EP1242193A2 - Procede de fabrication de surfaces metalliques a revetement et utilisation desdites surfaces - Google Patents

Procede de fabrication de surfaces metalliques a revetement et utilisation desdites surfaces

Info

Publication number
EP1242193A2
EP1242193A2 EP00983330A EP00983330A EP1242193A2 EP 1242193 A2 EP1242193 A2 EP 1242193A2 EP 00983330 A EP00983330 A EP 00983330A EP 00983330 A EP00983330 A EP 00983330A EP 1242193 A2 EP1242193 A2 EP 1242193A2
Authority
EP
European Patent Office
Prior art keywords
coating
pretreatment agent
layer
pretreatment
powder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP00983330A
Other languages
German (de)
English (en)
Other versions
EP1242193B1 (fr
Inventor
Heribert Domes
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chemetall GmbH
Original Assignee
Chemetall GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chemetall GmbH filed Critical Chemetall GmbH
Publication of EP1242193A2 publication Critical patent/EP1242193A2/fr
Application granted granted Critical
Publication of EP1242193B1 publication Critical patent/EP1242193B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50Multilayers
    • B05D7/52Two layers
    • B05D7/54No clear coat specified
    • B05D7/544No clear coat specified the first layer is let to dry at least partially before applying the second layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/10Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by other chemical means
    • B05D3/102Pretreatment of metallic substrates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/14Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions

Definitions

  • the invention relates to a method for producing coated metal surfaces, in which the coating can be carried out at high speed.
  • Such coatings are used today under the term "coil coating” for coating tapes.
  • the known high-speed coating processes have the disadvantage that the pretreatment and the primer are applied in two separate steps.
  • the object of the invention is to propose a process for the large-scale production of lacquered tapes, in which the pretreatment and priming can be applied in a single operation.
  • the object is achieved by a process for the production of coated metal surfaces at a coating speed of at least 25 m per minute when a pretreatment agent is applied to a cleaned or / and pickled metal surface, which is characterized in that on at least one surface of a metallic body according to a Cleaning or / and pickling the metallic surface to be treated, at least one pretreatment agent, in particular a solution and / or dispersion, is applied and then at least one layer of varnish is applied to part of the pretreated surface, with only one pretreatment agent and not one Paint produced coating is used as a treatment layer instead of a pretreatment and a primer layer.
  • a pretreatment agent in particular a solution and / or dispersion
  • the object is achieved by a method for producing coated metal surfaces at a coating speed of at least 25 m per minute when applying a pretreatment agent to a cleaned or / and pickled metal surface, which is characterized in that at least one pretreatment agent, in particular, on at least one surface of a metallic body after cleaning and / or pickling the metal surface to be treated a solution or / and dispersion is applied and then at least one lacquer layer is applied to at least part of the pretreated surface, the coating treated with a pretreatment agent being used as a treatment layer instead of a pretreatment and a primer layer and.
  • the pretreated surface or the pretreated surfaces will preferably be one side of a band, on which at least one of the narrow edge surfaces of the band may also have been partially pretreated.
  • the coating speed is preferably 40 to 600 m per minute, particularly preferably 75 to 160 m per minute.
  • the treatment layer takes over the functions of the primer.
  • the other part of the pretreated surface is no longer coated with a varnish on the coil coating system.
  • the method according to the invention can be used in such a way that moisture or residual moisture in the applied pretreatment layer is retained until it is coated in order to adjust the electrical conductivity of the pretreated surface which is necessary for the application of the coating layer.
  • the metal surface can contain in particular aluminum, iron, copper, magnesium, zinc and / or tin and can preferably be made of an aluminum alloy, a hot-dip galvanized or electrolytically galvanized iron material, a steel, a solid zinc material in the form of strips or sheets or one Tinplate exist.
  • the bodies can be flat or deformed, without or with recesses such as a perforated structure his.
  • the recesses of a perforated plate can all have the same or, if appropriate, also different geometries and sizes: for example circular holes, elongated holes, slots.
  • the cleaning or / and pickling of the metallic surface can be done by spraying or / and brushing with a cleaning or pickling solution or dipping into a bath of this solution.
  • the pretreatment of the cleaned or / and pickled surface can be carried out by spraying and squeezing e.g. with a roller, by spraying and blowing off e.g. with compressed air, by dipping and squeezing e.g. with a roller, by dipping and blowing off e.g. with compressed air or in the roll-coat process.
  • the treatment liquid is applied with a coating roller in or against the direction of the belt.
  • no subsequent rinsing is carried out in order to avoid erosion or damage to the applied layer and to avoid rinsing water contaminated with chemicals, which have to be post-treated for environmental reasons.
  • the pretreatment agent can be a preparation which contains a polymer dispersion with at least one resin from the group consisting of acrylate, epoxy, phenol, polyester, silicone polyester, polyurethane, styrene and resin based on urea-formaldehyde or a mixture thereof and / or a copolymer.
  • the preparation contains a non-volatile film-forming mixture.
  • the preparation can contain at least one resin as a solution and / or as a dispersion.
  • the preparation can contain at least one inorganic additive in dissolved form and / or as a finely divided powder, e.g. contain a carbonate, chromate, oxide, phosphate, silicate, sulfate.
  • the pretreatment agent can also be a resin-free preparation, the preparation being aluminum, fluoride, hydrofluoric acid, phosphate, phosphoric acid, three- or / and hexavalent chromate, chromic acid, silicate, silane, tannin, titanium, zinc, zirconium and / or self-organizing molecules, for example based on phosphonates, carboxylic acids, thiols and / or silanes.
  • a different pretreatment agent can be selected for one side of the tape than for the other side, wherein the side not intended for subsequent painting can be coated with a pretreatment agent containing organic resin.
  • a pretreatment agent containing organic resin e.g. only one side of a volume - e.g. the top - painted, while on the opposite side the pre-treatment acts as a finishing treatment.
  • the layer can either be partially dried or thoroughly dried. This can be implemented - in particular with the same belt speed and when using existing ovens - by a shorter dwell time under the active drying conditions, by a lower temperature in the oven or / and by less air movement for drying the belt.
  • At least one side of the pretreated surface is preferably coated with an organic coating which hardens or crosslinks sufficiently in a time of 1 second to 3 minutes, particularly preferably in a time of 5 seconds to 2 minutes.
  • a powder coating is preferably applied and baked, in particular a powder coating with good mechanical properties, high scratch resistance, good adhesion and high flexibility with regard to the forming.
  • the powder coating can be applied or burned in by spraying, fluidized bed sintering and / or powder cloud technology. Powder cloud technology is described, inter alia, in EP-A-0 678 466.
  • the stoving can be used instead of conventional forced air drying or floating forced air drying in particular by conductive drying in the case of magnetic materials or by infrared drying, in particular in the near infrared (NIR).
  • the pretreatment or treatment layer can have a layer thickness in the range from 0.1 to 50 ⁇ m, preferably in the range from 0.5 to 10 ⁇ m, very particularly preferably in the range from 1 to 3 ⁇ m.
  • the baked lacquer layer which is located on the pretreatment layer, can have a layer thickness after crosslinking in the range from 5 to 1000 ⁇ m, preferably in the range from 10 to 400 ⁇ m, very particularly preferably in the range from 15 to 60 ⁇ m.
  • a layer thickness in the range of 100 to 300 ⁇ m.
  • a single-layer topcoat is applied as the only lacquer to the strip to be coated.
  • a treatment layer can be formed with the pretreatment agent, which takes on the function of a pretreatment and at the same time a primer.
  • the primer takes on the function of corrosion protection, adhesion and flexibility, but not to a greater extent also an aesthetic function.
  • a powder for a monochrome unstructured coating, a powder for a multicolored unstructured coating or / and a powder for a multicolored structured coating can be used in the powder coating.
  • the coated surface can be at least partially protected by a film or adhesive film, in particular against mechanical impairment, for example during storage, transport and further processing.
  • the coated bodies can optionally be deformed, cut - in particular cut lengthways and / or in the transverse direction - and optionally deformed again, such as, for example, flared, roll-formed, deep-drawn and / or folded.
  • the products produced by the process according to the invention can be used as inner and outer cladding, device cladding e.g. for household appliances and small electrical appliances, in particular with decorated outer cladding, perforated plates, in particular for loudspeakers and soundproofing linings, room dividers, partitions, furniture elements, shelves, vehicle and aircraft interior linings such as Dashboards, frames and frame constructions, facings, lighting fixtures are used.
  • device cladding e.g. for household appliances and small electrical appliances, in particular with decorated outer cladding, perforated plates, in particular for loudspeakers and soundproofing linings, room dividers, partitions, furniture elements, shelves, vehicle and aircraft interior linings such as Dashboards, frames and frame constructions, facings, lighting fixtures are used.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Laminated Bodies (AREA)
  • Chemically Coating (AREA)
  • Paints Or Removers (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)
EP00983330A 1999-12-17 2000-12-14 Procede de fabrication de surfaces metalliques a revetement et utilisation desdites surfaces Expired - Lifetime EP1242193B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE19961411 1999-12-17
DE19961411A DE19961411A1 (de) 1999-12-17 1999-12-17 Verfahren zur Herstellung von beschichteten Metalloberflächen und deren Verwendung
PCT/EP2000/012745 WO2001043888A2 (fr) 1999-12-17 2000-12-14 Procede de fabrication de surfaces metalliques a revetement et utilisation desdites surfaces

Publications (2)

Publication Number Publication Date
EP1242193A2 true EP1242193A2 (fr) 2002-09-25
EP1242193B1 EP1242193B1 (fr) 2003-08-27

Family

ID=7933395

Family Applications (1)

Application Number Title Priority Date Filing Date
EP00983330A Expired - Lifetime EP1242193B1 (fr) 1999-12-17 2000-12-14 Procede de fabrication de surfaces metalliques a revetement et utilisation desdites surfaces

Country Status (10)

Country Link
US (1) US20030051772A1 (fr)
EP (1) EP1242193B1 (fr)
CN (1) CN1409657A (fr)
AT (1) ATE248032T1 (fr)
AU (1) AU774014C (fr)
CA (1) CA2394235A1 (fr)
DE (2) DE19961411A1 (fr)
ES (1) ES2203539T3 (fr)
WO (1) WO2001043888A2 (fr)
ZA (1) ZA200205289B (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10400337B2 (en) 2012-08-29 2019-09-03 Ppg Industries Ohio, Inc. Zirconium pretreatment compositions containing lithium, associated methods for treating metal substrates, and related coated metal substrates
US11518960B2 (en) 2016-08-24 2022-12-06 Ppg Industries Ohio, Inc. Alkaline molybdenum cation and phosphonate-containing cleaning composition
EP4273470A1 (fr) 2022-05-06 2023-11-08 Commissariat à l'énergie atomique et aux énergies alternatives Procédé de traitement de surface pour améliorer la performance d'un système thermodynamique avec cycle à absorption

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CN1320163C (zh) * 2003-10-28 2007-06-06 尚志精密化学股份有限公司 电泳涂装上漆方法
DE102005045034A1 (de) * 2005-09-21 2007-03-29 Rasselstein Gmbh Verfahren zur Passivierung der Oberfläche von beschichteten Metallbändern und Vorrichtung für das Aufbringen der Passivschicht auf ein metallisch beschichtetes Stahlband
DE102008059014A1 (de) 2008-05-28 2009-12-03 Basf Coatings Ag Verfahren zur Beschichtung von Metallbändern
JP5079037B2 (ja) * 2010-02-26 2012-11-21 住友軽金属工業株式会社 電気あるいは電子機器筐体用の導電性プレコートアルミニウム合金板
PL2890830T3 (pl) 2012-08-29 2019-01-31 Ppg Industries Ohio, Inc. Kompozycje cyrkonowe do obróbki wstępnej zawierające molibden, powiązane sposoby obróbki podłoży metalicznych i powiązane powlekane podłoża metaliczne
CN102896082B (zh) * 2012-10-22 2014-11-05 江苏奥新新能源汽车有限公司 一种涂装工艺
CN105457872A (zh) * 2015-12-31 2016-04-06 芜湖市金宇石化设备有限公司 一种车架的涂装工艺
CN107321575B (zh) * 2017-07-03 2019-06-07 重庆科技学院 点焊合金粉末辊涂器
DE102018209553A1 (de) * 2018-06-14 2019-12-19 Voestalpine Stahl Gmbh Verfahren zur herstellung von lackbeschichteten elektrobändern und lackbeschichtetes elektroband
CN109107857A (zh) * 2018-11-08 2019-01-01 北京星航机电装备有限公司 一种超音速飞行器弹体表面涂装方法

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US5279863A (en) * 1989-10-10 1994-01-18 David A. Lundy Electrostatic powder coating apparatus and method
US5059446A (en) * 1990-02-14 1991-10-22 Armco Inc. Method of producing plastic coated metal strip
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DE4409306A1 (de) * 1994-03-18 1995-09-21 Basf Ag Verfahren zur Modifizierung von Metalloberflächen
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10400337B2 (en) 2012-08-29 2019-09-03 Ppg Industries Ohio, Inc. Zirconium pretreatment compositions containing lithium, associated methods for treating metal substrates, and related coated metal substrates
US11518960B2 (en) 2016-08-24 2022-12-06 Ppg Industries Ohio, Inc. Alkaline molybdenum cation and phosphonate-containing cleaning composition
EP4273470A1 (fr) 2022-05-06 2023-11-08 Commissariat à l'énergie atomique et aux énergies alternatives Procédé de traitement de surface pour améliorer la performance d'un système thermodynamique avec cycle à absorption
FR3135316A1 (fr) 2022-05-06 2023-11-10 Commissariat A L'energie Atomique Et Aux Energies Alternatives Procede de traitement de surface pour ameliorer la performance d’un systeme thermodynamique avec cycle a absorption

Also Published As

Publication number Publication date
DE19961411A1 (de) 2001-06-21
CN1409657A (zh) 2003-04-09
AU774014C (en) 2005-04-28
ZA200205289B (en) 2003-07-28
EP1242193B1 (fr) 2003-08-27
AU2010401A (en) 2001-06-25
WO2001043888A3 (fr) 2001-12-06
CA2394235A1 (fr) 2001-06-21
ATE248032T1 (de) 2003-09-15
AU774014B2 (en) 2004-06-10
US20030051772A1 (en) 2003-03-20
DE50003490D1 (de) 2003-10-02
ES2203539T3 (es) 2004-04-16
WO2001043888A2 (fr) 2001-06-21

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