EP1636765A1 - Document de valeur comprenant une marque d'authenticite lisible par machine - Google Patents

Document de valeur comprenant une marque d'authenticite lisible par machine

Info

Publication number
EP1636765A1
EP1636765A1 EP04739618A EP04739618A EP1636765A1 EP 1636765 A1 EP1636765 A1 EP 1636765A1 EP 04739618 A EP04739618 A EP 04739618A EP 04739618 A EP04739618 A EP 04739618A EP 1636765 A1 EP1636765 A1 EP 1636765A1
Authority
EP
European Patent Office
Prior art keywords
marking substance
document
infrared
value
authenticity
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP04739618A
Other languages
German (de)
English (en)
Other versions
EP1636765B1 (fr
Inventor
Gerhard Stenzel
Wittich Kaule
Gerhard Schwenk
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Giesecke and Devrient GmbH
Original Assignee
Giesecke and Devrient GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Giesecke and Devrient GmbH filed Critical Giesecke and Devrient GmbH
Publication of EP1636765A1 publication Critical patent/EP1636765A1/fr
Application granted granted Critical
Publication of EP1636765B1 publication Critical patent/EP1636765B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G07CHECKING-DEVICES
    • G07DHANDLING OF COINS OR VALUABLE PAPERS, e.g. TESTING, SORTING BY DENOMINATIONS, COUNTING, DISPENSING, CHANGING OR DEPOSITING
    • G07D7/00Testing specially adapted to determine the identity or genuineness of valuable papers or for segregating those which are unacceptable, e.g. banknotes that are alien to a currency
    • G07D7/06Testing specially adapted to determine the identity or genuineness of valuable papers or for segregating those which are unacceptable, e.g. banknotes that are alien to a currency using wave or particle radiation
    • G07D7/12Visible light, infrared or ultraviolet radiation
    • GPHYSICS
    • G07CHECKING-DEVICES
    • G07DHANDLING OF COINS OR VALUABLE PAPERS, e.g. TESTING, SORTING BY DENOMINATIONS, COUNTING, DISPENSING, CHANGING OR DEPOSITING
    • G07D7/00Testing specially adapted to determine the identity or genuineness of valuable papers or for segregating those which are unacceptable, e.g. banknotes that are alien to a currency
    • G07D7/004Testing specially adapted to determine the identity or genuineness of valuable papers or for segregating those which are unacceptable, e.g. banknotes that are alien to a currency using digital security elements, e.g. information coded on a magnetic thread or strip
    • G07D7/0043Testing specially adapted to determine the identity or genuineness of valuable papers or for segregating those which are unacceptable, e.g. banknotes that are alien to a currency using digital security elements, e.g. information coded on a magnetic thread or strip using barcodes

Definitions

  • the invention relates to a document of value, a security element and a security paper with a machine-readable authenticity indicator.
  • the invention also relates to various methods for checking the authenticity of such value documents, a security element or a security paper.
  • Valuable documents such as banknotes, shares, bonds, certificates, vouchers, checks, high-quality admission tickets, but also other documents that are susceptible to counterfeiting, such as passports or other identification documents, are generally provided with various security features to increase counterfeit security.
  • infrared detectors are used, which are sensitive in the wavelength range from 780 nm to 800 nm and with which the infrared absorption of the security code can be detected.
  • Such infrared detectors are now commercially available and widely used.
  • the protection against counterfeiting by the security coding described can therefore no longer be rated as particularly high, since the part of the coding which is invisible to the human eye can also be detected by anyone without any particular effort. This gives rise to starting points for unauthorized imitations or readjustments of the security code of EP 0340898 A2.
  • a security feature is machine-readable, since an automatic authenticity check of a large number of documents of value can then be carried out in a short time, for example in a banknote processing machine.
  • an inconspicuous or invisible inspection of a document or a protected object is often sought, which can usually only be carried out with the aid of a machine-readable security feature.
  • the present invention is based on the object of specifying an authenticity indicator for documents of value and other objects to be secured, which avoids the disadvantages of the prior art and ensures increased security against forgery.
  • the authenticity mark should be machine-readable.
  • a security element for securing an object a security paper for the manufacture of security or Documents of value, methods for checking the authenticity of the objects mentioned and a device for carrying out the authenticity test are the subject of the subordinate claims. Developments of the invention are the subject of claims under.
  • the authenticity mark comprises a luminescent marking substance and a marking substance absorbing in the infrared spectral range. It has been found that when only one marking substance is used, it is relatively easy to analyze and imitate the authenticity mark, since only one property of the marking substance always has to be recognized and imitated. If, on the other hand, several substances are combined that have the same or very similar effects, for example different fluorescence, the two properties can influence each other during the detection, so that successful detection can no longer be guaranteed in all cases.
  • the marking substances do not interfere in the combination according to the invention, since different substance properties are queried during the detection. Furthermore, the infrared-absorbing marking substance does not provide an active signal for the analysis of the substances contained, so that the analysis is made significantly more difficult for the counterfeiter.
  • the analysis or re-enactment of luminescent marking substances is comparatively simple, since the radiation emitted can easily be made visible by irradiation of a wide spectral range.
  • the interaction of the two material properties is used as the basis for used the evaluation of the authenticity check.
  • the effects of the interaction between the two marking substances cannot be easily reproduced and therefore offer particularly high security against forgery.
  • the luminescent marking substance emits in the infrared spectral range, preferably at a wavelength ⁇ above approximately 1100 nm, particularly preferably above approximately 1200 nm.
  • This has the advantage that the luminescence is then not possible with conventional and easily available infrared detectors, which are mainly sensitive in the wavelength range from 780 to 800 nm, can be detected. Due to the bandgap of silicon of 1.12 eV, conventional silicon photodiodes do not allow detection of infrared radiation with wavelengths above about 1100 nm. Detectors for longer-wave infrared radiation are much more complex and are not available to everyone.
  • the luminescent marking substance emits in the absorption region of the infrared-absorbing marking substance. This allows the interaction effects of the two marking substances already mentioned to be exploited.
  • the luminescent marking substance is advantageously also excited in the infrared spectral range, preferably in the spectral range from approximately 800 nm to approximately 1000 nm.
  • the infrared-absorbing marking substance is essentially colorless in the visible spectral range or has only a weak intrinsic color. It is then invisible under normal lighting conditions or appears little striking.
  • the infrared-absorbing marking substance can be transparent in the visible. Even at a wavelength of approximately 800 nm, the infrared-absorbing marking substance advantageously does not yet have any significant absorption in order to avoid detection by commercially available infrared detectors.
  • the infrared-absorbing marking substance preferably exhibits significant absorption only in the spectral range between approximately 1200 nm and approximately 2500 nm, preferably in the spectral range between approximately 1500 nm and approximately 2000 nm.
  • the infrared absorption of the authenticity mark is then not detectable at the wavelengths of conventional infrared detectors, but only appears in the longer-wavelength and more difficult to access spectral range above 1200 nm and above 1500 nm.
  • Preferred infrared-absorbing markers have less than about 40%, in particular less than about 25% of the absorption in the visible spectral range in the range from 1200 nm to 2500 nm or in the range from 1500 nm to 2000 nm, based in each case on the area below Absorption curve for the respective spectral range.
  • infrared-absorbing marking substances are used, for example, substances based on doped semiconductor materials.
  • Substances containing metal oxide are also suitable. These are characterized in particular by their resistance to aging.
  • the infrared-absorbing marking substance is preferably in particle form with an average particle size of less than 50 ⁇ m. As a result, visible light is only slightly scattered by the particles, so that the marking substance is colorless or has only a weak intrinsic color.
  • Examples of infrared absorbers which have no appreciable absorption either in the visible or at about 800 nm are about 2,5-cyclohexadiene-1,4-diylidenes ⁇ is [N / N-bis (4-dibutylaminophenyl) ammonium] bis ( hexafluoroantimonate) with the formula C62H92N6Fi2Sb2, or the dyes ADS 990 MC with the formula 032H 3 ON 2 S 4 Ni, or ADS 1120P with the formula C52H44 CfeO ⁇ from Siber Hegner GmbH, Hamburg.
  • the luminescent marking substance can be formed on the basis of a host lattice doped with a side earth metal. Examples of such luminescent marking substances are contained, for example, in the publication WO 99/38701, the disclosure of which is included in the present application.
  • the luminescent marking substance and the infrared-absorbing marking substance are formed by separate substances which are inserted into the value document or onto which the value document is applied separately. This allows great flexibility in the selection of the two marking substances in order to be able to meet different and sometimes contradicting requirements, for example with regard to safety, durability, wear resistance and manufacturing costs.
  • the luminescent marking substance and the infrared-absorbing marking substance are introduced together as a mixture of substances into the value document or applied to the value document.
  • This variant also offers significant advantages because the mixture of substances can be applied in a single pass. This results, for example, in the printing of banknotes with significantly fewer restrictions Banknote design than when using two separately applied marking materials. In the latter case, it is often necessary to dispense with a visible printing process or an expensive additional printing process is carried out on another printing unit.
  • the luminescent marking substance to a large-area, invisible, infrared-absorbing feature, such as a barcode, a uniform and high area coverage of up to about 50% can be achieved.
  • the detection of luminescent markers in the conventional admixture with visible printing ink is often impaired by the colored pigments of the color.
  • the distribution of the marking substance is also very inconsistent due to the different printed images for banknotes with different denominations.
  • a test step can be omitted in quality control of the invisible print.
  • checking the print quality of the bar codes ensures that the correct line width of the color is printed.
  • the quality control of the admixed luminescent marking can then be limited to the incoming control of the color.
  • the luminescent marking substance is introduced over the entire surface into the value document or applied, for example printed, onto the value document.
  • the luminescent marking substance then provides a uniform background for an absorption or emission measurement, which can be used, for example, as a constant reference signal in an authenticity check.
  • Lich it is also possible Lich to apply or apply the luminescent marking substance only at selected locations, for example along predetermined tracks.
  • the document of value can comprise a substrate, in particular a paper substrate, in the volume of which the luminescent marking substance is introduced.
  • a substrate in particular a paper substrate
  • the methods according to the publications EP-A-O 659935 and DE 10120818 are suitable, the disclosures of which are included in the present application.
  • the pigment particles used for marking are admixed to a gas stream or a liquid stream and introduced into a paper web.
  • the methods are particularly suitable for marking security paper which is used for the production of security or value documents, such as bank notes, identity cards or the like.
  • the luminescent marking substance can be added to a coating slip or applied together with a surface sizing to the surface of a value document or to the substrate materials used for its production.
  • films are also particularly suitable for producing documents of value into which the luminescent marking substance can also be introduced, for example by coextrusion.
  • the infrared-absorbing marking substance is preferably applied to the value document, in particular it is printed on the value document. All suitable printing methods can be used for printing. Ink-jet printing is particularly preferred since curved surfaces can also be printed in a simple manner an individualization of the print for different objects is easily possible.
  • the arrangement of the infrared-absorbing marking substance represents information such as patterns, characters or codes.
  • the information is preferably in encrypted form.
  • the information shown can be, for example, a logo, a national emblem, a lettering or a letter / number combination.
  • the arrangement of the infrared-absorbing marking substance particularly preferably forms a bar code.
  • barcode in the context of the present invention encompasses any one- or two-dimensional pattern consisting of black bars and white bars (gaps).
  • the bar / gap sequence usually represents a binary sequence of numbers by guiding the radiation from a light-emitting or laser diode over the bars and the scattered light is picked up by a photodetector and fed to an evaluation unit which extracts the coded information from the pulse sequence obtained. Barcodes can be read and delivered very well by machine, especially in connection with check digits, an almost error-free reading result.
  • Code 39 which uses a barcode representation of 9 elements (5 bars and 4 spaces), three of which are wide and six narrow, can represent both numbers and letters.
  • the national currency (EUR, USD etc.) and value digits or other data such as the date of issue of the banknote can be encoded on a banknote.
  • the luminescent marking substance and the infrared-absorbing marking substance are present in overlapping areas of the value document. Then, for example, the partial absorption of the luminescence emission by the infrared-absorbing marking substance can be used as an indirect and difficult to imitate reading process.
  • the document of value has a printing layer which partially or completely covers the regions of the document of value provided with the infrared-absorbing marking substance.
  • the printing layer can be opaque in the visible spectral range and transparent or translucent in the absorption range of the infrared-absorbing marking substance, so that it hides the presence of the infrared-absorbing marking in the visible, but does not hinder the detection of infrared absorption at a test wavelength.
  • the printing layer can be opaque, in particular in the emission region of the luminescent marking substance, in order to enable a differentiated reading of an infrared-absorbing marking, as described below.
  • the printing layer is applied to the document of value using an intaglio printing technique.
  • the machine-readable authenticity indicator is advantageously designed over a large area, in particular with an area of 100 mm 2 or more, preferably with an area of 400 mm 2 or more.
  • Such a large-area authenticity indicator is particularly suitable for marking banknotes, since most money processing machines have transport belts that cover parts of the banknote.
  • large license plates can be read out more easily and with less expensive readers.
  • a larger area is also advantageous for the infrared-luminescent part of the authenticity mark.
  • the infrared-absorbing marking substance and / or the luminescent marking substance is incorporated in the authenticity mark with an area coverage of 30% or more, preferably of about 50%.
  • the invention also includes a security element for securing an object with a machine-readable authenticity indicator of the type described above in connection with the document of value.
  • the security element can in particular be detachably arranged on a carrier layer.
  • the security element is in the form of a label, seal, transfer ribbon, banderole or formed as another flat transfer element and can be applied to any objects to be secured, for example on packaging or wrappings, but also on securities and other security documents.
  • the invention also includes a security paper for the production of security or value documents, such as banknotes, identity cards or the like, with a machine-readable authenticity indicator, as described above in connection with the value document.
  • security paper for the production of security or value documents, such as banknotes, identity cards or the like, with a machine-readable authenticity indicator, as described above in connection with the value document.
  • a method for checking the authenticity of a value document, a security element or a security paper of the type described is characterized by the following steps:
  • the determination of the emission is advantageously carried out in a spatially resolved manner.
  • the emission of the authenticity indicator is determined on two opposite sides of the value document, security element or security paper.
  • the signal One side for example the back of a banknote, can then be used as a reference signal relative to which the signal of the other side, for example the front, can be evaluated.
  • the authenticity assessment can be carried out on the basis of a comparison of the emission from the opposite sides.
  • Another method according to the invention for checking the authenticity of a value document, a security element or a security paper comprises the steps:
  • the absorption of the authenticity mark is advantageously determined by means of a measurement, in particular a spatially resolved measurement, of the transmitted and / or remitted infrared radiation.
  • a further method according to the invention for checking the authenticity of a value document, a security element or a security paper is characterized by the following steps:
  • This process variant is based on an interaction between the two marking substances.
  • the method presupposes that the excited luminescent marking substance emits in the absorption region of the infrared-absorbing marking substance.
  • the absorption is then not determined by a remission or transmission measurement, but is shown in a locally suppressed luminescence emission after excitation of the luminescent marking substance.
  • the absorption measurement is preferably carried out in a spatially resolved manner. It goes without saying that this variant can also be combined with the two methods described above.
  • the absorption of the authenticity mark at a wavelength from the visible spectral range can be determined. This can ensure, for example, that the infrared-absorbing marking substance is not replaced by a simple infrared absorber, which can also be seen in the visible.
  • Irradiation of the authenticity mark is advantageously carried out using a light-emitting diode or a laser diode.
  • Laser diodes for example with an emission wavelength of 1550 ran, are particularly suitable.
  • the information in a particularly preferred method variant comprises the denomination, the currency, the Issue date, the country, the printer, or features of the value document or security element, and one or more of the above-mentioned information is read out and further processed during the authenticity check.
  • the described methods can in particular be advantageously carried out using a money processing machine, a banknote counting machine, a banknote sorting machine, a banknote reader for the blind or visually impaired, a banknote reader for the variety business or a pocket-sized banknote validator.
  • an infrared-absorbing marking has significant advantages over conventional fluorescence coding.
  • the automatic readability of the marking is significantly less disturbed by an underlying background print.
  • Soiling in the infrared spectral range is considerably less disturbing than in the visible and in the ultraviolet spectral range.
  • the signal / noise ratio of a measuring head is also significantly better with reflectance measurements than with fluorescence measurements, so that a higher resolution can be achieved.
  • FIG. 1 shows a schematic illustration of a banknote with a machine-readable authenticity indicator according to an exemplary embodiment of the invention
  • Fig. 2 in (a) a cross section of the banknote of Fig. 1 in the area of
  • FIG. 3 shows a detail from the cross section of a document of value with a luminescent coating according to another exemplary embodiment of the invention
  • FIG. 1 shows a schematic illustration of a bank note 10 which is provided in a partial area 12 with a machine-readable authenticity indicator.
  • the structure of the authenticity mark can best be seen in the cross section of the partial region 12 shown in FIG. 2 (a).
  • the authenticity mark comprises a marking substance which is luminescent in the infrared spectral range and which is introduced in the form of particles 14 into the volume of the fleece-like banknote substrate 16.
  • the particles 14 can be added to the paper or fiber mass before the sheet formation or can be introduced into the fiber matrix after the layer formation.
  • the luminescent particles 14 are distributed substantially uniformly over the substrate volume.
  • the authenticity mark further comprises an infrared-absorbing marking substance which is printed in the area 12 in the form of a bar code 20 on the front 18 of the bank note.
  • the barcode 20 contains a fixed bar code, a clear identification of the national currency, value digits and an indication of the year of issue Banknote.
  • the infrared-absorbing marking substance is transparent in the visible spectral range up to wavelengths of approximately 800 ran, so that the presence of the bar code 20 and in particular its information content cannot be seen by the naked eye for the user. Since the infrared-absorbing barcode 20 is also transparent in the near infrared, it cannot be detected even with commercially available infrared detectors based on silicon, which are sensitive at about 800 nm.
  • the absorption of the bar code 20 can, however, be detected with more complex infrared detectors at a wavelength of 1550 nm by a reflectance measurement.
  • 2 (b) schematically shows the course of the measured infrared absorption along the length 1 indicated in FIG. 2 (a).
  • the maximum values 0 and 1 show the limits of the partial region 12.
  • the information encoded in the bar code 20 can be read out from the position and width of the absorption peaks 22 and the absorption gaps 24.
  • the infrared luminescence of the luminescent marking substance 14 can be checked on the front or back of the bank note 10 as an additional authenticity feature.
  • FIG. 3 Another possibility of equipping a value document with the luminescent marking substance is shown in FIG. 3.
  • the luminescent marking substance is not arranged in the volume of the security substrate 30, but in the form of a luminescent coating 32 on the
  • the luminescent coating 32 can be a coating slip mixed with luminescent particles, a surface sizing, a top coat, a lacquer layer or a top coat. trade foil.
  • an infrared-absorbing barcode 38 is printed on the front side 36 of the substrate.
  • FIG. 4 shows an object 40 to be secured with a glued-on security element 42 which has been transferred from a transfer film to the object 40.
  • the security element 42 comprises an infrared-absorbing layer 44 with an infrared-absorbing marking substance of the type described above and a luminescent layer 46 arranged congruently above it.
  • the luminescent marking substance of the luminescent layer 46 is selected such that it runs at the test wavelength of 1550 , in which the infrared-absorbing layer 44 absorbs, is transparent, so that the information encoded in the layer 44 can be read out by a spatially resolved measurement of the reflected infrared radiation.
  • the presence of the infrared-absorbing layer 44 is hidden by the luminescent layer 46 in the visible spectral range.
  • FIG. 5 (a) shows a cross section in the region of the authenticity indicator of the banknote as in FIG. 2 (a).
  • the same elements are provided with the same reference numerals.
  • the banknote of FIG. 5 differs primarily by the imprint 50 executed in intaglio printing with an opaque in the visible spectral range, at the test wavelength of the infrared-absorbing marking substance, in the embodiment 1550 ran, however, transparent ink , Intaglio printing generally also leads to a tactile relief structure with a strong embossing in the printing area 50, which is not shown in the figure for the sake of simplicity.
  • the print 50 covers, in particular, part of the infrared barcode 20, so that in this case an infrared-absorbing marking substance which is not or not completely transparent can also be used in this case. A part of the bar code 20 is then visible, but another part is covered by the imprint 50. An attempt at forgery by reproducing the visible part of the bar code 20 will then become apparent at the latest when the overprinted part of the bar code 20 is measured.
  • FIG. 5 A measurement of the infrared absorption on the front of the bank note along the length 1 of the authenticity mark is shown in Fig. 5 (b). Since the print 50 is transparent at the test wavelength, essentially the same absorption curve 52 results as in the exemplary embodiment in FIG. 2.
  • 5 (c) shows the course of the luminescence emission measured on the back of the banknote at a test wavelength of 1550 ran after excitation with infrared radiation in the wavelength range from 800 nm to 1000 nm.
  • a constant emission signal 54 results, which serves as a reference for a Front measurement can serve.
  • 5 (d) finally shows the luminescence emission measured on the front of the banknote.
  • the luminescence radiation is absorbed by the infrared-absorbing marking substance, so that corresponding gaps occur in the measured luminescence profile 56.
  • the luminescence in the gaps of the bar code 20 can be reduced compared to the value outside the print 50 (reference symbol 58).
  • FIG. 6 shows yet another exemplary embodiment of a banknote according to the invention, in which, as a modification to the exemplary embodiment of FIG luminescent label 14 is emitted at about 1310 nm.
  • the infrared-absorbing barcode 20 absorbs both at 1310 nm and at the test wavelength of 1550 nm.
  • the print 60 applied in intaglio printing is transparent for the test wavelength of 1550 nm, but absorbs both in the visible spectral range and at the emission wavelength of the luminescent marker.
  • FIG. 6 (c) The course of the luminescence emission measured on the back of the banknote at a wavelength of 1310 nm is shown in FIG. 6 (c).
  • a constant reference signal 64 results.
  • FIG. 6 (d) finally shows the luminescence emission 66 measured on the front of the banknote at a wavelength of 1310 nm.
  • the luminescence radiation is emitted by both Bar of the bar code 20, as well as absorbed by the print 60, so that no luminescence can be measured at these locations.

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Engineering & Computer Science (AREA)
  • Computer Security & Cryptography (AREA)
  • Inspection Of Paper Currency And Valuable Securities (AREA)
  • Credit Cards Or The Like (AREA)

Abstract

L'invention concerne un document de valeur comprenant une marque d'authenticité lisible par machine. Selon l'invention, cette marque d'authenticité comprend une substance de marquage luminescente et une substance de marquage absorbant dans le domaine spectral de l'infrarouge.
EP04739618.9A 2003-06-12 2004-06-04 Document de valeur comprenant une marque d'authenticite lisible par machine Expired - Lifetime EP1636765B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10326983A DE10326983A1 (de) 2003-06-12 2003-06-12 Wertdokument mit einem maschinenlesbaren Echtheitskennzeichen
PCT/EP2004/006066 WO2004111951A1 (fr) 2003-06-12 2004-06-04 Document de valeur comprenant une marque d'authenticite lisible par machine

Publications (2)

Publication Number Publication Date
EP1636765A1 true EP1636765A1 (fr) 2006-03-22
EP1636765B1 EP1636765B1 (fr) 2013-12-25

Family

ID=33482917

Family Applications (1)

Application Number Title Priority Date Filing Date
EP04739618.9A Expired - Lifetime EP1636765B1 (fr) 2003-06-12 2004-06-04 Document de valeur comprenant une marque d'authenticite lisible par machine

Country Status (6)

Country Link
US (1) US20060131425A1 (fr)
EP (1) EP1636765B1 (fr)
CN (1) CN1799072A (fr)
DE (1) DE10326983A1 (fr)
RU (1) RU2345419C2 (fr)
WO (1) WO2004111951A1 (fr)

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WO2020249259A1 (fr) * 2019-06-13 2020-12-17 Giesecke+Devrient Currency Technology Gmbh Élément de sécurité présentant des encres d'impression différentes lors de l'éclairage par un rayonnement électromagnétique dans la plage des longueurs d'onde infrarouges

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DE10326983A1 (de) 2004-12-30
EP1636765B1 (fr) 2013-12-25
RU2345419C2 (ru) 2009-01-27
US20060131425A1 (en) 2006-06-22
RU2006100105A (ru) 2007-08-27
CN1799072A (zh) 2006-07-05
WO2004111951A1 (fr) 2004-12-23

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