EP1549729A1 - Procede pour produire un concentre de matieres odorantes solide - Google Patents

Procede pour produire un concentre de matieres odorantes solide

Info

Publication number: EP1549729A1
Authority: EP; European Patent Office
Prior art keywords: solid; fragrance; mixture; fatty alcohol; liquid
Prior art date: 2002-10-11
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

EP03748123A

Other languages

German (de)

English (en)

Other versions

EP1549729B2 (fr

EP1549729B1 (fr

Inventor

Raymond Heinz

Hans-Jürgen HUPPERT

Katharina Girke

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Bell Flavors and Fragrances Duft und Aroma GmbH

Original Assignee

Bell Flavors and Fragrances Duft und Aroma GmbH

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2002-10-11

Filing date

2003-10-08

Publication date

2005-07-06

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=32049241&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP1549729(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

2003-10-08 Application filed by Bell Flavors and Fragrances Duft und Aroma GmbH filed Critical Bell Flavors and Fragrances Duft und Aroma GmbH

2005-07-06 Publication of EP1549729A1 publication Critical patent/EP1549729A1/fr

2007-01-03 Application granted granted Critical

2007-01-03 Publication of EP1549729B1 publication Critical patent/EP1549729B1/fr

2014-06-04 Publication of EP1549729B2 publication Critical patent/EP1549729B2/fr

2023-10-08 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

239000003205 fragrance Substances 0.000 title claims abstract description 67
239000007787 solid Substances 0.000 title claims abstract description 44
239000012141 concentrate Substances 0.000 title claims abstract description 18
238000000034 method Methods 0.000 title claims abstract description 15
238000004519 manufacturing process Methods 0.000 title abstract description 8
239000000203 mixture Substances 0.000 claims abstract description 35
239000007788 liquid Substances 0.000 claims abstract description 26
150000002191 fatty alcohols Chemical class 0.000 claims abstract description 19
239000004094 surface-active agent Substances 0.000 claims abstract description 11
238000001816 cooling Methods 0.000 claims abstract description 10
238000007711 solidification Methods 0.000 claims abstract description 10
230000008023 solidification Effects 0.000 claims abstract description 10
239000002202 Polyethylene glycol Substances 0.000 claims abstract description 6
229920001223 polyethylene glycol Polymers 0.000 claims abstract description 6
235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 5
239000000194 fatty acid Substances 0.000 claims abstract description 5
229930195729 fatty acid Natural products 0.000 claims abstract description 5
150000004665 fatty acids Chemical class 0.000 claims abstract description 5
239000008247 solid mixture Substances 0.000 claims abstract 7
239000004064 cosurfactant Substances 0.000 claims description 8
238000002360 preparation method Methods 0.000 claims description 2
238000000465 moulding Methods 0.000 claims 1
238000010521 absorption reaction Methods 0.000 abstract 1
239000000344 soap Substances 0.000 description 14
239000003599 detergent Substances 0.000 description 8
239000000126 substance Substances 0.000 description 8
238000004851 dishwashing Methods 0.000 description 6
239000002537 cosmetic Substances 0.000 description 4
239000003845 household chemical Substances 0.000 description 4
239000000843 powder Substances 0.000 description 4
239000013042 solid detergent Substances 0.000 description 4
239000012876 carrier material Substances 0.000 description 3
239000008187 granular material Substances 0.000 description 3
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
239000000835 fiber Substances 0.000 description 2
239000000463 material Substances 0.000 description 2
VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
DCXXMTOCNZCJGO-UHFFFAOYSA-N Glycerol trioctadecanoate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
238000005520 cutting process Methods 0.000 description 1
238000004200 deflagration Methods 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
239000002360 explosive Substances 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
230000001771 impaired effect Effects 0.000 description 1
238000002156 mixing Methods 0.000 description 1
238000004806 packaging method and process Methods 0.000 description 1
238000003825 pressing Methods 0.000 description 1
230000002035 prolonged effect Effects 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
238000003860 storage Methods 0.000 description 1
239000003826 tablet Substances 0.000 description 1
238000005406 washing Methods 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
- C11D3/502—Protected perfumes
- C11D3/505—Protected perfumes encapsulated or adsorbed on a carrier, e.g. zeolite or clay

Definitions

the invention relates to a method for producing a solid fragrance concentrate, which, for. B. for perfuming solid soaps, solid detergents and dishwashing detergents in powder, granulate, chip or tablet form and other solid household chemical or cosmetic products.
fragrances or fragrance mixtures are liquid at normal temperature and often highly volatile substances, the introduction of which into solid household chemical or cosmetic products such as e.g. B. solid soaps or in powder, granule, chip or tablet detergent and dishwashing problems.
the known technologies for perfuming solid soaps are based, for. B. on an intensive blending of the piliert raw soap with liquid fragrance concentrate before extrusion and cutting and re-pressing to individual bars of soap. If the liquid fragrances are introduced into the piled raw soap in larger quantities, the consistency of the soap is negatively affected.
fragrances introduced into the solid soaps evaporate relatively quickly, because the base soap can only bind the fragrances in small amounts, so that after prolonged storage most of the solid soaps produced in this way absorb a large part of the Have lost fragrance.
Powdery solid detergents and dishwashing agents are intensively mixed with finely sprayed liquid fragrance concentrate before packaging or before they are formed into tablets, chips, etc. When the fragrance is sprayed, evaporation causes high losses of substance during production.
the often volatile and flammable fragrances together with air can form explosive gas-air mixtures, which can lead to deflagrations and fires in the manufacturing plants.
the object is achieved by the characterizing features of patent claim 1.
Advantageous embodiments of the invention form the features of subclaims 2 to 10.
fragrances are in the liquid state at a normal temperature of 20 ° C. Fragrances ready for use by the consumer are in most cases mixtures of up to 40, in some cases even more, individual fragrance components.
these fragrances or fragrance mixtures which are liquid at normal temperature, in relatively high concentrations and conveniently into solid soaps, powder or other solid detergents and dishwashing detergents or other solid household chemical or cosmetic products, without affecting the quality of the products is noticeably impaired or that disadvantages or dangers occur in the production process
the liquid fragrances are dissolved according to the invention in surfactants or cosurfactants which are solid at normal temperature.
liquid fragrances can be dissolved in the surfactants or cosurfactants or in the surfactant-cosurfactant mixtures and solidified to form a solid fragrance concentrate according to the invention.
fragrance substances were dissolved in a liquefied mixture of 30% by weight of fatty alcohol C22 and 30% by weight of polyethylene glycol, which had a solidification point of 60 ° C., at a temperature of 80 ° C.
the fatty alcohol-polyethylene glycol fragrance solution solidified on cooling at a temperature below 54 ° C. to give the solid fragrance concentrate according to the invention.
the solid fragrance concentrates obtained in the above manner can be produced in known form in pelletized or granulated form, and they can be used in this form in the production of solid soaps, powder, granule or tablet detergents and dishwashing detergents or other solid ones Add household chemical or cosmetic products easily and dose precisely.

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Life Sciences & Earth Sciences (AREA)
Dispersion Chemistry (AREA)
Detergent Compositions (AREA)
Fats And Perfumes (AREA)
Jellies, Jams, And Syrups (AREA)
Cosmetics (AREA)
Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

EP03748123.1A 2002-10-11 2003-10-08 Procede pour produire un concentre de matieres odorantes solide Expired - Lifetime EP1549729B2 (fr)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
DE10247583		2002-10-11
DE10247583A DE10247583C5 (de)	2002-10-11	2002-10-11	Verfahren zur Herstellung eines festen Riechstoffkonzentrates
PCT/EP2003/011109 WO2004035721A1 (fr)	2002-10-11	2003-10-08	Procede pour produire un concentre de matieres odorantes solide

Publications (3)

Publication Number	Publication Date
EP1549729A1 true EP1549729A1 (fr)	2005-07-06
EP1549729B1 EP1549729B1 (fr)	2007-01-03
EP1549729B2 EP1549729B2 (fr)	2014-06-04

Family

ID=32049241

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
EP03748123.1A Expired - Lifetime EP1549729B2 (fr)	2002-10-11	2003-10-08	Procede pour produire un concentre de matieres odorantes solide

Country Status (9)

Country	Link
US (1)	US7485610B2 (fr)
EP (1)	EP1549729B2 (fr)
JP (1)	JP2006516153A (fr)
CN (1)	CN1692154B (fr)
AT (1)	ATE350455T1 (fr)
DE (2)	DE10247583C5 (fr)
EA (1)	EA006727B1 (fr)
ES (1)	ES2280772T5 (fr)
WO (1)	WO2004035721A1 (fr)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE10357676A1 (de) *	2003-12-10	2005-07-21	Henkel Kgaa	Duftkomposite
GB2417204A (en)	2004-08-19	2006-02-22	Bell Flavours & Fragrances Ltd	Air treatment apparatus
DE102004052929A1 (de) *	2004-10-29	2006-05-04	Bell Flavors & Fragrances Duft Und Aroma Gmbh	Verfahren und Vorrichtung zur Herstellung von festem Duftstoff
DE102005025041A1 (de) *	2005-05-30	2006-12-07	Bell Flavors & Fragrances Duft Und Aroma Gmbh	Mittel zur Anwendung in Spülmaschinen sowie Vorrichtung für dessen dosierte Einbringung während der Spül- und Trocknungsphasen
DE102005036415A1 (de) *	2005-07-29	2007-02-01	Bell Flavors & Fragrances Duft Und Aroma Gmbh	Verfahren zur Anlagerung eines verflüchtigbaren Wirkstoffes an ein festes Stützmaterial und zur gesteuerten Freisetzung des Wirkstoffes in die Umgebung
DE102006029092A1 (de) *	2006-06-24	2007-12-27	Bell Flavors & Fragrances Duft Und Aroma Gmbh	Verfahren zur Aromatisierung von zellulosehaltigen Produkten
JP5465823B2 (ja) *	2006-12-13	2014-04-09	ユニ・チャーム株式会社	機能性シートおよび吸収性物品
DE102007037147A1 (de) *	2007-08-07	2009-02-12	Henkel Ag & Co. Kgaa	Duftkomposite mit verbesserter Duftfreisetzung
WO2010078067A1 (fr) *	2008-12-30	2010-07-08	Bell Flavors And Fragrances, Inc.	Traitement glucidique pour des articles parfumés
GB2471303A (en)	2009-06-24	2010-12-29	Bell Flavors & Fragrances Duft Und Aroma Gmbh	Microparticles and method of making microparticles
CA2682636C (fr) *	2009-11-05	2010-06-15	The Procter & Gamble Company	Additif a parfumer une buanderie
US8476219B2 (en)	2009-11-05	2013-07-02	The Procter & Gamble Company	Laundry scent additive
WO2012084061A1 (fr)	2010-12-23	2012-06-28	Symrise Ag	Granules de parfum pour détergents
US20130065812A1 (en) *	2011-09-14	2013-03-14	Ecolab Usa Inc.	Water-dilutable solid concentrate
US20130126634A1 (en)	2011-11-22	2013-05-23	Ecolab Usa Inc.	Solid air freshener
JP6151374B2 (ja)	2012-12-20	2017-06-21	ザプロクターアンドギャンブルカンパニー	洗濯物香り添加剤
CN103405346B (zh) *	2013-06-08	2015-04-22	苏州靖羽新材料有限公司	一种固体香水的制备方法
MX2017001220A (es)	2014-07-30	2017-10-02	Georgia Pacific Consumer Products Lp	Dispensadores de ambientador, cartuchos para los mismos, sistemas y metodos.
ES2881435T3 (es)	2015-10-23	2021-11-29	Basf Se	Soluciones sólidas de sustancias odorantes y aromatizantes con polímeros de vinilactama
WO2018030431A1 (fr)	2016-08-09	2018-02-15	Takasago International Corporation	Composition solide comprenant des parfums libres et encapsulés
WO2018055115A1 (fr) *	2016-09-26	2018-03-29	Henkel Ag & Co. Kgaa	Corps fusible contenant un parfum et contenant des tensioactifs non ioniques fortement éthoxylés
BR112019007819B1 (pt)	2016-11-02	2022-06-14	Dow Global Technologies Llc	Odorizante de ar em gel não aquoso sólido
CN107260128B (zh) *	2017-06-13	2020-09-29	江苏金森海默生物技术有限公司	一种嗅觉障碍检测试剂盒及其应用
DE102017222992A1 (de) *	2017-12-18	2019-06-19	Henkel Ag & Co. Kgaa	Herstellung parfümhaltiger Schmelzkörper
CN111286414B (zh) *	2019-11-28	2021-04-27	纳爱斯浙江科技有限公司	一种衣物留香珠及其制备方法
WO2025040240A1 (fr) *	2023-08-18	2025-02-27	Symrise Ag	Capsules d'huile de parfum pour formulations solides avec amplification de parfum
CN117467499A (zh) *	2023-11-29	2024-01-30	云南养瑞科技集团有限公司	一种液体香料等物质转为具有缓释功能的固体香料的方法

Family Cites Families (36)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE548617C (de) *	1930-10-08	1932-04-19	Hydrierwerke Akt Ges Deutsche	Verfahren zum Fixieren von Riechstoffen
US2300769A (en) *	1940-03-28	1942-11-03	Palol Perfumed Products Inc	Solid perfume
DE1120046B (de) *	1960-06-30	1961-12-21	Spitzner Arzneimittelfabrik G	Vermahlbares, rieselfaehiges Produkt aus aetherischen OElen, fluessigen Riechstoffen und Aromen und Verfahren zu seiner Herstellung
GB1169656A (en) *	1967-12-18	1969-11-05	Fumio Enomoto	Scented Composition
FR2123824A5 (en)	1971-02-02	1972-09-15	Oreal	Solid perfumed soap - contains a soap gel with volatile solvent water and volatile perfume
US3945950A (en)	1974-10-02	1976-03-23	Universal Oil Products Company	Solid perfumed compositions of matter
US4017574A (en) *	1975-06-04	1977-04-12	Colgate-Palmolive Company	Process for making variegated soap
GB1587122A (en) *	1976-10-29	1981-04-01	Procter & Gamble Ltd	Fabric conditioning compositions
PH17340A (en) *	1980-03-11	1984-08-01	Unilever Nv	Detergent composition
US4741899A (en) *	1983-06-06	1988-05-03	Bristol-Myers Company	Process for arresting the proliferation of organisms that convert axillary secretions to malodorous materials
JPS60182955A (ja) *	1984-03-01	1985-09-18	中村物産株式会社	固形状香料の製造方法
EP0334666A3 (fr) *	1988-03-23	1990-09-05	Union Camp Corporation	Support de parfum pour les compositions détergentes
CA2004270A1 (fr) *	1988-12-29	1990-06-29	William R. Michael	Microcapsules de substance parfumee servant a la preparation de detergents granulaires
US5002681A (en) *	1989-03-03	1991-03-26	The Procter & Gamble Company	Jumbo particulate fabric softner composition
CA2015737C (fr) *	1989-05-11	1995-08-15	Diane Grob Schmidt	Particules parfumees sous coquille
US5154842A (en) *	1990-02-20	1992-10-13	The Procter & Gamble Company	Coated perfume particles
ES2087144T3 (es) *	1990-07-31	1996-07-16	Procter & Gamble	Sistema mejorado de vehiculo y entrega de perfume para aplicaciones de lavado de ropa.
US5194172A (en) *	1990-09-13	1993-03-16	The Procter & Gamble Company	Aerated and freezer bar soap compositions containing sucrose as a mildness aid and a processing aid
US5635164A (en) *	1991-07-03	1997-06-03	The Mennen Company	Stick composition with sodium chloride and stearyl alcohol
US5378468A (en) *	1992-09-22	1995-01-03	The Mennen Company	Composition containing body activated fragrance for contacting the skin and method of use
TR28670A (tr) *	1993-06-02	1996-12-17	Procter & Gamble	Zeolitleri iceren parfüm birakma sistemi.
US5506201A (en) *	1994-04-29	1996-04-09	International Flavors & Fragrances Inc.	Formulation of a fat surfactant vehicle containing a fragrance
WO1997016163A1 (fr) *	1995-10-31	1997-05-09	The Procter & Gamble Company	Composition pour baton cosmetique deodorant
DE19710635A1 (de) *	1997-03-14	1998-09-17	Buck Chemie Gmbh	Gelbasierter Reinigungsblock für die Toilettenhygiene mit permanenter Raumluftbeduftung
DE19735783A1 (de) *	1997-08-18	1999-02-25	Henkel Kgaa	Hochdosierte Duftstoff-Formkörper
DE19744571A1 (de) *	1997-10-09	1999-04-15	Haarmann & Reimer Gmbh	Toilettensteine
US6086644A (en) *	1997-10-10	2000-07-11	Takasago International Corporation	Scented candle and manufacturing method for same
DE19746780A1 (de) *	1997-10-23	1999-04-29	Henkel Kgaa	Verfahren zur Herstellung von Duftperlen
DE19749760A1 (de) *	1997-11-11	1999-05-12	Henkel Kgaa	Mehrphasen-Stiftpräparat
DE19808757B4 (de) *	1998-03-02	2007-09-20	Henkel Kgaa	Duftperlen in Wasch- und Reinigungsmittelformkörpern
DE19917692A1 (de) *	1999-04-20	2000-10-26	Henkel Kgaa	Duftsäckchen
DE19948667A1 (de) *	1999-10-08	2001-04-12	Henkel Kgaa	Reinigungsmittelkomponente mit doppelkontrollierter Duftfreisetzung
US6531444B1 (en) *	2000-11-09	2003-03-11	Salvona, Llc	Controlled delivery system for fabric care products
DE10063428A1 (de) *	2000-12-20	2002-07-11	Henkel Kgaa	Dispersionen nanopartikulärer riechstoffhaltiger Kompositmaterialien
US20030126788A1 (en) *	2001-11-07	2003-07-10	Colloid Tech. Inc.	Storage stable translucent flammable article
US7381697B2 (en) *	2002-04-10	2008-06-03	Ecolab Inc.	Fabric softener composition and methods for manufacturing and using

2002
- 2002-10-11 DE DE10247583A patent/DE10247583C5/de not_active Expired - Fee Related
2003
- 2003-10-08 CN CN2003801006895A patent/CN1692154B/zh not_active Expired - Lifetime
- 2003-10-08 DE DE50306219T patent/DE50306219D1/de not_active Expired - Lifetime
- 2003-10-08 WO PCT/EP2003/011109 patent/WO2004035721A1/fr not_active Ceased
- 2003-10-08 ES ES03748123.1T patent/ES2280772T5/es not_active Expired - Lifetime
- 2003-10-08 EP EP03748123.1A patent/EP1549729B2/fr not_active Expired - Lifetime
- 2003-10-08 AT AT03748123T patent/ATE350455T1/de active
- 2003-10-08 EA EA200401487A patent/EA006727B1/ru not_active IP Right Cessation
- 2003-10-08 US US10/521,033 patent/US7485610B2/en not_active Expired - Lifetime
- 2003-10-08 JP JP2004544106A patent/JP2006516153A/ja active Pending

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO2004035721A1 *

Also Published As

Publication number	Publication date
EA006727B1 (ru)	2006-04-28
ES2280772T5 (es)	2014-09-19
DE10247583B4 (de)	2007-08-23
DE10247583A1 (de)	2004-04-29
EA200401487A1 (ru)	2005-10-27
WO2004035721A1 (fr)	2004-04-29
ATE350455T1 (de)	2007-01-15
CN1692154A (zh)	2005-11-02
JP2006516153A (ja)	2006-06-22
US20050227905A1 (en)	2005-10-13
ES2280772T3 (es)	2007-09-16
DE10247583C5 (de)	2009-04-30
EP1549729B2 (fr)	2014-06-04
US7485610B2 (en)	2009-02-03
CN1692154B (zh)	2010-04-28
DE50306219D1 (de)	2007-02-15
EP1549729B1 (fr)	2007-01-03

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