EP1204400A2 - Composition cosmetique aqueuse - Google Patents

Composition cosmetique aqueuse

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Publication number
EP1204400A2
EP1204400A2 EP00965885A EP00965885A EP1204400A2 EP 1204400 A2 EP1204400 A2 EP 1204400A2 EP 00965885 A EP00965885 A EP 00965885A EP 00965885 A EP00965885 A EP 00965885A EP 1204400 A2 EP1204400 A2 EP 1204400A2
Authority
EP
European Patent Office
Prior art keywords
polymer
weight
units
parts
monomers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP00965885A
Other languages
German (de)
English (en)
Inventor
Helmut Witteler
Axel Sanner
Bernhard Schlarb
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
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Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of EP1204400A2 publication Critical patent/EP1204400A2/fr
Withdrawn legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/046—Aerosols; Foams
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/54—Polymers characterized by specific structures/properties
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
    • A61Q1/06—Lipsticks
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q3/00—Manicure or pedicure preparations
    • A61Q3/02—Nail coatings
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring

Definitions

  • the present invention relates to an aqueous cosmetic composition, in particular in the form of a nail varnish or a hair setting formulation.
  • Nail care products especially in the form of nail polishes, are among the most used decorative cosmetics. They usually contain a synthetic resin as a film former as well as inorganic or organic pigments or dyes.
  • the nail polishes should have a high gloss, high hardness and good adhesion to substances containing keratin, such as fingernails, and should dry quickly at room temperature to form a non-sticky, uniform film. The high gloss and good adhesion should be maintained for as long as possible.
  • the film-forming resins used must be soluble in water-acetone mixtures.
  • the film-forming resins should be insoluble in water or water-alcohol mixtures so that the nail polish does not dissolve when it comes into contact with water or when handling common household chemicals.
  • Nail varnishes with aqueous emulsion polymers are increasingly being used as binders.
  • EP-0424112 describes nail polish formulations which contain an emulsion polymer with a core / shell structure as a binder.
  • the outer shell polymer has a softening temperature that is lower than that of the inner shell polymer.
  • the nail polish compositions described therein have inadequate adhesion to substrates containing keratin, e.g. B. on fingernails, show and quickly lose their shine after drying.
  • DE-19727504 discloses aqueous cosmetic formulations, in particular nail polish formulations, which contain, as binders, an emulsion polymer which can be obtained by polymerizing a mixture of certain monomers in the presence of a polymer containing an ionic or ionogenic group.
  • the formulations described have one sufficient adhesion to fingernails, but are not completely satisfactory when used as nail polish.
  • the painted surfaces quickly lose their shine and disadvantageously show a sticky sensory impression.
  • the object of the invention is therefore to provide an aqueous cosmetic composition, in particular a water-based nail polish, which after drying leads to films with good adhesion to substrates containing keratin in particular, high gloss and high gloss retention and freedom from tack.
  • an aqueous cosmetic composition which contains an emulsion polymer having a minimum film-forming temperature MFT determined in the absence of film-forming aids and at least one glass transition temperature T g of the dried film, where
  • This rule must apply to at least one glass transition temperature if the polymer has more than one glass transition temperature.
  • the emulsion polymer used according to the invention is characterized by its minimum film formation temperature, determined in the absence of film-forming aids, and the glass transition temperatures of the film which is obtained after drying.
  • the minimum film-forming temperature is the limit temperature above which a plastic dispersion will dry during drying under a crack-free film.
  • the minimum film formation temperature is determined under the conditions specified in DIN 53787.
  • the emulsion polymer has a solids content of 30 to 55% by weight.
  • the mean value from 10 independently carried out determinations is used as MFT.
  • the determination is made in the absence of film-forming aids or coalescing or leveling agents, ie the specific MFT is an intrinsic property of the emulsion polymer under investigation.
  • the formulated cosmetic composition can contain such auxiliary agents if desired.
  • the T g is determined using a commercially available DSC calorimeter with a heating rate of 20 ° C on a film, which is applied by applying the emulsion in a dry film thickness of 100 ⁇ m to glass and drying at 23 ° C and 50% humidity is obtained.
  • the emulsion polymer has a maximum particle size distribution in the range from 50 to 200 nm, preferably 80 to 150 nm.
  • the particle size distribution is the plot of the total volume of all particles in a class against the particle diameter.
  • Emulsion polymers with the specified particle size distribution lead to films with particularly high gloss and high gloss retention.
  • Emulsion polymers that can be used are obtained by polymerizing ethylenically unsaturated compounds (monomers) in a two-phase system with water as the continuous phase.
  • a water-soluble initiator system is usually used to initiate the polymerization.
  • the aqueous phase contains emulsifiers and / or protective colloids.
  • Monomers that can be used are e.g. B. -C-C 3 o-alkyl (meth) acrylates, vinyl esters, vinyl aromatics and mixtures thereof. Preferred monomers are discussed below in connection with preferred aspects of the invention.
  • Suitable protective colloids are hydrophilic polymers and copolymers, such as polyvinyl alcohols, polyacrylic acids, polyacrylamides, polyvinyl pyrrolidones, sulfonate-containing polyesters, sulfonate-containing polyamides, sulfonate-containing polyurethanes, carboxylate-containing PES, PA, PUR, sulfonate- or carboxylate-containing polyester amides. Hydrophilic protective colloids with ionic or ionogenic groups are preferred.
  • Particularly suitable emulsion polymers contain styrene and preferably at least one monomer selected from methyl methacrylate, n-butyl (meth) acrylate and tert-butyl (meth) acrylate and preferably at least one monomer selected from acrylic acid, methacrylic acid and crotonic acid.
  • the emulsion polymer contains at least 2% by weight, preferably 2 to 50% by weight, in particular 3 to 25% by weight, based on the total monomer units, of units of a monomer of the formula I,
  • R 1 and R 2 independently of one another represent a hydrogen atom or a methyl group and R 3 represents C 9 -C 30 alkyl, in particular C 12 -C 22 alkyl.
  • the radical R 3 can stand for branched, cyclic or linear alkyl, with linear alkyl being preferred.
  • Preferred examples of monomers of the formula I are esters of (meth) acrylic acid with C 12 -C 22 alcohols, such as lauryl acrylate, stearyl acrylate, lauryl methacrylate, stearyl methacrylate, esters of methyl methacrylic acid with C 2 -C 22 alcohols and also esters crotonic acid with C 12 -C 22 alcohols, of which lauryl acrylate, stearyl acrylate, lauryl methacrylate and / or stearyl methacrylate are particularly preferred.
  • the total proportion of styrene units and units of monomers of the formula I, based on the total monomer units is 15 to 80% by weight, in particular 30 to 60% by weight.
  • the emulsion polymer is preferably a multi-stage emulsion polymer which has at least one first polymer domain and at least one second polymer domain, the first polymer domain being composed of
  • the second polymer domain is essentially composed of neutral monomer units.
  • the preferred emulsion polymer is multi-stage, i. H. it has two or more polymer domains. It can be obtained by emulsion polymerization of a monomer or monomer mixture constituting a higher polymer domain in the presence of the polymer of the preceding stage.
  • a two-stage emulsion polymer is thus prepared by emulsion polymerizing a monomer mixture constituting the second polymer domain in the presence of a polymer consisting of the first polymer domain.
  • the latter generally acts as a protective coloid in emulsion polymerization.
  • first and second polymer domains are introduced for ease of reference for the purposes of the present description. In the case of three- or multi-stage emulsion polymers, no particular arrangement of these domains relative to other domains is implied.
  • the first polymer domain is composed of 5 to 50 parts by weight of monomer units with at least one ionic or ionogenic group and 50 to 95 parts by weight of neutral monomer units.
  • Monomer units with ionic or ionogenic groups are those which are derived from acidic or anionic, basic or cationic or amphoteric monomers. Ionic groups have a full ion charge or a multiple thereof. Ionogenic monomers can be converted into ionic groups by protonation / deprotonation or quaternization.
  • Anionic and cationic monomers can also be present simultaneously in the first polymer domain, it being possible for the two monomer types to be equimolar or one of the two monomer types to be present in a molar excess, so that the polymer thus produced is anionic or cationic to the outside.
  • This can e.g. B. be useful if one of the two types of monomers brings about an additional advantage, such as improved adhesion or dispersion stability.
  • Anionic or acidic monomers are e.g. B. ethylenically unsaturated mono- or dicarboxylic acids, preferably with 3 to 6 carbon atoms, and polymerizable or copolymerizable acidic carboxylic acid derivatives, such as (meth) acrylic acid, crotonic acid, maleic acid and their anhydrides and half esters, fumaric acid and -haibester, itaconic acid; unsaturated sulfonic acid derivatives, such as styrene sulfonic acid, vinyl sulfonic acid, 2-acrylamido-2-methyl-propanesulfonic acid or their salts; unsaturated phosphorus or phosphonic acid derivatives, such as vinylphosphonic acid or the phosphoric acid monoesters of polymerizable alcohols, such as, for. B. Butanediol monoacrylate or hydroxyethyl methacrylate.
  • Ethylenically unsaturated mono- or dicarboxylic acids such as acrylic acid, methacrylic acid and crotonic acid, are preferred anionic or acid monomers. These can advantageously be completely or partially neutralized.
  • Cationic or basic monomers are e.g. B. (meth) acrylic acid esters or amides of amino alcohols or diamines such as dialkylaminoalkyl (meth) acrylates or - (meth) acrylamides such as N, N-dimethylaminoethyl (meth) acrylate, N, N-dimethylaminoethyl methacrylate, N, N-dimethylaminopropylacrylamide, dialkylaminostyrenes, such as, for. B.
  • (meth) acrylic acid esters or amides of amino alcohols or diamines such as dialkylaminoalkyl (meth) acrylates or - (meth) acrylamides such as N, N-dimethylaminoethyl (meth) acrylate, N, N-dimethylaminoethyl methacrylate, N, N-dimethylaminopropylacrylamide, dialkylaminostyre
  • N, N-dimethylaminostyrene and N, N-dimethylaminomethylstyrene vinyl pyridines such as 4-vinylpyridine and 2-vinylpyridine, 1-vinylimidazole, and further compounds by reacting the above-mentioned basic monomers with known quaternizing reagents, such as alkyl halides, Benzyl halides, dialkyl sulfates, etc. can be produced.
  • amphoteric monomers are N- (3-sulfopropyl) -N-meth-acryloyloxyethyl-N, N-dimethylammonium betaine and N-carboxymethyl-N-methacryloyloxyethyl-N, N-dimethylammonium betaine.
  • Acid groups or tertiary amino groups can be converted into ionic groups by salt formation or quaternization reaction.
  • Neutral monomer units derive from neutral monomers, i.e. H. Monomers without ionic or ionogenic groups.
  • the neutral monomers also include the monomers of the formula I.
  • the emulsion polymer generally contains further neutral monomers, which can advantageously be divided into main monomers and different monomers (comonomers).
  • C ⁇ -C 8 alkyl (meth) acrylates such as methyl acrylate, methyl methacrylate, ethyl acrylate, ethyl methacrylate, propyl acrylate, propyl methacrylate, n-butyl acrylate, n-butyl methacrylate, 2-ethylhexyl acrylate;
  • Vinyl esters of Ci-Cig-alkane carboxylic acids in particular Ci-Cg-alkane carboxylic acids, such as vinyl acetate, vinyl propionate, vinyl laurate, vinyl stearate, vinyl neodecanoate;
  • Vinyl aromatics such as preferably styrene, ⁇ - and ⁇ -methylstyrene, ⁇ -butylstyrene, 4-butylstyrene, 4-decylstyrene; or cite mixtures thereof.
  • Aliphatic olefins having 2 to 8 carbon atoms and one or two olefinic double bonds such as butadiene, isoprene and chloroprene, and also ethylene, propylene and isobutylene can also be mentioned. Aliphatic olefins with two double bonds are less preferred main monomers.
  • Particularly preferred main monomers are styrene, methyl methacrylate, n-butyl (meth) acrylate and / or tert-butyl (meth) acrylate.
  • Suitable comonomers are e.g. B. hydroxyl-containing monomers such as hydroxyalkyl (meth) acrylates, e.g. B. hydroxypropyl or hydroxyethyl (meth) acrylate, amides or substituted amides of ethylenically unsaturated mono- or dicarboxylic acids, for. B. acrylamide, methacrylamide, N-methylolacrylamide, N-methylolmethacrylamide, and the etherified with Ci-C ⁇ -monohydric alcohols N-methylolacrylamides and N-methylolmethacrylamides.
  • Crosslinking monomers e.g. B.
  • nitriles are acrylonitrile and methacrylonitrile.
  • the vinyl halides are chlorine, fluorine or bromine-substituted ethylenically unsaturated compounds, preferably vinyl chloride and vinylidene chloride.
  • the second polymer domain is predominantly made up of neutral monomer units. It is preferably composed of 60 to 100 parts by weight of units of the main monomers mentioned above and 0 to 40 parts by weight of units of different monomers. The proportion of ionic monomer units is preferably below 5%.
  • the first polymer domain is composed of
  • the weight ratio of the first polymer domain to the second polymer domain is preferably in the range from 10:90 to 60:40, in particular 30:70 to 50:50.
  • the weight average molecular weight (M w ) of the polymer forming the first polymer domain is preferably above 10,000, particularly preferably from 20,000 to 200,000 (determined by gel permeation chromatography, using polystyrene as standard and tetrahydrofuran as eluent).
  • the polymer which forms the first polymer domain can be prepared by any polymerization process, but preferably by solution polymerization.
  • Suitable solvents for the solution polymerization of the first polymer domain are, for. B. those with a boiling point below 100 ° C at 1 bar or those that form an azeotrope with water, which, if desired, can be easily separated by distillation from the aqueous polymer dispersion or polymer solution.
  • leveling agents can also advantageously be added to the solvent. A later addition of these tools can be superfluous.
  • solvents examples include. B. alcohols or ketones with up to 8 carbon atoms, such as butanol, isobutanol, propanol, ethanol, methanol and methyl ethyl ketone.
  • the polymerization of the ethylenically unsaturated monomers can e.g. B. in a known manner by anionic or preferably radical polymerization, preferably in the presence of initiators.
  • radical initiators are z.
  • the amount of the initiator is preferably 0.2 to 5% by weight, particularly preferably 0.5 to 3% by weight, based on the monomers.
  • the polymerization temperature is preferably 50 to 150 ° C, particularly preferably 70 to 130 ° C.
  • regulators for. B.
  • mercaptoethanol tertiary dodecylmercapane, ethylhexylthioglycolate or diisopropylxanthogen sulfide, preferably in amounts of 0 to 3 wt .-%, based on the monomers, are added.
  • the polymer forming the first polymer domain can be prepared in one or more stages.
  • e.g. B. first a polymer with a high acid content and in the presence of which then a polymer with a lower acid content can be produced, as described for. B. is described in EP-A-320865.
  • the multi-stage production usually brings no further advantages, so that the one-stage production is preferred.
  • the monomers can be initially introduced or, preferably, metered in continuously.
  • the polymer forming the first polymer domain is obtained as a dispersion or preferably solution in the organic solvent.
  • the solids content is preferably 50 to 95% by weight, in particular 60 to 85% by weight.
  • the emulsion polymerization is then carried out to produce the multistage emulsion polymer.
  • the emulsion polymerization can be carried out in the usual manner, for. B. at temperatures of 30 to 95 ° C in the presence of a water-soluble initiator.
  • Suitable initiators are e.g. As sodium, potassium and ammonium persulfate, tert-butyl hydroperoxide, water-soluble azo compounds or redox initiator systems.
  • hydrogen peroxide small amounts of heavy metal salts, such as Cu (II) or Fe (III) salts, are preferably used.
  • the polymer forming the first polymer domain can be placed in water or another aqueous medium and / or added to the water together with monomers to be polymerized during the emulsion polymerization.
  • water is added to the solution of the polymer and then the organic solvent used for its production is predominantly distilled off.
  • the aqueous solution or dispersion of the first polymer domain obtained in this way is used in the production of the second polymer domain by emulsion polymerization.
  • the first polymer domain comprises acid groups or anhydride groups, some or preferably all of these are converted into salt groups before or during the transfer into the aqueous phase, ie. H. neutralized.
  • Suitable neutralizing agents are on the one hand mineral bases such as sodium carbonate or potassium carbonate and ammonia, on the other hand organic bases such as amino alcohols, e.g. B. 2-amino-2-methyl-1-propanol (AMP), triethanolamine, triisopropanolamine (TIPA), monoethanolamine, diethanolamine, tri [(2-hydroxy) -l-propyl] amine, 2-amino-2- methyl-1,3-propanediol (AMPD) or 2-amino-2-hydroxymethyl-1,3-propanediol and diamines, such as lysine.
  • mineral bases such as sodium carbonate or potassium carbonate and ammonia
  • organic bases such as amino alcohols, e.g. B. 2-amino-2-methyl-1-propanol (AMP), triethanolamine, triisopropanolamine (TIPA), monoethanolamine, diethanolamine, tri [(2-hydroxy) -l-propyl] amine, 2-amino-2-
  • emulsion polymerization in addition to the polymer forming the first polymer domain, no further emulsifiers, protective colloids or other dispersing aids are generally required; however, these can be added.
  • auxiliaries which reduce the viscosity are added during and after the emulsion polymerization.
  • These are preferably ionic compounds, in particular salts, which are derived from organic acids or bases. Examples include lysine hydrochloride and sodium citrate.
  • the aqueous cosmetic compositions according to the invention can be in a variety of forms, e.g. B.
  • Preferred embodiments of the cosmetic composition according to the invention relate to hair cosmetic formulations, hair care products and hair setting agents, in particular hair sprays, setting lotions, setting cream, foam setting agents, hair mousse, hair gel, agents for treating dandruff and hair loss, and hair restoration agents.
  • a particularly preferred embodiment of the cosmetic composition according to the invention is a water-based nail polish.
  • the aqueous cosmetic composition according to the invention preferably contains less than 10% by weight of volatile organic substances.
  • volatile organic substances are understood to mean those with a boiling point below 300 ° C. Such substances can serve as leveling agents, for example.
  • the emulsion polymer defined at the outset can be present in the aqueous cosmetic composition as the sole polymer or in a mixture with other polymers.
  • the solubility or redispersibility in water or aqueous media can be controlled.
  • the emulsion polymer according to the invention can be mixed with a water-soluble or water-redispersible polymer.
  • suitable water-soluble polymers are ionic polyamides, polyurethanes and polyesters and homopolymers and copolymers of ethylenically unsaturated monomers.
  • Cosmetic ingredients are known, for example, under the trade names Amerhold, Ultrahold, Ultrahold Strong, Luviflex VBM, Luvimer, Luviskol, Luviskol Plus, Luviset PUR, Acronal, Acudyne, Stepanhold, Lovocryl, Versatyl, Amphomer or Eastman AQ. Some of these polymers will be water soluble or redispersible only with the help of suitable neutralizing agents.
  • the water-soluble polymer can be used in any amount, e.g. B. up to 95 wt .-%, based on the sum of the polymers used. Surprisingly, even with small amounts of water-soluble polymer in a mixture with the emulsion polymer defined at the outset, a mixture redispersible in water is obtained.
  • aqueous cosmetic compositions according to the invention can contain further constituents, e.g. B. colorants such as pigments or dyes, surfactants, dispersants, wetting agents, thickeners, hair conditioners, humectants, leveling agents, preservatives, antifoams, chelating agents, buffers and UV absorbers.
  • colorants such as pigments or dyes, surfactants, dispersants, wetting agents, thickeners, hair conditioners, humectants, leveling agents, preservatives, antifoams, chelating agents, buffers and UV absorbers.
  • the pigments or dyes used should be relatively lightfast and not leak.
  • Pearlescent substances such as mica (mica), guanine, bismuth oxychloride or titanium dioxide on mica can also be used.
  • suitable pigments and dyes can be found in Madison G. de Navarre, The Chemistry and Manufacture of Cosmetics, Vol. 4, pp. 996-998 (2nd ed.).
  • Further suitable colorants are described in DE-4240743A, DE-19538700A, DE-19614637A, DE-19640619A, DE-19705960A, DE-19705962A, DE-19715995A, DE-19802234A, EP-0686674A, US-4009136, US-4487855, US-4612343 and US-5131916.
  • Surfactants or dispersants or wetting agents are often used as surface-active agents in nail coating preparations in order to support the uniform distribution of the pigment.
  • Inorganic pigments are usually hydrophilic and can be easily dispersed in an aqueous emulsion system.
  • Organic pigments are generally hydrophobic and sometimes require a dispersing or wetting agent that reduces the surface tension and enables an even distribution.
  • a list of suitable surface-active agents can be found in Encyclopedia of Chemical Technology, Surfactants, Vol. 19, p. 584 (1969), and the choice to be made in each case lies within the specialist knowledge and ability.
  • Particularly suitable surfactants are alkoxylated silicones, which can be added during or after the preparation of the emulsion polymer. Thickeners are used to prevent separation and sedimentation.
  • Suitable thickeners are, for example, natural gums, such as guar, gum arabic, cellulose and cellulose derivatives, silicates, such as V-gum (R) , clays, such as stearalkonium hectorite, and synthetic polymers, such as acrylates, e.g. B. Carbopol (R) and Acrys- sols ⁇ R) .
  • Suitable hair conditioning agents are known under the CTFA name "Polyquaternium”.
  • a humectant such as B. mono- and polyglycols, mono- and polyglycerols, sugar alcohols, alkylene oxides and polyalkylene oxides, in particular ethylene and propylene oxides (EO and PO), saccharides, glucosides, amino acids, urea and adducts of EO or PO with the compounds mentioned.
  • the humectants transfer moisture to the skin and are generally used in amounts of 0.01 to 30% by weight, preferably 0.1 to 10% by weight, based on the cosmetic composition.
  • Leveling agents can be added to lower the temperature at which the film can form.
  • the leveling agents therefore only serve a purpose during film formation. These are usually organic substances with a boiling point between 30 and 300 ° C.
  • a group of suitable leveling agents includes the glycol ethers, such as ethylene glycol aminobutyl ether, diethylene glycol monomethyl ether, propylene glycol monomethyl ether and dipropylene glycol monomethyl ether.
  • Other suitable leveling agents are ethylene glycol butyl ether acetate, propylene glycol butyl ether, ethyl 3-ethoxypropionate, 1-methoxy-2-propyl acetate, 1-methoxy-2-propanol, 1,2-propylene glycol 1-monomethyl ether, ethyl acetate and toluene.
  • Trade names of leveling agents based on these substances are Dowanol PnB, Eastman EEPS and Solvenon PM.
  • Preservatives are frequently used to prevent bacterial and fungal growth during the storage of the nail coating preparations.
  • Commonly used preservatives e.g. B. lower alkyl esters of p-hydroxybenzoic acid, such as methyl p-hydroxybenzoate, ethyl p-hydroxybenzoate, butyl p-hydroxybenzoate and hexyl p-hydroxybenzoate, 5-chloro-2-methyl-3- (2H ) -isothiazolon, 2-methyl-3- (2H) -isothiazolone, organic salts, such as potassium sorbate, inorganic salts, such as mercury salts, and formaldehyde and formaldehyde-releasing compounds.
  • Suitable anti-foaming agents can be used to prevent foaming and blistering during manufacture and application to the nails.
  • suitable antifoam agents are organopolysiloxanes and substituted organopolysiloxanes, such as methyl silicone and diethyl silicone, silicon dioxide, mixtures of silicon and silicon dioxide, and of organopolysiloxanes and silicon dioxide and polyoxyethylene-polyoxypropylene condensates.
  • Chelating agents remove heavy metal ions that can affect the stability of nail polishes.
  • Suitable chelating agents are ethylenediaminetetraacetic acid (EDTA) and its mono- and tetrasodium salt and tetrasodium pyrophosphate.
  • the nail polish formulation is buffered so that the pH is preferably between 6 and 10.
  • UV absorbers serve to prevent harmful effects of UV rays on the polymer, fading of the pigment or dye and brittleness of the nail coating film.
  • a list of suitable UV absorbers can be found in Encyclopedia of Chemical Technology, UV Absorbers, Vol. 21, pp. 115-122 (1969).
  • the cosmetic composition is preferably present in the cosmetic composition in amounts of 0.5 to 70% by weight, preferably 20 to 65% by weight, particularly preferably 25 to 50% by weight, calculated as a solid resin, based on the total weight of the cosmetic composition. If the amount used is less than 0.5%, the effect of the present invention cannot be obtained.
  • the dispersion of the emulsion polymer contains little coagulum and has fine disperse particles.
  • the aqueous cosmetic compositions in particular nail polish compositions, are no longer soluble in water / ethanol mixtures (EtOH: 0 to 50% by weight), have good film-forming properties, good gloss and in particular good adhesion to keratin containing substrates, e.g. B. fingernails.
  • a nail polish formulation according to the invention usually contains one or more ingredients which are known to the person skilled in the art under the following CTFA names: Acetyl Tributyl Citrate, Acetyl Triethyl Citrate, Acrylates Copoly ⁇ ter, Alcohol, Alcohol Denat., Aluminum Powder, Amyl Acetate, Apricot (Prunus Armeniaca) Kernel Oil, Benzophenone-1, Benzophenone-3, Bismuth Oxychloride, Butyl Acetate, n-Butyl Alcohol, Calcium Pantothenate, Camphor, Carmine, Cellulose Acetate Butyrate, Citric Acid, D&C Red No. 6, D&C Red No. 6 Barium Lake, D&C Red No. 7, D&C Red No.
  • the K value (also Fikentscher constant) is calculated from the solution viscosity of polymers and is explained in the specialist literature, for example by H.-G. Elias, Macromolecules, Vol. 1, Weghig & Wepf, Heidelberg 1990, pp. 98 f. Examples 2A, 2B, 2C; Comparative Example 2:
  • the template is heated to 85 ° C. with stirring in a nitrogen atmosphere.
  • Feed 1 is metered in in 10 minutes. After 85 ° C is reached, 20% of feed 3 are added.
  • Feed 2 is then metered in in 2 hours and the rest of feed 3 in 2.5 hours. The mixture is then stirred at 85 ° C for 1 hour and then cooled to room temperature.
  • Table 2 The compositions and characteristics are given in Table 2.
  • the sample is heated from room temperature to 120 ° C, then cooled to -60 ° C and then heated again to 120 ° C.
  • T g glass transition temperature
  • the glass transition temperature is measured at -60 ° C to 120 ° C. All heating and cooling processes are carried out at a rate of 20 ° C / min.
  • the particle size distribution was determined with a photon correlation spectroscope, model Autosicer 2c from Malvern Instruments. With this device, the total volume of all particles in a class is plotted against the particle diameter; that's the particle size distribution.
  • Mirapol 550 (CAS No. 26590-05-6) 3 g propylene glycol 2 g
  • Alkamuls EL 719 (trademark from Rhodia,
  • Gluadin AGP (trademark from Henkel, hydrolyzed
  • Carbopol 980 (trademark from B.F. Goodrich, CTFA name Carbomer) 1. .2 g
  • Aloe vera gel concentrate 10: 1 0. .5 g
  • Cremophor A 25 (trademark from BASF,
  • Cyclomethicone DC 345 (trademark from Dow Corning, cyclic oligodimethylsiloxane) 55.60 polysynlanes (trademark from Polyesther,
  • Oxybenzone (CAS No. 131-57-7) 4.00 g
  • Luviquat mono CP (trademark from BASF, CTFA name
  • Microcrystalline Wax SP 96 (trademark from Strahl &
  • Isostearyl behenate 2.30 g Cetiol LC (trademark from Henkel, CTFA name Coco-caprylate / caprate) 12.45 g
  • Myristyl myristate 7.60 g PPG-2 myristyl ether propionate (CAS No. 74775-06-7) 9.55 g Micapoly UV Shadow (from Centerchem, mixture of mica, titanium dioxide, cyclomethicone, dimethiconol, isododecane, ethylene-vinyl acetate)
  • Perfluorodecalin (CAS No. 306-94-5) 3.00 g pigments q.s.
  • Crodafos CES (trademark from Croda, mixture of cetearyl alcohol, dicetyl phosphate, ceteth-10 phosphate) 4.00 g Volpo S-2 (trademark from Croda, CTFA name
  • Hydrotriticum PVP (trademark from Croda, copolymer from
  • Germaben II watermark from Sutton, mixture of
  • Example 11 aqueous hair spray
  • Luvimer 100 P (trademark from BASF, copolymer of ethyl acrylate, tert-butyl acrylate and methacrylic acid) 0.5 g
  • Luvimer 100 P (trademark from BASF, copolymer of ethyl acrylate, tert-butyl acrylate and methacrylic acid) 3 g Polymer dispersion from Example 2B lg
  • Example 2B Polymer dispersion from Example 2B 1 g Luviskol VA 37 (trademark from BASF, copolymer from
  • Example 2B Polymer dispersion from Example 2B 1.5 g) 1 Luviflex Soft (trademark from BASF, copolymer from
  • CTFA name Ceteareth-25 0.2 g Luviquat Mono CP (trademark from BASF, CTFA name
  • Example 15 aqueous nail polish
  • Gantrez ES-435 (trademark from ISP, copolymer of vinyl methyl ether and maleic acid dibutyl ester,
  • Antaron WP-660 (trademark from ISP, copolymer from

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
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  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)

Abstract

La présente invention concerne composition cosmétique aqueuse comprenant un polymère en émulsion ayant une température minimale de formation de film (MFT) déterminée en l'absence d'agent de formation de film et au moins une température de transition vitreuse Tg du film sec, avec 35 °C ≤ Tg ≤ 80 °C et Tg - MFT ≥ 8 °C. La composition correspond en particulier à un vernis à ongles ou à une formulation fortifiante pour cheveux.
EP00965885A 1999-08-19 2000-08-18 Composition cosmetique aqueuse Withdrawn EP1204400A2 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE19939326 1999-08-19
DE1999139326 DE19939326A1 (de) 1999-08-19 1999-08-19 Wässrige kosmetische Zusammensetzung
PCT/EP2000/008094 WO2001013863A2 (fr) 1999-08-19 2000-08-18 Composition cosmetique aqueuse

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CN (1) CN1374850A (fr)
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WO (1) WO2001013863A2 (fr)

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Publication number Priority date Publication date Assignee Title
FR2814673B1 (fr) * 2000-09-29 2003-04-11 Oreal Composition cosmetique filmogene
US20060134051A1 (en) 2002-09-26 2006-06-22 Xavier Blin Glossy non-transfer composition comprising a sequenced polymer
CA2486926A1 (fr) * 2003-03-28 2004-10-14 Neutrogena Corporation Composition pour les ongles et utilisation associee
JP4940463B2 (ja) * 2005-07-15 2012-05-30 アサヌマ コーポレーション株式会社 水除去性美爪料
FR2908307B1 (fr) * 2006-11-10 2009-05-01 Oreal Composition cosmetique comprenant un phosphate d'alkyle et un ether d'alcool gras et de polyethyleneglycol, procedes et utilisations.
CN101810548B (zh) * 2010-04-30 2011-07-20 北京卡尔化工研究所 水基快干高光泽室温交联指甲漆树脂及其制备方法
JP5705067B2 (ja) 2010-08-30 2015-04-22 三菱鉛筆株式会社 美爪料組成物
DE102011077373A1 (de) * 2011-06-10 2012-12-13 Henkel Ag & Co. Kgaa Glanzgebende Haarumformungsmittel mit starkem Halt und gutem Haargefühl
CN102908263A (zh) * 2011-08-01 2013-02-06 许凤 一种纳米水性防水易更换指甲油
CN106068117A (zh) * 2014-03-07 2016-11-02 日本合成化学工业株式会社 整发剂用丙烯酸类树脂乳液和含有其的整发剂、以及整发方法
DE102015225204A1 (de) * 2015-12-15 2017-06-22 Henkel Ag & Co. Kgaa "Mittel und Verfahren zur temporären Verformung keratinhaltiger Fasern"
DE102015225210A1 (de) * 2015-12-15 2017-06-22 Henkel Ag & Co. Kgaa "Mittel und Verfahren zur temporären Verformung keratinhaltiger Fasern"
WO2017208666A1 (fr) * 2016-05-31 2017-12-07 花王株式会社 Produit cosmétique capillaire
CN107011474A (zh) * 2017-04-11 2017-08-04 南通拜森化工有限公司 指甲油用丙烯酸树脂及其制备方法

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US4158053A (en) * 1977-08-05 1979-06-12 Eli Lilly And Company Aqueous emulsion polymer nail coating formulations
JPH0818950B2 (ja) * 1992-05-01 1996-02-28 花王株式会社 化粧料
FR2733147B1 (fr) * 1995-04-24 1997-05-30 Fiabila Composition de matiere a usage cosmetique
US5925336A (en) * 1995-12-29 1999-07-20 Eastman Chemical Company Aqueous nail coating composition containing copolymerized colorants
FR2750600B1 (fr) * 1996-07-02 1998-09-11 Oreal Utilisation en cosmetique de copolymeres acryliques ; compositions mises en oeuvre
JP3243446B2 (ja) * 1998-03-24 2002-01-07 ダイセル化学工業株式会社 水性ネイルエナメル
EP1028691A4 (fr) * 1998-06-08 2001-10-04 Kirker Entpr Inc Compositions de vernis a ongles avec apparence decorative

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WO2001013863A3 (fr) 2001-07-26
JP2003507399A (ja) 2003-02-25
CN1374850A (zh) 2002-10-16
DE19939326A1 (de) 2001-02-22

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