EP1210061A1 - Utilisation de sels pour ameliorer le comportement de prise de colorants anioniques directs - Google Patents

Utilisation de sels pour ameliorer le comportement de prise de colorants anioniques directs

Info

Publication number
EP1210061A1
EP1210061A1 EP01921361A EP01921361A EP1210061A1 EP 1210061 A1 EP1210061 A1 EP 1210061A1 EP 01921361 A EP01921361 A EP 01921361A EP 01921361 A EP01921361 A EP 01921361A EP 1210061 A1 EP1210061 A1 EP 1210061A1
Authority
EP
European Patent Office
Prior art keywords
acid
salt
component
anionic
calcium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP01921361A
Other languages
German (de)
English (en)
Inventor
Manuela Javet
Christel Dousse
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Deutschland GmbH
Original Assignee
Wella GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wella GmbH filed Critical Wella GmbH
Publication of EP1210061A1 publication Critical patent/EP1210061A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/20—Halogens; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/67—Vitamins
    • A61K8/673—Vitamin B group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A61Q5/065—Preparations for temporary colouring the hair, e.g. direct dyes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/42—Colour properties
    • A61K2800/43—Pigments; Dyes
    • A61K2800/432—Direct dyes

Definitions

  • the present invention relates to the use of physiologically tolerable salts of inorganic or organic acids to improve the absorption behavior of anionic direct dyes, a 2-stage process for dyeing fibers and a multicomponent agent for non-oxidative dyeing of fibers (in particular keratin fibers such as human Hair), one component of which contains a colorant based on anionic direct dyes and the other component of which contains the physiologically tolerable salts.
  • Non-ionic and cationic dyes for example from the group of nitro dyes, azo dyes or anthraquinone and triphenylmethane dyes, are preferably used in commercially available non-oxidative colorants (so-called toning agents). Such tints are usually sufficiently gentle on the hair and survive several washes.
  • anionic dyes based on anionic dyes are predominantly used. Since keratin is negatively charged, if at all, the anionic dye, which is also negatively charged, can be rejected, which is why with anionic dyes in the acidic pH range, only relatively weak, uneven and poorly washable stains are obtained, while in the neutral and basic milieu these Dyes practically do not stain the keratin fiber at all.
  • the build-up behavior can be improved by adding so-called Carriem or penetration accelerators, such as benzyl alcohol or phenoxyethanol, but at the same time the already relatively strong skin tint is significantly enhanced by anionic dyes.
  • anionic dyes have currently only gained particular importance in Japan, since none of the usual direct draws for approved hair dyes are included in the Japanese positive list.
  • inorganic or organic salts to non-oxidative hair colorants
  • the use of these salts for improvement
  • the absorption behavior of anionic direct dyes is completely new and, based on the prior art, was also not predictable.
  • the present application therefore relates to the use of one or more physiologically tolerable salts of inorganic and / or organic acids to improve the absorption behavior of anionic direct dyes on keratin fibers, such as human hair.
  • the salts in particular are the chlorides, bromides, sulfates, lactates, tartrates, citrates, malates, glycolates, glycerophoshates, phantothenates, phosphinates, glutamates, gluconates, phosphates, formates, sorbates, aspartates, orotates, oxalates and acetates of sodium, potassium, magnesium , Calcium, ammonium, aluminum or zinc into consideration, the salts of calcium, magnesium, sodium and potassium, and in particular sodium chloride, potassium chloride, magnesium chloride, calcium chloride and calcium panthotenate and mixtures thereof, being preferred.
  • the salts of potassium and calcium are particularly preferred, in particular potassium chloride, calcium chloride and calcium panthotenate.
  • the salts can be used both individually and in the form of a mixture of several salts.
  • the salts can be formulated both in solid form, the salts being mixed with water or the colorant before use, and in the form of an aqueous preparation.
  • the total amount of salt used, based on the aqueous preparation or the colorant, is about 0.01 to 10 percent by weight, preferably 0.1 to 5 percent by weight, in particular 0.2 to 2.5 percent by weight.
  • Another object of the present application is a multi-stage process for dyeing keratin fibers, especially human hair, in which the fiber is first pretreated with one or more physiologically tolerable salts of an aqueous and / or organic acid-containing preparation, and then with at least one a dye containing an anionic direct dye is colored.
  • an aqueous preparation containing the physiologically acceptable salts is applied to the keratin fiber; for example by spraying an aqueous salt solution.
  • the colorant is then applied to the fiber pretreated with the salt, the colorant depending on the desired depth of color for about 5 to 60 minutes, preferably 15 to 30 minutes, at a temperature of about 20 to 50 degrees Celsius, in particular at 30 to 40 degrees Celsius.
  • the hair is rinsed with water, optionally washed with a shampoo and dried.
  • Another object of the present application is a multi-component kit for carrying out the dyeing process described above, which contains a first component containing at least one physiologically compatible salt of an inorganic or organic acid and a second component containing at least one anionic direct dye.
  • the first component can be present both in solid form and in the form of an aqueous preparation and contains at least one physiologically compatible salt of an inorganic or organic acid, preferably a chloride, bromide, sulfate, lactate, tartrate, citrate, malate, Glycolate, glycerophoshate, phantothenate, phosphinate, glutamate, gluconate, phosphate, formate, sorbate, aspartate, orotate, oxalate or acetate of sodium, potassium, magnesium, calcium, ammonium, aluminum or zinc, the salts of calcium and potassium, and in particular the sodium chloride, potassium chloride, magnesium chloride, calcium chloride and calcium panthotenate and mixtures thereof, and optionally additives. If the first component is in solid form, it must be mixed with water before use.
  • the salts of potassium and calcium are particularly preferred, in particular potassium chloride, calcium chloride and calcium panthotenate.
  • the total amount of salt used in the aqueous preparation is about 0.01 to 10 percent by weight, preferably 0.1 to 5 percent by weight, in particular 0.2 to 2.5 percent by weight.
  • the colorant can be in the form of a solution, in particular an aqueous or aqueous-alcoholic solution, a cream, a gel, an aerosol foam or an emulsion, and is a mixture of the dye components with the additives customary for such preparations.
  • anionic dyes 6-hydroxy-5 - [(4-sulfophenyl) azo] -2-naphthalenesulfonic acid disodium salt (CM 5985; Food Yellow No. 3; FD&C Yellow No. 6), 2,4-dinitro -1-naphthol-7-sulfonic acid disodium salt (CI10316; Acid Yellow No. 1; Food Yellow No. 1), 2- (indan-1, 3-dion-2-yl) quinolin-x, x-sulfonic acid (mixture from mono- and disulfonic acid) (CI47005; D&C Yellow No. 10; Food Yellow No. 13; Acid Yellow No.
  • the substantive dyes are used in the colorant in a total amount of about 0.01 to 10 percent by weight, preferably 0.1 to 5 percent by weight.
  • the colorant can, if necessary, contain other customary and suitable synthetic or natural substantive dyes.
  • Usual additives in solutions, creams, emulsions, aerosol foams or gels are, for example, solvents such as water, lower aliphatic alcohols, for example ethanol, n-propanol and isopropanol, glycol ethers or glycols such as glycerol and 1,2-propanediol, which are used alone or in combination with one another become.
  • solvents such as water, lower aliphatic alcohols, for example ethanol, n-propanol and isopropanol, glycol ethers or glycols such as glycerol and 1,2-propanediol, which are used alone or in combination with one another become.
  • the tinting agent for cosmetic agents can be known additives, for example wetting agents or emulsifiers from the classes of anionic, cationic, amphoteric or nonionic surface-active substances, such as fatty alcohol sulfates, oxyethylated fatty alcohol sulfates, alkyl sulfonates, alkylbenzenesulfonates, alkyltrimethylammonium salts, alkylbetaoleols, oxethylated fatty acids, oxethylated fatty acids, oxethylated fatty acids, oxethylated fatty acids, oxethylated fatty acids, oxethylated fatty acids, oxethylated fatty acids, oxethylated fatty acids, oxethylated fatty acids, oxethylated fatty acids, oxethylated fatty acids,
  • thickeners such as higher fatty alcohols, starch or cellulose derivatives, perfumes, hair pretreatment agents, conditioners, hair swelling agents, preservatives, petroleum jelly, paraffin oil and fatty acids as well as care agents such as cationic resins, lanolin derivatives, cholesterol, pantothenic acid and betaine.
  • the ingredients mentioned are in the usual amounts for such purposes used, for example the wetting agents and emulsifiers in concentrations of approximately 0.5 to 30 percent by weight (based on the colorant), the thickeners in an amount of approximately 0.1 to 25 percent by weight (based on the colorant) and the care substances in one concentration from about 0.1 to 5.0 percent by weight (based on the colorant).
  • the colorant of the second component additionally contains at least one surface-active compound from the group of anionic, amphoteric and nonionic wetting agents and surfactants, the formulation as non-ionic, anionic or amphoteric cream being particularly preferred.
  • the addition of the surface-active compounds results in a particularly low skin coloration.
  • the pH of the ready-to-use colorant is about 1 to 9, in particular 2.5 to 8.5.
  • the desired pH can be adjusted by adding organic or inorganic acids or alkalizing agents, for example with phosphoric acid, hydrochloric acid, acetic acid, salicylic acid, malonic acid, gluconic acid lactone or ⁇ -hydroxycarboxylic acids such as glycolic acid, lactic acid, tartaric acid, citric acid or malic acid, or alkalizing agents Agents such as alkanolamines, alkylamines, alkali hydroxides, ammonium hydroxide, alkali carbonates, ammonium carbonates or alkali phosphates.
  • physiologically compatible inorganic and / or organic salts enable a significant improvement in the absorption behavior of anionic dyes on keratin fibers such as For example, hair, wool or silk, which enables more intensive and long-lasting dyeing to be achieved with a low skin coloration.
  • the salts are particularly well suited for improving the absorption behavior of anionic direct dyes on keratin fibers, they can also be used very advantageously in the dyeing of other natural or synthetic fibers, for example cotton, viscose, nylon or cellulose acetate, with anionic direct dyes.
  • Bleached hair is first pretreated with a spray solution that contains 1 percent by weight calcium chloride and 1 percent by weight potassium chloride. Following this pretreatment, 50 g of the above tinting cream are applied to the hair. After a Exposure time of 30 minutes at 40 ° C, the hair is rinsed with water and dried. A brown color is obtained.
  • Bleached hair is first pretreated with a spray solution containing 5% by weight calcium pantothenate. Following this pretreatment, 50 g of the above tinting cream are applied to the hair. After an exposure time of 30 minutes at 40 ° C, the hair is rinsed with water and dried. A brown color is obtained.
  • Bleached hair is first pretreated with a spray solution containing 5% by weight calcium pantothenate. Following this pretreatment, 50 g of the above tinting cream are applied to the hair. After an exposure time of 30 minutes at 40 ° C, the hair is rinsed with water and dried. An orange-red color is obtained.
  • Bleached hair is first pretreated with a spray solution containing 5% by weight calcium pantothenate. Following this pretreatment, 50 g of the above tinting cream are applied to the hair. After an exposure time of 30 minutes at 40 ° C, the hair is rinsed with water and dried. A violet color is obtained.
  • the tinting agents according to Examples 1 to 5 are in each case with and without pretreatment in the manner described in the Examples Coloring hair used and then compared the intensity of the dyeings obtained. The results are summarized in Table 2 below.
  • the L * a * b * color measurement values determined in the present examples were determined using a color measuring device from Minolta, type Chromameter II.
  • the L-value stands for the brightness (i.e. the lower the L-value, the greater the color intensity)
  • the a-value is a measure of the red component (i.e. the larger the a-value, the greater the red component is larger).
  • the b-value is a measure of the blue component of the color, the more negative the b-value, the greater the blue component.

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

La présente invention concerne l'utilisation de sels physiologiquement compatibles d'acides organiques ou inorganiques pour améliorer le comportement de prise de colorants anioniques directs, un procédé en deux étapes de coloration de fibres, ainsi qu'un produit à plusieurs constituants pour la coloration non oxydative de fibres (en particulier de fibres kératiniques telles que des cheveux humains) dont un constituant contient un colorant à base de substances colorantes anioniques directes et dont l'autre constituant contient les sels physiologiquement compatibles.
EP01921361A 2000-07-05 2001-03-29 Utilisation de sels pour ameliorer le comportement de prise de colorants anioniques directs Withdrawn EP1210061A1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10032752A DE10032752A1 (de) 2000-07-05 2000-07-05 Verwendung von Salzen zur Verbesserung des Aufziehverhaltens von anionischen direktziehenden Farbstoffen
DE10032752 2000-07-05
PCT/EP2001/003605 WO2002002062A1 (fr) 2000-07-05 2001-03-29 Utilisation de sels pour ameliorer le comportement de prise de colorants anioniques directs

Publications (1)

Publication Number Publication Date
EP1210061A1 true EP1210061A1 (fr) 2002-06-05

Family

ID=7647931

Family Applications (1)

Application Number Title Priority Date Filing Date
EP01921361A Withdrawn EP1210061A1 (fr) 2000-07-05 2001-03-29 Utilisation de sels pour ameliorer le comportement de prise de colorants anioniques directs

Country Status (6)

Country Link
US (1) US20020189031A1 (fr)
EP (1) EP1210061A1 (fr)
JP (1) JP2004501943A (fr)
AU (1) AU2001248361A1 (fr)
DE (1) DE10032752A1 (fr)
WO (1) WO2002002062A1 (fr)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1428497A1 (fr) * 2002-12-12 2004-06-16 KPSS-Kao Professional Salon Services GmbH Composition de prétraitment des cheveux avant coloration à l'aide des colorants directs acides
US6905523B2 (en) * 2003-03-13 2005-06-14 Aveda Corporation Hair color application using cluster-modified water
US7074244B2 (en) 2003-07-03 2006-07-11 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Hair dyeing method including an aligning step
US7060111B2 (en) 2003-07-03 2006-06-13 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Method for providing more vibrant, natural and long-lasting color to hair
EP1559403A1 (fr) * 2004-01-28 2005-08-03 KPSS-Kao Professional Salon Services GmbH Composition pour la teinture de cheveux humains
EP1759684A1 (fr) * 2005-09-02 2007-03-07 Wella Aktiengesellschaft Prodédé de décoloration de fibres kératiniques
EP2713989A2 (fr) * 2011-05-27 2014-04-09 The Procter and Gamble Company Article solide soluble de coloration capillaire
FR2990852A1 (fr) * 2012-05-24 2013-11-29 Oreal Colorant ou azurant anionique a contre ion ammonium ou phosphonium, composition de teinture les comprenant et procede de coloration des fibres keratiniques a partir de ces colorants
WO2017197099A1 (fr) * 2016-05-12 2017-11-16 L'oreal Procédés et compositions permettant d'améliorer la qualité et la durabilité de la couleur de cheveux artificiellement colorés
US9820922B1 (en) 2016-05-12 2017-11-21 L'oreal Methods and compositions for improving the quality and durability of color in artificially colored hair
US9839590B2 (en) 2016-05-12 2017-12-12 L'oreal Methods and compositions for improving the quality and durability of color in artificially colored hair
US9833394B1 (en) 2016-05-12 2017-12-05 L'oreal Methods and compositions for improving the quality and durability of color in artificially colored hair
US10363208B2 (en) * 2017-08-30 2019-07-30 L'oreal Methods for improving the durability of color in artificially colored hair
US10426716B2 (en) 2017-08-30 2019-10-01 L'oreal Compositions and methods for improving color deposit and durability of color in artificially colored hair
GB201800877D0 (en) 2018-01-19 2018-03-07 Perachem Ltd Method and composition
US10328009B1 (en) * 2018-03-29 2019-06-25 L'oreal Methods and compositions for improving the durability of color in artificially colored hair
FR3096896B1 (fr) * 2019-06-07 2025-10-31 Di Visco Nouvelle composition pour la coloration des cheveux
DE102019219650A1 (de) * 2019-12-16 2021-06-17 Henkel Ag & Co. Kgaa Tönungsconditioner mit verbesserter Färbeleistung
EP4410266A1 (fr) * 2023-01-31 2024-08-07 Kao Corporation Procédé de teinture de fibres kératiniques
FR3163862A1 (fr) * 2024-06-27 2026-01-02 L'oreal Procédé de coloration des cheveux comprenant l’application d’un un sel minéral et d’une composition comprenant un composé (poly)carbodiimide, un polymère spécifique et un agent colorant

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GB1241832A (en) * 1968-08-23 1971-08-04 Beecham Group Ltd Cosmetic preparations
DE19705875C1 (de) * 1997-02-15 1998-04-02 Wella Ag Mittel zum oxidativen Färben von Haaren
JPH11217319A (ja) * 1998-01-27 1999-08-10 Hoyu Co Ltd 染毛剤組成物
DE19941450A1 (de) * 1999-08-31 2001-03-01 Schwarzkopf Gmbh Hans Haarfärbeverfahren
US6540791B1 (en) * 2000-03-27 2003-04-01 The Procter & Gamble Company Stable alkaline hair bleaching compositions and method for use thereof

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Also Published As

Publication number Publication date
DE10032752A1 (de) 2002-01-31
US20020189031A1 (en) 2002-12-19
JP2004501943A (ja) 2004-01-22
WO2002002062A1 (fr) 2002-01-10
AU2001248361A1 (en) 2002-01-14

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