EP1613185A2 - Durchlöcherungssichere textilstruktur, insbesondere für schuhsohlen - Google Patents
Durchlöcherungssichere textilstruktur, insbesondere für schuhsohlenInfo
- Publication number
- EP1613185A2 EP1613185A2 EP20040727364 EP04727364A EP1613185A2 EP 1613185 A2 EP1613185 A2 EP 1613185A2 EP 20040727364 EP20040727364 EP 20040727364 EP 04727364 A EP04727364 A EP 04727364A EP 1613185 A2 EP1613185 A2 EP 1613185A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- fabric
- fibers
- aramidic
- layers
- textile structure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004753 textile Substances 0.000 title claims abstract description 32
- 239000000835 fiber Substances 0.000 claims abstract description 65
- 239000004744 fabric Substances 0.000 claims abstract description 51
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 11
- 239000002759 woven fabric Substances 0.000 claims abstract description 11
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 10
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 6
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 6
- 229910010293 ceramic material Inorganic materials 0.000 claims abstract description 6
- 239000011248 coating agent Substances 0.000 claims abstract description 6
- 238000000576 coating method Methods 0.000 claims abstract description 6
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 3
- 239000000843 powder Substances 0.000 claims abstract description 3
- 239000003082 abrasive agent Substances 0.000 claims abstract 3
- -1 aluminum silicates Chemical class 0.000 claims abstract 2
- 229920000728 polyester Polymers 0.000 claims description 26
- 239000004952 Polyamide Substances 0.000 claims description 13
- 229920002647 polyamide Polymers 0.000 claims description 13
- 229920000271 Kevlar® Polymers 0.000 claims description 9
- 239000000919 ceramic Substances 0.000 claims description 9
- 150000001875 compounds Chemical class 0.000 claims description 8
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 claims description 6
- 239000004814 polyurethane Substances 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 229920005749 polyurethane resin Polymers 0.000 claims description 5
- 230000001681 protective effect Effects 0.000 claims description 5
- 229920002292 Nylon 6 Polymers 0.000 claims description 4
- 238000001746 injection moulding Methods 0.000 claims description 2
- 150000004760 silicates Chemical class 0.000 claims description 2
- 238000005524 ceramic coating Methods 0.000 claims 2
- 229920001225 polyester resin Polymers 0.000 abstract 1
- 239000004645 polyester resin Substances 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 31
- 239000000203 mixture Substances 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 230000035515 penetration Effects 0.000 description 5
- 229920002635 polyurethane Polymers 0.000 description 4
- 239000002344 surface layer Substances 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 2
- 238000003780 insertion Methods 0.000 description 2
- 230000037431 insertion Effects 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 238000009958 sewing Methods 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 238000004381 surface treatment Methods 0.000 description 2
- 238000004026 adhesive bonding Methods 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B7/00—Footwear with health or hygienic arrangements
- A43B7/32—Footwear with health or hygienic arrangements with shock-absorbing means
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/026—Composites, e.g. carbon fibre or aramid fibre; the sole, one or more sole layers or sole part being made of a composite
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/12—Soles with several layers of different materials
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F41—WEAPONS
- F41H—ARMOUR; ARMOURED TURRETS; ARMOURED OR ARMED VEHICLES; MEANS OF ATTACK OR DEFENCE, e.g. CAMOUFLAGE, IN GENERAL
- F41H5/00—Armour; Armour plates
- F41H5/02—Plate construction
- F41H5/04—Plate construction composed of more than one layer
- F41H5/0471—Layered armour containing fibre- or fabric-reinforced layers
- F41H5/0485—Layered armour containing fibre- or fabric-reinforced layers all the layers being only fibre- or fabric-reinforced layers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/30—Woven fabric [i.e., woven strand or strip material]
Definitions
- This invention concerns a textile structure suitable for use in footwear, particularly safety footwear, which is required to have a high level of resistance to penetration by sharp objects such as nails and the like, especially through the sole.
- the main object of this invention is to provide a protective textile structure to be used in footwear, particularly shoe soles, which structure offers high resistance to piercing and penetration by sha ⁇ and pointed objects, while having limited thickness and weight, adequate flexibility and reduced cost.
- a further object of this invention is to provide a perforation-resistant textile structure that is also antistatic and/or resistant to high temperatures.
- - Fig. 1 is a schematic illustration of a first textile structure in conformity with the invention
- - Fig. 2 shows the polyester fabric used in the structure of Fig. 1;
- Fig. 3 and 4 illustrate, respectively, the profile of the wa ⁇ and weft of the fabric in Fig. 2;
- FIG. 5 is a schematic illustration of a second textile structure in conformity with the invention.
- a textile structure 10,10' resistant to perforation in conformity with the invention basically consists of a number of layers 12, 14, 12', 14' of woven fabrics bonded together by means of a thermoplastic film.
- the structure consists of one or more layers 12,12' of woven aramidic fibers and one or more layers of high tenacity non-aramidic fibers (for example, polyamide, polyester, polyolefin, liquid crystal fibers) woven into a fabric structure.
- Each separate layer of fabric has, preferably on the right side, a treated surface 16 coated with a polyurethane and/or acrylic resin reinforced with powders of hard, abrasive substances, preferably micronized ceramic materials in the form of silicates, e.g. of aluminum.
- the layers of aramidic fibers can be individually alternated with layers of fabric in non-aramidic fibers.
- a first textile structure resistant to perforation consists of a multilayer structure 10 including a layer 12 of a woven fabric in aramidic fibers and, stacked on this layer 12, three layers 14 of a woven fabric in high tenacity polyester fiber. The layers are bonded together by means of a thermoplastic film. At least one side of each layer has been provided with a surface ceramic treatment 16.
- the layers of fabric 12,14 are treated on the right side of the surface, the layer of aramidic fabric 12 and the adjacent layer 14 of polyester fabric with the treated surface 16 being in contact, the remaining layers of polyester fabric having the treated surface in contact with the untreated surface of the adjacent layer.
- both outer surfaces of the multilayer structure 10 are untreated. It is also advantageous to use the structure described above inside the soles of footwear with the layer in aramidic fibers on the tread side.
- a structure produced in conformity with this invention has high mechanical resistance to perforation by pointed metal objects and impedes their progress through the layers of fabric.
- this structure is advantageously characterized by the fact of being composed in a proportion that does not exceed about 15 % by weight - of the total weight of the textile fibers used - of aramidic fibers, with the remaimng part in high tenacity polyester fibers. This greatly reduces the production costs with respect to structures consisting entirely of aramidic fibers, maintaining it on the order of the production costs of structures consisting of metal plates, over which it has the advantage of being highly flexible.
- the fabric produced in this way has a finished weight of 340 ⁇ 350 ⁇ 5% gr/sq.mt. with a composition by weight of approximately 80% Kevlar ®, 10% polyurethane, 5% acrylic, 5% aluminum silicate.
- Fabric in polyester fibers - compound weave (illustrated in Figures 2 to 4), made up of two simple weaves 3X3;
- the fabric produced in this way has a finished weight of 690 ⁇ 720 ⁇ 5% gr/sq.mt. with a composition by weight of approximately 86% polyester fibers, 7% polyurethane, 3.5% acrylic, 3.5% aluminum silicate.
- the weaves used make it possible to produce fabrics with very tightly woven yarns, making their structure highly cohesive to provide by their very construction a good resistance to penetration, while maintaining a high degree of flexibility.
- the compound weave used for the fabric in polyester fiber has been found to be particularly effective in the production of the multilayer structure 10.
- the bonding between the layers of fabric is obtained by hot calandering with the insertion of a thermoplastic film (polyolefin and/or polyurethane and/or polyester) between the layers of the structure; processing the combination with heat causes the bonding by merger of the ceramic material both with the thermoplastic film and with the surface layer of the adjacent fabric layer so as to obtain a single unit with a total thickness of not more than 3 mm and limited weight.
- a thermoplastic film made of polyester that is resistant to high temperatures a structure can be obtained that is particularly suitable for footwear designed to be used in the presence of high heat sources.
- the textile structure described above has a general composition of:
- Tests carried out on the structure have proven its effective resistance to a force of at least 1100N exerted by a nail, as foreseen by standards pr EN ISO 20344, EN 344/92 and EN 12568/98.
- an antistatic structure is obtained which can be used in footwear for which this feature is required.
- the fabric in aramidic fibers with: - the wa ⁇ yarns consisting, every 74 threads, of a first yarn repeated 73 times in Kevlar® 730 dtex and a second yarn repeated once in high tenacity polyamide 180 dtex in two ply twisted with a filament in stainless steel measuring 60 micron in diameter (a composition thus consisting of 82%) polyamide and 18% stainless steel);.
- the fabric in polyester fiber is in turn preferably produced with:
- FIG. 5 A second example of a textile structure resistant to perforation in conformity with the invention is schematically illustrated in Fig, 5.
- the structure 10' includes two bonded multilayers 120,140, consisting of a first set of three stacked layers of a woven fabric 12' in aramidic fibers provided with a surface ceramic treatment 16 and a second set of three stacked layers of a woven fabric 14' in high tenacity polyamide provided with a surface ceramic treatment.
- at least two adjacent layers 12' of fabric in aramidic fibers or two adjacent layers of fabric 14' in polyamide fibers or the two adjacent layers of the multilayer structures 120,140 have the treated surfaces 16 in contact with each other so that both the outer surfaces (top and bottom) of the structure 10' are not treated.
- Fabric in aramidic fibers as in the first example described above.
- Fabric in polyamide fibers - weft rep weave;
- the fabric produced in this way has a finished weight of about 300 gr/sq.mt. with a composition by weight of 80% of polyamide fibers, 10% polyurethane, 5% acrylic, 5% aluminum silicate.
- a structure composed of three layers of fabric in aramidic fibers and three layers of fabric in high tenacity polyamide as described above, has a general composition of:
- a textile structure capable of resisting penetration is also thermally insulating and can be used, in the traditional way, as a protective insert into soles which are applied to footwear by means of sewing or gluing.
- This structure can also be used advantageously in the production of footwear the sole of which is directly made on the upper by injection molding.
- this structure can constitute the insole, which is first sewn onto the upper after which the sole is injected. It has been ascertained, in fact, that the effective resistance to perforation and penetration of a nail, according to the terms of standard EN 344/92, does not prevent sewing the structure onto the upper, using needles of an appropriate type.
- the invention thus conceived is susceptible to numerous alterations and variations, all coming within the sphere of the inventive concept. Also, all the details can be replaced with technically equivalent elements.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Public Health (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Ceramic Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Laminated Bodies (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
- Bedding Items (AREA)
- Knitting Of Fabric (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITPO20030005 ITPO20030005A1 (it) | 2003-04-14 | 2003-04-14 | Struttura tessile resistente alla perforazione specialmente per suole di scarpe |
| PCT/IT2004/000208 WO2004089143A2 (en) | 2003-04-14 | 2004-04-14 | Puncture resistant textile structure, especially for shoe soles |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1613185A2 true EP1613185A2 (de) | 2006-01-11 |
| EP1613185B1 EP1613185B1 (de) | 2008-07-02 |
Family
ID=33156359
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP20040727364 Expired - Lifetime EP1613185B1 (de) | 2003-04-14 | 2004-04-14 | Verwendung einer durchlöcherungssicheren textilstruktur für schuhsohlen |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US20060211318A1 (de) |
| EP (1) | EP1613185B1 (de) |
| CN (1) | CN1787755A (de) |
| AT (1) | ATE399483T1 (de) |
| CA (1) | CA2521626A1 (de) |
| DE (1) | DE602004014749D1 (de) |
| IT (1) | ITPO20030005A1 (de) |
| WO (1) | WO2004089143A2 (de) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3348686A1 (de) * | 2017-01-12 | 2018-07-18 | Antonio Moron de Blas, S.L. | Kett- und schussstoff für nichtmetallischen sohlen von sicherheitsschuhwerk und erhaltene innensohle |
Families Citing this family (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0329813D0 (en) | 2003-12-23 | 2004-01-28 | Terra Plana Internat Ltd | Footwear |
| ITMI20052019A1 (it) * | 2005-10-24 | 2007-04-25 | Lanzi Egisto S P A | Soletta antinfortunistica |
| DE102005050861B4 (de) * | 2005-10-24 | 2015-06-18 | Gerlinger Industries Ag | Durchstoßresistente Schuhsohle |
| EP1780004A1 (de) | 2005-10-27 | 2007-05-02 | Main Style, S.L. | Durchstechsicheres Gewebe |
| ES2276614B2 (es) * | 2005-10-27 | 2008-10-16 | Main Style, S.L. | Tejido anti-perforacion. |
| ITMI20061830A1 (it) * | 2006-09-26 | 2008-03-27 | Lenzi Egisto Spa | Soletta antinfortunistica |
| US20090000148A1 (en) * | 2007-06-26 | 2009-01-01 | Lacrosse Footwear, Inc. | Puncture resistant footbed |
| EP2064965A1 (de) * | 2007-11-27 | 2009-06-03 | Wellmax Products Co., Ltd. | Durchbohrungsresistentes planares Bauteil |
| TW201014710A (en) * | 2008-10-13 | 2010-04-16 | Tiong Liong Ind Co Ltd | Puncture alleviating material |
| US20130143460A1 (en) | 2010-06-15 | 2013-06-06 | Tyr Tactical, Llc | High performance composite fabric |
| IT1402017B1 (it) * | 2010-10-11 | 2013-08-28 | Pro Systems S P A | Materiale composito per protezione balistica e relativo procedimento di preparazione. |
| CH705638A2 (de) * | 2011-10-10 | 2013-04-15 | Schoeller Textil Ag | Durchtrittsichere Schuhinnensohle und Verfahren zur Herstellung. |
| US8883661B2 (en) | 2011-11-18 | 2014-11-11 | Pro-Systems S.P.A. | Composite material for ballistic protection and relative method of preparation |
| CN102493202A (zh) * | 2011-12-01 | 2012-06-13 | 山东三达科技发展公司 | 一种复合防刺片材及防弹防刺复合材料 |
| US9668539B2 (en) * | 2012-02-09 | 2017-06-06 | Simon La Rochelle | Footwear with sole protection |
| WO2014200465A1 (en) * | 2013-06-11 | 2014-12-18 | Honeywell International Inc. | Perforation-resistant flexible insert for garment or footwear |
| WO2015101929A1 (en) * | 2014-01-03 | 2015-07-09 | Vibram S.P.A. | Sole resistant to perforation and method of manufacturing thereof |
| US10463106B2 (en) * | 2014-02-13 | 2019-11-05 | Nike, Inc. | Sole assembly with textile shell and method of manufacturing same |
| JP7240876B2 (ja) | 2015-10-02 | 2023-03-16 | ナイキ イノベイト シーブイ | 履物のための板 |
| KR102208854B1 (ko) | 2015-10-02 | 2021-01-28 | 나이키 이노베이트 씨.브이. | 신발류를 위한 발포체를 갖는 플레이트 |
| CN105231565B (zh) * | 2015-10-20 | 2018-01-16 | 杭州华水布艺有限公司 | 一种含冰凉材料的防刺防护面料 |
| JP6452903B1 (ja) | 2015-12-02 | 2019-01-16 | カービテックス インコーポレイテッド | 調整可能異方性特質を有する接合繊維強化型複合材料アセンブリ |
| CN113261746B (zh) | 2016-07-20 | 2023-02-17 | 耐克创新有限合伙公司 | 鞋板 |
| WO2018017885A1 (en) | 2016-07-20 | 2018-01-25 | Nike Innovate C.V. | Footwear plate |
| CN106724675A (zh) * | 2016-12-06 | 2017-05-31 | 太仓大唐化纤厂 | 一种耐磨的抗静电地毯 |
| IT201700051624A1 (it) * | 2017-05-12 | 2018-11-12 | U Invest S R L | Scarpa di sicurezza defaticante. |
| KR102247685B1 (ko) * | 2017-09-28 | 2021-04-30 | 코오롱인더스트리 주식회사 | 신발용 내답판 및 그의 제조방법 |
| EP3654797B1 (de) | 2018-04-16 | 2023-08-02 | NIKE Innovate C.V. | Laufsohlenplatte |
| US11344078B2 (en) | 2018-04-16 | 2022-05-31 | Nike, Inc. | Outsole plate |
| US11109639B2 (en) | 2018-05-23 | 2021-09-07 | Carbitex, Inc. | Footwear insert formed from a composite assembly having anti-puncture and anisotropic properties |
| CN111150172A (zh) * | 2019-12-24 | 2020-05-15 | 温州市巨伦鞋业有限公司 | 一种劳保鞋的防刺穿鞋底及其制备方法 |
| CN111890758B (zh) * | 2020-07-24 | 2023-04-07 | 江西棱志特种材料有限公司 | 一种以多层接结为基础的三维防刺布的织造工艺 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5677029A (en) * | 1990-11-19 | 1997-10-14 | Alliedsignal Inc. | Ballistic resistant fabric articles |
| US5480706A (en) * | 1991-09-05 | 1996-01-02 | Alliedsignal Inc. | Fire resistant ballistic resistant composite armor |
| IL114627A (en) * | 1994-07-28 | 1999-03-12 | Akzo Nobel Nv | Protective clothing against stab and projectile wounds |
| US6368989B1 (en) * | 1999-01-12 | 2002-04-09 | E. I. Du Pont De Nemours And Company | Puncture resistant composite |
| WO2001051263A1 (en) * | 2000-01-14 | 2001-07-19 | Spectrum Medsystems, Inc. | Safety shoes and other protective articles comprising a fabric-plastic composite and their methods of manufacture |
| AT408918B (de) * | 2000-03-14 | 2002-04-25 | Astron Elastomerprodukte Ges M | Mehrschichtmaterial zum schutz von körperteilen |
-
2003
- 2003-04-14 IT ITPO20030005 patent/ITPO20030005A1/it unknown
-
2004
- 2004-04-14 DE DE200460014749 patent/DE602004014749D1/de not_active Expired - Fee Related
- 2004-04-14 EP EP20040727364 patent/EP1613185B1/de not_active Expired - Lifetime
- 2004-04-14 CN CNA2004800099577A patent/CN1787755A/zh active Pending
- 2004-04-14 US US10/552,534 patent/US20060211318A1/en not_active Abandoned
- 2004-04-14 CA CA 2521626 patent/CA2521626A1/en not_active Abandoned
- 2004-04-14 WO PCT/IT2004/000208 patent/WO2004089143A2/en not_active Ceased
- 2004-04-14 AT AT04727364T patent/ATE399483T1/de not_active IP Right Cessation
Non-Patent Citations (1)
| Title |
|---|
| See references of WO2004089143A2 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3348686A1 (de) * | 2017-01-12 | 2018-07-18 | Antonio Moron de Blas, S.L. | Kett- und schussstoff für nichtmetallischen sohlen von sicherheitsschuhwerk und erhaltene innensohle |
Also Published As
| Publication number | Publication date |
|---|---|
| ITPO20030005A1 (it) | 2004-10-15 |
| CA2521626A1 (en) | 2004-10-21 |
| WO2004089143A3 (en) | 2004-11-18 |
| US20060211318A1 (en) | 2006-09-21 |
| DE602004014749D1 (de) | 2008-08-14 |
| WO2004089143A2 (en) | 2004-10-21 |
| EP1613185B1 (de) | 2008-07-02 |
| CN1787755A (zh) | 2006-06-14 |
| ATE399483T1 (de) | 2008-07-15 |
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