EP1434566A2 - Mousses nettoyantes cosmetiques - Google Patents

Mousses nettoyantes cosmetiques

Info

Publication number
EP1434566A2
EP1434566A2 EP02774663A EP02774663A EP1434566A2 EP 1434566 A2 EP1434566 A2 EP 1434566A2 EP 02774663 A EP02774663 A EP 02774663A EP 02774663 A EP02774663 A EP 02774663A EP 1434566 A2 EP1434566 A2 EP 1434566A2
Authority
EP
European Patent Office
Prior art keywords
preparation according
cleaning
cleaning preparation
surfactant
foam
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP02774663A
Other languages
German (de)
English (en)
Inventor
Harald Albrecht
Stephan Ruppert
Petra Koch
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beiersdorf AG
Original Assignee
Beiersdorf AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Beiersdorf AG filed Critical Beiersdorf AG
Publication of EP1434566A2 publication Critical patent/EP1434566A2/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/046—Aerosols; Foams
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60—Sugars; Derivatives thereof
    • A61K8/602—Glycosides, e.g. rutin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair

Definitions

  • the present invention relates to a cosmetic cleaning agent which is a combination of packaging and application agent and a liquid cleaning preparation and is converted into a stable foam with the aid of the applicator.
  • Foams are structures made of gas-filled, spherical or polyhedral cells, which are delimited by liquid, semi-liquid, highly viscous or solid cell bridges.
  • the cell bridges connected via so-called nodes, form a coherent framework.
  • the foam lamellae (closed-cell foam) stretch between the cell bars. If the foam lamellae are destroyed or flow back into the cell webs at the end of foam formation, an open-line foam is obtained.
  • Foams are also thermodynamically unstable, since surface energy can be obtained by reducing the surface. The stability and therefore the existence of a foam depends on the extent to which it can prevent its self-destruction.
  • Cosmetic foams are generally dispersed systems composed of liquids and gases, the liquid being the dispersant and the gas being the dispersed substance. Foams made from low-viscosity liquids are temporarily stabilized by surface-active substances (surfactants, foam stabilizers). Because of their large inner surface, such surfactant foams have a strong adsorption capacity, which is used, for example, in cleaning and washing processes. Accordingly, cosmetic foams are particularly found in the
  • foam gas is blown into suitable liquids, or foam formation is achieved by vigorous beating, shaking, spraying or stirring the liquid in the gas atmosphere in question, provided that the liquids contain suitable surfactants or other surface-active substances (so-called foaming agents) that besides interfacial activity also possess a certain film-forming ability.
  • suitable surfactants or other surface-active substances so-called foaming agents
  • Cosmetic foams have the advantage over other cosmetic preparations in that they allow a fine distribution of active ingredients on the skin.
  • cosmetic foams can generally only be achieved by using special surfactants, which are also often not very kind to the skin.
  • Foam formation is caused by mechanical pump systems - as described in WO 00/78629 A1 - in which the liquid surfactant preparation for fine-pore air enrichment is passed through a sieve-like fabric or a similar structure at high speed in order to achieve the desired foam formation.
  • a design change of known pump foamers can reduce the penetration (suction) of spray water and thus the contamination problem so much that there is almost no need to add disinfectants / preservatives / bactericides to the surfactant preparation, which in turn is a decisive advantage in terms of skin compatibility.
  • the splash water protection on the foam pumping system is brought about by the ventilation openings or channels being protected by a shield-like or roof-like collar, so that splashing water is guided past the ventilation openings.
  • the collar is shaped in such a way that it reliably prevents the splash water from penetrating into the inner construction or is derived from the sensitive inner construction, so that contact of the microbiologically contaminated water with the surfactant preparation in any form is excluded.
  • the pump foamers from Airspray International BV are preferred, particularly preferably the splash-proof pump foamers (Airspray International BV, type
  • Airspray International BV type
  • a cosmetic cleaning product would comprise
  • a pump foamer containing a storage container and a pump mechanism designed as a closure with a riser pipe for foaming the surfactant solution in the storage container helps to solve the problem of odor and color, since this combination of surfactants produces an excellent foam and has almost no inherent odor and is colorless.
  • the admixture of active ingredients and auxiliary substances is possible within certain concentration ranges without loss of foam quality. This makes it possible to combine cleaning and skin care in one product and a very pleasant feeling on the skin is achieved after cleaning.
  • low concentrations of water-insoluble emollients are within the meaning of the invention.
  • the nonionic surfactant (s) are preferably used
  • alkanolamides such as cocamides MEA / DEA / MIPA
  • amine oxides such as cocoamidopropylamine oxide
  • esters which are formed by esterification of carboxylic acids with ethylene oxide, glycerol, sorbitan or other alcohols,
  • ethers for example ethoxylated / propoxylated alcohols, ethoxylated / propoxylated esters, ethoxylated / propoxylated glycerol esters, ethoxylated / propoxylated cholesterols, ethoxylated / propoxylated triglyceride esters, ethoxylated propoxylated lanolin, ethoxylated / propoxylated polysiloxanes, propoxylated POE ethers, and alkylpolyglycosyl such as lauryl polyglycosides, Decylglycoside and cocoglycoside.
  • alkylpolyglycosyl such as lauryl polyglycosides, Decylglycoside and cocoglycoside.
  • sucrose esters, ethers 7 polyglycerol esters, diglycerol esters, monoglycerol esters 8. methyl glucose esters, esters of hydroxy acids
  • alkyl polyglucosides in particular lauryl glucoside, decyl glycoside and cocoglycoside, have proven to be advantageous.
  • the anionic surfactant (s) are selected from the groups acylamino acids and their salts, carboxylic acids and their derivatives, phosphoric acid esters and their salts, sulfonic acids and their salts and sulfuric acid esters.
  • the compounds listed in each case are preferably used as anionic surfactants.
  • acylglutamates for example sodium acylglutamate, di-TEA-palmitoylaspartate and sodium caprylic / capric glutamate, sodium cocoylglutamate
  • acylpeptides for example palmitoyl-hydrolysed milk protein, sodium cocoyl-hydrolyzed soy protein and sodium / potassium-cocoylagenyside
  • sarcosinates for example myristoyl sarcosin, TEA-lauroyl sarcosinate, sodium lauroyl sarcosinate and sodium cocoyl sarcosinate
  • taurates for example sodium lauroyl taurate and sodium methyl cocoyl taurate
  • Carboxylic acids and derivatives such as 1. carboxylic acids, for example lauric acid, aluminum stearate, magnesium alkanolate and zinc undecylenate,
  • ester carboxylic acids for example calcium stearoyl lactylate, laureth-6 citrate and sodium PEG-4 lauramide carboxylate
  • ether carboxylic acids for example sodium laureth-13 carboxylate
  • Phosphoric acid esters and salts such as DEA-oleth-10-phosphate and dilaureth-4-phosphate
  • Sulfonic acids and salts such as 1. acyl isethionates, e.g. Sodium / ammonium cocoyl isethionate,
  • alkyl sulfonates for example sodium cocosmonoglyceride sulfate, sodium C 12-14 olefin sulfonate, sodium lauryl sulfoacetate and magnesium PEG-3 cocamide sulfate, 4.
  • sulfosuccinates for example dioctyl sodium sulfosuccinate, disodium laureth sulfosuccinate, disodium lauryl sulfosuccinate and sulfosuccinate sulfonate sulfosuccinate and sulfosuccinate sulfonate and sulfosuccinate sulfonate and disodium aminosulfinate sulfonate and sulfosuccinate sulfonate and disodium aminosulfinate sulfonate and sulfosuccinate sulfonate and sulfosuccinate
  • V. sulfuric acid esters such as 1. alkyl ether sulfate, for example sodium, ammonium, magnesium, MIPA,
  • TIPA laureth sulfate sodium myreth sulfate and sodium C 12-13 pareth sulfate, 2. alkyl sulfates, for example sodium, ammonium and TEA lauryl sulfate.
  • alcyl glutamates in particular sodium cocoyl glutamate, have proven to be advantageous.
  • Surfactant concentrations in the range from 2 to 15% by weight, in particular in the range from 4 to 9% by weight (always based on the total weight of the formulation) are particularly advantageous.
  • the ratio of anionic to nonionic surfactant should be like a to b - with a and b having a rational number between 2 and 5.
  • An optionally desired oil component of the cosmetic or dermatological cleaning preparations in the sense of the present invention is advantageously selected from the group of esters from saturated and / or unsaturated, branched and / or unbranched alkane carboxylic acids with a chain length of 3 to 30 carbon atoms and saturated and / or unsaturated , branched and / or unbranched alcohols with a chain length of 3 to 30 carbon atoms, from the group of esters of aromatic carboxylic acids and saturated and / or unsaturated, branched and / or unbranched alcohols with a chain length of 3 to 30 carbon atoms.
  • ester oils can then advantageously be selected from the group of isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl oleate, n-butyl stearate, n-hexyl laurate, n-decyl oleate, isooctyl stearate, isononyl stearate, isononylisononanoate, ethyl-2-ethylhexyl, ethyl-2-ethylhexyl 2-hexyldecyl stearate, 2-octyldodecyl palmitate, oleyl oleate, olerlerucate, erucyl oleate, erucylerucate as well as synthetic, semi-synthetic and natural mixtures of such esters, e.g.
  • the oil component can advantageously be selected from the group of branched and unbranched hydrocarbons and waxes, the silicone oils, the dialkyl ethers, the group of saturated or unsaturated, branched or unbranched alcohols, and also the fatty acid triglycerides, especially the triglycerol esters of saturated and / or unsaturated, branched and / or unbranched alkane carboxylic acids with a chain length of 8 to 24, in particular 12 to 18, carbon atoms.
  • the fatty acid triglycerides can for example be advantageously selected from the group of synthetic, semi-synthetic and natural oils, e.g. As olive oil, sunflower oil, soybean oil, peanut oil, rapeseed oil, almond oil, palm oil, coconut oil, palm kernel oil and the like.
  • any mixtures of such oil and wax components can also be used advantageously for the purposes of the present invention. It may also be advantageous to use waxes, for example cetyl palmitate, as the sole lipid component of the oil phase.
  • the oil component is advantageously selected from the group consisting of 2-ethylhexyl isostearate, octyl dodecanol, isotridecyl isononanoate, isoeicosane, 2-ethylhexyl icocoate, C12-15-alkyl benzoate, caprylic capric acid triglyceride, dicaprylyl ether.
  • hydrocarbons paraffin oil, squalane and squalene can be used advantageously for the purposes of the present invention.
  • the oil component can advantageously also have a content of cyclic or linear silicone oils or consist entirely of such oils, although it is preferred to use an additional content of other oil phase components in addition to the silicone oil or the silicone oils.
  • Cyclomethicone (octamethylcyclotetrasiloxane) is advantageously used as the silicone oil to be used according to the invention.
  • other silicone oils can also be used advantageously for the purposes of the present invention, for example hexamethylcyclotrisiloxane, polydimethylsiloxane, poly (methylphenylsiloxane).
  • the oil component is also advantageously selected from the group of phospholipids.
  • the phospholipids are phosphoric acid esters of acylated glycerols.
  • the phosphatidylcholines are, for example, the lecithins, which are characterized by the general structure
  • R 'and R typically represent unbranched aliphatic radicals with 15 or 17 carbon atoms and up to 4 cis double bonds.
  • Preferred for the use of these oil components in the sense of the invention is the combination with solubilizers, in particular in the form of the hydrogenated fatty acid monoglycerides , Fatty acid diglycerides and / or fatty acid triglycerides which have been ethoxylated and have a degree of ethoxylation of 20 to 500.
  • solubilizers in particular in the form of the hydrogenated fatty acid monoglycerides , Fatty acid diglycerides and / or fatty acid triglycerides which have been ethoxylated and have a degree of ethoxylation of 20 to 500.
  • the raw materials PEG-200 hydrogenated glyceryl palmitate, PEG-100 hydrogenated glyceryl palmitate and PEG-40 hydrogenated castor oil have proven to be particularly advantageous.
  • film formers Such polymers with at least partially quaternized nitrogen groups (hereinafter referred to as “film formers”) are preferably those which are selected from the group of substances which, according to the INCI nomenclature (International Nomenclature Cosmetic Ingredient), have the name "Polyquaternium” wear, for example:
  • Polyquaternium-2 (Chemical Abstracts No. 63451-27-4, e.g. Mirapol® A-15)
  • Polyquaternium-5 (copolymer of the acrylamide and the ß-methacryloxyethyltrimethylammonium methosulfate, CAS No. 26006-22-4)
  • Polyquatium-6 (homopolymer of N, N-dimethyl-N-2-propenyl-2-propen-1-aminium chloride, CAS No. 26062-79-3, e.g. Merquat® 100
  • Polyquaternium-17 CAS-No. 90624-75-2 e.g. Mirapol® AD-1 polyquaternium-19 quaternized water-soluble polyvinyl alcohol polyquaternium-20 water-dispersible quaternized polyvinyl octadecyl ether polyquaternium-21 polysiloxane-polydimethyl-dimethylammonium acetate copolymer, e.g. Abil® B 9905
  • Polyquaternium-28 vinylpyrrolidone / methacrylamidopropyltrimethylammonium chloride copolymer e.g. Gafquat® HS-100
  • Polyquaternium-29 e.g. Lexquat® CH Polyquaternium-31 CAS no. 136505-02-7, e.g. Hypan® QT 100 Polyquatemium-32 N, N, N-trimethyl-2 - [(2-methyl-1-oxo-2-propenyl) oxy] -ethanaminium chloride, polymer with 2-propenamide, CAS no. 35429-19-7
  • polymers polyquatemium-10 and polyquatemium-22 have proven to be advantageous.
  • the cosmetic and dermatological preparations according to the invention can contain cosmetic auxiliaries of the kind normally used in such preparations, for example preservatives, bactericides, virucides, perfumes, substances for preventing foaming, dyes, pigments which have a coloring effect, not less the definition of the thickeners according to the invention, thickeners, surface-active substances, emulsifiers, softening, moisturizing and / or moisturizing substances, anti-inflammatory substances, medicaments, fats, oils, waxes or other conventional constituents of a cosmetic or dermatological formulation such as alcohols, polyols, polymers, foam stabilizers, Electrolytes, organic solvents.
  • cosmetic auxiliaries of the kind normally used in such preparations, for example preservatives, bactericides, virucides, perfumes, substances for preventing foaming, dyes, pigments which have a coloring effect, not less the definition of the thickeners according to the invention, thickeners, surface-active substances, emulsifiers, soften

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)

Abstract

La présente invention concerne un produit nettoyant cosmétique qui associe un moyen de conditionnement et d'application et une préparation nettoyante liquide, laquelle se transforme en mousse stable au moyen de l'applicateur.
EP02774663A 2001-09-29 2002-09-27 Mousses nettoyantes cosmetiques Withdrawn EP1434566A2 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10148392A DE10148392A1 (de) 2001-09-29 2001-09-29 Kosmetische Reinigungsschäume
DE10148392 2001-09-29
PCT/EP2002/010895 WO2003028671A2 (fr) 2001-09-29 2002-09-27 Mousses nettoyantes cosmetiques

Publications (1)

Publication Number Publication Date
EP1434566A2 true EP1434566A2 (fr) 2004-07-07

Family

ID=7700975

Family Applications (1)

Application Number Title Priority Date Filing Date
EP02774663A Withdrawn EP1434566A2 (fr) 2001-09-29 2002-09-27 Mousses nettoyantes cosmetiques

Country Status (4)

Country Link
US (1) US20040265243A1 (fr)
EP (1) EP1434566A2 (fr)
DE (1) DE10148392A1 (fr)
WO (1) WO2003028671A2 (fr)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102004031668A1 (de) * 2004-06-25 2006-02-09 Beiersdorf Ag Produkte zur Reinigung der Intimregion
DE102004062775A1 (de) 2004-12-21 2006-06-29 Stockhausen Gmbh Alkoholischer Pumpschaum
US8114855B2 (en) * 2006-11-22 2012-02-14 L'oreal Low density cosmetic formulations, cosmetic products containing the same and methods of treating hair, nails and/or skin using the same
ES2382110T3 (es) * 2007-05-10 2012-06-05 Neubourg Skin Care Gmbh & Co. Kg Formulaciones de espuma exentas de tensioactivo
DE102008038137A1 (de) * 2008-08-18 2010-02-25 Henkel Ag & Co. Kgaa Sulfatfreies mildes Tensidsystem zur Haut- und Haarreinigung
PL2335675T3 (pl) 2009-12-10 2015-08-31 Neubourg Skin Care Gmbh & Co Kg Wolne od emulgatorów, stabilizowane polimerem formulacje pianki
EP4208145A1 (fr) * 2020-09-03 2023-07-12 Edgewell Personal Care Brands, LLC Composition d'aide au rasage

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Publication number Priority date Publication date Assignee Title
US6088A (en) * 1849-02-06 Improved method of boring gun-barrels
US3962150A (en) * 1974-04-10 1976-06-08 Richardson-Merrell Inc. Foam producing cleansing compositions
WO1993009761A1 (fr) * 1991-11-22 1993-05-27 Richardson-Vicks Inc. Compositions combinees de nettoyage et d'hydratation de la peau
US5635469A (en) * 1993-06-10 1997-06-03 The Procter & Gamble Company Foaming cleansing products
EP0728475A3 (fr) * 1995-02-21 1997-03-19 Kao Corp Nettoyant épidermique
NL1001366C2 (nl) * 1995-10-06 1997-04-08 Airspray Int Bv Inrichting voor het afgeven van een luchtvloeistofmengsel, in het bijzonder schuim en daarvoor bestemde bedieningseenheid.
GB9612595D0 (en) * 1996-06-15 1996-08-21 Smithkline Beecham Plc Composition
GB9626552D0 (en) * 1996-12-20 1997-02-05 Procter & Gamble Packaged personnal cleansing product
US6280757B1 (en) * 1997-05-22 2001-08-28 The Procter & Gamble Company Cleansing articles for skin or hair
WO1999015133A1 (fr) * 1997-09-25 1999-04-01 The Procter & Gamble Company Compositions moussantes pour produits d'hygiene
US6030931A (en) * 1998-02-03 2000-02-29 Chesebrough-Pond's Usa Co., Division Of Conopco, Inc. Foaming cleansing skin product
NL1012419C2 (nl) * 1999-06-23 2000-12-28 Airspray Nv Spuitbus voor het afgeven van een vloeistof.
DE10007321A1 (de) * 2000-02-17 2001-08-23 Henkel Kgaa Reinigungsschaum
US6537952B2 (en) * 2000-08-31 2003-03-25 Unilever Home And Personal Care, Usa Division Of Conopco, Inc. Foaming anti-bacterial cleansing skin product with low water insoluble emollients and foam dispenser

Non-Patent Citations (2)

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Title
None *
See also references of WO03028671A3 *

Also Published As

Publication number Publication date
DE10148392A1 (de) 2003-04-30
WO2003028671A2 (fr) 2003-04-10
US20040265243A1 (en) 2004-12-30
WO2003028671A3 (fr) 2003-11-20

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