EP1551774A2 - Purification d'eau avec des surfaces catalytiques et des micro-organismes - Google Patents

Purification d'eau avec des surfaces catalytiques et des micro-organismes

Info

Publication number
EP1551774A2
EP1551774A2 EP03785487A EP03785487A EP1551774A2 EP 1551774 A2 EP1551774 A2 EP 1551774A2 EP 03785487 A EP03785487 A EP 03785487A EP 03785487 A EP03785487 A EP 03785487A EP 1551774 A2 EP1551774 A2 EP 1551774A2
Authority
EP
European Patent Office
Prior art keywords
water
microorganisms
bacteria
catalytically active
mixed culture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP03785487A
Other languages
German (de)
English (en)
Inventor
Christian Uphoff
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Umwelttechnik Georg Fritzmeier GmbH and Co KG
Original Assignee
Umwelttechnik Georg Fritzmeier GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Umwelttechnik Georg Fritzmeier GmbH and Co KG filed Critical Umwelttechnik Georg Fritzmeier GmbH and Co KG
Publication of EP1551774A2 publication Critical patent/EP1551774A2/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/725Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/34Biological treatment of water, waste water, or sewage characterised by the microorganisms used
    • C02F3/341Consortia of bacteria
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/30Treatment of water, waste water, or sewage by irradiation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/78Treatment of water, waste water, or sewage by oxidation with ozone
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/42Nature of the water, waste water, sewage or sludge to be treated from bathing facilities, e.g. swimming pools
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/04Oxidation reduction potential [ORP]
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00Use of specific compounds during water treatment
    • C02F2305/10Photocatalysts
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/34Biological treatment of water, waste water, or sewage characterised by the microorganisms used
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage

Definitions

  • the present invention relates to a method for purifying water and the use of this method.
  • Water can be mentioned in swimming pools and private households as examples.
  • a ceramic or polymer surface doped with catalyst substances can be used as the catalytically active surface.
  • catalyst substances are organic and / or inorganic catalyst compounds.
  • a ceramic surface is used which contains titanium dioxide (TiO 2) or indium tin oxide. Conveniently, such a ceramic surface can be a commercially available tile. It has been found that the method according to the invention can be used advantageously, for example, in the purification of swimming pool water. It is also possible to clean facade tiles using the method according to the invention. The use of such materials for wastewater treatment is known from DE 199 13 011 AI.
  • Photosynthetic microorganisms which are optionally phototrophic are preferably used in the process according to the invention.
  • Optional phototrophic means that the microorganisms can grow both under anaerobic conditions in the light and under aerobic conditions in the dark.
  • Photosynthetic bacteria include gram-negative aerobic rod-shaped and circular bacteria as well as gram-positive circular bacteria. These can have endospores or be present without spores. These include, for example, gram-positive actinomycetes and related bacteria.
  • nitrogen-binding organisms can also be mentioned.
  • algae such as Anabena Nostoc in symbiosis with Azola.
  • actinomycetes e.g. B. Frankia in symbiosis with alder and bacteria, such as Rhizobium in symbiosis with legumes.
  • Aerobic algae, Azotobacter, methane oxidizing bacteria and sulfur bacteria can also be used. This also includes green sulfur bacteria and brown-green photosynthesis bacteria. Violet sulfur bacteria and violet sulfur bacteria cannot be mentioned here either.
  • prochlorophytes, cyanobacteria, green sulfur bacteria, purple bacteria forms similar to chloroflexus and heliobacterium and as optional phototrophic microorganisms Heliobacillus-like shapes are included.
  • the aforementioned optional phototrophic microorganisms can also be present as mixtures of two or more of them. In a very special embodiment, all six of the microorganisms mentioned are present as a mixture.
  • the light that drives photosynthesis comes from the luminous bacteria, which are contained as a second essential component in the microbiological composition used in the method according to the invention.
  • These luminous bacteria have a luminosity, i. H. they are able to emit light quanta. It is a system that works enzymatically.
  • the luciferin-luciferase system can be mentioned here as an example.
  • the mixed culture contains a proportion of microorganisms, especially bacteria that
  • Microorganisms such as Archaea are used for the facile electron transfer of the reduction and other microorganisms such as slime molds protect the mixed culture and also serve to emit phosphorizing light. It is believed that there is a constant near the catalytic surface
  • Such minor components are preferably plant extracts, enzymes, trace elements, polysaccharides, algin derivatives, other microorganisms as above.
  • the secondary components can be present individually or in combination in the microbiological composition.
  • the plant extracts can contain, for example, plantain, hops, etc.
  • a solution is generally used as the nutrient solution for the microbiological composition used, which contributes to the fact that the constituents contained therein, in particular the microorganisms, can easily live in them. It is particularly important that the interaction of the photosynthetic bacteria and the luminous bacteria is fully effective. It has been shown that a biological nutrient solution with molasses, in particular raw sugar molasses or sugar beet molasses, is suitable as the main component.
  • the photosynthetic microorganisms and the luminous bacteria are normally in one in the microbiological composition according to the invention
  • the amount of the mixed culture solution used in the process according to the invention is not a particular one
  • the components described above are homogenized so that a microbiotic culture is present as the first intermediate product of the method according to the invention, the proportion of which is adjusted depending on the water to be treated. If appropriate, the mixed culture is frozen for later use or lyophilized in vacuo with dehydration.
  • the drying parameters are set so that the microorganisms are not damaged.
  • Preliminary tests showed that a Cooling rate with more than 30 ° C per minute, preferably about 40 ° C per minute or faster is optimal in order to prevent damage to the microorganisms.
  • the initial sharp drop in the oxygen concentration is due to the fact that the toxic components must first be broken down by the microorganisms. After the extensive breakdown of these toxic components, the oxygen content increases due to the decomposition of the organic components and the associated production of oxygen, until it reaches a largely constant level.
  • a visual assessment of the wastewater shows that it has become much clearer compared to the initial cloudy state due to the decomposition of the organic components.
  • the advantageous effect of the method according to the invention can also be demonstrated if the container is covered from daylight or another light source - the effect of the light-emitting bacteria is evidently sufficient to break down the organic constituents via the microorganisms and the photocatalytic effect of the lining enable.
  • the redox potential of more than 700 mV in contaminated waters can be increased to a range of 350-400 mV using the method according to the invention. After the microorganisms have been separated off via a membrane, the remaining redox potential could then be set to> + 800 mV by adding minimal amounts of ozone and chlorine.
  • the method according to the invention is also advantageously suitable for cleaning water in public and private facilities. These include, for example, swimming pools, fountains, etc.
  • the waters contaminated with algae can be cleaned quickly and effectively using the method according to the invention. This means that bodies of water contaminated with pollutants that do not get into the sewage treatment plants can also be cleaned. This includes, for example, waste water from agriculture, such as horse channels, etc.
  • the method according to the invention can be used to effectively purify water without the need for a special apparatus. The process is gentle on the environment and harmless to the people working with it.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Water Supply & Treatment (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Organic Chemistry (AREA)
  • Microbiology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Physical Water Treatments (AREA)
  • Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)
  • Catalysts (AREA)
  • Biological Treatment Of Waste Water (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)

Abstract

La présente invention concerne un procédé pour purifier de l'eau. Ce procédé consiste à ajouter à l'eau se trouvant dans un environnement catalytique une solution qui contient une fraction d'une culture mixte microbiotique. Ce procédé s'avère efficace lorsqu'il est mis en oeuvre pour purifier des eaux usées et des eaux se trouvant dans des installations publiques et privées.
EP03785487A 2002-10-16 2003-10-16 Purification d'eau avec des surfaces catalytiques et des micro-organismes Withdrawn EP1551774A2 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10248315 2002-10-16
DE10248315 2002-10-16
PCT/DE2003/003460 WO2004035478A2 (fr) 2002-10-16 2003-10-16 Purification d'eau avec des surfaces catalytiques et des micro-organismes

Publications (1)

Publication Number Publication Date
EP1551774A2 true EP1551774A2 (fr) 2005-07-13

Family

ID=32086957

Family Applications (1)

Application Number Title Priority Date Filing Date
EP03785487A Withdrawn EP1551774A2 (fr) 2002-10-16 2003-10-16 Purification d'eau avec des surfaces catalytiques et des micro-organismes

Country Status (7)

Country Link
US (1) US7160461B2 (fr)
EP (1) EP1551774A2 (fr)
AU (1) AU2003294612A1 (fr)
CA (1) CA2502223A1 (fr)
DE (1) DE10348732A1 (fr)
RU (1) RU2005114527A (fr)
WO (1) WO2004035478A2 (fr)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102005050414A1 (de) * 2005-10-19 2007-04-26 Georg Fritzmeier Gmbh & Co. Kg Optoreaktor
DE102006005585A1 (de) * 2005-12-01 2007-06-06 Georg Fritzmeier Gmbh & Co. Kg Abwasserbehandlungsanlage
DE102007006446A1 (de) * 2006-02-03 2007-08-23 Georg Fritzmeier Gmbh & Co. Kg Verfahren zur Aufbereitung von organisches Material beinhaltenden Abfällen, beispielsweise Grünabfällen
US8388844B2 (en) * 2007-08-10 2013-03-05 Arizona Board Of Regents For And On Behalf Of Arizona State University Intimate coupling of photocatalysis and biodegradation in a photocatalytic circulating-bed biofilm reactor
DE102007052566A1 (de) * 2007-11-03 2009-05-07 H. & M. Gutberlet Gmbh Industrievertretungen C.D.H. Reinigungsvorrichtung zur Reinigung von insbesondere mit Algen oder Moos befallenen flächigen Gegenständen sowie Reinigungsverfahren mit einer derartigen Reinigungsvorrichtung
US8491789B2 (en) * 2009-07-31 2013-07-23 Brian E. Butters Water treatment process for the reduction of THM and HAA formation
CN102701464B (zh) * 2012-06-25 2013-09-04 福建省洋屿化工工贸有限公司 生态菌床污水处理工艺
CN105749952A (zh) * 2016-03-16 2016-07-13 扬州大学 B、N、Ti共掺杂漂浮型环境修复材料的制备方法及其应用
CN106268908A (zh) * 2016-08-19 2017-01-04 扬州大学 一种去除有机污染物的石墨相C3N4掺杂TiO2负载膨胀珍珠岩的漂浮型环境修复材料及其制备方法
CN115487661B (zh) * 2022-10-09 2024-08-06 浙江工业大学 一种光电驱动微生物光电解池降解1,2-二氯乙烷的方法

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5194161A (en) * 1989-09-25 1993-03-16 Board Of Regents, The University Of Texas System Materials and methods for enhanced photocatalyzation of organic compounds with palladium
DE69415228T2 (de) 1993-07-12 1999-06-02 Ishihara Sangyo Kaisha Ltd., Osaka Verfahren zur Herstellung eines Photokatalysators und Verfahren zur Wasserreinigung
JP3125696B2 (ja) 1996-04-25 2001-01-22 ダイキン工業株式会社 流体浄化装置
FR2764210B1 (fr) * 1997-06-09 1999-07-16 Inst Francais Du Petrole Catalyseur d'hydrogenation selective utilisable pour le traitement des coupes essences contenant des diolefines et des composes styreniques
EP1238068A1 (fr) * 1999-12-08 2002-09-11 California Institute Of Technology Evolution dirigee de voies de biosynthese et de biodegradation
FR2806006B1 (fr) 2000-03-07 2002-09-06 Nanopoudres Technologies Nouveaux reacteurs photocatalytiques a base de dioxyde de titane sur support silice pour le traitement de l'air et de l'eau
DE10062812B4 (de) 2000-12-18 2009-07-09 Georg Fritzmeier Gmbh & Co. Kg Mikrobiologische Zusammensetzung
DE20120403U1 (de) 2001-10-11 2002-06-06 Böhme, Mario, 64846 Groß-Zimmern Vorrichtung zur Entkeimung von Wasser

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO2004035478A2 *

Also Published As

Publication number Publication date
DE10348732A1 (de) 2004-05-06
US7160461B2 (en) 2007-01-09
US20050242024A1 (en) 2005-11-03
AU2003294612A1 (en) 2004-05-04
RU2005114527A (ru) 2006-01-20
CA2502223A1 (fr) 2004-04-29
WO2004035478A2 (fr) 2004-04-29
AU2003294612A8 (en) 2004-05-04
WO2004035478A3 (fr) 2004-07-01

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