EP1606036A2 - Insektrepellant, universalinsektenvertilgungsmittel, und dessen herstellungsverfahren - Google Patents

Insektrepellant, universalinsektenvertilgungsmittel, und dessen herstellungsverfahren

Info

Publication number
EP1606036A2
EP1606036A2 EP04720638A EP04720638A EP1606036A2 EP 1606036 A2 EP1606036 A2 EP 1606036A2 EP 04720638 A EP04720638 A EP 04720638A EP 04720638 A EP04720638 A EP 04720638A EP 1606036 A2 EP1606036 A2 EP 1606036A2
Authority
EP
European Patent Office
Prior art keywords
acetate
insecticide
insect repellant
insect
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
EP04720638A
Other languages
English (en)
French (fr)
Inventor
Georges Camprasse
Serge Camprasse
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=32893294&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP1606036(A2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Individual filed Critical Individual
Publication of EP1606036A2 publication Critical patent/EP1606036A2/de
Ceased legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08—Magnoliopsida [dicotyledons]
    • A01N65/28—Myrtaceae [Myrtle family], e.g. teatree or clove
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/06—Coniferophyta [gymnosperms], e.g. cypress
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08—Magnoliopsida [dicotyledons]
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08—Magnoliopsida [dicotyledons]
    • A01N65/10—Apiaceae or Umbelliferae [Carrot family], e.g. parsley, caraway, dill, lovage, fennel or snakebed
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08—Magnoliopsida [dicotyledons]
    • A01N65/22—Lamiaceae or Labiatae [Mint family], e.g. thyme, rosemary, skullcap, selfheal, lavender, perilla, pennyroyal, peppermint or spearmint
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08—Magnoliopsida [dicotyledons]
    • A01N65/24—Lauraceae [Laurel family], e.g. laurel, avocado, sassafras, cinnamon or camphor
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/40—Liliopsida [monocotyledons]
    • A01N65/44—Poaceae or Gramineae [Grass family], e.g. bamboo, lemon grass or citronella grass

Definitions

  • the present invention relates to an insect repellant and insecticide produced from organic chemical compounds contained in botanical aromatic essences, biologically and biochemically defined, extracted by steam distillation or by cold pressure from the various organs of plants and trees. , previously discriminated against and whose combined effects have a repulsive or lethal action on most seasonal insects.
  • aromatic essences are noble waste products from the metabolism of plants and trees. They are lipophilic, volatile products, made up of many chemicals which are not very soluble in water. These volatile essences diffuse through the epidermis of the leaves and flowers and spread a very pronounced odor. They mainly result from the metabolism of terpenes and that of C6 - C3 compounds.
  • the main molecule is; the isoprene unit composed of 5 carbon atoms.
  • Terpenes are composed of a variable number of isoprene units to form monoterpenes, sesquiterpenes, diterpenes.
  • Monoterpenes composed of two isoprene units linked to ten carbon atoms, have either a cyclohexane ring and two double bonds, or a bicyclic ring with nested rings related to unsaturated hydrocarbons. These compounds have well-defined properties: irritants, anti-infectives, insecticides and repellents. We also find the monoterpene structure in pyrethrins and iridoids.
  • Sesquiterpenes composed of three isoprene units, forming a simple acyclic chain, condensed, sometimes several nested cycles, are also related to unsaturated carbides C15H24 and have many interesting pharmacological properties.
  • ketones are present in aromatic essences. These are compounds where an oxygen atom binds to a carbon atom to form a unit that attaches to a hydrocarbon compound, as do acids 3 esters, which are complex combinations of carbon, hydrogen and of oxygen, as well as lactones whose molecular weight is very high and which are found only in certain aromatic essences obtained by pressure.
  • Insects are the most important class of arthropod phylum and include around thirty important orders in pathology, hygiene and agronomy. Some species are harmful to crops, woods, grains, domestic or wild animals and can be intermediate hosts of Cestodes, others are vectors of infectious or parasitic diseases. The presence of insects such as flies, mosquitoes, midges, horseflies, wasps etc. in the premises where humans and animals stay, generates multiple drawbacks, namely bites, spread of infectious or parasitic diseases, contamination of food etc ..
  • Insects have an extraordinary resistance thanks to the chemical composition and the impermeability of their integuments.
  • ultra-perfected sensory apparatuses which can reside at the level of the antennae as well as at the level of the body and the legs, they become vulnerable to the actions of certain substances which can reach them via these organs.
  • insecticidal properties of pyrethrum have been known since antiquity, the flower heads of which contain numerous constituents and a mixture of pyrethrins, substances which are very toxic to cold-blooded animals such as insects and worms, while being slightly toxic to man.
  • Patent WO 03/015522 A1 develops formulas composed essentially of anti-mite action monoterpenes:
  • insecticide preparations are described mixing essential oils and 1 L0 synthetic molecules to make insecticide blocks, while Catherine REGNAULT , Roger and Ail demonstrate that the same constituents of different essential oils do not have similar effects on the same types of insects.
  • patent WO 00/00213 proposes the formulation of insecticides against head and body lice comprising three different essential oils per preparation.
  • aromatics entering into the composition of the product according to the invention are biologically and biochemically defined according to the molecules which they contain and whose properties confer to them not only insect repellant effects but also insecticides.
  • the biochemical definition of an aromatic essence precisely characterizes the chemical molecules that compose it. Indeed, it is recognized that the biochemical composition of the same plant varies by country, soil, growing conditions, harvest time. This characterizes the biochemical specificity. Finally, whenever necessary, the producing organ is specified.
  • the product according to the invention is composed of the following aromatic essences: Aniba rosaedora - Artemisia absinthium - Cedrus atlantica - Cirrus aurantifolia - Cirrus bergamia - Cupres sempervirens - Cymbopogon citratus - Eucalyptus globulus - Eugenia caryophyllata - Euphoria punicea - Foeniculum vulgare - Helichrysum italicum - Juniperus communis - Laurus nobilis - La ⁇ vandula latifolia spica- Melaleuca alternifolia - Melale ⁇ ca viridifolia - Melissa officinalis - Mentha pipicusumerusumerususericusumerusumerususerumususumerusususususususus - Pog ⁇ stemon cablin - Rosmarinus
  • the aromatic essences entering into the composition of the product according to the invention are for example: Aniba rosaedora botanically, biologically and biochemically defined, obtained by steam distillation of the heart of the wood and whose gas chromatography has revealed the molecules following chemicals:
  • Cedrus atlantica botanically, biologically and biochemically defined, obtained by distillation of wood with water vapor, revealed by gas chromatography,
  • Cirrus aurantifolia botanically, biologically and biochemically defined, obtained by steam distillation of the whole fruit, whose chemical components separated and identified by gas chromatography are:
  • Citrus bergamia botanically, biologically and biochemically defined, obtained by cold pressing of the skin of the fruit whose gas chromatography has revealed - three alcohols: linalool, nerol, terpineol,
  • Cupresus sempervirens obtained by steam distillation of fresh leaves, twigs and cones and whose gas chromatography has separated the following chemical molecules:
  • camphene camphene
  • p-cymene p-cymene
  • ⁇ pinene sylvestrene
  • camphene fenchene, ⁇ phellandrene and ⁇ pinene, whose antiseptic, antiviral, bactericidal, parasiticidal properties are reinforced by recognized insect repellant properties.
  • An Alcoholature of the nucleus of the fruit of Euphoria punicea is obtained by simple maceration for 30 days in alcohol at 90 °, protected from light until a burgundy-colored solution with powerful vasodilatory properties is obtained.
  • a phellandrene a pinene, camphene, dipentene, limonene, which give them, in addition to anti-microbial, antiseptic, powerful insecticidal properties.
  • Juniperus communis properties botanically, biologically and biochemically defined, obtained by steam distillation of needles and wood and whose gas chromatography to reveal chemical molecules such as: - two sesquiterpenes: cadinene and cedrene,
  • Lavandula latifolia spica botanically, biologically and biochemically defined, obtained by steam distillation of fresh flowers and whose gas chromatography identifies the following molecules:
  • esters geranyl acetate, lavandulyl acetate, lynalyl acetate,
  • sesquiterpene ⁇ caryophyllene
  • - two terpenes limonene and a pinene with anti-microbial, antiseptic, bactericidal, deodorant, fungicidal, sanitizing and especially insecticidal properties.
  • Melaleuca viridifolia botanically, biologically and biochemically defined, obtained by steam distillation of twigs of flowers and young shoots, whose chemical composition obtained by gas chromatography consists of the following molecules: - an acid: the acid 3-methylbutanoic acid,
  • citronellic acid the recognized insecticidal properties of which are associated with bactericidal properties.
  • Mentha piperita botanically, biologically and biochemically defined, obtained by steam distillation of the whole plant and whose gas chromatography has revealed the following chemical molecules:
  • sabinene compounds which give the essences of Pelargonium graveolens powerful insecticidal, fungicidal, repellant, deodorant and antimicotic properties.
  • Pinus sylvestris botanically, biologically and biochemically defined, obtained by steam distillation of twigs, needles and cones subjected to gas chromatography show in their components the following chemical molecules:
  • sesquiterpene cadinene
  • - five terpenes camphene, dipentene, phellandrene, pinene, sylvestrene
  • Pogostemon cablin botanically, biologically and biochemically defined, obtained by steam distillation of the dried and fermented leaves and subjected to gas chromatography which identified the following chemical molecules:
  • Rosmarinus officinalis obtained by steam distillation of the leaves and flowering tops, subjected to gas chromatography, are composed of the following chemical molecules:
  • santalene - an alcohol: santalol, episantanol,
  • Thymus serpillum botanically, biologically and biochemically defined, obtained by steam distillation of flowering stems and whose gas chromatography has made it possible to identify
  • Vetiveria zizano ⁇ des botanically, biologically and biochemically defined, obtained by steam distillation of the roots, and whose gas chromatography allowed to isolate - an acid: benzoic acid,
  • vetivone which gives the complex antiseptic properties, associated with powerful insect repellant properties.
  • the aromatic essences composing the product according to the invention have a volatility index ranging from 5 to 100, that is to say essences of higher, medium and lower classes. Indeed, the volatility index of Eucalyptus globulus for example is 5, of higher class indicating that the lightness of this essence allows it a faster diffusion, giving it a higher tone, immediate action.
  • the aromatic essence of Citrus bergamia has a volatility index of 55, which indicates a medium tone
  • the aromatic essences of Pogostemon cablin, Vetiveria zizano ⁇ des and Pelargonium graveolens have a basic tone.
  • the presence of aromatic essences having these three types of tone, namely superior, medium and basic gives the product according to the invention, its originality. Indeed, the aromatic essences at the higher tone have an immediate and rapid action the aromatic essences at the medium tone explain the persistence, the aromatic essences at the base tone fix the essences at the medium tone by prolonging their diffusion.
  • the insect repellant and / or insecticidal effects of aromatic essences being limited in time and in space because of their volatile nature, their use is more readily limited to electric diffusers or to devices with very localized effects. It was therefore necessary, with the aim on the one hand of increasing its persistence, and on the other hand of broadening its use in aerosols, with the aim of causing an immediate killing effect, to find a process who would allow it.
  • Additives, such as resins, waxes have already been proposed, but the chemical molecules which compose them are likely to react with those of aromatic essences and to modify their behavior.
  • the product according to the invention contains aragonite biocrystals reduced to a powder of very fine particle size, namely from 0.5 to 1 micron.
  • biocrystals are composed of two phases: an organic phase, essentially collagen, and an inorganic phase, calcium carbonate crystallized in aragonitic form.
  • the presence of these biocrystals gives the product according to the invention residual properties in time and space.
  • These biocrystals, impregnated with the products according to the invention behave like microcapsules which, fixed to the shell and to the wings of insects like pollen, release the product according to the invention in a delayed manner, thereby increasing its duration d 'action.
  • the density of Faragonite close to 2.7, causes an overweight in the wings of small insects such as mosquitoes, and contributes to disturb the flight.
  • the product according to the invention according to a preferred embodiment, and without this example being limiting, can be presented for example in the form below:
  • Aromatic essences of Cupresus sempiverens biochemically defined with the following molecules: sabinol - furfurol - camphene - cymene - alpha pinene - sylvestrene - terpenyl acetate 5 ml
  • Aromatic essences Eugenia carryophyllata biochemically defined with the following molecules: eugenol - eugenyl acetate 5 ml
  • Aromatic essences of Mentha piperita biochemically defined with the following molecules: menthol - menthyl acetate - menthone 5 ml
  • Aromatic essences of Pinus sylvestris biochemically defined with the following molecules: borneol - bornyl acetate - terpenyl acetate - candinene - camphene - dipentene - ⁇ phellandrene - pinene - sylvestrene 5 ml
  • Thymus serpiUum biochemically defined with the following molecules: thymol - carvacrol - caffeic acid - rosmarinic acid - p-cimene - linalol 5 ml
  • Aromatic essences of Vetiveria zizanoides biochemically defined with the following molecules: benzoic acid - vetiverol - vetivene - furfurol - vetivone 5 ml
  • the product according to the invention is mixed with various solvents, such as those already mentioned, such as, for example, alcohols, hydrocarbons or hydrocarbon alcohol mixtures, at concentrations of 1.5% or 3% in order to undergo efficacy tests.
  • solvents such as those already mentioned, such as, for example, alcohols, hydrocarbons or hydrocarbon alcohol mixtures, at concentrations of 1.5% or 3% in order to undergo efficacy tests.
  • the speed of rotation of the propeller being approximately 1500 revolutions / minute, the mixture is stirred constantly for thirty minutes at the end of which are poured 10 ml of a commercial dispersant until a solution of viscosity is obtained. of 10.30 m. Not, for example, which defines the product according to the invention.
  • the product according to the invention can be packaged in hermetically closed stainless steel containers and stored in a cold room until conditioned, with constant stirring.
  • the following example illustrates the particularity of the product according to the invention: two translucent plastic enclosures of 60 liters each are produced, separated by a removable panel. By opening the first enclosure, one hundred flies of age and equivalent size are introduced, coming from different strains.
  • the experimental conditions are as follows: temperature 26 ° C, humidity rate 60%.
  • the normal activity of the flies is noted before spraying the product according to the invention in an aerosol for five seconds. There is an immediate killing effect on flies affected by the aerosol cloud, with a KT50 (50% mortality rate) after four minutes.
  • the biochemical analysis of the softened parts shows the presence of triterpene sapogenin, the highly hemolytic properties of which lethally degrade the blood elements of the insects studied, and cause suffocation.
  • the example described above demonstrates that the presence of fragments of aragonite biocrystals in the product according to the invention, characteristically potentiates not only its persistence but induces a lethal delay effect due to the deacetylation of the shell of insects and thereby increases its insecticidal properties.
  • its mode of action is similar to that of organophosphates and pyrethroids acting by contact and by ingestion, by inhibiting the transmission of cholinestherase by probably fixing on the active sites of this enzyme, and preventing it from hydrolyzing Facethylcholine, hence prolonging the action of this chemical mediator and indirect reinforcement of the central and peripheral cholinergic effects.
  • the product according to the invention is an irreversible cholinesterase inhibitor located in the neurons and at the neuromuscular junction, which explains the mortality rate at first contact and the absence of recovery after 24 hours.
  • the product according to the invention can be mixed, without these examples being limiting, with vectors serving as solvents such as hydrocarbons of the group derived from propane, saturated hydrocarbon with 3 carbons, with isoparaffinic hydrocarbon, with alcohols such as ethyl alcohol. , - methyl alcohol, to an ethyl / isopropyl mixture, to resins in order to increase the persistence or to demineralized water.
  • vectors serving as solvents such as hydrocarbons of the group derived from propane, saturated hydrocarbon with 3 carbons, with isoparaffinic hydrocarbon, with alcohols such as ethyl alcohol. , - methyl alcohol, to an ethyl / isopropyl mixture, to resins in order to increase the persistence or to demineralized water.
  • the product according to the invention is also in the form of solutions of different viscosities in electric diffusers. It can also enter into the composition of candles intended to repel insects such as flies, mosquitoes and wasps or in it
  • the product according to the invention mixed with surfactants can enter into the composition of shampoos, soaps, lotions, for all types of domestic animals, at different concentrations depending on the size and the species of animals considered.
  • the product according to the invention can be packaged in pressure vessels fitted with devices allowing spraying in the premises.

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Natural Medicines & Medicinal Plants (AREA)
  • Mycology (AREA)
  • Biotechnology (AREA)
  • Microbiology (AREA)
  • Agronomy & Crop Science (AREA)
  • Plant Pathology (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Botany (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
EP04720638A 2003-03-14 2004-03-15 Insektrepellant, universalinsektenvertilgungsmittel, und dessen herstellungsverfahren Ceased EP1606036A2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR0303149 2003-03-14
FR0303149A FR2852204A1 (fr) 2003-03-14 2003-03-14 Insectifuge et insecticide universel son procede de fabrication
PCT/FR2004/000629 WO2004082358A2 (fr) 2003-03-14 2004-03-15 Insectifuge, insecticide universel, son procede de fabrication

Publications (1)

Publication Number Publication Date
EP1606036A2 true EP1606036A2 (de) 2005-12-21

Family

ID=32893294

Family Applications (1)

Application Number Title Priority Date Filing Date
EP04720638A Ceased EP1606036A2 (de) 2003-03-14 2004-03-15 Insektrepellant, universalinsektenvertilgungsmittel, und dessen herstellungsverfahren

Country Status (3)

Country Link
EP (1) EP1606036A2 (de)
FR (1) FR2852204A1 (de)
WO (1) WO2004082358A2 (de)

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US6524605B1 (en) 1999-08-06 2003-02-25 Iowa State University Research Foundation, Inc. Biorational repellents obtained from terpenoids for use against arthropods
US7939091B2 (en) * 1999-08-06 2011-05-10 Iowa State University Research Foundation, Inc. Biorational repellents obtained from terpenoids for use against arthropods
FR2906441B1 (fr) * 2006-09-29 2013-01-18 Ab7 Ind Repulsif insectes a base de molecules naturelles.
WO2008082028A1 (en) * 2006-12-28 2008-07-10 Bio & Hnt, Inc. Mosquito repellent comprising an esterified glycerol.
KR100754416B1 (ko) * 2007-05-17 2007-08-31 (주)바이오앤에이치엔티 모기 기피제 조성물
FR2958500B1 (fr) * 2010-04-07 2013-02-08 Jd Invest Preparation insecticide, insectifuge, ovicide, larvicide, nymphicide
US9999218B2 (en) 2011-10-04 2018-06-19 0903608 B.C. Ltd. Pest control formulations and methods of making and using same
CA2849270C (en) * 2011-10-04 2021-11-23 0903608 B.C. Ltd. Pest control formulations and methods of making and using same
MX363121B (es) * 2013-09-25 2019-03-11 Veronica Ayala Gutierrez Susana Una mezcla de aniba rosaeodora y styrax portoricensis para eliminar olores vaginales.
FR3019971B1 (fr) * 2014-04-22 2017-05-05 Greenpharma Sas Composition repulsive pour animaux sauvages ou domestiques
US10743535B2 (en) 2017-08-18 2020-08-18 H&K Solutions Llc Insecticide for flight-capable pests
CN114467963B (zh) * 2021-07-01 2024-02-13 山东中医药大学 一种用于金银花的杀虫剂复配载药微球及其制备方法
CN113907094B (zh) * 2021-09-29 2022-10-28 华南农业大学 一种紫外杀菌增效剂法国丝柏精油及其应用

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Also Published As

Publication number Publication date
WO2004082358A2 (fr) 2004-09-30
FR2852204A1 (fr) 2004-09-17
WO2004082358A3 (fr) 2004-10-28

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