EP1507020A3 - Durch Plasmaspritzen aufgebrachte Schicht für Zylinderlaufflächen von Motorblöcken und Verfahren zu deren Herstellung - Google Patents
Durch Plasmaspritzen aufgebrachte Schicht für Zylinderlaufflächen von Motorblöcken und Verfahren zu deren Herstellung Download PDFInfo
- Publication number
- EP1507020A3 EP1507020A3 EP04011394A EP04011394A EP1507020A3 EP 1507020 A3 EP1507020 A3 EP 1507020A3 EP 04011394 A EP04011394 A EP 04011394A EP 04011394 A EP04011394 A EP 04011394A EP 1507020 A3 EP1507020 A3 EP 1507020A3
- Authority
- EP
- European Patent Office
- Prior art keywords
- engine blocks
- cylinder bores
- sprayed layer
- plasma sprayed
- plasma
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 238000007750 plasma spraying Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/12—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
- C23C4/14—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying for coating elongate material
- C23C4/16—Wires; Tubes
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/12—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
- C23C4/134—Plasma spraying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B7/00—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
- B05B7/14—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas designed for spraying particulate materials
- B05B7/1404—Arrangements for supplying particulate material
- B05B7/1431—Arrangements for supplying particulate material comprising means for supplying an additional liquid
- B05B7/1436—Arrangements for supplying particulate material comprising means for supplying an additional liquid to a container where the particulate material and the additional liquid are brought together
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/06—Metallic material
- C23C4/08—Metallic material containing only metal elements
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/10—Oxides, borides, carbides, nitrides or silicides; Mixtures thereof
- C23C4/11—Oxides
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Coating By Spraying Or Casting (AREA)
- Cylinder Crankcases Of Internal Combustion Engines (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
Abstract
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH9199 | 1999-01-19 | ||
| CH9199 | 1999-01-19 | ||
| CH24599 | 1999-02-09 | ||
| CH24599 | 1999-02-09 | ||
| EP99811122A EP1022351B2 (de) | 1999-01-19 | 1999-12-08 | Durch Plasmaspritzen aufgebrachte Schicht für Zylinderlaufflächen von Motorblöcken und Verfahren zu deren Herstellung |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP99811122A Division EP1022351B2 (de) | 1999-01-19 | 1999-12-08 | Durch Plasmaspritzen aufgebrachte Schicht für Zylinderlaufflächen von Motorblöcken und Verfahren zu deren Herstellung |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP1507020A2 EP1507020A2 (de) | 2005-02-16 |
| EP1507020A3 true EP1507020A3 (de) | 2005-04-20 |
| EP1507020B1 EP1507020B1 (de) | 2007-06-27 |
Family
ID=25683486
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP04011394A Expired - Lifetime EP1507020B1 (de) | 1999-01-19 | 1999-12-08 | Durch Plasmaspritzen aufgebrachte Schicht für Zylinderlaufflächen von Motorblöcken und Verfahren zu deren Herstellung |
| EP99811122A Expired - Lifetime EP1022351B2 (de) | 1999-01-19 | 1999-12-08 | Durch Plasmaspritzen aufgebrachte Schicht für Zylinderlaufflächen von Motorblöcken und Verfahren zu deren Herstellung |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP99811122A Expired - Lifetime EP1022351B2 (de) | 1999-01-19 | 1999-12-08 | Durch Plasmaspritzen aufgebrachte Schicht für Zylinderlaufflächen von Motorblöcken und Verfahren zu deren Herstellung |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US6548195B1 (de) |
| EP (2) | EP1507020B1 (de) |
| JP (2) | JP3967511B2 (de) |
| KR (1) | KR100593342B1 (de) |
| AT (2) | ATE267275T1 (de) |
| CA (1) | CA2296155C (de) |
| DE (2) | DE59909522D1 (de) |
| ES (2) | ES2288232T3 (de) |
| PT (2) | PT1507020E (de) |
Families Citing this family (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19963223A1 (de) * | 1999-12-27 | 2001-06-28 | Volkswagen Ag | Stahlhaltiges Material für eine Plasmaabscheidung |
| CH694664A5 (de) | 2000-06-14 | 2005-05-31 | Sulzer Metco Ag | Durch Plasmaspritzen eines Spritzpulvers aufgebrachte eisenhaltige Schicht auf einer Zylinderlauffläche. |
| US6756083B2 (en) * | 2001-05-18 | 2004-06-29 | Höganäs Ab | Method of coating substrate with thermal sprayed metal powder |
| CH695339A5 (de) * | 2002-02-27 | 2006-04-13 | Sulzer Metco Ag | Zylinderlaufflächenschicht für Verbrennungsmotoren sowie Verfahren zu deren Herstellung. |
| JP3910145B2 (ja) | 2003-01-06 | 2007-04-25 | 日本発条株式会社 | 溶射被膜およびその製造方法 |
| DE10324279B4 (de) * | 2003-05-28 | 2006-04-06 | Daimlerchrysler Ag | Verwendung von FeC-Legierung zur Erneuerung der Oberfläche von Zylinderlaufbuchsen |
| CA2514493C (en) * | 2004-09-17 | 2013-01-29 | Sulzer Metco Ag | A spray powder |
| GB2421207A (en) * | 2004-12-16 | 2006-06-21 | Cosworth Technology Ltd | Casting with a halogen containing compound provided on the mould surface |
| JP4818659B2 (ja) * | 2005-08-08 | 2011-11-16 | いすゞ自動車株式会社 | 内燃機関の燃焼室用摺動部材及びその製造方法 |
| EP1757710A1 (de) | 2005-08-23 | 2007-02-28 | Sulzer Metco Coatings GmbH | Werkstück mit einer thermisch gespritzten Oberflächenschicht |
| DE102005040015B3 (de) * | 2005-08-23 | 2007-04-12 | Brückner Maschinenbau GmbH | Walze sowie Verfahren zu deren Herstellung |
| DE102006042549C5 (de) * | 2006-09-11 | 2017-08-17 | Federal-Mogul Burscheid Gmbh | Nasse Zylinderlaufbuchse mit kavitationsresistenter Oberfläche |
| KR100878878B1 (ko) * | 2007-06-14 | 2009-01-15 | 주식회사뉴테크 | 용사기술을 이용한 엔진블록 라이너외벽 코팅 방법 |
| JP5111965B2 (ja) | 2007-07-24 | 2013-01-09 | 株式会社日立製作所 | 記憶制御装置及びその制御方法 |
| JP5257756B2 (ja) * | 2007-12-05 | 2013-08-07 | 日産自動車株式会社 | 鉄系溶射被膜、その形成方法及び摺動部材 |
| JP5651922B2 (ja) | 2009-03-04 | 2015-01-14 | 日産自動車株式会社 | シリンダブロック及び溶射皮膜形成方法 |
| DE102009016650B3 (de) * | 2009-04-07 | 2010-07-29 | Federal-Mogul Burscheid Gmbh | Gleitelement mit einstellbaren Eigenschaften |
| JP5455149B2 (ja) * | 2009-05-28 | 2014-03-26 | 日産自動車株式会社 | 鉄系溶射被膜 |
| CN101818318A (zh) * | 2010-05-05 | 2010-09-01 | 北京科技大学 | 一种大气等离子体喷涂法制备细晶钨、钼涂层的方法 |
| DE102010021300B4 (de) | 2010-05-22 | 2012-03-22 | Daimler Ag | Drahtförmiger Spritzwerkstoff, damit erzeugbare Funktionsschicht und Verfahren zum Beschichten eines Substrats mit einem Spritzwerkstoff |
| US20120258254A1 (en) * | 2011-04-06 | 2012-10-11 | Basf Corporation | Methods For Providing High-Surface Area Coatings To Mitigate Hydrocarbon Deposits On Engine And Powertrain Components |
| FR2974610B1 (fr) * | 2011-04-26 | 2013-05-17 | Peugeot Citroen Automobiles Sa | Procede de realisation des surfaces de chambres a combustion d'un bloc moteur en alliage d'aluminium |
| EP2650398B8 (de) * | 2012-04-11 | 2015-05-13 | Oerlikon Metco AG, Wohlen | Spritzpulver mit einer superferritischen Eisenbasisverbindung, sowie ein Substrat, insbesondere Bremsscheibe mit einer thermischen Spritzschicht |
| DE102012009496B4 (de) | 2012-05-14 | 2017-05-11 | Stahlwerk Ergste Westig Gmbh | Chromstahl |
| JP6038349B2 (ja) * | 2012-12-12 | 2016-12-07 | アーベーベー ターボ システムズ アクチエンゲゼルシャフト | 耐摩耗性層および耐摩耗性層の製造方法 |
| DE102012112394A1 (de) * | 2012-12-17 | 2014-06-18 | Dr. Ing. H.C. F. Porsche Aktiengesellschaft | Verfahren zum Herstellen eines beschichteten Magnesiumbauteils |
| EP2829713B1 (de) * | 2013-07-26 | 2018-11-07 | Sulzer Metco AG | Werkstück mit einer Ausnehmung zur Aufnahme eines Kolbens |
| KR101922159B1 (ko) * | 2014-11-04 | 2018-11-27 | 현대중공업 주식회사 | 피스톤 스커트부 코팅재 조성물 및 이를 이용한 피스톤 스커트부의 코팅방법 |
| US9945318B2 (en) | 2015-12-04 | 2018-04-17 | Hyundai Motor Company | Cylinder block |
| CN105543759A (zh) * | 2015-12-18 | 2016-05-04 | 合肥中澜新材料科技有限公司 | 一种高硬度耐腐蚀发动机汽缸内壁耐磨涂层及其制备方法 |
| WO2017137500A1 (de) | 2016-02-12 | 2017-08-17 | Oerlikon Surface Solutions Ag, Päffikon | Tribologisches system eines verbrennungsmotors mit beschichtung |
| JP7406917B2 (ja) * | 2016-05-27 | 2023-12-28 | エリコン メテコ アクチェンゲゼルシャフト、ヴォーレン | コーティング法、熱コーティング、および熱コーティングを有するシリンダ |
| CN107214341B (zh) * | 2017-05-24 | 2019-05-24 | 大连理工大学 | 一种钢-耐磨铜合金层状轴瓦材料、其制备装置及制备方法 |
| JP7083295B2 (ja) * | 2018-08-22 | 2022-06-10 | トヨタ自動車東日本株式会社 | 摺動部材及びその製造方法 |
| JP7159111B2 (ja) * | 2019-05-28 | 2022-10-24 | 日本ピストンリング株式会社 | 摺動部材と潤滑油との組み合わせ |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB558182A (en) * | 1942-03-09 | 1943-12-24 | British Piston Ring Company Lt | Improvements in and in the manufacture of metal inserts |
| GB1390662A (en) * | 1972-05-05 | 1975-04-16 | Ass Eng Ltd | Sintered ferrous machinery components and process for their manufacture |
| EP0816527A1 (de) * | 1996-06-21 | 1998-01-07 | Ford Motor Company Limited | Verfahren zum Aufbringen einer thermisch aufgespritzten Beschichtung auf Metallsubstrate |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR735928A (fr) * | 1931-05-29 | 1932-11-17 | Procédé de fabrication de pièces de machines en métaux légers à surface protégée contre l'usure | |
| DE940082C (de) * | 1950-11-17 | 1956-03-08 | Goetzewerke | Verfahren zur Herstellung von Zylinderlaufbuechsen |
| JPS5432421B2 (de) * | 1973-01-09 | 1979-10-15 | ||
| US4060653A (en) * | 1974-02-22 | 1977-11-29 | Kennecott Copper Corporation | Composite wire |
| JPS57101662A (en) * | 1980-12-16 | 1982-06-24 | Riken Corp | Sliding component part |
| JPS6031901B2 (ja) * | 1981-10-12 | 1985-07-25 | 本田技研工業株式会社 | プラズマ溶射皮膜形成方法 |
| JPH0222444A (ja) * | 1988-07-08 | 1990-01-25 | Sanyo Special Steel Co Ltd | 耐銹耐摩耗用鋼 |
| US5358547A (en) * | 1993-02-18 | 1994-10-25 | Holko Kenneth H | Cobalt-phosphorous-base wear resistant coating for metallic surfaces |
| JPH07243528A (ja) * | 1994-03-02 | 1995-09-19 | Teikoku Piston Ring Co Ltd | 摺動部材の組合せ |
| US5466906A (en) | 1994-04-08 | 1995-11-14 | Ford Motor Company | Process for coating automotive engine cylinders |
| US5554278A (en) * | 1994-06-03 | 1996-09-10 | Henderson; Bruce L. | Quick change oil recycler |
| JP3044182B2 (ja) * | 1994-06-24 | 2000-05-22 | プラクスエア・エス・ティー・テクノロジー・インコーポレイテッド | 酸化物分散MCrAlY基コーティングを生成する方法 |
| US5663124A (en) | 1994-12-09 | 1997-09-02 | Ford Global Technologies, Inc. | Low alloy steel powder for plasma deposition having solid lubricant properties |
| US5592927A (en) * | 1995-10-06 | 1997-01-14 | Ford Motor Company | Method of depositing and using a composite coating on light metal substrates |
| US5766693A (en) * | 1995-10-06 | 1998-06-16 | Ford Global Technologies, Inc. | Method of depositing composite metal coatings containing low friction oxides |
| US5622753A (en) * | 1996-04-08 | 1997-04-22 | Ford Motor Company | Method of preparing and coating aluminum bore surfaces |
| US5723187A (en) * | 1996-06-21 | 1998-03-03 | Ford Global Technologies, Inc. | Method of bonding thermally sprayed coating to non-roughened aluminum surfaces |
| AU1655000A (en) * | 1998-11-25 | 2000-06-13 | Joma Chemical As | Material for producing a corrosion- and wear-resistant layer by thermal spraying |
-
1999
- 1999-12-08 AT AT99811122T patent/ATE267275T1/de active
- 1999-12-08 DE DE59909522T patent/DE59909522D1/de not_active Expired - Lifetime
- 1999-12-08 ES ES04011394T patent/ES2288232T3/es not_active Expired - Lifetime
- 1999-12-08 EP EP04011394A patent/EP1507020B1/de not_active Expired - Lifetime
- 1999-12-08 PT PT04011394T patent/PT1507020E/pt unknown
- 1999-12-08 PT PT99811122T patent/PT1022351E/pt unknown
- 1999-12-08 DE DE59914394T patent/DE59914394D1/de not_active Expired - Lifetime
- 1999-12-08 EP EP99811122A patent/EP1022351B2/de not_active Expired - Lifetime
- 1999-12-08 ES ES99811122T patent/ES2221343T5/es not_active Expired - Lifetime
- 1999-12-08 AT AT04011394T patent/ATE365814T1/de active
- 1999-12-29 US US09/476,009 patent/US6548195B1/en not_active Expired - Lifetime
-
2000
- 2000-01-12 KR KR1020000001269A patent/KR100593342B1/ko not_active Expired - Lifetime
- 2000-01-17 CA CA002296155A patent/CA2296155C/en not_active Expired - Lifetime
- 2000-01-19 JP JP2000010617A patent/JP3967511B2/ja not_active Expired - Lifetime
-
2001
- 2001-10-23 US US10/001,132 patent/US6572931B2/en not_active Expired - Lifetime
-
2007
- 2007-01-18 JP JP2007009236A patent/JP4644687B2/ja not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB558182A (en) * | 1942-03-09 | 1943-12-24 | British Piston Ring Company Lt | Improvements in and in the manufacture of metal inserts |
| GB1390662A (en) * | 1972-05-05 | 1975-04-16 | Ass Eng Ltd | Sintered ferrous machinery components and process for their manufacture |
| EP0816527A1 (de) * | 1996-06-21 | 1998-01-07 | Ford Motor Company Limited | Verfahren zum Aufbringen einer thermisch aufgespritzten Beschichtung auf Metallsubstrate |
Also Published As
| Publication number | Publication date |
|---|---|
| ES2221343T5 (es) | 2009-06-12 |
| EP1022351A1 (de) | 2000-07-26 |
| JP4644687B2 (ja) | 2011-03-02 |
| US6572931B2 (en) | 2003-06-03 |
| EP1022351B1 (de) | 2004-05-19 |
| US20020051851A1 (en) | 2002-05-02 |
| ES2221343T3 (es) | 2004-12-16 |
| US6548195B1 (en) | 2003-04-15 |
| JP2000212717A (ja) | 2000-08-02 |
| ATE365814T1 (de) | 2007-07-15 |
| EP1507020A2 (de) | 2005-02-16 |
| CA2296155A1 (en) | 2000-07-19 |
| DE59914394D1 (de) | 2007-08-09 |
| PT1022351E (pt) | 2004-10-29 |
| JP3967511B2 (ja) | 2007-08-29 |
| KR100593342B1 (ko) | 2006-06-26 |
| EP1507020B1 (de) | 2007-06-27 |
| ES2288232T3 (es) | 2008-01-01 |
| KR20000071238A (ko) | 2000-11-25 |
| CA2296155E (en) | 2000-07-19 |
| EP1022351B2 (de) | 2009-02-25 |
| ATE267275T1 (de) | 2004-06-15 |
| CA2296155C (en) | 2004-09-14 |
| PT1507020E (pt) | 2007-07-13 |
| JP2007191795A (ja) | 2007-08-02 |
| DE59909522D1 (de) | 2004-06-24 |
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