EP1610963A2 - Procede pour remplir des films decores, par injection - Google Patents

Procede pour remplir des films decores, par injection

Info

Publication number
EP1610963A2
EP1610963A2 EP04718631A EP04718631A EP1610963A2 EP 1610963 A2 EP1610963 A2 EP 1610963A2 EP 04718631 A EP04718631 A EP 04718631A EP 04718631 A EP04718631 A EP 04718631A EP 1610963 A2 EP1610963 A2 EP 1610963A2
Authority
EP
European Patent Office
Prior art keywords
protective element
film
decorated
thermoplastic
mold cavity
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP04718631A
Other languages
German (de)
English (en)
Inventor
Roland KÜNZEL
Axel Kaminski
Winfried Kohl
Klaus Schürmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Covestro Deutschland AG
Original Assignee
Bayer MaterialScience AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer MaterialScience AG filed Critical Bayer MaterialScience AG
Publication of EP1610963A2 publication Critical patent/EP1610963A2/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
    • B29C45/14778—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles the article consisting of a material with particular properties, e.g. porous, brittle
    • B29C45/14795—Porous or permeable material, e.g. foam
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
    • B29C45/14836—Preventing damage of inserts during injection, e.g. collapse of hollow inserts, breakage
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C3/00—Processes, not specifically provided for elsewhere, for producing ornamental structures
    • B44C3/02—Superimposing layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
    • B29C2045/1486—Details, accessories and auxiliary operations
    • B29C2045/14868—Pretreatment of the insert, e.g. etching, cleaning
    • B29C2045/14877—Pretreatment of the insert, e.g. etching, cleaning preheating or precooling the insert for non-deforming purposes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
    • B29C45/14688—Coating articles provided with a decoration

Definitions

  • the invention relates to a method for the back injection of decorated foils with a thermoplastic, in which the decorated foil is protected from washing out.
  • Foiling behind is a widely used process for the design of surfaces.
  • a decorated film is shaped, trimmed and then placed in the injection mold and back-molded.
  • the decor is protected by the transparent foil on the outside.
  • the decor is exposed to high thermal loads and shear stresses, which leads to washouts in the area of the injection points. It is known to cover the decorative layer with a protective layer in order to avoid washing out, so that the melt does not come into direct contact with the decorative layer.
  • Such a protective layer consists, for example, of polycarbonate (PC), acrylonitrile-butadiene-styrene (ABS), polymethyl methacrylate (PMMA), acrylonitrile-styrene-acrylate (ASA). It is either applied directly during the manufacture of a component by means of coextrusion or subsequently laminated with the aid of adhesion promoters. This process is described, for example, in P. Enewoldsen, H. Braun, Foil Back Injection Molding - Decorating in an Injection Molding Machine, KU Ku tstoffe 89 (1999) 9, pages 102-104.
  • PC polycarbonate
  • ABS acrylonitrile-butadiene-styrene
  • PMMA polymethyl methacrylate
  • ASA acrylonitrile-styrene-acrylate
  • a disadvantage of this method is that protection of the entire surface is actually not necessary, since leaching occurs only locally at the injection points. The cost of materials is therefore higher than necessary. Furthermore, this multilayer structure can lead to a reduced adhesion of the decorative layer to the entire component.
  • a major disadvantage, however, is the lack of three-dimensional deformation. Thermoforming is only possible to a limited extent, since in most cases the adhesive sealer with which the protective layer is applied to the decorative layer leads to the formation of gas bubbles between the layers. Furthermore, with such multilayer films, only deformation below the softening point is possible. The high pressure forming process used for this is limited in its deformation area.
  • the injection mold can also be adapted so that the shear rate and the throughput, eg volume throughput, are lower per injection point. This requires however, a higher number of gating points, which results in an increased number of weld lines and, associated therewith, a loss of strength at the weld lines.
  • a method is also known in which the decorative layer is partially overprinted with a clear lacquer, for example a two-component polyurethane lacquer, in the area of the injection points.
  • a clear lacquer for example a two-component polyurethane lacquer
  • the invention is therefore based on the object of developing a method for the back injection of decorated foils, in which wash-outs on the decorated foil in the region of the melt inlet openings into the foil cavity of the injection mold are avoided.
  • the invention accordingly relates to a method for injecting decorated foils with a thermoplastic plastic, the foil being in full contact with the inner wall of the mold cavity, which is characterized in that the decorated foil before injecting in the region of one or more inlet openings for the thermoplastic material is provided with a protective element in the mold cavity.
  • the protective element is applied to the decorative layer of the decorated film opposite one or more inlet openings, so that the plastic melt does not come into contact with the decor in the region of the injection point when it is injected into the mold cavity.
  • the protective element serves as a thermal insulator. It prevents the heat of the thermoplastic from melting on the printing ink during back injection and flowing with the melt.
  • the protective element also offers mechanical protection by preventing the melt from coming into direct contact with the decorated film. In this way, the protective element protects the printing ink from the high shear stresses when injecting in the area of the injection points.
  • the area of the protective element depends on the area of the washout.
  • the size of the inlet opening through which the thermoplastic enters the injection mold essentially determines the area of the washout.
  • the area of the protective element is preferably at least twice, preferably at least ten times, the cross section of the respectively opposite inlet opening.
  • the protective element is preferably a net, fabric, braid or fleece made of metal, plastic and / or natural material and / or a foil made of metal and / or plastic.
  • metal plastic and / or natural material
  • foil made of metal and / or plastic.
  • metals aluminum, copper, alloys or steel
  • plastics elastomers or thermoplastics can be used as plastics elastomers or thermoplastics.
  • the plastics can optionally also be provided with reinforcing and / or fillers, for example glass fibers.
  • the protective element can consist, for example, of the following plastics: polycarbonate (PC), acrylonitrile butadiene styrene (ABS), styrene acrylonitrile (SAN), polybutylene terephthalate (PBT), polyamide (PA), thermoplastic polyurethane (TPU), polyethylene terephthalate ( PET), polystyrene (PS), polyoxymethylene (POM), popoley rubber, in particular polypropylene (PP), polyester, polymethyl methacrylate (PMMA), thermoplastic polyvinyl chloride (PVC) or mixtures of thermoplastic materials.
  • PC polycarbonate
  • ABS acrylonitrile butadiene styrene
  • SAN styrene acrylonitrile
  • PBT polybutylene terephthalate
  • PA polyamide
  • TPU thermoplastic polyurethane
  • PET polyethylene terephthalate
  • PS polystyrene
  • POM polyoxymethylene
  • Cotton, cellulose, hemp, flax or cork can be selected.
  • a combination of the fabrics and / or materials mentioned is also possible.
  • the thickness of the protective element depends on the amount of plastic injected through the inlet opening.
  • the protective element preferably has a thickness of at least 50 ⁇ m.
  • the protective element is preferably applied to the decorated film by means of an adhesive binding.
  • Adhesives used for this purpose are, for example, aqueous polyurethane dispersions, aqueous acrylate copolymer dispersions and polyurethanes dissolved in organic solvents.
  • the protective element can also be applied by heating the film and then pressing the protective element with the film.
  • the protective element can be applied to the decorated film by welding.
  • the method according to the invention enables direct gating without washing out. It is therefore not necessary to spray on tabs or pins.
  • Direct injection also has the advantage that cascade technology, i.e. the delayed activation of the entry openings can be used.
  • cascade technology i.e. the delayed activation of the entry openings can be used.
  • no structural changes to the injection mold are necessary, e.g. the introduction of additional gates to reduce the volume throughput per gate.
  • the protective element can also be adapted to the local shape of the decorated film.
  • the material and processing costs are i. Compared to conventional methods, it is less, since the amount of material for protection is reduced to a minimum and only a protective element has to be applied locally instead of a full-surface protective layer.
  • unfilled or reinforced or reinforced fillers are used, such as polycarbonate, acrylonitrile-butadiene-styrene (ABS), styrene-acrylonitrile (SAN), polybutylene terephthalate (PBT), polyamide ( PA), thermoplastic polyurethane (TPU), polyethylene terephthalate (PET), polystyrene (PS), polyoxymethylene (POM), polyolefms, e.g. polyethylene (PE), polypropylene (PP), polyester, polymethyl methacrylate (PMMA), elastomer-modified blends, thermoplastic PVC or mixtures of thermoplastic materials.
  • ABS acrylonitrile-butadiene-styrene
  • SAN styrene-acrylonitrile
  • PBT polybutylene terephthalate
  • PA polyamide
  • TPU thermoplastic polyurethane
  • PET polyethylene terephthalate
  • PS polystyrene
  • POM polyoxym
  • the layer thickness of the back-molded thermoplastic varies greatly depending on the application.
  • the thickness of the plastic layer is preferably 1 to 6 mm. However, it can vary from a few tenths of a millimeter to more than 10 mm (thermoplastic foam casting).
  • the decorated film consists, for example, of polycarbonate, ABS, cellulose esters, polyethylene (PE), polypropylene (PP), polyethylene terephthalate (PET), polybutylene terephthalate (PBT), polymethyl methacrylate (PMMA), PVC, polyester, polysulfones, polyether sulfones, polyether ether ketones (PEEK) ), Polyaryl ether sulfones, polyurethane (PU) and polyamide (PA).
  • functional multilayer films, films made from plastic mixtures, blends or films provided with reinforcing and / or fillers can also be used.
  • the film is decorated, for example, using the screen printing process.
  • Other possible processes for decorating the film are painting, laminating, pad printing, offset, thermal transfer, high pressure (incl. Flexo), planographic printing, gravure printing, inkjet, photography, thermography, magnetography, ionography, electrography.
  • the usual printing colors e.g. Screen printing inks used.
  • FIG. 1 shows a schematic illustration of a film 2 with decorative layer 6, which is inserted into the mold cavity 7 of an injection molding tool 1 and which is in full contact with the inner wall of the mold cavity 7.
  • the decorative layer 6 is provided with a protective element 4.
  • the thermoplastic 3 Via the inlet opening 5 of the injection molding tool 1, the thermoplastic 3 enters the mold cavity 7 for the back injection of the film 2 provided with a decorative layer 6. example
  • the example describes the injection molding of a decorated foil for an engine cover.
  • the film was a film made of polycarbonate (PC), which was screen-printed on the back with a solution of synthetic synthetic resins in organic solvents (Noriphan® HTR from Pröll, Germany). After printing, the film was thermoformed and then trimmed. Protective elements made of polycarbonate with an area of 24 ⁇ 75 mm 2 were then applied to the printed film in the area of the injection points.
  • the protective elements were provided with an adhesive agent made of polyurethane, dissolved in organic solvents (Mecotherm® L110 from Kissel and Wolf, Germany).
  • the film provided with protective elements was placed in the mold cavity of the injection mold and back-injected with polyamide 6. The size of the bleed was 50 x 3.6 mm 2 .
  • the mass of thermoplastic material per gate was 80 g.

Landscapes

  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)
  • Moulds For Moulding Plastics Or The Like (AREA)

Abstract

L'invention concerne un procédé permettant de remplir des films décorés (2) par injection d'une matière thermoplastique (3) dans la cavité d'un moule (7) comportant une ou plusieurs ouvertures d'entrée (5) pour la matière thermoplastique (3). Le film (2) s'applique sur toute sa surface sur la paroi intérieure de la cavité de moule (7) et le film décoré (2) est muni d'un élément de protection (4), avant remplissage par injection, dans la zone d'au moins une ouverture d'entrée (5).
EP04718631A 2003-03-21 2004-03-09 Procede pour remplir des films decores, par injection Withdrawn EP1610963A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10312610A DE10312610A1 (de) 2003-03-21 2003-03-21 Verfahren zum Hinterspritzen von dekorierten Folien
PCT/EP2004/002390 WO2004082926A2 (fr) 2003-03-21 2004-03-09 Procede pour remplir des films decores, par injection

Publications (1)

Publication Number Publication Date
EP1610963A2 true EP1610963A2 (fr) 2006-01-04

Family

ID=32921052

Family Applications (1)

Application Number Title Priority Date Filing Date
EP04718631A Withdrawn EP1610963A2 (fr) 2003-03-21 2004-03-09 Procede pour remplir des films decores, par injection

Country Status (7)

Country Link
US (1) US20040183229A1 (fr)
EP (1) EP1610963A2 (fr)
JP (1) JP2006520707A (fr)
KR (1) KR20050113658A (fr)
CN (1) CN1764554A (fr)
DE (1) DE10312610A1 (fr)
WO (1) WO2004082926A2 (fr)

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WO2014198749A1 (fr) * 2013-06-14 2014-12-18 Bayer Materialscience Ag Pièces moulées en 3d résistant aux chocs quelle que soit leur direction
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Also Published As

Publication number Publication date
JP2006520707A (ja) 2006-09-14
DE10312610A1 (de) 2004-09-30
CN1764554A (zh) 2006-04-26
KR20050113658A (ko) 2005-12-02
US20040183229A1 (en) 2004-09-23
WO2004082926A2 (fr) 2004-09-30
WO2004082926A3 (fr) 2005-03-31

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