EP1211193A1 - Vakuumverpackung oder Verpackung unter modifizierter Atmosphäre von Flüssigkeiten absondernden Nahrungsmitteln - Google Patents
Vakuumverpackung oder Verpackung unter modifizierter Atmosphäre von Flüssigkeiten absondernden Nahrungsmitteln Download PDFInfo
- Publication number
- EP1211193A1 EP1211193A1 EP00830794A EP00830794A EP1211193A1 EP 1211193 A1 EP1211193 A1 EP 1211193A1 EP 00830794 A EP00830794 A EP 00830794A EP 00830794 A EP00830794 A EP 00830794A EP 1211193 A1 EP1211193 A1 EP 1211193A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- foil
- tray
- thermoplastic material
- gas
- expanded thermoplastic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 235000013305 food Nutrition 0.000 title claims abstract description 42
- 239000007788 liquid Substances 0.000 title claims abstract description 30
- 239000011888 foil Substances 0.000 claims abstract description 87
- 239000002131 composite material Substances 0.000 claims abstract description 72
- 239000000463 material Substances 0.000 claims abstract description 61
- 239000012815 thermoplastic material Substances 0.000 claims abstract description 59
- 229920003023 plastic Polymers 0.000 claims abstract description 54
- 239000004033 plastic Substances 0.000 claims abstract description 54
- 239000004094 surface-active agent Substances 0.000 claims abstract description 16
- 238000004321 preservation Methods 0.000 claims abstract 2
- 238000000034 method Methods 0.000 claims description 26
- 230000008878 coupling Effects 0.000 claims description 17
- 238000010168 coupling process Methods 0.000 claims description 17
- 238000005859 coupling reaction Methods 0.000 claims description 17
- 230000008569 process Effects 0.000 claims description 14
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 claims description 10
- 239000004715 ethylene vinyl alcohol Substances 0.000 claims description 10
- 239000004698 Polyethylene Substances 0.000 claims description 8
- 238000005098 hot rolling Methods 0.000 claims description 8
- 229920000573 polyethylene Polymers 0.000 claims description 8
- 238000002360 preparation method Methods 0.000 claims description 8
- 239000004793 Polystyrene Substances 0.000 claims description 7
- 229920001577 copolymer Polymers 0.000 claims description 7
- -1 polypropylene Polymers 0.000 claims description 7
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- UFRKOOWSQGXVKV-UHFFFAOYSA-N ethene;ethenol Chemical compound C=C.OC=C UFRKOOWSQGXVKV-UHFFFAOYSA-N 0.000 claims description 6
- 229920002223 polystyrene Polymers 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 6
- 239000004677 Nylon Substances 0.000 claims description 5
- 229920001778 nylon Polymers 0.000 claims description 5
- RZXDTJIXPSCHCI-UHFFFAOYSA-N hexa-1,5-diene-2,5-diol Chemical compound OC(=C)CCC(O)=C RZXDTJIXPSCHCI-UHFFFAOYSA-N 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- 239000004743 Polypropylene Substances 0.000 claims description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 3
- 229920001155 polypropylene Polymers 0.000 claims description 3
- 239000004800 polyvinyl chloride Substances 0.000 claims description 3
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 3
- 239000011343 solid material Substances 0.000 claims description 3
- 239000005995 Aluminium silicate Substances 0.000 claims description 2
- 239000005909 Kieselgur Substances 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 2
- 235000012211 aluminium silicate Nutrition 0.000 claims description 2
- 239000000440 bentonite Substances 0.000 claims description 2
- 229910000278 bentonite Inorganic materials 0.000 claims description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 2
- 239000004927 clay Substances 0.000 claims description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 2
- 239000010439 graphite Substances 0.000 claims description 2
- 229910002804 graphite Inorganic materials 0.000 claims description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 2
- 238000002844 melting Methods 0.000 claims description 2
- 230000008018 melting Effects 0.000 claims description 2
- 239000010445 mica Substances 0.000 claims description 2
- 229910052618 mica group Inorganic materials 0.000 claims description 2
- 239000005033 polyvinylidene chloride Substances 0.000 claims description 2
- 239000008262 pumice Substances 0.000 claims description 2
- 229920001059 synthetic polymer Polymers 0.000 claims description 2
- 239000007789 gas Substances 0.000 description 11
- 238000004806 packaging method and process Methods 0.000 description 9
- 230000004888 barrier function Effects 0.000 description 7
- 239000004794 expanded polystyrene Substances 0.000 description 7
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 230000008901 benefit Effects 0.000 description 5
- 238000009448 modified atmosphere packaging Methods 0.000 description 5
- 238000009461 vacuum packaging Methods 0.000 description 5
- 241000251468 Actinopterygii Species 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 238000005520 cutting process Methods 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 238000005096 rolling process Methods 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 238000003856 thermoforming Methods 0.000 description 4
- 239000001569 carbon dioxide Substances 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 239000011261 inert gas Substances 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 235000013372 meat Nutrition 0.000 description 3
- 238000007789 sealing Methods 0.000 description 3
- 238000003466 welding Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229940123973 Oxygen scavenger Drugs 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000008246 gaseous mixture Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 2
- 239000011800 void material Substances 0.000 description 2
- 241000755266 Kathetostoma giganteum Species 0.000 description 1
- 229910004727 OSO3H Inorganic materials 0.000 description 1
- 229910006069 SO3H Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 235000013601 eggs Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000007765 extrusion coating Methods 0.000 description 1
- 210000000416 exudates and transudate Anatomy 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000013012 foaming technology Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000010297 mechanical methods and process Methods 0.000 description 1
- 230000002906 microbiologic effect Effects 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 239000008239 natural water Substances 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D81/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
- B65D81/24—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants
- B65D81/26—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants with provision for draining away, or absorbing, or removing by ventilation, fluids, e.g. exuded by contents; Applications of corrosion inhibitors or desiccators
- B65D81/264—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants with provision for draining away, or absorbing, or removing by ventilation, fluids, e.g. exuded by contents; Applications of corrosion inhibitors or desiccators for absorbing liquids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D81/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
- B65D81/18—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents providing specific environment for contents, e.g. temperature above or below ambient
- B65D81/20—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents providing specific environment for contents, e.g. temperature above or below ambient under vacuum or superatmospheric pressure, or in a special atmosphere, e.g. of inert gas
Definitions
- the present invention relates to the field of modified atmosphere packaging or vacuum packaging of food products by means of packages made of plastic material.
- the invention relates to a package for food products comprising a tray made of thermoplastic material, having barrier properties with respect to gases and having absorbing power with respect to any liquid released by the food products, and a hermetically sealed cover for said tray.
- the present invention relates to a tray to be used in the aforesaid package and a process for the preparation of such tray.
- the second technique foresees instead the use of a tray of expanded plastic material wrapped externally by a gas-impermeable film.
- the food product is placed onto the bottom of the tray and this is closed by means of a plastic material film which is impermeable to gases.
- a modified atmosphere is set inside it in the above mentioned way.
- the third technique foresees the use of a tray made of expanded plastic material which is rendered gas-impermeable through the coupling of a film provided with gas-barrier properties onto the inner face of the tray. Before sealing it with a cover of gas-barrier film, the replacement of the air of the package with a suitable gas mixture is carried out.
- a drawback of the tray obtained by means of the aforesaid third technique is the impossibility of absorbing the liquids released by the food products, apart from using an absorbing pad between the food product and the bottom of the tray, which, however negatively influences the production costs and complicates the operations of disposal and recycle of the packages after use.
- a problem which has been encountered with the first two above mentioned techniques is the impossibility of removing completely the oxygen from the inner atmosphere of the tray, as the closed-cell structure of the trays in expanded plastic material holds air, notwithstanding the application of vacuum, in order to release it gradually in the space above the food product.
- oxygen scavengers chemical substances adapted to neutralise the residual oxygen
- iron and its derivatives in presence of acids such as iron and its derivatives in presence of acids (US 5 698 250).
- Patent Application WO 00/46125 describes a tray having absorbing properties which is suitable for vacuum packaging or modified atmosphere packaging of food products which may release liquids.
- a tray consists of a structure made of open cell plastic material enclosed between two films of which at least one is impermeable to the gases respectively applied onto its inner and outer surface.
- the film applied onto the inner surface is interrupted by perforations in order to allow the liquid to penetrate into a predetermined portion of the underlying open-cell structure.
- said portion is sealed by welding the two films in predetermined points in order to prevent the liquid provided inside it from migrating into the remaining open-cell structure of the tray.
- the films may be welded or glued in correspondence of the cutting surfaces provided at the ends of the edge in order to prevent the liquid from migrating outside of the tray.
- the technical problem at the basis of the present invention is that of providing a package for modified atmosphere packaging or vacuum packaging of food products susceptible of releasing liquids which would be of easier and more economical manufacture and which would allow to maintain substantially unaltered the gas atmosphere set inside it or the vacuum before use.
- a vacuum or modified atmosphere package for food products which are susceptible of releasing liquids, comprising:
- said tray consists of the aforesaid upper and lower layers and of a further layer arranged, at least in correspondence of the bottom, above the aforesaid upper layer and consisting of a non-expanded film or foil of plastic material, provided with through holes or slots on at least part of its upper surface.
- such film or foil is rendered opaque, to allow the concealment of the absorbed liquid.
- the opacification may be realised through incorporation of titanium dioxide into the plastic material.
- the gas-barrier composite film defining the cover is preferably adhered to the folded-up edge of the tray by means of heat sealing.
- Such film may be identical to the gas-barrier composite film which defines the lower layer of the tray and which is arranged above the upper layer of the tray in correspondence of the edge as a consequence of the folding.
- the gas-barrier composite film defining the lower layer and the cover of the tray is a multilayered film comprising at least one gas-barrier layer in plastic material and at least one layer made of a thermoplastic material.
- further layers may be foreseen in order to provide the structure of the aforesaid film with the desired mechanical and thickness characteristics.
- the material forming the gas-barrier layer may be chosen from the group comprising polymers and copolymers of ethylene vinyl alcohol (EVAL, EVOH), nylon, polyvinylidene chloride (PVDC), poly- or copolyamides and combination thereof.
- EVAL ethylene vinyl alcohol
- PVDC polyvinylidene chloride
- the aforesaid material is a polymer or copolymer of ethylene vinyl alcohol or nylon.
- multilayered barrier film of the above indicated type suitable to the purposes of the present invention are those described in the US Patent 4,735,855.
- Examples of particularly preferred multilayered gas-barrier films are the multilayered films produced and sold by the Firm B-PACK having a thickness of 50-60 micron and comprising a gas-barrier layer consisting of EVOH and two layers consisting of polyethylene (PE) and polystyrene (PS), respectively.
- the plastic material which forms the expanded foil having substantially open cells and the non-expanded film or foil of the tray is preferably chosen from the group comprising polystyrene, polypropylene, polyethylene, polyethylene terephtalate, polyvinyl chloride and their copolymers. Polystyrene is particularly preferred.
- the grams per square meter of the foil of open-cell thermoplastic material are preferably comprised in the range from 150 to 350 g/m 2 .
- the surfactant provides the capacity of absorbing aqueous liquids by the foil of open-cells thermoplastic material.
- It can be chosen among the conventional anionic, cationic and nonionic surfactants and is preferably a salt of a sulphonic acid having the formula R-SO 3 H or of a sulphonic ester having the formula R-OSO 3 H, wherein R is chosen from the group comprising alkyl and alkylaryl, with an alkaline metal or an alkaline-earth metal.
- a surfactant which is particularly useful for the purposes of the present invention is the aliphatic sulphonate sold by the firm NOVACROME with the name HOSTASTAT SYSTEM E 3904®.
- the layer of expanded open-cells plastic material advantageously contains a finely-divided solid material able to absorb the aforesaid smelly substances.
- a material like this is preferably chosen from the group comprising aluminium oxide, bentonite, kaolin, activated carbon, zeolites, synthetic polymers having a high melting point such as polyphenyloxide and polyimmides, graphite, mica, diatomaceous earth, pumice and clay.
- the packaging according to the present invention allows preserving perishable food products, such as meat and fish, for several days without any remarkable deterioration in their organoleptic and microbiological properties, concealing the exudate and absorbing possible smelly volatile substances into the layer of open-cells expanded plastic material.
- the packaging according to the present invention has the advantage of maintaining constant the atmosphere originally set inside it without any gas transportation taking place towards the outside or the inside of the package through the upper layer of open-cells thermoplastic material and the cutting surfaces of the tray provided in correspondence of the ends of the edge.
- the aforesaid cutting surfaces are turned towards the inside of the tray through the edge folding and are arranged below the gas-barrier composite film which forms the cover, preventing in such a way any exchange of gas with the outside.
- the air inside the tray may be completely removed by virtue of the open-cells structure of the layer of expanded plastic material and eventually replaced with the gaseous atmosphere of desired composition chosen as a function of the food product to be packaged.
- the absorption of the liquids released by the food products is not provided by the interposition of an absorbing pad between the food product and the bottom of the tray, but rather by exploiting the absorbing properties of the layer of expanded open-cells plastic material containing a surfactant.
- a material different from the plastic material of which the tray consists is thus avoided, i.e. a cellulosic material such as paper or paperboard, thus facilitating the disposal or recycle operations of the packages after their use.
- the tray of the aforesaid package comprises two layers and is obtained through a process according to any one of the claims 15 to 18.
- the tray of the aforesaid package comprises three layers and is obtained through a process according to any one of the claims 19 to 24.
- the coupling of the foil of open-cells thermoplastic material with the gas-barrier composite film and with the non-expanded foil may be realised by means of hot rolling, use of adhesives or any other method conventionally used for this purpose.
- the coupling by means of hot rolling is particularly preferred.
- the foil of open-cells thermoplastic material obtained through the conventional techniques of annular or flat-head extrusion with injection of expanding gases, may be initially hot-rolled with a non-expanded film or foil obtained through coextrusion or subsequently extruded through the techniques known as "extrusion coating", obtaining a first composite leaf.
- Such first composite leaf is perforated and rolled, in-line or out-of-line, with a gas-barrier composite film.
- This latter rolling operation is preferably carried out at a temperature comprised in the range 185-210 °C whereas the rolling of the foil of open-cells thermoplastic material with a non-expanded film or foil is preferably carried out at a temperature of 160-180°C.
- the holes or slots in the non-expanded film and in the foil of open-cells thermoplastic material may be made in a conventional way, for example by means of punching machines. Such perforations allow the passage of the liquid released by the food product contained in the tray into the foil of open-cells thermoplastic material.
- thermoforming of the semifinished tray and the folding of the respective edge are carried out in a conventional way, preferably by thermoforming in a dedicated mould at a temperature comprised in the range 160-220°C.
- thermoforming operations may be carried out in sequence in a single mould or in different moulds using suitable conventional methods, such as vacuum suction, compressed air injection, mechanical methods, etc.
- the package according to the present invention is obtained by means of procedures already known in the art, for example from the US Patent 5,744,181.
- the food product to be packed is placed onto the bottom of the above described tray and the tray is sealed under vacuum or under modified atmosphere by adhering a gas-barrier composite film onto the lower layer of the tray in correspondence of the folded edge.
- the aforesaid gas-barrier film is adhered onto the lower layer of the tray in correspondence of the folded edge through thermoforming.
- the package according to the invention may be under vacuum or under modified atmosphere.
- the modified atmosphere is obtained through application of vacuum and subsequent injection of inert gases, such as nitrogen and carbon dioxide, or of mixture containing oxygen according to the kind of food product to be packed and preserved.
- a package according to the invention comprises a tray 1 and a cover 2.
- the tray 1 has a bottom 3 onto which a food product 4 is placed before its packaging and side walls 5 which end up in a folded edge 6.
- the structure of the tray 1 consists of a foil 7 made of expanded polystyrene having substantially open cells, whose upper surface is coated by a non-expanded polystyrene film 8 and whose lower surface is coated by a multilayered film 9 comprising a gas-barrier layer made of EVOH or nylon.
- the film 8 has a plurality of holes 10 of predetermined diameter that extend into the thickness of the underlying expanded polystyrene foil 7 by a predetermined amount so as to allow the liquid released by the food product 4, in this specific instance meat, to penetrate into the substantially open cells of the foil 7 passing through such holes 10.
- the open cell structure of the foil 7 has a close network of capillary void channels which put the single cells in communication and allow them to receive and keep the liquid penetrated through the aforesaid holes 10.
- the liquid is kept like by a sponge, and, because of the strong capillary interactions between the void channels and the liquid, it cannot return onto the upper surface of the bottom 3 of the tray 1 by passing through the holes 10, even if this is inclined or even turned upside down.
- the penetration of the liquid is also enhanced by the presence of a surfactant in the foil 7; the surfactant, in fact, remarkably reduces the natural water repellency of the plastic material, increasing the adhesion forces between the solid (plastic material) and the liquid until these overcome the cohesion forces between the molecules of the liquid, thus allowing the liquid to penetrate into the structure provided with substantially open cells of the foil 7 through the holes 10.
- the folded edge 6 has a substantially U-shaped cross-section and comprises a first portion 11 protruding from the side walls 5 linked to a second folded portion 12.
- the multilayered barrier film 9 is arranged above the corresponding portion of the foil of expanded polystyrene 7.
- the cover 2 consists of a multilayered barrier film and is applied onto the tray 1 through heat welding in correspondence of the second portion 12 of the folded edge 6. Such a cover 2 is applied at the end of the packaging procedure, after having created the vacuum or modified the atmosphere inside the tray 1 in which the food product 4 has been placed.
- the package according to the invention has the advantage that the liquid released by the food products may be absorbed onto the entire inner surface of the tray because of its structural features which foresee an intermediate absorbing layer consisting of a foil of thermoplastic material with substantially open cells. Further on, any smelly volatile substances released by the food product (for example fish) may be absorbed by the active substances included into the porous open-cells foil.
- a further advantage of the package according to the present invention is the high effectiveness of the heat welding of the cover with the folded edge of the tray because, as a result of such folding, the materials which are welded together may be identical to each other or extremely compatible.
- a foil made of expanded polystyrene with substantially open cells having a weight (grams per square meter) of 300 g/m 2 , a thickness of 4,5 mm and a density of 60 g/l, was prepared by extrusion of a suitable mixture.
- the foil so produced was immediately sent to a hot rolling station in which a OPS-type opacified non-expanded polystyrene film, having a thickness of 25 micron, was applied in correspondence of a surface of such foil by rolling at a temperature of 160°C.
- the composite leaf thus obtained was perforated in correspondence of the free surface of the non-expanded polystyrene film by means of a plurality of metal nails.
- a multilayered barrier film of the PE//EVOH//PS type, produced by B-pack and having a thickness of 60 micron was applied in correspondence of the free surface of the aforesaid foil, thus obtaining a perforated composite leaf.
- This last rolling was carried out at a temperature of 170°C and a conveying speed of 15 m/min.
- the perforated composite leaf was sent into a thermoforming machine wherein it was taken to an average temperature of 200 °C and then thermoformed in a suitable mould obtaining a tray according to the present invention.
- the tray was sent to a packaging machine comprising a chamber equipped with a suitable mould and with apertures for the air intake and/or the inlet of a gaseous mixture.
- the cover consisted of a multilayered barrier film of the PE/EVOH/PE type and had a thickness of 50 micron.
- the chamber was then closed, the air contained therein was evacuated by applying a reduced pressure of 1-4 millibar and afterwards a gaseous mixture consisting of 70 % oxygen and 30 % carbon dioxide was introduced into the chamber.
- the aforesaid cover was heat welded onto the folded edge of the tray obtaining a package according to the invention.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Food Science & Technology (AREA)
- Packages (AREA)
- Laminated Bodies (AREA)
- Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
- Packging For Living Organisms, Food Or Medicinal Products That Are Sensitive To Environmental Conditiond (AREA)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT00830794T ATE288393T1 (de) | 2000-11-30 | 2000-11-30 | Vakuumverpackung oder verpackung unter modifizierter atmosphäre von flüssigkeiten absondernden nahrungsmitteln |
| DE60017920T DE60017920T2 (de) | 2000-11-30 | 2000-11-30 | Vakuumverpackung oder Verpackung unter modifizierter Atmosphäre von Flüssigkeiten absondernden Nahrungsmitteln |
| EP00830794A EP1211193B1 (de) | 2000-11-30 | 2000-11-30 | Vakuumverpackung oder Verpackung unter modifizierter Atmosphäre von Flüssigkeiten absondernden Nahrungsmitteln |
| ES00830794T ES2237402T3 (es) | 2000-11-30 | 2000-11-30 | Envase al vacio o con atmosfera modificada para alimentos que tienden a soltar liquidos. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP00830794A EP1211193B1 (de) | 2000-11-30 | 2000-11-30 | Vakuumverpackung oder Verpackung unter modifizierter Atmosphäre von Flüssigkeiten absondernden Nahrungsmitteln |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1211193A1 true EP1211193A1 (de) | 2002-06-05 |
| EP1211193B1 EP1211193B1 (de) | 2005-02-02 |
Family
ID=8175573
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP00830794A Expired - Lifetime EP1211193B1 (de) | 2000-11-30 | 2000-11-30 | Vakuumverpackung oder Verpackung unter modifizierter Atmosphäre von Flüssigkeiten absondernden Nahrungsmitteln |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP1211193B1 (de) |
| AT (1) | ATE288393T1 (de) |
| DE (1) | DE60017920T2 (de) |
| ES (1) | ES2237402T3 (de) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003006337A1 (en) * | 2001-07-12 | 2003-01-23 | Cryovac, Inc. | Self-absorbing gas-barrier receptacle for food packaging and food package obtained therefrom |
| EP1411003A1 (de) * | 2002-10-16 | 2004-04-21 | Magic Pack S.R.L. | Schale zur Aufnahme von Nahrungsmitteln sowie Verfahren und System zur Herstellung der Schale |
| EP1348640A3 (de) * | 2002-03-29 | 2004-08-11 | SIRAP-GEMA S.p.A. | Vakuumverpackung oder Verpackung unter modifizierter Atmosphäre von Flüssigkeiten absondernden Nahrungsmitteln |
| EP1484260A1 (de) * | 2003-06-02 | 2004-12-08 | Mark Ewald | Flüssigkeitsaufnahmeelement |
| DE10324821A1 (de) * | 2003-06-02 | 2005-01-05 | Ewald Mark | Flüssigkeitsaufnahmeelement |
| FR2859185A1 (fr) * | 2003-08-29 | 2005-03-04 | Huhtamaki France Sa | Barquette absorbante avec ou sans barriere et procede de fabrication |
| EP1659068A1 (de) | 2004-11-22 | 2006-05-24 | Coopbox Europe S.P.A. | Kunststoffschale für Einpackung von Lebensmitteln, die zu Flüssigkeitsabsonderung neigen |
| EP1950147A1 (de) * | 2006-12-15 | 2008-07-30 | Sagem S.r.l | Verpackung für Nahrungsmittelprodukte und Herstellungsverfahren dafür |
| FR2945280A1 (fr) * | 2009-05-07 | 2010-11-12 | Charal | Emballage avec absorbeur d'exsudats |
| WO2011067305A1 (en) | 2009-12-02 | 2011-06-09 | Cryovac, Inc. | Self-absorbing gas-barrier receptacle for food packaging and food package obtained therefrom |
| CN102514833A (zh) * | 2011-12-29 | 2012-06-27 | 红云红河烟草(集团)有限责任公司 | 一种烟用香糖料长期保存的方法 |
| WO2012114130A1 (en) * | 2011-02-25 | 2012-08-30 | Agri-Tech Global Technologies Limited | Containers and polymeric films having embedded micro-porous particles |
| CN113978039A (zh) * | 2021-07-27 | 2022-01-28 | 广东美士达药包材料股份有限公司 | 一种可防止高温高湿环境下出现分层的铝箔药品包装复合袋生产工艺 |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2308946B1 (es) * | 2008-05-16 | 2009-09-16 | Caladero, S.L. | Sistema de envasado para productos alimenticios procedentes del mar, frescos, congelados y/o vivos. |
| CN114801382B (zh) * | 2021-01-29 | 2024-01-05 | 湖北守护者检测科技有限公司 | 低挥发物聚合物高阻隔膜材料及其制备方法 |
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| US3574642A (en) | 1969-05-15 | 1971-04-13 | American Can Co | Package for and method of packaging meats |
| US3610509A (en) | 1969-05-27 | 1971-10-05 | Thomas W Winstead | Skin-coated article formed of foamed thermoplastic material |
| EP0090507A1 (de) | 1982-03-22 | 1983-10-05 | Mobil Oil Corporation | Kondensatabsorbierendes Verpackungsmaterial für Schnellimbiss und Verpackungsverfahren |
| US4735855A (en) | 1986-08-04 | 1988-04-05 | W. R. Grace & Co., Cryovac Div. | Thermoformable laminate |
| US5115624A (en) | 1985-11-14 | 1992-05-26 | Seawell Corporation N.V. | Thermoplastic skin packing means |
| EP0642907A2 (de) | 1993-08-02 | 1995-03-15 | Hoechst Aktiengesellschaft | Formgebilde aus einem thermoplastischen Kunststoff, Verfahren zu seiner Herstellung sowie seine Verwendung |
| EP0690013A1 (de) * | 1994-06-27 | 1996-01-03 | Synbra Technology B.V. | Schale aus Schaumkunststoff |
| WO1997036504A1 (en) | 1996-04-03 | 1997-10-09 | Tenneco Packaging Inc. | Modified atmosphere package |
| US5744181A (en) | 1995-03-01 | 1998-04-28 | W. R. Grace & Co.-Conn. | Packaging method using thermoplastic materials and package obtained thereby |
| EP0849309A1 (de) | 1996-12-18 | 1998-06-24 | SIRAP-GEMA S.p.A. | Verfahren zur Herstellung einer offenzelligen Polystyrolschaumfolie und daraus hergestellte Verpackungsschale |
| DE29723954U1 (de) * | 1996-09-19 | 1999-12-02 | Linpac Plastics Ltd., Knottingley, West Yorkshire | Schale zur Aufnahme von Flüssigkeiten absondernden Nahrungs- und Genußmitteln |
| WO2000026113A1 (en) | 1998-10-29 | 2000-05-11 | Edward Armando Colombo | Packaging system for preserving perishable items |
| WO2000046125A1 (en) | 1999-02-06 | 2000-08-10 | Linpac Plastics Limited | Packaging tray formed from absorbant material |
-
2000
- 2000-11-30 EP EP00830794A patent/EP1211193B1/de not_active Expired - Lifetime
- 2000-11-30 AT AT00830794T patent/ATE288393T1/de not_active IP Right Cessation
- 2000-11-30 ES ES00830794T patent/ES2237402T3/es not_active Expired - Lifetime
- 2000-11-30 DE DE60017920T patent/DE60017920T2/de not_active Expired - Fee Related
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3574642A (en) | 1969-05-15 | 1971-04-13 | American Can Co | Package for and method of packaging meats |
| US3610509A (en) | 1969-05-27 | 1971-10-05 | Thomas W Winstead | Skin-coated article formed of foamed thermoplastic material |
| EP0090507A1 (de) | 1982-03-22 | 1983-10-05 | Mobil Oil Corporation | Kondensatabsorbierendes Verpackungsmaterial für Schnellimbiss und Verpackungsverfahren |
| US5115624A (en) | 1985-11-14 | 1992-05-26 | Seawell Corporation N.V. | Thermoplastic skin packing means |
| US4735855A (en) | 1986-08-04 | 1988-04-05 | W. R. Grace & Co., Cryovac Div. | Thermoformable laminate |
| EP0642907A2 (de) | 1993-08-02 | 1995-03-15 | Hoechst Aktiengesellschaft | Formgebilde aus einem thermoplastischen Kunststoff, Verfahren zu seiner Herstellung sowie seine Verwendung |
| EP0690013A1 (de) * | 1994-06-27 | 1996-01-03 | Synbra Technology B.V. | Schale aus Schaumkunststoff |
| US5744181A (en) | 1995-03-01 | 1998-04-28 | W. R. Grace & Co.-Conn. | Packaging method using thermoplastic materials and package obtained thereby |
| WO1997036504A1 (en) | 1996-04-03 | 1997-10-09 | Tenneco Packaging Inc. | Modified atmosphere package |
| US5698250A (en) | 1996-04-03 | 1997-12-16 | Tenneco Packaging Inc. | Modifield atmosphere package for cut of raw meat |
| DE29723954U1 (de) * | 1996-09-19 | 1999-12-02 | Linpac Plastics Ltd., Knottingley, West Yorkshire | Schale zur Aufnahme von Flüssigkeiten absondernden Nahrungs- und Genußmitteln |
| EP0849309A1 (de) | 1996-12-18 | 1998-06-24 | SIRAP-GEMA S.p.A. | Verfahren zur Herstellung einer offenzelligen Polystyrolschaumfolie und daraus hergestellte Verpackungsschale |
| WO2000026113A1 (en) | 1998-10-29 | 2000-05-11 | Edward Armando Colombo | Packaging system for preserving perishable items |
| WO2000046125A1 (en) | 1999-02-06 | 2000-08-10 | Linpac Plastics Limited | Packaging tray formed from absorbant material |
Non-Patent Citations (1)
| Title |
|---|
| KLEMPNER AND FRISCH: "Handbook of Polymeric Foams and Foam Technology", 1991, CARL HANSER VERLAG |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003006337A1 (en) * | 2001-07-12 | 2003-01-23 | Cryovac, Inc. | Self-absorbing gas-barrier receptacle for food packaging and food package obtained therefrom |
| US6983575B2 (en) | 2001-07-12 | 2006-01-10 | Cryovac, Inc. | Self-absorbing gas-barrier receptacle for food packaging and food package obtained therefrom |
| EP1348640A3 (de) * | 2002-03-29 | 2004-08-11 | SIRAP-GEMA S.p.A. | Vakuumverpackung oder Verpackung unter modifizierter Atmosphäre von Flüssigkeiten absondernden Nahrungsmitteln |
| EP1411003A1 (de) * | 2002-10-16 | 2004-04-21 | Magic Pack S.R.L. | Schale zur Aufnahme von Nahrungsmitteln sowie Verfahren und System zur Herstellung der Schale |
| EP1484260A1 (de) * | 2003-06-02 | 2004-12-08 | Mark Ewald | Flüssigkeitsaufnahmeelement |
| DE10324821A1 (de) * | 2003-06-02 | 2005-01-05 | Ewald Mark | Flüssigkeitsaufnahmeelement |
| FR2859185A1 (fr) * | 2003-08-29 | 2005-03-04 | Huhtamaki France Sa | Barquette absorbante avec ou sans barriere et procede de fabrication |
| EP1510470A3 (de) * | 2003-08-29 | 2005-12-14 | Huhtamaki France S.A. | Absorbierende Schale mit oder ohne Barriereschicht und Herstellungsverfahren |
| EP1659068A1 (de) | 2004-11-22 | 2006-05-24 | Coopbox Europe S.P.A. | Kunststoffschale für Einpackung von Lebensmitteln, die zu Flüssigkeitsabsonderung neigen |
| EP1950147A1 (de) * | 2006-12-15 | 2008-07-30 | Sagem S.r.l | Verpackung für Nahrungsmittelprodukte und Herstellungsverfahren dafür |
| FR2945280A1 (fr) * | 2009-05-07 | 2010-11-12 | Charal | Emballage avec absorbeur d'exsudats |
| WO2011067305A1 (en) | 2009-12-02 | 2011-06-09 | Cryovac, Inc. | Self-absorbing gas-barrier receptacle for food packaging and food package obtained therefrom |
| WO2012114130A1 (en) * | 2011-02-25 | 2012-08-30 | Agri-Tech Global Technologies Limited | Containers and polymeric films having embedded micro-porous particles |
| CN102514833A (zh) * | 2011-12-29 | 2012-06-27 | 红云红河烟草(集团)有限责任公司 | 一种烟用香糖料长期保存的方法 |
| CN113978039A (zh) * | 2021-07-27 | 2022-01-28 | 广东美士达药包材料股份有限公司 | 一种可防止高温高湿环境下出现分层的铝箔药品包装复合袋生产工艺 |
| CN113978039B (zh) * | 2021-07-27 | 2023-06-30 | 广东美士达药包材料股份有限公司 | 一种可防止高温高湿环境下出现分层的铝箔药品包装复合袋生产工艺 |
Also Published As
| Publication number | Publication date |
|---|---|
| DE60017920D1 (de) | 2005-03-10 |
| EP1211193B1 (de) | 2005-02-02 |
| ATE288393T1 (de) | 2005-02-15 |
| ES2237402T3 (es) | 2005-08-01 |
| DE60017920T2 (de) | 2006-04-13 |
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