emissionsarmen Polyurethan-Weichschaumstoffen
US6855658B1 (en) 2003-08-26 2005-02-15 Bayer Antwerp, N.V. Hydroxide containing double metal cyanide (DMC) catalysts
KR20060120012A (ko) * 2003-10-10 2006-11-24 쉘 인터내셔날 리써취 마트샤피지 비.브이. 폴리에테르 폴리올의 제조방법
CN1329423C (zh) * 2003-10-31 2007-08-01 上海化工研究院 环氧烷烃聚合催化剂和不同分子量聚环氧烷烃的制备方法
DE102004048735A1 (de) * 2004-10-05 2006-04-27 Basf Ag Verfahren zur kontinuierlichen Herstellung von DMC-Katalysatoren
TW200922968A (en) * 2007-06-27 2009-06-01 Shell Int Research An alkoxylate composition and a process for preparing the same
CN101684184A (zh) 2008-09-27 2010-03-31 巴斯夫欧洲公司 可通过使用可再生的原料获得的聚氨酯鞋底
DE102014209408A1 (de) 2014-05-19 2015-11-19 Evonik Degussa Gmbh Ethoxylatherstellung unter Verwendung hoch aktiver Doppelmetallcyanid-Katalysatoren
DE102014209407A1 (de) 2014-05-19 2015-11-19 Evonik Degussa Gmbh Hoch aktive Doppelmetallcyanid-Katalysatoren und Verfahren zu deren Herstellung
EP3106221A1 (fr) * 2015-06-15 2016-12-21 Universität Hamburg Procede de preparation de catalyseurs a cyanures metalliques doubles et leur utilisation dans des reactions de polymerisation

Family Cites Families (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE203735C (fr)
DE203734C (fr)
DE148957C (fr)
GB1063525A (en) 1963-02-14 1967-03-30 Gen Tire & Rubber Co Organic cyclic oxide polymers, their preparation and tires prepared therefrom
US3278459A (en) 1963-02-14 1966-10-11 Gen Tire & Rubber Co Method of making a polyether using a double metal cyanide complex compound
US3427256A (en) 1963-02-14 1969-02-11 Gen Tire & Rubber Co Double metal cyanide complex compounds
US3278458A (en) 1963-02-14 1966-10-11 Gen Tire & Rubber Co Method of making a polyether using a double metal cyanide complex compound
US3278457A (en) * 1963-02-14 1966-10-11 Gen Tire & Rubber Co Method of making a polyether using a double metal cyanide complex compound
US3427334A (en) 1963-02-14 1969-02-11 Gen Tire & Rubber Co Double metal cyanides complexed with an alcohol aldehyde or ketone to increase catalytic activity
US3829505A (en) 1970-02-24 1974-08-13 Gen Tire & Rubber Co Polyethers and method for making the same
US3941849A (en) 1972-07-07 1976-03-02 The General Tire & Rubber Company Polyethers and method for making the same
AU552988B2 (en) 1982-03-31 1986-06-26 Shell Internationale Research Maatschappij B.V. Polymerizing epoxides and catalyst suspensions for this
AU551979B2 (en) 1982-03-31 1986-05-15 Shell Internationale Research Maatschappij B.V. Epoxy polymerisation catalysts
US4764567A (en) 1986-11-20 1988-08-16 Basf Corporation Process for the preparation of polyoxyalkylene block polyethers having enhanced properties
US4843054A (en) 1987-02-26 1989-06-27 Arco Chemical Technology, Inc. Preparation of filterable double metal cyanide complex catalyst for propylene oxide polymerization
EP0283148B1 (fr) 1987-02-26 1997-07-30 ARCO Chemical Technology, L.P. Préparation d'un catalyseur filtrable à base d'un complexe cyanure à doubles métaux utilisable pour la préparation de l'oxyde d'alcoylène
US4877906A (en) 1988-11-25 1989-10-31 Arco Chemical Technology, Inc. Purification of polyols prepared using double metal cyanide complex catalysts
US5010047A (en) 1989-02-27 1991-04-23 Arco Chemical Technology, Inc. Recovery of double metal cyanide complex catalyst from a polymer
JP3068890B2 (ja) * 1991-05-29 2000-07-24 旭硝子株式会社 ポリエーテル類の製造方法
US5158922A (en) * 1992-02-04 1992-10-27 Arco Chemical Technology, L.P. Process for preparing metal cyanide complex catalyst
US5470813A (en) 1993-11-23 1995-11-28 Arco Chemical Technology, L.P. Double metal cyanide complex catalysts
US5712216A (en) * 1995-05-15 1998-01-27 Arco Chemical Technology, L.P. Highly active double metal cyanide complex catalysts
US5426081A (en) 1993-12-23 1995-06-20 Arco Chemical Technology, L.P. Polyurethane foam-supported double metal cyanide catalysts for polyol synthesis
CA2138063C (fr) * 1993-12-23 2007-02-20 Bi Le-Khac Catalyseurs a base de cyanure de metal double sur support de mousse de polyurethane pour la synthese des polyols
US5416241A (en) 1994-01-27 1995-05-16 Arco Chemical Technology, L.P. Method for purifying polyether polyols made with double metal cyanide catalysts
US5482908A (en) 1994-09-08 1996-01-09 Arco Chemical Technology, L.P. Highly active double metal cyanide catalysts
US5627122A (en) * 1995-07-24 1997-05-06 Arco Chemical Technology, L.P. Highly active double metal cyanide complex catalysts
US5545601A (en) 1995-08-22 1996-08-13 Arco Chemical Technology, L.P. Polyether-containing double metal cyanide catalysts
US5639705A (en) 1996-01-19 1997-06-17 Arco Chemical Technology, L.P. Double metal cyanide catalysts and methods for making them
US5627120A (en) 1996-04-19 1997-05-06 Arco Chemical Technology, L.P. Highly active double metal cyanide catalysts
US5714428A (en) 1996-10-16 1998-02-03 Arco Chemical Technology, L.P. Double metal cyanide catalysts containing functionalized polymers
DE19709031A1 (de) 1997-03-06 1998-09-10 Basf Ag Verfahren zur Herstellung von Doppelmetallcyanidkatalysatoren
JP2001519468A (ja) 1997-10-13 2001-10-23 バイエル・アクチエンゲゼルシヤフト ポリエーテルポリオールを製造するための結晶質複金属シアン化物触媒
DE19840846A1 (de) * 1998-09-07 2000-03-09 Basf Ag Verfahren zur Herstellung von Fettalkoholalkoxylaten

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO0074843A1 *

Also Published As

Publication number Publication date
US6800583B2 (en) 2004-10-05
AU5395800A (en) 2000-12-28
WO2000074843A1 (fr) 2000-12-14
MXPA01011992A (es) 2002-05-06
AR024177A1 (es) 2002-09-04
US20020006864A1 (en) 2002-01-17
US20050004343A1 (en) 2005-01-06

Similar Documents

Publication Publication Date Title
EP1194229A1 (fr) Composes a base de cyanure polymetallique, leur procede de production et leur utilisation
EP1259561B1 (fr) Procede de production de composes du type des cyanures polymetalliques
DE69508009T2 (de) Hochwirksame Doppelmetallcyanidkatalysatoren
DE69705613T2 (de) Hochwirksame doppelmetallcyanidkatalysatoren
EP1685179B1 (fr) Procede de production d'alcools de polyether
DE69634930T2 (de) Verfahren zur herstellung von polyoxyalkylenpolyolen, mit einem niedrigen gehalt an übergangsmetallen, die unter verwendung von doppelmetallcyanidkomplexkatalysatoren hergestellt wunden
DE60100807T2 (de) Dmc komplexkatalysator und verfahren zu seiner herstellung
EP1866084A2 (fr) Procede de fabrication de catalyseurs dmc
EP1034035A1 (fr) Catalyseurs cristallins de cyanure de metaux composites pour preparer des polyols de polyether
WO2001080994A1 (fr) Procede de production de catalyseurs a base de cyanure metallique double
DE19709031A1 (de) Verfahren zur Herstellung von Doppelmetallcyanidkatalysatoren
EP1244519A1 (fr) Procede de production de catalyseurs de cyanure bimetallique (dmc)
EP1189695A1 (fr) Suspensions de composes cyanure polymetallique sous forme de plaquettes, leur preparation et leur utilisation pour produire des alcools de polyether
DE602004004531T2 (de) Nanoskalige dmc-katalysatorpartikel
DE10008635A1 (de) Verfahren zur Herstellung von Polyetherpolyolen
WO2021165283A2 (fr) Procédé pour produire des catalyseurs à base de cyanure bimétallique
EP1517940B1 (fr) Procede de production de catalyseurs dmc
EP1963012A1 (fr) Procédé de fabrication de composés de cyanures multimétalliques
EP1265945B1 (fr) Procede de preparation de polyetherpolyols en presence d'un catalyseur sous forme de complexe multimetal-cyanure
EP1185367B1 (fr) Procede de preparation de polyether polyols en presence de catalyseurs a base de cyanure polymetallique cristallin
WO1999044940A1 (fr) Procede de production de catalyseurs de cyanure metallique double
WO2004022227A1 (fr) Procede pour produire des catalyseurs a base de cyanures polymetalliques
DE102004048735A1 (de) Verfahren zur kontinuierlichen Herstellung von DMC-Katalysatoren
DE10057891A1 (de) Verfahren zur Aufarbeitung von Polyetherpolyolen

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20011204

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE

AX Request for extension of the european patent

Free format text: AL;LT;LV;MK;RO;SI

17Q First examination report despatched

Effective date: 20030724

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION HAS BEEN REFUSED

18R Application refused

Effective date: 20040503