EP1702390B1 - Balai de charbon ainsi que procédé et matériau pour la fabrication dudit balai - Google Patents
Balai de charbon ainsi que procédé et matériau pour la fabrication dudit balai Download PDFInfo
- Publication number
- EP1702390B1 EP1702390B1 EP04803858A EP04803858A EP1702390B1 EP 1702390 B1 EP1702390 B1 EP 1702390B1 EP 04803858 A EP04803858 A EP 04803858A EP 04803858 A EP04803858 A EP 04803858A EP 1702390 B1 EP1702390 B1 EP 1702390B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- metal
- carbon brush
- sintering
- base
- pulverulent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 49
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 41
- 239000000463 material Substances 0.000 title claims description 17
- 238000000034 method Methods 0.000 title claims description 8
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- 229910052751 metal Inorganic materials 0.000 claims abstract description 75
- 239000002184 metal Substances 0.000 claims abstract description 74
- 238000005245 sintering Methods 0.000 claims abstract description 28
- 238000003825 pressing Methods 0.000 claims abstract description 21
- 238000003466 welding Methods 0.000 claims abstract description 13
- 239000003575 carbonaceous material Substances 0.000 claims abstract description 12
- 238000005476 soldering Methods 0.000 claims abstract description 8
- 239000007769 metal material Substances 0.000 claims abstract description 6
- 239000010953 base metal Substances 0.000 claims description 15
- 229910052802 copper Inorganic materials 0.000 claims description 14
- 239000010949 copper Substances 0.000 claims description 14
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 11
- 239000000654 additive Substances 0.000 claims description 11
- 238000002844 melting Methods 0.000 claims description 11
- 239000000843 powder Substances 0.000 claims description 11
- 229910045601 alloy Inorganic materials 0.000 claims description 9
- 239000000956 alloy Substances 0.000 claims description 9
- 230000008018 melting Effects 0.000 claims description 9
- 229910052718 tin Inorganic materials 0.000 claims description 9
- 230000000996 additive effect Effects 0.000 claims description 7
- 239000010439 graphite Substances 0.000 claims description 7
- 229910002804 graphite Inorganic materials 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 6
- 229910052797 bismuth Inorganic materials 0.000 claims description 5
- 229910052738 indium Inorganic materials 0.000 claims description 5
- 239000012071 phase Substances 0.000 claims description 4
- 229910000881 Cu alloy Inorganic materials 0.000 claims description 3
- 239000007791 liquid phase Substances 0.000 claims description 3
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical class [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 2
- 229910003465 moissanite Inorganic materials 0.000 claims description 2
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 2
- 239000000454 talc Substances 0.000 claims description 2
- 229910052623 talc Inorganic materials 0.000 claims description 2
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims 3
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims 3
- 229910010272 inorganic material Inorganic materials 0.000 claims 2
- 239000011147 inorganic material Substances 0.000 claims 2
- 239000011368 organic material Substances 0.000 claims 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 1
- 229910052593 corundum Inorganic materials 0.000 claims 1
- 235000012222 talc Nutrition 0.000 claims 1
- 229910001845 yogo sapphire Inorganic materials 0.000 claims 1
- 239000010410 layer Substances 0.000 description 30
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 229910052742 iron Inorganic materials 0.000 description 3
- 229920000049 Carbon (fiber) Polymers 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 239000004917 carbon fiber Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 229910000679 solder Inorganic materials 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 239000002346 layers by function Substances 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000004663 powder metallurgy Methods 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01R—ELECTRICALLY-CONDUCTIVE CONNECTIONS; STRUCTURAL ASSOCIATIONS OF A PLURALITY OF MUTUALLY-INSULATED ELECTRICAL CONNECTING ELEMENTS; COUPLING DEVICES; CURRENT COLLECTORS
- H01R39/00—Rotary current collectors, distributors or interrupters
- H01R39/02—Details for dynamo electric machines
- H01R39/38—Brush holders
- H01R39/39—Brush holders wherein the brush is fixedly mounted in the holder
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01R—ELECTRICALLY-CONDUCTIVE CONNECTIONS; STRUCTURAL ASSOCIATIONS OF A PLURALITY OF MUTUALLY-INSULATED ELECTRICAL CONNECTING ELEMENTS; COUPLING DEVICES; CURRENT COLLECTORS
- H01R39/00—Rotary current collectors, distributors or interrupters
- H01R39/02—Details for dynamo electric machines
- H01R39/18—Contacts for co-operation with commutator or slip-ring, e.g. contact brush
- H01R39/20—Contacts for co-operation with commutator or slip-ring, e.g. contact brush characterised by the material thereof
Definitions
- Carbon brushes for electric motors or generators must be attached to a holder that provides the necessary system pressure on the commutator or the like. And allows the wear of the carbon brush corresponding Nachvantterrorism.
- a particularly suitable for the carbon brush because of its simplicity, cost-effectiveness and low weight carrier is a leaf spring, which can take over the function of power transmission in addition to the function of the holder and guide. However, it raises the problem of attachment of the carbon brush to the leaf spring such that on the one hand, the required mechanical strength in continuous operation and on the other hand, the transmission of high currents is ensured.
- a carbon brush according to the preamble of claim 1 is known, which is attached to a serving as a support leaf spring by welding or soldering and tinned for this purpose on the surface to be connected to the carrier, nickel-plated or metallized in any other way.
- Out DE 40 40 002 A1 is a carbon brush for a gasoline pump motor is known, which is soldered to a serving as a leaf spring and for this purpose has a solderable layer consisting of a copper layer and a deposited thereon tin layer.
- a solderable layer consisting of a copper layer and a deposited thereon tin layer.
- US 5270504 A is a sliding contact element, such.
- carbon brush known which has a layer structure of alternating copper-free and copper-containing graphite layers, wherein in the copper-free graphite layers, a filler material is included, which consists of a metal or a metal alloy having a lower melting temperature than copper.
- a metal layer for a soldered or welded connection with a metallic carrier is not provided.
- the invention has for its object to provide a carbon brush and a method and a material for their production, which allows a simple, mechanically and electrically highly resilient connection with a leaf spring.
- a carbon brush which in addition to the usual, single or multilayer main body of pressed and sintered carbon material has at least one outer layer of metallic material, which ensures the weldability or solderability of the carbon brush, said metal layer also produced by pressing and sintering and connected to the main body.
- a suitable welding method eg ultrasonic welding, laser welding or the like
- soldering must be applied and also for the production of carbon brushes with a weldable metal layer, a material must be available, on the one hand in the powder metallurgy processing well with the carbon material of the main body of the carbon brush connects and on the other hand with the selected method well to weld or solder.
- pure copper and its alloys as well as iron or steel are not suitable because their coefficient of thermal expansion and modulus of elasticity is not compatible with that of the carbon material of the main body of the carbon brush in the sintering process. Materials that are similar to the carbon material of the main body of the carbon brush, are also eliminated because they can not be welded due to the contained graphite part.
- a metallic material in the form of a powder mixture of a component A, a ductile and low-melting component B and possibly further additives C both needs, namely the good connection by pressing and sintering with the functional carbon material of the body of the carbon brush on the one hand and the good weldability or solderability on the other hand at the same time.
- the constituent A constitutes the predominant part, preferably more than 80%, of the material and preferably consists of copper or a copper alloy with, for example, Sn, Zn, Ni or Ag. It is preferably in powder form with a mean diameter D 50 of 15 to 25 microns before.
- Component B is an additional metal which has a higher ductility and lower melting point than component A.
- the melting point is 400 ° C or below and the elongation at break is 5% or above.
- Component B is preferably Sn or an alloy of Sn with, for example, Cu, Ag, Sb, Zn, Ga, In, Bi or Pb.
- the metal component B may also consist of In and / or Bi or an alloy with In or Bi. Its proportion of the total powder mixture of the material is preferably 1.5 to 15 percent by weight.
- the additional metal B is preferably present in an average particle size D 50 of 15 to 35 microns.
- the material may preferably contain one or more non-metallic, organic and / or inorganic additives C in powder form.
- non-metallic, organic and / or inorganic additives C examples include stearates, graphite, talc, SiC or Al 2 O 3 .
- Their average grain size D 50 is preferably not more than 20 microns.
- the specified material can be powder metallurgically properly processed by pressing and sintering and combines perfectly with the functional layer (body) of the carbon brush to form a metal layer with excellent weldability and solderability. It has been found that during pressing and sintering, the low-melting and ductile metal B wets the base metal A, but does not or little diffuses into it.
- the base metal A and at least the major part of the further metal B form two separate metal phases intimately bonded together by pressing and sintering, but substantially unalloyed with each other.
- the heat treatment i. H. sintering the metal layer at a temperature lower than the melting point of the base metal A but higher than the melting point of the further metal B. It is thus preferably a liquid sintering in which the further metal B is in the liquid phase, while the base metal A is in a solid, powdery phase.
- the sintering temperature is advantageously in the range of 300 to 700 ° C, preferably in the range of 400 to 500 ° C.
- the non-metallic, organic or inorganic additive C is not wetted by the metal B in the sintering process, thereby preventing an undesirably large diffusion of the metal B into the parent metal A.
- the carbon brush has a main body 1, which is produced in a conventional manner single-layer or multi-layer of a conventional carbon material for carbon brushes, in particular a graphite mixture with additives, by pressing and heat treatment (sintering).
- a conventional carbon material for carbon brushes in particular a graphite mixture with additives
- the well weldable or solderable metal layer (2) which is also made of the abovementioned powdery material according to the invention by pressing and optionally sintering and is permanently connected to the base body 1.
- Base body 1 and weldable metal layer 2 can be produced simultaneously by pressing and sintering and connected to each other, or it can be the base body 1 prefabricated and subsequently formed the weldable metal layer 2 by pressing and sintering.
- the weldable metal layer 2 makes it possible to attach the entire carbon brush by welding to a leaf spring 3, for example by welding points 4 or z. B. by a continuous weld.
- the thickness of the sintered metal layer 2 depends on the requirements of the welding or soldering method selected for the connection to the leaf spring 3.
- the thickness of the metal layer 2 is in the range of 0.2 to 5 mm.
- a thickness of the metal layer 2 of less than 1 mm, in particular in the range of 0.2 to 0.5 mm, should generally suffice.
- a thickness of at least 1 mm, z. B. in the range of 2 to 4 mm be advantageous.
Landscapes
- Motor Or Generator Current Collectors (AREA)
- Powder Metallurgy (AREA)
- Manufacture Of Motors, Generators (AREA)
- Carbon And Carbon Compounds (AREA)
- Laminated Bodies (AREA)
Claims (14)
- Balai de charbon comprenant un corps de base (1) fabriqué en matériau de charbon et une couche de métal (2) appliquée sur une surface extérieure du corps de base, qui peut être reliée par soudage ou brasage à un support métallique, la couche métallique (2) étant une couche fabriquée à partir de poudre de métal par pressage et éventuellement frittage et reliée de façon indétachable au corps de base (1) par pressage et éventuellement frittage, caractérisé en ce que la couche de métal (2) contient un métal de base (A) et au moins un autre métal (B) avec une ductilité supérieure et un point de fusion plus faible que le métal de base (A), l'autre métal (B) étant présent au moins principalement sous forme d'une phase métallique séparée du métal de base (A), qui est liée de façon intime avec le métal de base (A) par pressage et éventuellement frittage, mais principalement ne forme pas d'alliage avec lui.
- Balai de charbon selon la revendication 1,
caractérisé en ce que l'autre métal (B) est choisi de telle sorte qu'il mouille le métal de base (A) à la température de frittage en phase liquide, mais ne diffuse pas ou peu dans ce métal. - Balai de charbon selon la revendication 1 ou 2,
caractérisé en ce que l'autre métal (B) est composé d'étain, d'indium ou de bismuth ou d'un alliage de ces métaux. - Balai de charbon selon la revendication 1,
caractérisé en ce que l'autre métal (B) présente un point de fusion de pas plus que 400°C et un allongement à la rupture de pas moins que 5 %. - Balai de charbon selon l'une quelconque des revendications 1 à 4,
caractérisé en ce que l'autre métal (B) est présent dans une fraction comprise entre 1,5 et 15 % en poids de la couche de métal (2). - Balai de charbon selon l'une quelconque des revendications 1 à 5,
caractérisé en ce que la couche de métal (2) contient en outre un additif (C) à base de matériau non métallique, organique et/ou inorganique. - Balai de charbon selon la revendication 6, caractérisé en ce que l'additif (C) non métallique contient des stéarates, du graphite, du talc, du SiC ou du Al2O3.
- Balai de charbon selon l'une quelconque des revendications 1 à 7,
caractérisé en ce que sa couche de métal (2) est liée à un support (3) en métal par soudage ou brasage. - Balai de charbon selon la revendication 8,
caractérisé en ce que le support est un ressort à lame (3). - Matériau pour la fabrication d'une couche de métal soudable et/ou brasable d'un balai de charbon selon l'une quelconque des revendications 1 à 9, se composant d'un mélange de poudres, qui contient un métal principal (A) pulvérulent et un métal supplémentaire (B) pulvérulent avec une ductilité supérieure et un point de fusion inférieur au métal principal (A), le métal principal (A) étant du cuivre ou un alliage de cuivre et le métal supplémentaire (B) étant de l'étain, de l'indium ou du bismuth ou un alliage de ces métaux, et le matériau ne contenant pas plus de 0,5 % en poids de graphite.
- Matériau selon la revendication 10,
caractérisé en ce qu'il contient un additif (C) pulvérulent en matériau non métallique, organique et/ou inorganique. - Matériau selon la revendication 10 ou 11,
caractérisé en ce que le métal supplémentaire (B) est présent dans une fraction de 1,5 à 15 % en volume de mélange de poudres. - Procédé pour la fabrication d'un balai de charbon, qui présente un corps de base en matériau de charbon et une couche métallique reliée de façon indétachable à ce matériau, présentant les étapes suivantes :a) fabrication du corps de base par pressage et frittage d'un matériau pulvérulent contenant du charbon ;b) en même temps que l'étape a) ou à la suite de cette étape : fabrication de la couche métallique par pressage et frittage d'un matériau métallique pulvérulent, la couche métallique étant liée par pressage et frittage de façon indétachable au corps de base ;c) le matériau métallique pulvérulent contenant un mélange d'un métal de base A pulvérulent et d'au moins un autre métal B pulvérulent avec une ductilité supérieure et un point de fusion inférieur au métal de base A, etd) l'autre métal B et la température de frittage étant choisis de telle sorte que l'autre métal mouille le métal de base A lors du frittage en phase liquide, mais ne diffuse pas ou peu dans ce métal, de telle sorte que, dans la couche métallique, l'autre métal B est présent au moins principalement sous forme d'une phase métallique séparée du métal de base A et principalement non alliée à lui.
- Procédé selon la revendication 13,
caractérisé en ce que le métal principal A est composé de cuivre ou d'alliage de cuivre et l'autre métal B est composé d'étain, d'indium ou de bismuth ou d'un alliage de ces métaux.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10359896A DE10359896A1 (de) | 2003-12-19 | 2003-12-19 | Kohlebürste sowie Verfahren und Werkstoff zu ihrer Herstellung |
| PCT/EP2004/014235 WO2005064756A1 (fr) | 2003-12-19 | 2004-12-14 | Balai de charbon ainsi que procede et materiau pour la fabrication dudit balai |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1702390A1 EP1702390A1 (fr) | 2006-09-20 |
| EP1702390B1 true EP1702390B1 (fr) | 2007-12-05 |
Family
ID=34683604
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP04803858A Expired - Lifetime EP1702390B1 (fr) | 2003-12-19 | 2004-12-14 | Balai de charbon ainsi que procédé et matériau pour la fabrication dudit balai |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US20060260436A1 (fr) |
| EP (1) | EP1702390B1 (fr) |
| JP (1) | JP2007515146A (fr) |
| CN (1) | CN1902792A (fr) |
| AT (1) | ATE380408T1 (fr) |
| DE (2) | DE10359896A1 (fr) |
| ES (1) | ES2297520T3 (fr) |
| WO (1) | WO2005064756A1 (fr) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102006051678A1 (de) * | 2006-10-30 | 2008-05-15 | Schunk Modultechnik Gmbh | Schleifkontakt |
| JP2008118831A (ja) | 2006-11-08 | 2008-05-22 | Mabuchi Motor Co Ltd | 金属黒鉛質ブラシ |
| DE102007026265B4 (de) | 2007-06-05 | 2014-04-10 | Gerhard Präzisionspresstechnik GmbH | Kohlebürste |
| DE102008059478B4 (de) | 2008-11-28 | 2015-07-30 | Schunk Kohlenstofftechnik Gmbh | Kohlebürste zur Übertragung hoher Ströme |
| CN102439183A (zh) * | 2009-04-28 | 2012-05-02 | 大丰工业株式会社 | 无铅铜系烧结滑动材料及滑动部件 |
| FR2972082B1 (fr) | 2011-02-28 | 2013-03-29 | Mersen France Amiens Sas | Balai de contact |
| DE102011015579B4 (de) * | 2011-03-30 | 2017-03-23 | Heraeus Deutschland GmbH & Co. KG | Elastischer Schleifkontakt und Verfahren zu dessen Herstellung |
| CN106329286B (zh) * | 2015-07-01 | 2019-06-11 | 苏州东南佳新材料股份有限公司 | 一种动车组接地回流装置用电刷的制备方法 |
| DE102017209340B4 (de) * | 2017-06-01 | 2022-12-15 | Schunk Carbon Technology Gmbh | Ableitvorrichtung zur Ableitung elektrischer Ströme |
| CN109244686B (zh) * | 2018-07-26 | 2021-06-18 | 合德华厦安防科技有限公司 | 一种用于接地系统的芯棒及其制备方法 |
| WO2023086436A1 (fr) * | 2021-11-10 | 2023-05-19 | National Electrical Carbon Products, Inc. | Balai de charbon |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1259454A (fr) * | 1968-05-23 | 1972-01-05 | ||
| DE2444957C2 (de) * | 1974-09-20 | 1982-08-12 | Robert Bosch Gmbh, 7000 Stuttgart | Verfahren zur Herstellung eines Verbundwerkstoffs aus kohlenstoffhaltigem Pulver und Metallpulver |
| JPS57185685A (en) * | 1981-05-09 | 1982-11-15 | Toho Beslon Co | Brush for electric machine and method of producing same |
| DE59105627D1 (de) * | 1991-07-22 | 1995-07-06 | Carbone Ag | Gleitkontaktstück für hohe Stromdichten. |
| DE19900023A1 (de) * | 1999-01-02 | 2000-07-06 | Carbone Ag | Verfahren zur Herstellung einer Bürste aus einem pulverförmigen Werkstoff sowie eine Bürste, die nach einem solchen Verfahren hergestellt ist |
| DE10207406A1 (de) * | 2002-02-21 | 2003-09-11 | K Tec Gmbh | Halterung für eine Kohlebürste |
-
2003
- 2003-12-19 DE DE10359896A patent/DE10359896A1/de not_active Withdrawn
-
2004
- 2004-12-14 JP JP2006544315A patent/JP2007515146A/ja not_active Withdrawn
- 2004-12-14 WO PCT/EP2004/014235 patent/WO2005064756A1/fr not_active Ceased
- 2004-12-14 AT AT04803858T patent/ATE380408T1/de not_active IP Right Cessation
- 2004-12-14 DE DE502004005669T patent/DE502004005669D1/de not_active Expired - Fee Related
- 2004-12-14 ES ES04803858T patent/ES2297520T3/es not_active Expired - Lifetime
- 2004-12-14 CN CNA2004800375469A patent/CN1902792A/zh active Pending
- 2004-12-14 EP EP04803858A patent/EP1702390B1/fr not_active Expired - Lifetime
-
2006
- 2006-06-15 US US11/453,385 patent/US20060260436A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| CN1902792A (zh) | 2007-01-24 |
| DE502004005669D1 (de) | 2008-01-17 |
| EP1702390A1 (fr) | 2006-09-20 |
| ATE380408T1 (de) | 2007-12-15 |
| US20060260436A1 (en) | 2006-11-23 |
| ES2297520T3 (es) | 2008-05-01 |
| WO2005064756A1 (fr) | 2005-07-14 |
| DE10359896A1 (de) | 2005-07-21 |
| JP2007515146A (ja) | 2007-06-07 |
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