EP1849855A1 - Compositions assouplissantes thixotropiques - Google Patents

Compositions assouplissantes thixotropiques Download PDF

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Publication number
EP1849855A1
EP1849855A1 EP06113229A EP06113229A EP1849855A1 EP 1849855 A1 EP1849855 A1 EP 1849855A1 EP 06113229 A EP06113229 A EP 06113229A EP 06113229 A EP06113229 A EP 06113229A EP 1849855 A1 EP1849855 A1 EP 1849855A1
Authority
EP
European Patent Office
Prior art keywords
fabric softener
groups
viscosity
alkyl
hydrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP06113229A
Other languages
German (de)
English (en)
Inventor
Ulrike Dr. Kottke
Michael Fender
Harald Dr. Jakob
Kurt Seidel
Ellen Reuter
Eberhard Esselborn
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Evonik Operations GmbH
Original Assignee
Evonik Degussa GmbH
Degussa GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Evonik Degussa GmbH, Degussa GmbH filed Critical Evonik Degussa GmbH
Priority to EP06113229A priority Critical patent/EP1849855A1/fr
Priority to PCT/EP2007/053302 priority patent/WO2007125005A1/fr
Priority to EP07727773A priority patent/EP2010637A1/fr
Priority to CNA2007800066882A priority patent/CN101389741A/zh
Priority to US12/226,636 priority patent/US20090124533A1/en
Publication of EP1849855A1 publication Critical patent/EP1849855A1/fr
Withdrawn legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/003—Colloidal solutions, e.g. gels; Thixotropic solutions or pastes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/001—Softening compositions
    • C11D3/0015—Softening compositions liquid
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3726—Polyurethanes

Definitions

  • the invention is directed to viscous aqueous fabric softeners.
  • Aqueous fabric softeners are usually added to the last rinse when washing laundry in a washing machine to give the laundry a softer feel.
  • Such fabric softeners usually contain fabric softening quaternary ammonium salts in an amount of 2 to 20% by weight as active components dispersed in an aqueous solution.
  • fabric softeners with a content of active components of up to 10% by weight generally have only a low viscosity and are therefore difficult to meter in the application.
  • consumers typically judge the effectiveness of a fabric softener by its viscosity and estimate a more highly viscous fabric softener to be more effective. Too high a viscosity, however, is undesirable because it results in the application to incomplete flushing in the washing machine. Therefore, there is a need for aqueous fabric softeners having an increased, precisely predetermined viscosity.
  • fabric softeners containing an oligomeric ester quat and a thickener selected from ethoxylated and / or propoxylated cellulose, ethoxylated and / or propoxylated C 10-15 fatty alcohol or an ethoxylated and / or propoxylated fatty alcohol polyurethane are known.
  • Suitable thickeners include the Accusol 880 TM polyurethane polymer marketed by Rohm and Haas.
  • Fabric softeners which contain a quaternary ammonium salt and a Fatty alcohol ethoxylate diurethane polymer as thickener.
  • Suitable thickeners mentioned are products of BASF with the code numbers 71495, 71496 and 71497.
  • the fabric softener during mixing and filling has a lower viscosity than the desired viscosity of the final product.
  • the viscosity of the fabric softener does not change during storage to allow quality control of the viscosity of the product produced during manufacture and to ensure that the quality of the product does not change during storage.
  • aqueous fabric softeners which contain a polyurethane thickener and have a reversibly thixotropic flow behavior.
  • the invention therefore relates to aqueous fabric softeners which comprise at least one textile softening quaternary ammonium salt and at least one polyurethane thickener and which have a reversibly thixotropic flow behavior.
  • Thixotropic flow behavior of a fabric softening agent means that the viscosity of the fabric softening agent decreases with a shear load and rises again after the end of the shear load.
  • a reversibly thixotropic flow behavior in the context of the invention is present when the viscosity of the Softener at a shear load decreases and after the end of the shear load within a short time, ie usually less than one hour, again rises to at least 90% of the initial value.
  • the fabric softeners according to the invention preferably have a quiescent viscosity in the linear viscoelastic range of more than 100 mPa.s, the viscosity being measured according to DIN 53019 in a rotary viscometer with cylinder geometry.
  • the linear-viscoelastic region is the region of small shear stresses in which the elastic component G 'of the complex shear modulus is independent of the shear stress.
  • the viscosity of these preferred fabric softeners decreases to less than 30% of the quiescent viscosity and rises again to more than 80% of the quiescent viscosity in less than 10 minutes after the end of the shear stress.
  • fabric softeners in which the viscosity at a shear stress with a shear stress of 30 Pa to less than 20% of the rest viscosity decreases and rises after the end of the shear stress in less than 10 minutes back to more than 90% of the rest viscosity.
  • the fabric softeners according to the invention preferably have a viscosity in the range from 200 to 3000 mPa ⁇ s, particularly preferably in the range from 400 to 1500 mPa ⁇ s.
  • Polyurethane thickeners in the context of the invention are thickening polymers in aqueous solution, their Polymer skeleton is obtained by polyaddition from diisocyanates and diols.
  • Such polyurethane thickeners and their preparation are known to those skilled in the art, for example from US 4,155,892 ,
  • the fabric softeners according to the invention preferably contain a polyurethane thickener, which is an addition product of a diisocyanate with a polyalkylene glycol, wherein the addition product carries at the chain ends in each case a C 14 -C 20 -alkyl radical.
  • the diisocyanate is preferably an aliphatic diisocyanate and is more preferably selected from hexamethylene diisocyanate, isophorone diisocyanate and dicyclohexylmethylene diisocyanate.
  • the polyalkylene glycol preferably comprises more than 80 mol% of ethylene oxide monomer units and preferably has a molecular weight of at least 3000 g / mol.
  • Quaternary ammonium salts with textile softening effect and their preparation are known to the person skilled in the art.
  • the fabric softeners according to the invention preferably contain quaternary ammonium salts of the formula (I) (I) R 2 4-m N + [(CH 2 ) n -QR 3 ] m X - wherein the groups R 2 independently of one another are C 1 -C 6 -alkyl, C 1 -C 6 -hydroxyalkyl or benzyl, the groups R 3 independently of one another are hydrogen or linear or branched C 11 -C 22 -alkyl or -alkenyl, where at least one of the radicals R 3 is not hydrogen, the groups Q are independently selected from groups of the formulas -OC (O) -, -C (O) O-, -NR 4 -C (O) -, -C (O) -NR 4 -, -OC (O ) -O-, -CHR 5 -OC (O) - or -CH (OCOR 3 ) -CH 2 -OC (O) -, wherein R
  • Chlorides, bromide, methylsulfate, ethylsulfate, sulfate and nitrate are particularly suitable anions suitable for fabric softeners.
  • R 2 is methyl
  • Q is -OC (O) - or -NH-C (O) -
  • m is 2 or 3
  • n 2 and X - chloride or methyl sulfate.
  • these compounds are used in the form of mixtures, compounds containing on average from 1.2 to 2.5 groups R 3 which are not hydrogen. More preferably, the proportion of non-hydrogen groups R 3 is on average 1.4 to 2.0, most preferably 1.6 to 1.9.
  • Preferred compounds of the formula (I) are quaternary ammonium salts of the formulas (II) to (IV) (II) R 6 N + [CH 2 CHR 8 OH] [CH 2 CHR 8 OC (O) R 7 ] 2 X - (III) R 6 2 N + [CH 2 CHR 8 OC (O) R 7 ] 2 X - (IV) R 6 N + [CH 2 CHR 8 OH] [CH 2 CH 2 NHC (O) R 7 ] 2 X - where the groups R 6 independently of one another are C 1 -C 6 -alkyl, C 1 -C 6 -hydroxyalkyl or benzyl, the groups R 7 are independently linear or branched C 11 -C 22 alkyl or alkenyl, and the groups R 8 are hydrogen or methyl.
  • the group -C (O) R 7 is preferably a fatty acid residue.
  • Suitable fatty acids are obtainable from natural triglycerides, preferably from tallow, vegetable oils, partially hydrogenated tallow or partially hydrogenated vegetable oils.
  • Suitable sources of triglycerides are, for example, soybean oil, tallow, partially hydrogenated tallow, palm oil, palm kernel oil, rapeseed oil, coconut oil, sunflower oil, corn oil, rice oil and tall oil.
  • the fatty acids from natural sources are usually mixtures of unbranched and branched, and saturated and unsaturated aliphatic fatty acids.
  • fatty acids obtained from various natural sources may be used in admixture.
  • the proportion of unsaturated fatty acid residues R 7 is preferably at least 10%, particularly preferably at least 25% and in particular 40% to 70%.
  • the proportion of polyunsaturated groups R 7 is preferably less than 10%, particularly preferably less than 5% and in particular less than 3%. If necessary, the proportion of polyunsaturated fatty acid residues can be reduced by partial hydrogenation to improve the storage stability of the product in terms of color change and odor development.
  • the proportion of unsaturated fatty acid residues is preferably in the range of an iodine value of from 5 to 150, particularly preferably 5 to 50.
  • the ratio of cis and trans isomers of the double bonds is preferably greater than 1: 1 and more preferably in the range of 4: 1 to 50: 1.
  • quaternary ammonium salts of the formulas (V) to (VII) (V) R 6 2 R 7 2 N + X - (VI) [R 7 -C (O) NHCH 2 CH 2 ] 2 N + R 6 [CH 2 CH 2 OH] X - wherein the radicals R 6 , R 7 and X have the same meaning as in the formulas (II) to (IV) and Q is -OC (O) - or -NH-C (O) -.
  • the aqueous fabric softeners according to the invention preferably contain one or more quaternary ammonium salts in a total amount of from 2 to 10% by weight, more preferably from 2 to 6% by weight, and one or more polyurethane thickeners in a total amount of from 0.001 to 2% by weight. %, more preferably 0.005 to 1 wt .-% and in particular 0.005 to 0.5 wt .-%.
  • aqueous fabric softeners according to the invention may additionally contain further additives which are known to the person skilled in the art for the formulation of fabric softeners, in particular those from US Pat US 6,737,392 Column 8, line 1 to column 14, line 6 known additives.
  • compositions of the prepared aqueous fabric softeners are shown in Table 1.
  • Table 1 Fabric Softening Compositions (The balance at 100% by weight is water, dye and perfume oil) example Rewoquat WE 18 [Wt .-%] Tego Visco Plus 3030 [Wt .-%] Accusol 880 [Wt .-%] Acrysol RM-8W [Wt .-%] Acrysol RM-825 [Wt .-%] 1 3 0.1 - - - 2 3 0.25 - - - 3 3 0.5 - - - * 4 3 - 0.17 - - 5 * 3 - 0.43 - - 6 * 3 - 0.86 - - 7 4 0.5 - - - 8th* 4 - 0.86 - - 9 * 4 - - 1.7 - 10 * 4 - - - 1.2 11 5 0.1 12 5 0.05 - - 13 5 0,025 - - - 14 * 5 - 0.
  • the thixotropic flow behavior was determined using a rotary viscometer model Stresstech from the manufacturer Reologica. The measurements were made with cylinder geometry by oscillating measurement at an oscillation frequency of 1 Hz in a measuring cup model 26.5 mm diameter EMB-Z3 using a model CC25 oscillating cylinder with 25 mm outer diameter. It was measured at 23 ° C immediately after 300 s at a shear stress of 0.2 Pa, 120 s at a shear stress of 30 Pa and 900 s at a shear stress of 0.2 Pa. Control measurements at the same frequency of oscillation at which the viscosity was determined as a function of the shear stress ensured that all samples were measured with a shear stress of 0.2 Pa in the linear viscoelastic region.
  • the viscosity was determined within 0.5 h after the preparation and after 12 weeks storage at room temperature. Viscosity was measured with a Brookfield viscometer at 20 ° C with spindle LVT # 2 at a rotational speed of 30 min -1 .
  • Table 3 Viscosity before and after 12 weeks storage example Viscosity after preparation [mPa s] Viscosity after storage [mPa s] viscosity change [%] 1 235 265 +13 2 410 420 + 2 3 510 560 +10 * 4 325 210 -35 5 * 345 280 -19 6 * 950 480 -49 11 745 880 +18 12 530 620 +17 13 375 340 - 9 14 * 760 300 -61 15 * 740 320 -57 16. * 430 265 -38 * not according to the invention
  • the fabric softeners according to the invention with a polyurethane thickener which causes a reversibly thixotropic flow behavior show a good stability of the viscosity, which changes little during storage over 12 weeks compared to the viscosity immediately after production.
  • a quality control after production it is possible with these fabric softeners to ensure that the product reaches the consumer with a predetermined viscosity.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
EP06113229A 2006-04-27 2006-04-27 Compositions assouplissantes thixotropiques Withdrawn EP1849855A1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
EP06113229A EP1849855A1 (fr) 2006-04-27 2006-04-27 Compositions assouplissantes thixotropiques
PCT/EP2007/053302 WO2007125005A1 (fr) 2006-04-27 2007-04-04 Agent assouplissant thixotrope
EP07727773A EP2010637A1 (fr) 2006-04-27 2007-04-04 Agent assouplissant thixotrope
CNA2007800066882A CN101389741A (zh) 2006-04-27 2007-04-04 触变性织物柔软剂
US12/226,636 US20090124533A1 (en) 2006-04-27 2007-04-04 Thixotropic Fabric Softeners

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP06113229A EP1849855A1 (fr) 2006-04-27 2006-04-27 Compositions assouplissantes thixotropiques

Publications (1)

Publication Number Publication Date
EP1849855A1 true EP1849855A1 (fr) 2007-10-31

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EP06113229A Withdrawn EP1849855A1 (fr) 2006-04-27 2006-04-27 Compositions assouplissantes thixotropiques
EP07727773A Withdrawn EP2010637A1 (fr) 2006-04-27 2007-04-04 Agent assouplissant thixotrope

Family Applications After (1)

Application Number Title Priority Date Filing Date
EP07727773A Withdrawn EP2010637A1 (fr) 2006-04-27 2007-04-04 Agent assouplissant thixotrope

Country Status (4)

Country Link
US (1) US20090124533A1 (fr)
EP (2) EP1849855A1 (fr)
CN (1) CN101389741A (fr)
WO (1) WO2007125005A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2746377A1 (fr) * 2012-12-20 2014-06-25 The Procter & Gamble Company Structuration améliorée utilisant un structurant externe et un cosmotrope
WO2016009150A1 (fr) * 2014-07-18 2016-01-21 Coatex Composition d'assouplissement des tissus comprenant un epaississant heur

Families Citing this family (29)

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Publication number Priority date Publication date Assignee Title
GB0512095D0 (en) * 2005-06-14 2005-07-20 Unilever Plc Fabric softening composition
US8361953B2 (en) * 2008-02-08 2013-01-29 Evonik Goldschmidt Corporation Rinse aid compositions with improved characteristics
CN102803456B (zh) 2010-04-01 2014-06-11 赢创德固赛有限公司 织物柔软剂活性组合物
AP3143A (en) 2010-04-01 2015-02-28 Evonik Degussa Gmbh Fabric softener active composition
HUE033227T2 (en) 2010-04-28 2017-11-28 Evonik Degussa Gmbh Textile softener composition
US8507425B2 (en) 2010-06-29 2013-08-13 Evonik Degussa Gmbh Particulate fabric softener comprising ethylenediamine fatty acid amides and method of making
DE102010062156A1 (de) 2010-10-25 2012-04-26 Evonik Goldschmidt Gmbh Polysiloxane mit stickstoffhaltigen Gruppen
DE102011078382A1 (de) 2011-06-30 2013-01-03 Evonik Goldschmidt Gmbh Mikroemulsion von quaternären Ammoniumgruppen enthaltenden Polysiloxanen, derenHerstellung und Verwendung
DE102011110100A1 (de) 2011-08-12 2013-02-14 Evonik Goldschmidt Gmbh Verfahren zu Herstellungen von Polysiloxanen mit stickstoffhaltigen Gruppen
WO2013113453A1 (fr) 2012-01-30 2013-08-08 Evonik Industries Ag Composition active d'assouplissant pour textile
EP2847307B1 (fr) 2012-05-07 2016-04-06 Evonik Degussa GmbH Composition d'agent actif assouplissant pour tissus et son procédé de fabrication
DE102013206175A1 (de) 2013-04-09 2014-10-09 Evonik Industries Ag Polysiloxan-Polyether-Copolymere mit Amino- und/oder quaternären Ammoniumgruppen im Polyetherteil und Verfahren zu deren Herstellung
BR102014025172B1 (pt) 2013-11-05 2020-03-03 Evonik Degussa Gmbh Método para fabricação de um éster de ácido graxo de metisulfato de tris-(2-hidroxietil)-metilamônio, e composição ativa de amaciante de roupa
CA2931183C (fr) 2014-01-22 2019-05-07 Halliburton Energy Services, Inc. Agglomerats d'agents de soutenement micrometriques et nanometriques destines a etre utilises dans des operations souterraines
FR3023845B1 (fr) 2014-07-18 2018-01-05 Coatex Sas Composition d'assouplissement des tissus comprenant un epaississant heur.
EP2997958B1 (fr) * 2014-09-22 2021-03-10 Evonik Operations GmbH Émulsion contenant des esterquats liquides et polymères épaississants
UA119182C2 (uk) 2014-10-08 2019-05-10 Евонік Дегусса Гмбх Активна композиція для пом'якшувача тканини
SG11201906199UA (en) 2017-02-09 2019-08-27 Evonik Degussa Gmbh Polymers for hydrophobic and oleophobic textile finishing
CN121407385A (zh) 2017-09-06 2026-01-27 赢创运营有限公司 特别用于生产织物柔软剂配制物的包含季铵化合物的微乳剂
ES2939182T3 (es) 2017-09-25 2023-04-19 Evonik Operations Gmbh Concentrados estables al almacenamiento que contienen polisiloxanos y su empleo, preferentemente en composiciones de mantenimiento textil
EP3818137B1 (fr) 2018-07-05 2022-11-09 Evonik Operations GmbH Substances actives pour formulations de lavage et de nettoyage fortement visqueuses
JP2023051094A (ja) * 2021-09-30 2023-04-11 ライオン株式会社 液体柔軟剤組成物
JP2023051098A (ja) * 2021-09-30 2023-04-11 ライオン株式会社 液体柔軟剤組成物
JP2023051095A (ja) * 2021-09-30 2023-04-11 ライオン株式会社 液体柔軟剤組成物
JP2023051096A (ja) * 2021-09-30 2023-04-11 ライオン株式会社 液体柔軟剤組成物
JP2023051097A (ja) * 2021-09-30 2023-04-11 ライオン株式会社 液体柔軟剤組成物
WO2024011447A1 (fr) 2022-07-13 2024-01-18 Evonik Operations Gmbh Composition active d'adoucissant textile pour la préparation d'une composition d'adoucissant textile transparent
WO2025036787A1 (fr) 2023-08-17 2025-02-20 Evonik Operations Gmbh Substances actives pour compositions nettoyantes
CN121794357A (zh) 2023-08-17 2026-04-03 赢创运营有限公司 用于清洁组合物的活性物质

Citations (7)

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Publication number Priority date Publication date Assignee Title
US4155892A (en) * 1975-10-03 1979-05-22 Rohm And Haas Company Polyurethane thickeners for aqueous compositions
EP0385749A2 (fr) * 1989-03-02 1990-09-05 Unilever Plc Composition adoucissante pour le linge
DE9107984U1 (de) * 1991-06-28 1992-10-29 Joh. A. Benckiser Gmbh, 6700 Ludwigshafen Flüssiges, wäßriges, viskoses Tensidsystem
EP0799887A1 (fr) * 1996-04-01 1997-10-08 The Procter & Gamble Company Compositions assouplissantes pour tissus
WO2000004118A1 (fr) * 1998-07-20 2000-01-27 Colgate-Palmolive Compositions adoucissantes contenant un polymere de diurethane comme epaississant
EP1295591A1 (fr) * 2000-06-26 2003-03-26 Shiseido Company Limited Preparation de soin pour les cheveux
US20040087472A1 (en) * 2002-11-01 2004-05-06 Jean-Paul Grandmaire Aqueous composition comprising oligomeric esterquats

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Publication number Priority date Publication date Assignee Title
PH18436A (en) * 1980-11-07 1985-07-08 Unilever Nv A fabric softening composition and a process for preparing it
DE60308901T2 (de) * 2002-12-20 2007-05-24 Degussa Gmbh Flüssige wasch- und reinigungsmittelzusammensetzung

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4155892A (en) * 1975-10-03 1979-05-22 Rohm And Haas Company Polyurethane thickeners for aqueous compositions
EP0385749A2 (fr) * 1989-03-02 1990-09-05 Unilever Plc Composition adoucissante pour le linge
DE9107984U1 (de) * 1991-06-28 1992-10-29 Joh. A. Benckiser Gmbh, 6700 Ludwigshafen Flüssiges, wäßriges, viskoses Tensidsystem
EP0799887A1 (fr) * 1996-04-01 1997-10-08 The Procter & Gamble Company Compositions assouplissantes pour tissus
WO2000004118A1 (fr) * 1998-07-20 2000-01-27 Colgate-Palmolive Compositions adoucissantes contenant un polymere de diurethane comme epaississant
EP1295591A1 (fr) * 2000-06-26 2003-03-26 Shiseido Company Limited Preparation de soin pour les cheveux
US20040087472A1 (en) * 2002-11-01 2004-05-06 Jean-Paul Grandmaire Aqueous composition comprising oligomeric esterquats

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2746377A1 (fr) * 2012-12-20 2014-06-25 The Procter & Gamble Company Structuration améliorée utilisant un structurant externe et un cosmotrope
WO2014099852A1 (fr) * 2012-12-20 2014-06-26 The Procter & Gamble Company Structuration améliorée faisant appel à un agent structurant extérieur et à un cosmotrope
WO2016009150A1 (fr) * 2014-07-18 2016-01-21 Coatex Composition d'assouplissement des tissus comprenant un epaississant heur

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Publication number Publication date
WO2007125005A1 (fr) 2007-11-08
EP2010637A1 (fr) 2009-01-07
CN101389741A (zh) 2009-03-18
US20090124533A1 (en) 2009-05-14

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