EP1865105B1 - Process for making paper using cationic amylopectin starch - Google Patents

Process for making paper using cationic amylopectin starch Download PDF

Info

Publication number: EP1865105B1
Authority: EP; European Patent Office
Prior art keywords: starch; amylopectin; cationic; pulp; potato
Prior art date: 2006-06-09
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Active

Application number

EP06076199A

Other languages

German (de)

English (en)

French (fr)

Other versions

EP1865105A1 (en

Inventor

Thomas Albert Wielema

Jan Baas

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Cooperative Avebe UA

Original Assignee

Cooperative Avebe UA

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2006-06-09

Filing date

2006-06-09

Publication date

2009-09-16

2006-06-09 Priority to PT06076199T priority Critical patent/PT1865105E/pt

2006-06-09 Application filed by Cooperative Avebe UA filed Critical Cooperative Avebe UA

2006-06-09 Priority to EP06076199A priority patent/EP1865105B1/en

2006-06-09 Priority to DK06076199.6T priority patent/DK1865105T3/da

2006-06-09 Priority to AT06076199T priority patent/ATE443179T1/de

2006-06-09 Priority to SI200630499T priority patent/SI1865105T1/sl

2006-06-09 Priority to PL06076199T priority patent/PL1865105T3/pl

2006-06-09 Priority to ES06076199T priority patent/ES2333741T3/es

2006-06-09 Priority to DE602006009237T priority patent/DE602006009237D1/de

2007-06-08 Priority to US12/303,574 priority patent/US20100230063A1/en

2007-06-08 Priority to EA200900677A priority patent/EA016520B1/ru

2007-06-08 Priority to JP2009514224A priority patent/JP2009540137A/ja

2007-06-08 Priority to BRPI0712653-0A priority patent/BRPI0712653A2/pt

2007-06-08 Priority to CA2654156A priority patent/CA2654156C/en

2007-06-08 Priority to AU2007256038A priority patent/AU2007256038B2/en

2007-06-08 Priority to MX2008015152A priority patent/MX2008015152A/es

2007-06-08 Priority to PCT/NL2007/050272 priority patent/WO2007142528A1/en

2007-06-08 Priority to CN2007800214422A priority patent/CN101466894B/zh

2007-12-12 Publication of EP1865105A1 publication Critical patent/EP1865105A1/en

2009-09-16 Application granted granted Critical

2009-09-16 Publication of EP1865105B1 publication Critical patent/EP1865105B1/en

2026-06-09 Anticipated expiration legal-status Critical

Status Active legal-status Critical Current

Links

229920002472 Starch Polymers 0.000 title claims abstract description 90
235000019698 starch Nutrition 0.000 title claims abstract description 88
239000008107 starch Substances 0.000 title claims abstract description 79
229920000945 Amylopectin Polymers 0.000 title claims abstract description 44
125000002091 cationic group Chemical group 0.000 title claims abstract description 41
238000000034 method Methods 0.000 title claims abstract description 10
230000008569 process Effects 0.000 title claims description 5
239000000126 substance Substances 0.000 claims description 19
244000061456 Solanum tuberosum Species 0.000 claims description 18
235000002595 Solanum tuberosum Nutrition 0.000 claims description 16
239000011121 hardwood Substances 0.000 claims description 15
229920003043 Cellulose fiber Polymers 0.000 claims description 7
229920002261 Corn starch Polymers 0.000 claims description 6
235000019759 Maize starch Nutrition 0.000 claims description 6
239000000725 suspension Substances 0.000 claims description 6
240000003183 Manihot esculenta Species 0.000 claims description 5
235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 claims description 5
240000007472 Leucaena leucocephala Species 0.000 claims description 3
235000010643 Leucaena leucocephala Nutrition 0.000 claims description 3
235000007173 Abies balsamea Nutrition 0.000 claims description 2
239000004857 Balsam Substances 0.000 claims description 2
244000018716 Impatiens biflora Species 0.000 claims description 2
244000204900 Talipariti tiliaceum Species 0.000 claims description 2
DCSRPHQBFSYJNN-UHFFFAOYSA-L disodium 4-[(2-arsonophenyl)diazenyl]-3-hydroxynaphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].Oc1c(N=Nc2ccccc2[As](O)(O)=O)c2ccc(cc2cc1S([O-])(=O)=O)S([O-])(=O)=O DCSRPHQBFSYJNN-UHFFFAOYSA-L 0.000 claims description 2
244000004281 Eucalyptus maculata Species 0.000 claims 1
239000007900 aqueous suspension Substances 0.000 claims 1
229920001131 Pulp (paper) Polymers 0.000 abstract description 3
229920001592 potato starch Polymers 0.000 description 18
239000008187 granular material Substances 0.000 description 14
235000013339 cereals Nutrition 0.000 description 13
244000166124 Eucalyptus globulus Species 0.000 description 10
229920000856 Amylose Polymers 0.000 description 8
108010039811 Starch synthase Proteins 0.000 description 8
238000004381 surface treatment Methods 0.000 description 8
238000004519 manufacturing process Methods 0.000 description 7
108090000623 proteins and genes Proteins 0.000 description 7
230000008901 benefit Effects 0.000 description 6
239000000835 fiber Substances 0.000 description 6
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
238000004513 sizing Methods 0.000 description 5
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
239000000945 filler Substances 0.000 description 4
238000012239 gene modification Methods 0.000 description 4
230000005017 genetic modification Effects 0.000 description 4
235000013617 genetically modified food Nutrition 0.000 description 4
230000005764 inhibitory process Effects 0.000 description 4
239000000203 mixture Substances 0.000 description 4
230000008030 elimination Effects 0.000 description 3
238000003379 elimination reaction Methods 0.000 description 3
150000002632 lipids Chemical class 0.000 description 3
230000035772 mutation Effects 0.000 description 3
239000000049 pigment Substances 0.000 description 3
102000004169 proteins and genes Human genes 0.000 description 3
230000009467 reduction Effects 0.000 description 3
238000006467 substitution reaction Methods 0.000 description 3
102100031260 Acyl-coenzyme A thioesterase THEM4 Human genes 0.000 description 2
108090000790 Enzymes Proteins 0.000 description 2
102000004190 Enzymes Human genes 0.000 description 2
101000638510 Homo sapiens Acyl-coenzyme A thioesterase THEM4 Proteins 0.000 description 2
235000016976 Quercus macrolepis Nutrition 0.000 description 2
240000006394 Sorghum bicolor Species 0.000 description 2
235000011684 Sorghum saccharatum Nutrition 0.000 description 2
240000008042 Zea mays Species 0.000 description 2
235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 description 2
235000002017 Zea mays subsp mays Nutrition 0.000 description 2
239000000654 additive Substances 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
230000000692 anti-sense effect Effects 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
229910000019 calcium carbonate Inorganic materials 0.000 description 2
239000011248 coating agent Substances 0.000 description 2
238000000576 coating method Methods 0.000 description 2
230000006872 improvement Effects 0.000 description 2
235000009973 maize Nutrition 0.000 description 2
238000006116 polymerization reaction Methods 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
239000000243 solution Substances 0.000 description 2
239000004382 Amylase Substances 0.000 description 1
102000013142 Amylases Human genes 0.000 description 1
108010065511 Amylases Proteins 0.000 description 1
235000018185 Betula X alpestris Nutrition 0.000 description 1
235000018212 Betula X uliginosa Nutrition 0.000 description 1
241000219495 Betulaceae Species 0.000 description 1
240000008395 Elaeocarpus angustifolius Species 0.000 description 1
241000196324 Embryophyta Species 0.000 description 1
WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
240000005979 Hordeum vulgare Species 0.000 description 1
235000007340 Hordeum vulgare Nutrition 0.000 description 1
241000218652 Larix Species 0.000 description 1
235000005590 Larix decidua Nutrition 0.000 description 1
235000000391 Lepidium draba Nutrition 0.000 description 1
229920000881 Modified starch Polymers 0.000 description 1
240000007594 Oryza sativa Species 0.000 description 1
235000007164 Oryza sativa Nutrition 0.000 description 1
241000218657 Picea Species 0.000 description 1
235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
241000018646 Pinus brutia Species 0.000 description 1
235000011613 Pinus brutia Nutrition 0.000 description 1
244000062793 Sorghum vulgare Species 0.000 description 1
241000519995 Stachys sylvatica Species 0.000 description 1
235000009430 Thespesia populnea Nutrition 0.000 description 1
235000021307 Triticum Nutrition 0.000 description 1
244000098338 Triticum aestivum Species 0.000 description 1
230000006978 adaptation Effects 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
150000003868 ammonium compounds Chemical class 0.000 description 1
235000019418 amylase Nutrition 0.000 description 1
229920006320 anionic starch Polymers 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
238000009395 breeding Methods 0.000 description 1
230000001488 breeding effect Effects 0.000 description 1
230000009172 bursting Effects 0.000 description 1
239000004464 cereal grain Substances 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
239000003086 colorant Substances 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
238000010410 dusting Methods 0.000 description 1
235000013399 edible fruits Nutrition 0.000 description 1
230000000694 effects Effects 0.000 description 1
238000005187 foaming Methods 0.000 description 1
238000009472 formulation Methods 0.000 description 1
239000008103 glucose Substances 0.000 description 1
238000002955 isolation Methods 0.000 description 1
230000014759 maintenance of location Effects 0.000 description 1
239000000463 material Substances 0.000 description 1
235000019713 millet Nutrition 0.000 description 1
235000019426 modified starch Nutrition 0.000 description 1
125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 1
229920000867 polyelectrolyte Polymers 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
235000012015 potatoes Nutrition 0.000 description 1
125000001453 quaternary ammonium group Chemical group 0.000 description 1
239000002994 raw material Substances 0.000 description 1
235000009566 rice Nutrition 0.000 description 1
239000011122 softwood Substances 0.000 description 1
241000894007 species Species 0.000 description 1
238000005728 strengthening Methods 0.000 description 1
PUVAFTRIIUSGLK-UHFFFAOYSA-M trimethyl(oxiran-2-ylmethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CC1CO1 PUVAFTRIIUSGLK-UHFFFAOYSA-M 0.000 description 1
230000003313 weakening effect Effects 0.000 description 1
238000009736 wetting Methods 0.000 description 1
229940100445 wheat starch Drugs 0.000 description 1
239000002023 wood Substances 0.000 description 1
LTVDFSLWFKLJDQ-UHFFFAOYSA-N α-tocopherolquinone Chemical compound CC(C)CCCC(C)CCCC(C)CCCC(C)(O)CCC1=C(C)C(=O)C(C)=C(C)C1=O LTVDFSLWFKLJDQ-UHFFFAOYSA-N 0.000 description 1

Images

Classifications

- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
- D21H17/24—Polysaccharides
- D21H17/28—Starch
- D21H17/29—Starch cationic

Definitions

the invention relates to the field of papermaking. More in particular, the invention relates to improvements in papermaking from hardwood pulps, such as eucalyptus.
Eucalyptus such as E. grandis and E. globulus, are generally associated with the Iberian Peninsula and Latin America. In other regions of the world, there are sound logistical reasons for using indigenous species as alder, acacia, birch and oak.
All hardwoords have some common structural features in the wood, most notably the vessels, which ramify through the stem and act as water pipes, distributing water from the roots to other parts of the tree. Vessels are normally much wider than the fibers, which is responsible for many of the problems caused by vessels in papermaking. The inclusion of the hardwood vessels in the furnish has caused some serious print quality problems in many hardwoord pulps, especially with eucalyptus.
the problem vessel picking may be significantly reduced by using a specific starch in the paper pulp, i.e. in the wet-end.
a specific starch in the paper pulp i.e. in the wet-end.
surface sizing may be omitted completely, or can be substituted by a pre-coat operation.
the specific starch used according to the invention is an cationic amylopectin starch.
cationic starch in papermaking has been described previously.
US patent 2,935,436 discloses that a number of advantages is associated with the use of cationic starch instead of non-cationic starch. Examples of these advantages are increased retention of starch, fillers and pigments, increased paper strength (bursting strength, breaking strength, folding strength) and lower dosage.
European patent application 0 703 314 discloses a method for manufacturing paper wherein a cationic amylopectin potato starch is added to an aqueous solution of cellulose fibers, optionally in addition to other additives, followed by forming paper from this suspension in a conventional manner.
US 5,635,028 describes a process of making a creped tissue paper comprising the use of a cationic amylopectin-type amioca starch.
US 6,001,166 describes a method of manufacturing paper comprising the use of an aqueous alkyldiketene dispersion comprising a cationic starch having an amylopectin content of at least 95 wt.%.
starch types consist of granules in which two types of glucose polymers are present. These are amylose (15-35 wt.% on dry substance) and amylopectin (65-85 wt.% on dry substance).
Amylose consists of unbranched or slightly branched molecules having an average degree of polymerization of 1000 to 5000, depending on the starch type.
Amylopectin consists of very large, highly branched molecules having an average degree of polymerization of 1,000,000 or more.
the commercially most important starch types (maize starch, potato starch, wheat starch and tapioca starch) contain 15 to 30 wt.% amylose.
starch granules nearly completely consist of amylopectin. Calculated as weight percent on dry substance, these starch granules contain more than 95%, and usually more than 98% amylopectin. The amylose content of these cereal starch granules is thus less than 5%, and usually less than 2%.
the above cereal varieties are also referred to as waxy cereal grains, and the amylopectin-starch granules isolated therefrom as waxy cereal starches.
Elimination or inhibition of the expression of the GBSS gene in the potato is also possible by using so-called antisense inhibition.
This genetic modification of the potato is described in R.G.F. Visser et al., "Inhibition of the expression of the gene for granule-bound starch synthase in potato by antisense constructs", Mol. Gen. Genet., (1991), 225:289-296 .
the invention contemplates the use of cationic starch obtained from cereal and fruit sources on the one hand, and root and tuber sources on the other hand.
cereal starches waxy maize starch has proven very suitable. In general, however, root and tuber starches are more preferred.
root and tuber starches are more preferred.
cationic amylopectin-potato starch and amylopectin-tapioca starch as a strengthening agent in paper has been found to lead to a particularly strong paper sheet.
cationic starch Methods of making cationic starch are known per se, and have for instance been elucidated by D.B. Solarek: Cationic Starches, in the book of O.B. Würzburg (Ed.): Modified Starches: Properties and Uses, CRC Press Inc., Boca Raton, Florida, 1986, pp. 113-130 .
the methods described in this book can also be used for the preparation of cationic amylopectin starch by using an amylopectin starch, of a particular chosen botanical source, as raw material.
ammonium compounds preferably quaternary ones
the amount of cationic starch that is used will depend on the kind of pulp that is used, the working conditions and the desired paper properties. Preferably, 0.05 to 10 wt.% and more preferably 0.1 to 2 wt.% of cationic amylopectin starch, dry substance, calculated on the paper pulp, dry substance, is used.
the cationic amylopectin starch is preferably first gelatinized in water.
the resultant starch solution optionally after further dilution, is added to the pulp mass. It is also possible, however, to mix pre-gelatinized cold-soluble cationic amylopectin starch with the pulp mass, either as dry product or after dissolution in water).
surface treatments of the manufactured paper may be carried out to a lesser extent, or can be omitted altogether.
Surface treatment of a paper sheet such as surface sizing or coating, have conventionally be used to increase the vessel picking resistance of the paper to be manufactured. Typically, such surface treatments involve the use of starch.
the starch pick-up in a surface treatment in a process for manufacturing paper in accordance with the invention may be as low as from 0.5 to 6 wt.% based on the sheet weight, and preferably from 1 to 4 wt.% based on the sheet weight.
a reduction in starch pick-up will lead to a reduction in final sheet weight.
This loss in sheet weight can be compensated by the addition of a pigment in the surface treatment formulation.
the cationic starch products were slurried in water, forming a starch suspension with 10 % by weight of starch. This suspension was gelatinized with steam. The obtained starch solution was diluted with water to 1 % by weight dry substance.
the test pulp consisted of a mixture of 38 % long fibers, 28 % short fiber (Eucalyptus) and 34 % CTMP. Calcium carbonate was added as filler to obtain a final ash content of 16 % in the paper sheet. The amount of added cationic starch was 1.0 % by weight (dry substance).
the test pulp was made into hand sheets (sheet weight 80 g/m 2 ) with a hand sheet former. The hand sheets were dried to a moisture content of 7 % by weight.
the vessel picking tendency was determined by performing the linting with a Prufbau dry pick test as described in Tappi Journal, July 1994, page 185 .
the test ink was a high tack inkt (Huber 408004).
the vessel picking tendency was assessed visually. The results are depicted in figure 1 .
the test pulp consisted of a mixture of 42 % long fibers, 8 % short fiber (Eucalyptus) and 50 % CTMP. Calcium carbonate was added as filler to obtain a final ash content of 16 % in the paper sheet. The amount of added cationic starch was 1.0 % by weight (dry substance).
the test pulp was made into hand sheets (sheet weight 80 g/m 2 ) with a hand sheet former. The hand sheets were dried to a moisture content of 7 % by weight.

Landscapes

Paper (AREA)
Polysaccharides And Polysaccharide Derivatives (AREA)

EP06076199A 2006-06-09 2006-06-09 Process for making paper using cationic amylopectin starch Active EP1865105B1 (en)

Priority Applications (17)

Application Number	Priority Date	Filing Date	Title
EP06076199A EP1865105B1 (en)	2006-06-09	2006-06-09	Process for making paper using cationic amylopectin starch
DK06076199.6T DK1865105T3 (da)	2006-06-09	2006-06-09	Fremgangsmåde til fremstilling af papir ved anvendelse af kationisk amylopektinstivelse
AT06076199T ATE443179T1 (de)	2006-06-09	2006-06-09	Verfahren zum herstellen von papier unter verwendung von kationischer amylopektinstärke
SI200630499T SI1865105T1 (sl)	2006-06-09	2006-06-09	Postopek za izdelavo papirja ob uporabi kationskega amilopektinskega Ĺˇkroba
PL06076199T PL1865105T3 (pl)	2006-06-09	2006-06-09	Sposób wytwarzania papieru z zastosowaniem kationowej skrobi amylopektynowej
ES06076199T ES2333741T3 (es)	2006-06-09	2006-06-09	Procesp para la fabricacion de papel utilizando almidon cationico de amilopectina.
DE602006009237T DE602006009237D1 (de)	2006-06-09	2006-06-09	Verfahren zum Herstellen von Papier unter Verwendung von kationischer Amylopektinstärke
PT06076199T PT1865105E (pt)	2006-06-09	2006-06-09	Processo para o fabrico de papel com recurso a amido catiónico essencialmente à base de amilopectina
US12/303,574 US20100230063A1 (en)	2006-06-09	2007-06-08	Process for making paper using cationic amylopectin starch
JP2009514224A JP2009540137A (ja)	2006-06-09	2007-06-08	カチオン性アミロペクチンデンプンを用いて紙を作製するための方法
BRPI0712653-0A BRPI0712653A2 (pt)	2006-06-09	2007-06-08	processo para fabricaÇço de papel, papel, e, uso de um amido catiânico de amilopectina
CA2654156A CA2654156C (en)	2006-06-09	2007-06-08	Process for making paper using cationic amylopectin starch
AU2007256038A AU2007256038B2 (en)	2006-06-09	2007-06-08	Process for making paper using cationic amylopectin starch
MX2008015152A MX2008015152A (es)	2006-06-09	2007-06-08	Proceso para fabricar papel usando almidon de amilopectina cationico.
EA200900677A EA016520B1 (ru)	2006-06-09	2007-06-08	Применение катионного амилопектинового крахмала при изготовлении бумаги для снижения выщипывания бумаги
CN2007800214422A CN101466894B (zh)	2006-06-09	2007-06-08	利用阳离子支链淀粉造纸的方法
PCT/NL2007/050272 WO2007142528A1 (en)	2006-06-09	2007-06-08	Process for making paper using cationic amylopectin starch

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
EP06076199A EP1865105B1 (en)	2006-06-09	2006-06-09	Process for making paper using cationic amylopectin starch

Publications (2)

Publication Number	Publication Date
EP1865105A1 EP1865105A1 (en)	2007-12-12
EP1865105B1 true EP1865105B1 (en)	2009-09-16

Family

ID=37891531

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
EP06076199A Active EP1865105B1 (en)	2006-06-09	2006-06-09	Process for making paper using cationic amylopectin starch

Country Status (17)

Country	Link
US (1)	US20100230063A1 (da)
EP (1)	EP1865105B1 (da)
JP (1)	JP2009540137A (da)
CN (1)	CN101466894B (da)
AT (1)	ATE443179T1 (da)
AU (1)	AU2007256038B2 (da)
BR (1)	BRPI0712653A2 (da)
CA (1)	CA2654156C (da)
DE (1)	DE602006009237D1 (da)
DK (1)	DK1865105T3 (da)
EA (1)	EA016520B1 (da)
ES (1)	ES2333741T3 (da)
MX (1)	MX2008015152A (da)
PL (1)	PL1865105T3 (da)
PT (1)	PT1865105E (da)
SI (1)	SI1865105T1 (da)
WO (1)	WO2007142528A1 (da)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP2009243013A (ja) *	2008-03-31	2009-10-22	Nippon Paper Industries Co Ltd	澱粉を塗布した印刷用紙
EP2199462A1 (en) *	2008-12-18	2010-06-23	Coöperatie Avebe U.A.	A process for making paper
CN103343478B (zh) *	2013-07-03	2016-03-30	金华盛纸业（苏州工业园区）有限公司	一种湿部淀粉及其应用
HRP20200077T1 (hr) *	2014-11-19	2020-06-26	Omya International Ag	Postupak proizvodnje filera
KR20220111279A (ko)	2019-12-23	2022-08-09	케미라 오와이제이	종이, 판지 등의 제조에 사용하기 위한 조성물 및 이의 용도
EP4177398B1 (en)	2021-11-05	2024-08-14	Ahlstrom Oyj	Transfer paper for sublimation printing

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2935436A (en) *	1957-05-09	1960-05-03	Nat Starch Chem Corp	Method of making paper containing a starch ether and product produced thereby
SE461404C (sv) *	1988-06-22	1999-11-15	Betzdearborn Inc	Limningskomposition, förfarande för framställning därav, förfarande för framställning av limmat papper, och limmat papper
NL9401487A (nl) *	1994-09-13	1996-04-01	Avebe Coop Verkoop Prod	Werkwijze voor het vervaardigen van papier, alsmede aldus vervaardigd papier.
US5635028A (en)	1995-04-19	1997-06-03	The Procter & Gamble Company	Process for making soft creped tissue paper and product therefrom
DE19540998A1 (de)	1995-11-03	1997-05-07	Basf Ag	Wäßrige Alkyldiketen-Dispersionen und ihre Verwendung als Leimungsmittel für Papier
DE19713755A1 (de) *	1997-04-04	1998-10-08	Basf Ag	Verfahren zur Herstellung von Papier, Pappe und Karton mit hoher Trockenfestigkeit

2006
- 2006-06-09 ES ES06076199T patent/ES2333741T3/es active Active
- 2006-06-09 DE DE602006009237T patent/DE602006009237D1/de active Active
- 2006-06-09 PT PT06076199T patent/PT1865105E/pt unknown
- 2006-06-09 EP EP06076199A patent/EP1865105B1/en active Active
- 2006-06-09 PL PL06076199T patent/PL1865105T3/pl unknown
- 2006-06-09 AT AT06076199T patent/ATE443179T1/de active
- 2006-06-09 DK DK06076199.6T patent/DK1865105T3/da active
- 2006-06-09 SI SI200630499T patent/SI1865105T1/sl unknown
2007
- 2007-06-08 CA CA2654156A patent/CA2654156C/en not_active Expired - Fee Related
- 2007-06-08 EA EA200900677A patent/EA016520B1/ru not_active IP Right Cessation
- 2007-06-08 AU AU2007256038A patent/AU2007256038B2/en not_active Ceased
- 2007-06-08 US US12/303,574 patent/US20100230063A1/en not_active Abandoned
- 2007-06-08 CN CN2007800214422A patent/CN101466894B/zh not_active Expired - Fee Related
- 2007-06-08 BR BRPI0712653-0A patent/BRPI0712653A2/pt not_active IP Right Cessation
- 2007-06-08 WO PCT/NL2007/050272 patent/WO2007142528A1/en not_active Ceased
- 2007-06-08 JP JP2009514224A patent/JP2009540137A/ja active Pending
- 2007-06-08 MX MX2008015152A patent/MX2008015152A/es active IP Right Grant

Also Published As

Publication number	Publication date
AU2007256038A1 (en)	2007-12-13
US20100230063A1 (en)	2010-09-16
PT1865105E (pt)	2009-12-23
SI1865105T1 (sl)	2010-01-29
EA016520B1 (ru)	2012-05-30
ATE443179T1 (de)	2009-10-15
BRPI0712653A2 (pt)	2012-11-20
DE602006009237D1 (de)	2009-10-29
CN101466894B (zh)	2012-10-17
ES2333741T3 (es)	2010-02-26
CA2654156A1 (en)	2007-12-13
MX2008015152A (es)	2008-12-15
DK1865105T3 (da)	2010-01-18
EP1865105A1 (en)	2007-12-12
CA2654156C (en)	2012-10-16
CN101466894A (zh)	2009-06-24
AU2007256038B2 (en)	2010-06-24
EA200900677A1 (ru)	2009-10-30
WO2007142528A1 (en)	2007-12-13
JP2009540137A (ja)	2009-11-19
PL1865105T3 (pl)	2010-02-26

Legal Events

Date	Code	Title	Description
2007-11-09	PUAI	Public reference made under article 153(3) epc to a published international application that has entered the european phase	Free format text: ORIGINAL CODE: 0009012
2007-12-12	AK	Designated contracting states	Kind code of ref document: A1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC NL PL PT RO SE SI SK TR
2007-12-12	AX	Request for extension of the european patent	Extension state: AL BA HR MK YU
2008-05-14	17P	Request for examination filed	Effective date: 20080331
2008-06-25	17Q	First examination report despatched	Effective date: 20080527
2008-08-20	AKX	Designation fees paid	Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC NL PL PT RO SE SI SK TR
2008-08-20	AXX	Extension fees paid	Extension state: MK Payment date: 20080331 Extension state: BA Payment date: 20080331 Extension state: RS Payment date: 20080331 Extension state: HR Payment date: 20080331 Extension state: AL Payment date: 20080331
2009-04-14	GRAP	Despatch of communication of intention to grant a patent	Free format text: ORIGINAL CODE: EPIDOSNIGR1
2009-08-11	GRAS	Grant fee paid	Free format text: ORIGINAL CODE: EPIDOSNIGR3
2009-08-14	GRAA	(expected) grant	Free format text: ORIGINAL CODE: 0009210
2009-09-16	AK	Designated contracting states	Kind code of ref document: B1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC NL PL PT RO SE SI SK TR
2009-09-16	AX	Request for extension of the european patent	Extension state: AL BA HR MK RS
2009-09-16	REG	Reference to a national code	Ref country code: GB Ref legal event code: FG4D
2009-09-30	REG	Reference to a national code	Ref country code: CH Ref legal event code: EP
2009-10-14	REG	Reference to a national code	Ref country code: IE Ref legal event code: FG4D
2009-10-29	REF	Corresponds to:	Ref document number: 602006009237 Country of ref document: DE Date of ref document: 20091029 Kind code of ref document: P
2009-12-23	REG	Reference to a national code	Ref country code: PT Ref legal event code: SC4A Free format text: AVAILABILITY OF NATIONAL TRANSLATION Effective date: 20091216
2009-12-31	REG	Reference to a national code	Ref country code: CH Ref legal event code: NV Representative=s name: TROESCH SCHEIDEGGER WERNER AG
2010-01-12	REG	Reference to a national code	Ref country code: SE Ref legal event code: TRGR
2010-01-18	REG	Reference to a national code	Ref country code: DK Ref legal event code: T3
2010-01-27	REG	Reference to a national code	Ref country code: GR Ref legal event code: EP Ref document number: 20090403175 Country of ref document: GR
2010-02-26	REG	Reference to a national code	Ref country code: PL Ref legal event code: T3 Ref country code: ES Ref legal event code: FG2A Ref document number: 2333741 Country of ref document: ES Kind code of ref document: T3
2010-03-31	PG25	Lapsed in a contracting state [announced via postgrant information from national office to epo]	Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20090916
2010-04-30	PG25	Lapsed in a contracting state [announced via postgrant information from national office to epo]	Ref country code: CZ Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20090916 Ref country code: RO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20090916 Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20100116 Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20090916
2010-05-31	PG25	Lapsed in a contracting state [announced via postgrant information from national office to epo]	Ref country code: SK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20090916
2010-07-23	PLBE	No opposition filed within time limit	Free format text: ORIGINAL CODE: 0009261
2010-07-23	STAA	Information on the status of an ep patent application or granted ep patent	Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT
2010-07-30	PGFP	Annual fee paid to national office [announced via postgrant information from national office to epo]	Ref country code: IE Payment date: 20100618 Year of fee payment: 5
2010-08-25	26N	No opposition filed	Effective date: 20100617
2010-12-31	PGFP	Annual fee paid to national office [announced via postgrant information from national office to epo]	Ref country code: GR Payment date: 20100621 Year of fee payment: 5
2011-01-31	PG25	Lapsed in a contracting state [announced via postgrant information from national office to epo]	Ref country code: MC Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20100630
2011-07-29	PGFP	Annual fee paid to national office [announced via postgrant information from national office to epo]	Ref country code: LV Payment date: 20110610 Year of fee payment: 6 Ref country code: LT Payment date: 20110524 Year of fee payment: 6
2011-08-31	PGFP	Annual fee paid to national office [announced via postgrant information from national office to epo]	Ref country code: SI Payment date: 20110527 Year of fee payment: 6 Ref country code: PL Payment date: 20110524 Year of fee payment: 6
2012-03-14	REG	Reference to a national code	Ref country code: GR Ref legal event code: ML Ref document number: 20090403175 Country of ref document: GR Effective date: 20120105
2012-03-28	REG	Reference to a national code	Ref country code: IE Ref legal event code: MM4A
2012-04-30	PG25	Lapsed in a contracting state [announced via postgrant information from national office to epo]	Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20110609
2012-05-31	PG25	Lapsed in a contracting state [announced via postgrant information from national office to epo]	Ref country code: GR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20120105
2012-08-22	REG	Reference to a national code	Ref country code: NL Ref legal event code: PLEX Effective date: 20120814
2012-09-28	PG25	Lapsed in a contracting state [announced via postgrant information from national office to epo]	Ref country code: HU Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20100317 Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20090916 Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20100609
2012-10-31	PG25	Lapsed in a contracting state [announced via postgrant information from national office to epo]	Ref country code: TR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20090916
2013-01-25	REG	Reference to a national code	Ref country code: LT Ref legal event code: MM4D Effective date: 20120609
2013-01-31	PG25	Lapsed in a contracting state [announced via postgrant information from national office to epo]	Ref country code: LT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20120609
2013-02-28	PG25	Lapsed in a contracting state [announced via postgrant information from national office to epo]	Ref country code: LV Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20120609
2013-02-28	REG	Reference to a national code	Ref country code: SI Ref legal event code: KO00 Effective date: 20130118
2013-05-31	PG25	Lapsed in a contracting state [announced via postgrant information from national office to epo]	Ref country code: SI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20120610
2013-07-31	PGFP	Annual fee paid to national office [announced via postgrant information from national office to epo]	Ref country code: DK Payment date: 20130619 Year of fee payment: 8 Ref country code: CH Payment date: 20130621 Year of fee payment: 8
2013-08-30	PG25	Lapsed in a contracting state [announced via postgrant information from national office to epo]	Ref country code: PL Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20120609
2013-08-30	PGFP	Annual fee paid to national office [announced via postgrant information from national office to epo]	Ref country code: PT Payment date: 20130607 Year of fee payment: 8
2013-09-30	REG	Reference to a national code	Ref country code: PL Ref legal event code: LAPE
2014-12-17	REG	Reference to a national code	Ref country code: PT Ref legal event code: MM4A Free format text: LAPSE DUE TO NON-PAYMENT OF FEES Effective date: 20141209
2015-01-19	REG	Reference to a national code	Ref country code: DK Ref legal event code: EBP Effective date: 20140630
2015-01-30	PG25	Lapsed in a contracting state [announced via postgrant information from national office to epo]	Ref country code: PT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20141209
2015-01-30	REG	Reference to a national code	Ref country code: CH Ref legal event code: PL
2015-04-30	PG25	Lapsed in a contracting state [announced via postgrant information from national office to epo]	Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20140630 Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20140630
2015-06-19	REG	Reference to a national code	Ref country code: FR Ref legal event code: PLFP Year of fee payment: 10
2015-07-31	PG25	Lapsed in a contracting state [announced via postgrant information from national office to epo]	Ref country code: DK Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20140630
2015-07-31	PGFP	Annual fee paid to national office [announced via postgrant information from national office to epo]	Ref country code: FI Payment date: 20150611 Year of fee payment: 10 Ref country code: ES Payment date: 20150626 Year of fee payment: 10 Ref country code: GB Payment date: 20150618 Year of fee payment: 10 Ref country code: DE Payment date: 20150619 Year of fee payment: 10 Ref country code: SE Payment date: 20150618 Year of fee payment: 10
2015-08-31	PGFP	Annual fee paid to national office [announced via postgrant information from national office to epo]	Ref country code: AT Payment date: 20150619 Year of fee payment: 10 Ref country code: IT Payment date: 20150622 Year of fee payment: 10 Ref country code: NL Payment date: 20150529 Year of fee payment: 10 Ref country code: BE Payment date: 20150618 Year of fee payment: 10 Ref country code: FR Payment date: 20150619 Year of fee payment: 10
2016-12-30	PG25	Lapsed in a contracting state [announced via postgrant information from national office to epo]	Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20160630
2017-01-03	REG	Reference to a national code	Ref country code: DE Ref legal event code: R119 Ref document number: 602006009237 Country of ref document: DE
2017-01-31	PG25	Lapsed in a contracting state [announced via postgrant information from national office to epo]	Ref country code: FI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20160609
2017-01-31	REG	Reference to a national code	Ref country code: SE Ref legal event code: EUG
2017-02-08	REG	Reference to a national code	Ref country code: NL Ref legal event code: MM Effective date: 20160701
2017-02-15	REG	Reference to a national code	Ref country code: AT Ref legal event code: MM01 Ref document number: 443179 Country of ref document: AT Kind code of ref document: T Effective date: 20160609
2017-02-28	PG25	Lapsed in a contracting state [announced via postgrant information from national office to epo]	Ref country code: SE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20160610
2017-03-01	GBPC	Gb: european patent ceased through non-payment of renewal fee	Effective date: 20160609
2017-03-31	REG	Reference to a national code	Ref country code: FR Ref legal event code: ST Effective date: 20170228
2017-04-28	PG25	Lapsed in a contracting state [announced via postgrant information from national office to epo]	Ref country code: DE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20170103 Ref country code: FR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20160630
2017-05-31	PG25	Lapsed in a contracting state [announced via postgrant information from national office to epo]	Ref country code: NL Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20160701 Ref country code: AT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20160609 Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20160609
2017-06-30	PG25	Lapsed in a contracting state [announced via postgrant information from national office to epo]	Ref country code: IT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20160609
2018-05-31	PG25	Lapsed in a contracting state [announced via postgrant information from national office to epo]	Ref country code: ES Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20160610
2018-12-04	REG	Reference to a national code	Ref country code: ES Ref legal event code: FD2A Effective date: 20181204
2023-06-14	P01	Opt-out of the competence of the unified patent court (upc) registered	Effective date: 20230505

Publication	Publication Date	Title
KR102669134B1 (ko)	2024-05-23	종이, 판재 또는 이와 유사한 것을 제조하는 방법
US6843888B2 (en)	2005-01-18	Starches for use in papermaking
KR101516901B1 (ko)	2015-05-04	충전제 조성물 및 복합체 물질을 제조하는 방법
CA2654156C (en)	2012-10-16	Process for making paper using cationic amylopectin starch
EP1235959B1 (en)	2004-04-14	A process for making paper
US6777548B1 (en)	2004-08-17	Oxidation of starch
JP2018531328A (ja)	2018-10-25	紙および板紙用の水性表面処理組成物
JP2018531328A6 (ja)	2018-12-13	紙および板紙用の水性表面処理組成物
JP5398844B2 (ja)	2014-01-29	製紙方法
CA2334532C (en)	2008-03-11	A process for making paper
EP0703314B1 (en)	1999-05-19	Method for manufacturing paper, and paper manufactured thereby
EP0737777B1 (en)	2001-11-07	Method for surface sizing paper, and paper thus obtained
CN115349042B (zh)	2024-07-12	含有阴离子纤维素衍生物的产品及其在造纸工业中的用途
WO2026084027A1 (ja)	2026-04-23	耐油紙