EP1904355A2 - Korrosionsverhindernder und reibungsvermindernder überzug und niedertemperaturverfahren - Google Patents

Korrosionsverhindernder und reibungsvermindernder überzug und niedertemperaturverfahren

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Publication number
EP1904355A2
EP1904355A2 EP06786777A EP06786777A EP1904355A2 EP 1904355 A2 EP1904355 A2 EP 1904355A2 EP 06786777 A EP06786777 A EP 06786777A EP 06786777 A EP06786777 A EP 06786777A EP 1904355 A2 EP1904355 A2 EP 1904355A2
Authority
EP
European Patent Office
Prior art keywords
coating
product
lubrication
freezing point
corrosion protection
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP06786777A
Other languages
English (en)
French (fr)
Other versions
EP1904355A4 (de
Inventor
William E. Olliges
Floyd Roberts
Gerry Arner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Advanced Lubrication Technology Inc
Original Assignee
Advanced Lubrication Technology Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Advanced Lubrication Technology Inc filed Critical Advanced Lubrication Technology Inc
Publication of EP1904355A2 publication Critical patent/EP1904355A2/de
Publication of EP1904355A4 publication Critical patent/EP1904355A4/de
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M107/00Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/02Hydrocarbon polymers; Hydrocarbon polymers modified by oxidation
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • C09D5/082Anti-corrosive paints characterised by the anti-corrosive pigment
    • C09D5/086Organic or non-macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M139/00Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing atoms of elements not provided for in groups C10M127/00 - C10M137/00
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/087Boron oxides, acids or salts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/10Compounds containing silicon
    • C10M2201/102Silicates
    • C10M2201/1023Silicates used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/04Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing aromatic monomers, e.g. styrene
    • C10M2205/043Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing aromatic monomers, e.g. styrene used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/04Ethers; Acetals; Ortho-esters; Ortho-carbonates
    • C10M2207/046Hydroxy ethers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/287Partial esters
    • C10M2207/289Partial esters containing free hydroxy groups
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/084Acrylate; Methacrylate
    • C10M2209/0845Acrylate; Methacrylate used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/10Amides of carbonic or haloformic acids
    • C10M2215/1006Amides of carbonic or haloformic acids used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/045Polyureas; Polyurethanes
    • C10M2217/0453Polyureas; Polyurethanes used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/02Unspecified siloxanes; Silicones
    • C10M2229/025Unspecified siloxanes; Silicones used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00Form in which the lubricant is applied to the material being lubricated
    • C10N2050/015Dispersions of solid lubricants
    • C10N2050/02Dispersions of solid lubricants dissolved or suspended in a carrier which subsequently evaporates to leave a lubricant coating
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2070/00Specific manufacturing methods for lubricant compositions

Definitions

  • the present invention relates to coatings for friction reduction and the prevention of corrosion. More particularly, the present invention relates to polymer carried lubrication and corrosion protection coatings suited for extreme environments.
  • Wheel lubrication is known in the art. Archeological evidence shows the use of tallow for wheel lubrication dating prior to 1400 B.C. The study of lubrication and frictional coefficients may be considered to have started in the late 1880's in England when Tower produced his studies on railroad car journal bearings in 1885. Since then, numerous artisans have engaged in the endeavor of finding lubricants and coatings suited to optimize the advantageous aspects of friction reduction in various environments.
  • Lubrication coatings fall typically into two broad categories, fluid film lubrication and dry film lubrication. Each of these prior art methods of providing lubrication suffer from their own respective set of drawbacks.
  • fluid film lubrication the load on moving surfaces is supported entirely by the fluid between the opposing surfaces. Pressure on the film develops through the motion of the surfaces, this motion then in turn delivers the lubricant into a converging wedge-shaped zone.
  • the behavior of the moving surfaces is totally dependent on the fluidity or viscous behavior of the lubricant. Film pressure and power loss are dependent on the viscosity of the lubricant as well as the configuration of the moving surfaces, and lubricant shear strength.
  • Dry lubricants present their own set of drawbacks. Typically, dry lubricants are applied as thin coatings or as particulate materials to reduce wear and friction of moving surfaces. As noted by Levy, these films or particulate materials may comprise or incorporate solid or particulate carbon-graphite, lead babbitt, bronze, aluminum, polyethylene or polytetrafluoroethylene solid or articulate materials in a binder where the film or particulates are adhered to one or both of the moving surfaces.
  • dry lubricant film or particulates is controlled to some degree by the bfnfaeT where' sol ⁇ cT ' ⁇ f 1' particulate lubricants are employed as well as conditions of use such as the load, surface temperatures generated during use, speed of the moving surfaces, hardening, fatigue, welding, recrystallization, oxidation and hydrolysis.
  • dry lubricants typically are not able to provide any scrub resistance or weathering resistance, thereby greatly reducing their usefulness in any event.
  • Some embodiments of the present invention overcome the practical problems described above and offer additional advantages as well. Some embodiments of the present invention solve various of the above-described drawbacks by providing coatings providing friction reduction and corrosion protection. Others of the embodiments of the present invention solve various of the above-described drawbacks by providing lubrication coatings demonstrating longevity in extreme environments including harsh weather conditions and harsh operating conditions. Yet other embodiments of the present invention provide additional advantages to the foregoing such as providing coatings that are non-toxic and biodegradable and/or coatings that are inexpensive enough for mass production and use. These and other advantages are obtained according to the present invention as described in more detail herein.
  • compositions and processes described herein enhance the various advantages of the related art and also substantially obviate one or more of the limitations and disadvantages of the described prior compositions and processes.
  • a process and a material which provides for corrosion protection and lubrication in operating environments conventionally described as outside or exterior there is provided a process and a material which provides corrosion protection and lubrication in operating environments deemed extreme relating to the human comfort zone, whether it be temperature, precipitation, or otherwise.
  • a process and a material which provides corrosion protection and lubrication in the presence of corrosive forces in at least one embodiment, there is provided a process and a material which provides corrosion protection and lubrication in the presence of corrosive forces.
  • a process and a material adapted for applying a coating in a manner akin to a conventional paint in at least one embodiment, there is provided a process and a material adapted for applying a coating in a manner akin to a conventional paint.
  • the advantageous aspect of this embodiment of the invention will be appreciated given that in applying a coating to a surface in temperatures below freezing, such as negative 20 degrees Farenheit, the attention to detail of the operator may momentarily wander. In order for any anticorrosive coating to be effective, it is important that surfaces be coated completely. Being able to apply the coatings of these embodiments of the invention in a manner typical to a conventional paint, a drawback of dry film lubricants (which are applied McKW ⁇ 'i'gf&iM %$nt) may be overcome and complete coatings of surfaces achieved.
  • a structural coating for simultaneously providing corrosion protection and a reduction of the coefficient of friction in an exterior benign or harsh environment comprising a polymeric resin, a borate-based additive, and a dynamic stabilization material.
  • the polymeric resin preferably comprises a resin from the durable structural coating class of resins, including but not limited to acrylics, urethanes, epoxies, vinyl acrylics, styrene butadienes, ureas, polyurea, silicones, and silicates.
  • the borate-based additive comprises a single additive for simultaneously providing corrosion protection through electrochemical binding of active surface corrosive sites, lubrication enhancement through the creation and re-supply to a surface where friction contact occasionally occurs of a weak slip lane crystalline material which may be a locally formed product utilizing local atmospheric humidity, and a material for reaction with an initiator to provide for freezing point depression during coating application.
  • the dynamic stabilization material creates a balance of stabilized material for supply of corrosion protection product, lubrication reduction product, and freezing point depression product.
  • the structural coating may include operative components for dispersing particles, providing surface activity for chemically and or mechanically binding the operative components to the polymeric resin following application of the coating, assisting with the coalescing of the structural resin, assisting with the control of liquid phase viscosity and assisting with the control of liquid phase PH.
  • boric oxide is used as a starting point material providing corrosion protection through the transference of boric acid to the corrosive metallic interface, borate esters as liquid phase freezing point depression, and coefficient of friction reduction through the reaction with environmental humidity of boric oxide diffused to the surface.
  • the dynamic stabilization material comprises a blend of 2,2,4 trimethyl-1,3 pentanediol monoisobutryate and 2,2,1 aminotmethyl propanol.
  • An advantageous feature of this embodiment of the invention is that reaction of boric acid occurs with the diol monoester to form 2,2,4 trimethyl-1 ,3 pentanediol borate monoisobutryate (a borate ester).
  • a process of simultaneously passivating a surface subject to corrosive forces and reducing the frictional coefficient between the surface and a source of sliding, rolling, or sliding rolling friction comprising applying an initial coating followed by functional operation of said coating effecting passivation of a surface by continuously migrating boric acid to the specific areas to be passivated, wherein the migration is being driven by an established chemical potential gradient, and wherein the coating also reduces the coefficient of friction through migration of boric acid to the operative surface in contact with an environment of nonzero humidity, wherein the migration is also being driven through a locally derived chemical potential gradient.
  • An advantageous feature of this process is that in may be initiated at temperatures ranging from about 120 degress Fahrenheit to about negative 36 degrees Fahrenheit.
  • the process may be effectuated using the kinetic energy of atomized particle bombardment to initiate adhesive interfacial chemical reaction to occur.
  • the interracial chemical reaction may occur between the surface subject to corrosive forces and boric acid.
  • a borate ester may stabilize the coating during initial application.
  • the borate ester is itself stabilized during the application process through a dynamic balance of boric acid, borate ester, and anhydroxy groups.
  • the coatings are safe.
  • coatings having a finite ecological endpoint wherein the endpoint is the time required for biodegradation of the coating.
  • coating having a breakdown time of 1 to 5 years or 3 to 10 years.
  • the coatings of these embodiments of the present invention give off a VOC of less than 50 grams per liter of applied coating.
  • the present invention will be described in connection with coatings particularly useful railroads and other rail systems, it will be readily apparent to one of ordinary skill in the art that the present invention can be applied to a multiplicity of fields and uses.
  • the present invention may be used in any field for any task requiring a coating adapted for providing friction reduction and corrosion prevention.
  • the present invention may be used in any field for any task requiring a nontoxic and/or biodegradable lubricant or corrosion protectant or an inexpensive coating available in mass quantities.
  • Steel-rail and steel-wheel transportation systems including freight, passenger and mass transit ⁇ yst ' feirfis "Suffer "from " extensive wear of mechanical components, such as wheels, rails and other rail components, such as ties.
  • the origin of such wear of the mechanical components is typically considered a result of the frictional forces generated between the wheel and the rail during operation of the system.
  • the wear between rail and track is not from a coating standpoint as relevant as the friction generated between components as the rail bed system responds to the passing weight of the railcar.
  • the frictional forces generated during operation are certainly to blame for degradation of rail systems, however, less attended to is the condition of the components at the time of use.
  • Rust Oxidation of a metal
  • Switches are subject to a high volume of corrosive forces, typically in an unprotected environment. They must operate with a very high factor of safety through substantial weathering forces for years during which ⁇ 'se M ⁇ ifW'tiedi ⁇ ehf of ' intermittent A switch failure may lead to a preponderance of undesirable consequences.
  • Lubricants such as greases and oils must be replenished on to frequent a schedule and may fail from either too high a frequency of use or strong weathering conditions.
  • Dry film lubricants while appropriate from a frequency of use standpoint do not tend to protect equipment sufficiently from corrosion due because they are typically difficult to apply in such a manner that they fully cover surfaces using in service application processes as described below. Additionally dry film lubricants do not posses a scrub resistance so that when forces are produced in directions other than those where a dry film lubricant material provides appropriate slip planes (basal plane in graphite) they are easily removed and rendered ineffective. Such forces are generated by weathering from rail, snow, ground movement, etc.
  • a presently preferred embodiment of the current invention is a process of simultaneously passivating a surface subject to corrosive forces and reducing the frictional coefficient between this surface and a surface which would be considered a source of sliding, rolling, or sliding rolling friction.
  • the process involves applying a coating using conventional coating application procedures such as spraying brushing or rolling the coating onto the surfaces requiring protection.
  • This first process step may occur in ambient conditions ranging from 120 deg F to negative 36 deg F.
  • This borate ester borate may itself be stabilized during the application process through a dynamic balance of boric acid, borate ester, and anhydroxy groups.
  • the adhesion between the applied surface and the preformed coating process may be effected by using the kinetic energy of atomized particle bombardment to initiate adhesive interfacial chemical reaction to occur. Additionally, the adhesion may be promoted by using the kinetic energy of atomized particle bombardment to initiate adhesive interfacial chemical reaction to occur between the applie'd ' sufface sTiBje ' cf to corrosive forces and boric acid.
  • the coating which is also claimed in this application is a structural coating for simultaneously providing corrosion protection and a reduction of the coefficient of friction in a exterior benign or extreme environment where the coating is comprising a polymeric resin from the durable structural coating class of resins; examples of which would be acrylics, urethanes, epoxies, vinyl acrylics, styrene butadienes, ureas, polyurea, silicones, and silicates; a single additive for simultaneously providing corrosion protection through electrochemical binding of active surface corrosive sites, lubrication enhancement through the creation and resupply to a surface where frictional contact occasionally occurs of a weak slip plane crystalline material which may be a locally formed product utilizing local atmospheric humidity, and material for reaction with an initiator to provide for "freezing point depression during coating application; and a dynamic stabilization material which creates a balance of stabilized material for supply of corrosion protection product, lubrication reduction product, and freezing point depression product.
  • boric oxide is used as a starting point material providing corrosion protection through the transference of boric acid to the corrosive metallic interface, Borate Esters as liquid phase freezing point depression, and coefficient of friction reduction through the reaction with environmental humidity of boric oxide diffused to the surface.
  • the reaction can take place in an acidic environment such as one catalyzed by the acrylic acid polymer.
  • borate esters are well known as plasticizers and flame retardants.
  • the reaction of boric acid may occur with said diol monoester to form 2,2,4 trimethyl-1 ,3 pentanediol borate monoisobutryate as said borate ester.
  • the coating may additionally provide during formulating additives for creating surface activity for chemically and or mechanically binding operative components to the polymeric resin following application of the coating.
  • Useful additives also typically include materials which assist with the coalescing of said structural resin and materials which assist with the control of liquid phase viscosity, and control of liquid phase Ph.
  • the dynamic stabilization material mentioned may be a blend of 2,2,4 trimethly-1 ,3 pentanediol monoisobutyrate and 2,2,1 Amino Methyl Propanol.
  • This invention has specific relevance to railway switches such that a section of railway track which may be mechanically moved from one position to another position without disassembly or detachment from the ground may be effectively coated with a composition comprising a polymeric resin from the durable structural coating class of resins.
  • a polymeric resin from the durable structural coating class of resins.
  • Some examples of such resins would be acrylics, urethanes, epoxies, vinyl acfy I fds 1 ; ' " s ⁇ y rene "" But act ⁇ e'h es , ureas, polyurea, silicones, and silicates.
  • This coating would also contain a single additive for simultaneously providing corrosion protection through electrochemical binding of active surface corrosive sites, lubrication enhancement through the creation and resupply to all operative surfaces where frictional contact occasionally occurs of a weak slip plane crystalline material which may be a locally formed product utilizing local atmospheric humidity, and material for reaction with an initiator to provide for freezing point depression during coating application.
  • a dynamic stabilization material would be used which creates a balance of stabilized material for supply of corrosion protection product, lubrication reduction product, and freezing point depression product
  • a railway switch coated with a composition on surfaces other than the railcar wheel interface surface is of very high commercial relevance.
  • Such a switch would consist of a switch and a coating comprising; a polymeric resin from the durable structural coating class of resins; examples of which would be acrylics, urethanes, epoxies, vinyl acrylics, styrene butadienes, ureas, polyurea, silicones, and silicates; a single additive for simultaneously providing corrosion protection through electrochemical binding of active surface corrosive sites, lubrication enhancement through the creation and resupply to all operative surfaces where frictional contact occasionally occurs of a weak slip plane crystalline material which may be a locally formed product utilizing local atmospheric humidity, and material for reaction with an initiator to provide for freezing point depression during coating application; and a dynamic stabilization material which creates a balance of stabilized material for supply of corrosion protection product, lubrication reduction product, and freezing point depression product.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Lubricants (AREA)
  • Paints Or Removers (AREA)
  • Laminated Bodies (AREA)
EP06786777A 2005-07-11 2006-07-11 Rostschutz- und reibminderungsbeschichtung und niedertemperaturverfahren Withdrawn EP1904355A4 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US69754105P 2005-07-11 2005-07-11
US11/456,520 US20070021310A1 (en) 2005-07-11 2006-07-10 Corrosion Prevention and Friction Reduction Coating and Low Temperature Process
PCT/US2006/026737 WO2007008802A2 (en) 2005-07-11 2006-07-11 Corrosion prevention and friction reduction coating and low temperature process

Publications (2)

Publication Number Publication Date
EP1904355A2 true EP1904355A2 (de) 2008-04-02
EP1904355A4 EP1904355A4 (de) 2010-04-28

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Country Status (7)

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US (1) US20070021310A1 (de)
EP (1) EP1904355A4 (de)
JP (1) JP2009500516A (de)
KR (1) KR20080033386A (de)
BR (1) BRPI0613038A2 (de)
CA (1) CA2615163A1 (de)
WO (1) WO2007008802A2 (de)

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EP1904355A4 (de) 2010-04-28
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BRPI0613038A2 (pt) 2010-12-14
WO2007008802A2 (en) 2007-01-18
KR20080033386A (ko) 2008-04-16
CA2615163A1 (en) 2007-01-18
US20070021310A1 (en) 2007-01-25

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