EP1904355A2 - Korrosionsverhindernder und reibungsvermindernder überzug und niedertemperaturverfahren - Google Patents
Korrosionsverhindernder und reibungsvermindernder überzug und niedertemperaturverfahrenInfo
- Publication number
- EP1904355A2 EP1904355A2 EP06786777A EP06786777A EP1904355A2 EP 1904355 A2 EP1904355 A2 EP 1904355A2 EP 06786777 A EP06786777 A EP 06786777A EP 06786777 A EP06786777 A EP 06786777A EP 1904355 A2 EP1904355 A2 EP 1904355A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- coating
- product
- lubrication
- freezing point
- corrosion protection
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 88
- 239000011248 coating agent Substances 0.000 title claims abstract description 70
- 230000009467 reduction Effects 0.000 title claims abstract description 19
- 238000000034 method Methods 0.000 title claims description 37
- 230000008569 process Effects 0.000 title claims description 33
- 238000005536 corrosion prevention Methods 0.000 title description 3
- 239000000463 material Substances 0.000 claims abstract description 40
- 238000005260 corrosion Methods 0.000 claims abstract description 39
- 230000007797 corrosion Effects 0.000 claims abstract description 39
- 238000005461 lubrication Methods 0.000 claims abstract description 35
- 230000008014 freezing Effects 0.000 claims abstract description 21
- 238000007710 freezing Methods 0.000 claims abstract description 21
- 238000006243 chemical reaction Methods 0.000 claims abstract description 20
- 239000000654 additive Substances 0.000 claims abstract description 19
- 230000000996 additive effect Effects 0.000 claims abstract description 15
- 239000002952 polymeric resin Substances 0.000 claims abstract description 14
- 229920003002 synthetic resin Polymers 0.000 claims abstract description 14
- 230000006641 stabilisation Effects 0.000 claims abstract description 13
- 238000011105 stabilization Methods 0.000 claims abstract description 13
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000002178 crystalline material Substances 0.000 claims abstract description 7
- 239000003999 initiator Substances 0.000 claims abstract description 7
- 239000000314 lubricant Substances 0.000 claims description 23
- -1 vinyl acrylics Chemical compound 0.000 claims description 20
- 239000004327 boric acid Substances 0.000 claims description 18
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 17
- 229920006397 acrylic thermoplastic Polymers 0.000 claims description 13
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 13
- 229920005989 resin Polymers 0.000 claims description 12
- 239000011347 resin Substances 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 10
- 239000007791 liquid phase Substances 0.000 claims description 8
- 229910011255 B2O3 Inorganic materials 0.000 claims description 7
- 239000004593 Epoxy Substances 0.000 claims description 7
- 229920002396 Polyurea Polymers 0.000 claims description 7
- 235000013877 carbamide Nutrition 0.000 claims description 7
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical group O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims description 7
- 125000003700 epoxy group Chemical group 0.000 claims description 7
- 230000005012 migration Effects 0.000 claims description 7
- 238000013508 migration Methods 0.000 claims description 7
- 239000002245 particle Substances 0.000 claims description 7
- 229920000647 polyepoxide Polymers 0.000 claims description 7
- 229920001296 polysiloxane Polymers 0.000 claims description 7
- 238000005096 rolling process Methods 0.000 claims description 7
- 150000004760 silicates Chemical class 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 7
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 claims description 7
- 150000003672 ureas Chemical class 0.000 claims description 7
- 150000003673 urethanes Chemical class 0.000 claims description 7
- 229920002554 vinyl polymer Polymers 0.000 claims description 7
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical class C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 6
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 6
- 239000000853 adhesive Substances 0.000 claims description 4
- 230000001070 adhesive effect Effects 0.000 claims description 4
- NOBCHLZYNBXWMA-UHFFFAOYSA-N B(O)(O)O.CC(CO)(C(C(C)C)O)C Chemical compound B(O)(O)O.CC(CO)(C(C(C)C)O)C NOBCHLZYNBXWMA-UHFFFAOYSA-N 0.000 claims description 3
- 150000002009 diols Chemical class 0.000 claims description 3
- 230000000694 effects Effects 0.000 claims description 3
- 230000007613 environmental effect Effects 0.000 claims description 3
- 230000000087 stabilizing effect Effects 0.000 claims description 3
- 238000002161 passivation Methods 0.000 claims description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 2
- 239000003112 inhibitor Substances 0.000 claims 1
- 239000000758 substrate Substances 0.000 claims 1
- 239000012530 fluid Substances 0.000 description 5
- 150000001642 boronic acid derivatives Chemical class 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000005069 Extreme pressure additive Substances 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 239000011236 particulate material Substances 0.000 description 2
- JCTXKRPTIMZBJT-UHFFFAOYSA-N 2,2,4-trimethylpentane-1,3-diol Chemical compound CC(C)C(O)C(C)(C)CO JCTXKRPTIMZBJT-UHFFFAOYSA-N 0.000 description 1
- 229910000906 Bronze Inorganic materials 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000006065 biodegradation reaction Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000005619 boric acid group Chemical group 0.000 description 1
- 239000010974 bronze Substances 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
- C10M107/02—Hydrocarbon polymers; Hydrocarbon polymers modified by oxidation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
- C09D5/086—Organic or non-macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M139/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing atoms of elements not provided for in groups C10M127/00 - C10M137/00
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/087—Boron oxides, acids or salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/10—Compounds containing silicon
- C10M2201/102—Silicates
- C10M2201/1023—Silicates used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/04—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing aromatic monomers, e.g. styrene
- C10M2205/043—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing aromatic monomers, e.g. styrene used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
- C10M2207/046—Hydroxy ethers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/287—Partial esters
- C10M2207/289—Partial esters containing free hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
- C10M2209/084—Acrylate; Methacrylate
- C10M2209/0845—Acrylate; Methacrylate used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/10—Amides of carbonic or haloformic acids
- C10M2215/1006—Amides of carbonic or haloformic acids used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/045—Polyureas; Polyurethanes
- C10M2217/0453—Polyureas; Polyurethanes used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/02—Unspecified siloxanes; Silicones
- C10M2229/025—Unspecified siloxanes; Silicones used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/015—Dispersions of solid lubricants
- C10N2050/02—Dispersions of solid lubricants dissolved or suspended in a carrier which subsequently evaporates to leave a lubricant coating
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2070/00—Specific manufacturing methods for lubricant compositions
Definitions
- the present invention relates to coatings for friction reduction and the prevention of corrosion. More particularly, the present invention relates to polymer carried lubrication and corrosion protection coatings suited for extreme environments.
- Wheel lubrication is known in the art. Archeological evidence shows the use of tallow for wheel lubrication dating prior to 1400 B.C. The study of lubrication and frictional coefficients may be considered to have started in the late 1880's in England when Tower produced his studies on railroad car journal bearings in 1885. Since then, numerous artisans have engaged in the endeavor of finding lubricants and coatings suited to optimize the advantageous aspects of friction reduction in various environments.
- Lubrication coatings fall typically into two broad categories, fluid film lubrication and dry film lubrication. Each of these prior art methods of providing lubrication suffer from their own respective set of drawbacks.
- fluid film lubrication the load on moving surfaces is supported entirely by the fluid between the opposing surfaces. Pressure on the film develops through the motion of the surfaces, this motion then in turn delivers the lubricant into a converging wedge-shaped zone.
- the behavior of the moving surfaces is totally dependent on the fluidity or viscous behavior of the lubricant. Film pressure and power loss are dependent on the viscosity of the lubricant as well as the configuration of the moving surfaces, and lubricant shear strength.
- Dry lubricants present their own set of drawbacks. Typically, dry lubricants are applied as thin coatings or as particulate materials to reduce wear and friction of moving surfaces. As noted by Levy, these films or particulate materials may comprise or incorporate solid or particulate carbon-graphite, lead babbitt, bronze, aluminum, polyethylene or polytetrafluoroethylene solid or articulate materials in a binder where the film or particulates are adhered to one or both of the moving surfaces.
- dry lubricant film or particulates is controlled to some degree by the bfnfaeT where' sol ⁇ cT ' ⁇ f 1' particulate lubricants are employed as well as conditions of use such as the load, surface temperatures generated during use, speed of the moving surfaces, hardening, fatigue, welding, recrystallization, oxidation and hydrolysis.
- dry lubricants typically are not able to provide any scrub resistance or weathering resistance, thereby greatly reducing their usefulness in any event.
- Some embodiments of the present invention overcome the practical problems described above and offer additional advantages as well. Some embodiments of the present invention solve various of the above-described drawbacks by providing coatings providing friction reduction and corrosion protection. Others of the embodiments of the present invention solve various of the above-described drawbacks by providing lubrication coatings demonstrating longevity in extreme environments including harsh weather conditions and harsh operating conditions. Yet other embodiments of the present invention provide additional advantages to the foregoing such as providing coatings that are non-toxic and biodegradable and/or coatings that are inexpensive enough for mass production and use. These and other advantages are obtained according to the present invention as described in more detail herein.
- compositions and processes described herein enhance the various advantages of the related art and also substantially obviate one or more of the limitations and disadvantages of the described prior compositions and processes.
- a process and a material which provides for corrosion protection and lubrication in operating environments conventionally described as outside or exterior there is provided a process and a material which provides corrosion protection and lubrication in operating environments deemed extreme relating to the human comfort zone, whether it be temperature, precipitation, or otherwise.
- a process and a material which provides corrosion protection and lubrication in the presence of corrosive forces in at least one embodiment, there is provided a process and a material which provides corrosion protection and lubrication in the presence of corrosive forces.
- a process and a material adapted for applying a coating in a manner akin to a conventional paint in at least one embodiment, there is provided a process and a material adapted for applying a coating in a manner akin to a conventional paint.
- the advantageous aspect of this embodiment of the invention will be appreciated given that in applying a coating to a surface in temperatures below freezing, such as negative 20 degrees Farenheit, the attention to detail of the operator may momentarily wander. In order for any anticorrosive coating to be effective, it is important that surfaces be coated completely. Being able to apply the coatings of these embodiments of the invention in a manner typical to a conventional paint, a drawback of dry film lubricants (which are applied McKW ⁇ 'i'gf&iM %$nt) may be overcome and complete coatings of surfaces achieved.
- a structural coating for simultaneously providing corrosion protection and a reduction of the coefficient of friction in an exterior benign or harsh environment comprising a polymeric resin, a borate-based additive, and a dynamic stabilization material.
- the polymeric resin preferably comprises a resin from the durable structural coating class of resins, including but not limited to acrylics, urethanes, epoxies, vinyl acrylics, styrene butadienes, ureas, polyurea, silicones, and silicates.
- the borate-based additive comprises a single additive for simultaneously providing corrosion protection through electrochemical binding of active surface corrosive sites, lubrication enhancement through the creation and re-supply to a surface where friction contact occasionally occurs of a weak slip lane crystalline material which may be a locally formed product utilizing local atmospheric humidity, and a material for reaction with an initiator to provide for freezing point depression during coating application.
- the dynamic stabilization material creates a balance of stabilized material for supply of corrosion protection product, lubrication reduction product, and freezing point depression product.
- the structural coating may include operative components for dispersing particles, providing surface activity for chemically and or mechanically binding the operative components to the polymeric resin following application of the coating, assisting with the coalescing of the structural resin, assisting with the control of liquid phase viscosity and assisting with the control of liquid phase PH.
- boric oxide is used as a starting point material providing corrosion protection through the transference of boric acid to the corrosive metallic interface, borate esters as liquid phase freezing point depression, and coefficient of friction reduction through the reaction with environmental humidity of boric oxide diffused to the surface.
- the dynamic stabilization material comprises a blend of 2,2,4 trimethyl-1,3 pentanediol monoisobutryate and 2,2,1 aminotmethyl propanol.
- An advantageous feature of this embodiment of the invention is that reaction of boric acid occurs with the diol monoester to form 2,2,4 trimethyl-1 ,3 pentanediol borate monoisobutryate (a borate ester).
- a process of simultaneously passivating a surface subject to corrosive forces and reducing the frictional coefficient between the surface and a source of sliding, rolling, or sliding rolling friction comprising applying an initial coating followed by functional operation of said coating effecting passivation of a surface by continuously migrating boric acid to the specific areas to be passivated, wherein the migration is being driven by an established chemical potential gradient, and wherein the coating also reduces the coefficient of friction through migration of boric acid to the operative surface in contact with an environment of nonzero humidity, wherein the migration is also being driven through a locally derived chemical potential gradient.
- An advantageous feature of this process is that in may be initiated at temperatures ranging from about 120 degress Fahrenheit to about negative 36 degrees Fahrenheit.
- the process may be effectuated using the kinetic energy of atomized particle bombardment to initiate adhesive interfacial chemical reaction to occur.
- the interracial chemical reaction may occur between the surface subject to corrosive forces and boric acid.
- a borate ester may stabilize the coating during initial application.
- the borate ester is itself stabilized during the application process through a dynamic balance of boric acid, borate ester, and anhydroxy groups.
- the coatings are safe.
- coatings having a finite ecological endpoint wherein the endpoint is the time required for biodegradation of the coating.
- coating having a breakdown time of 1 to 5 years or 3 to 10 years.
- the coatings of these embodiments of the present invention give off a VOC of less than 50 grams per liter of applied coating.
- the present invention will be described in connection with coatings particularly useful railroads and other rail systems, it will be readily apparent to one of ordinary skill in the art that the present invention can be applied to a multiplicity of fields and uses.
- the present invention may be used in any field for any task requiring a coating adapted for providing friction reduction and corrosion prevention.
- the present invention may be used in any field for any task requiring a nontoxic and/or biodegradable lubricant or corrosion protectant or an inexpensive coating available in mass quantities.
- Steel-rail and steel-wheel transportation systems including freight, passenger and mass transit ⁇ yst ' feirfis "Suffer "from " extensive wear of mechanical components, such as wheels, rails and other rail components, such as ties.
- the origin of such wear of the mechanical components is typically considered a result of the frictional forces generated between the wheel and the rail during operation of the system.
- the wear between rail and track is not from a coating standpoint as relevant as the friction generated between components as the rail bed system responds to the passing weight of the railcar.
- the frictional forces generated during operation are certainly to blame for degradation of rail systems, however, less attended to is the condition of the components at the time of use.
- Rust Oxidation of a metal
- Switches are subject to a high volume of corrosive forces, typically in an unprotected environment. They must operate with a very high factor of safety through substantial weathering forces for years during which ⁇ 'se M ⁇ ifW'tiedi ⁇ ehf of ' intermittent A switch failure may lead to a preponderance of undesirable consequences.
- Lubricants such as greases and oils must be replenished on to frequent a schedule and may fail from either too high a frequency of use or strong weathering conditions.
- Dry film lubricants while appropriate from a frequency of use standpoint do not tend to protect equipment sufficiently from corrosion due because they are typically difficult to apply in such a manner that they fully cover surfaces using in service application processes as described below. Additionally dry film lubricants do not posses a scrub resistance so that when forces are produced in directions other than those where a dry film lubricant material provides appropriate slip planes (basal plane in graphite) they are easily removed and rendered ineffective. Such forces are generated by weathering from rail, snow, ground movement, etc.
- a presently preferred embodiment of the current invention is a process of simultaneously passivating a surface subject to corrosive forces and reducing the frictional coefficient between this surface and a surface which would be considered a source of sliding, rolling, or sliding rolling friction.
- the process involves applying a coating using conventional coating application procedures such as spraying brushing or rolling the coating onto the surfaces requiring protection.
- This first process step may occur in ambient conditions ranging from 120 deg F to negative 36 deg F.
- This borate ester borate may itself be stabilized during the application process through a dynamic balance of boric acid, borate ester, and anhydroxy groups.
- the adhesion between the applied surface and the preformed coating process may be effected by using the kinetic energy of atomized particle bombardment to initiate adhesive interfacial chemical reaction to occur. Additionally, the adhesion may be promoted by using the kinetic energy of atomized particle bombardment to initiate adhesive interfacial chemical reaction to occur between the applie'd ' sufface sTiBje ' cf to corrosive forces and boric acid.
- the coating which is also claimed in this application is a structural coating for simultaneously providing corrosion protection and a reduction of the coefficient of friction in a exterior benign or extreme environment where the coating is comprising a polymeric resin from the durable structural coating class of resins; examples of which would be acrylics, urethanes, epoxies, vinyl acrylics, styrene butadienes, ureas, polyurea, silicones, and silicates; a single additive for simultaneously providing corrosion protection through electrochemical binding of active surface corrosive sites, lubrication enhancement through the creation and resupply to a surface where frictional contact occasionally occurs of a weak slip plane crystalline material which may be a locally formed product utilizing local atmospheric humidity, and material for reaction with an initiator to provide for "freezing point depression during coating application; and a dynamic stabilization material which creates a balance of stabilized material for supply of corrosion protection product, lubrication reduction product, and freezing point depression product.
- boric oxide is used as a starting point material providing corrosion protection through the transference of boric acid to the corrosive metallic interface, Borate Esters as liquid phase freezing point depression, and coefficient of friction reduction through the reaction with environmental humidity of boric oxide diffused to the surface.
- the reaction can take place in an acidic environment such as one catalyzed by the acrylic acid polymer.
- borate esters are well known as plasticizers and flame retardants.
- the reaction of boric acid may occur with said diol monoester to form 2,2,4 trimethyl-1 ,3 pentanediol borate monoisobutryate as said borate ester.
- the coating may additionally provide during formulating additives for creating surface activity for chemically and or mechanically binding operative components to the polymeric resin following application of the coating.
- Useful additives also typically include materials which assist with the coalescing of said structural resin and materials which assist with the control of liquid phase viscosity, and control of liquid phase Ph.
- the dynamic stabilization material mentioned may be a blend of 2,2,4 trimethly-1 ,3 pentanediol monoisobutyrate and 2,2,1 Amino Methyl Propanol.
- This invention has specific relevance to railway switches such that a section of railway track which may be mechanically moved from one position to another position without disassembly or detachment from the ground may be effectively coated with a composition comprising a polymeric resin from the durable structural coating class of resins.
- a polymeric resin from the durable structural coating class of resins.
- Some examples of such resins would be acrylics, urethanes, epoxies, vinyl acfy I fds 1 ; ' " s ⁇ y rene "" But act ⁇ e'h es , ureas, polyurea, silicones, and silicates.
- This coating would also contain a single additive for simultaneously providing corrosion protection through electrochemical binding of active surface corrosive sites, lubrication enhancement through the creation and resupply to all operative surfaces where frictional contact occasionally occurs of a weak slip plane crystalline material which may be a locally formed product utilizing local atmospheric humidity, and material for reaction with an initiator to provide for freezing point depression during coating application.
- a dynamic stabilization material would be used which creates a balance of stabilized material for supply of corrosion protection product, lubrication reduction product, and freezing point depression product
- a railway switch coated with a composition on surfaces other than the railcar wheel interface surface is of very high commercial relevance.
- Such a switch would consist of a switch and a coating comprising; a polymeric resin from the durable structural coating class of resins; examples of which would be acrylics, urethanes, epoxies, vinyl acrylics, styrene butadienes, ureas, polyurea, silicones, and silicates; a single additive for simultaneously providing corrosion protection through electrochemical binding of active surface corrosive sites, lubrication enhancement through the creation and resupply to all operative surfaces where frictional contact occasionally occurs of a weak slip plane crystalline material which may be a locally formed product utilizing local atmospheric humidity, and material for reaction with an initiator to provide for freezing point depression during coating application; and a dynamic stabilization material which creates a balance of stabilized material for supply of corrosion protection product, lubrication reduction product, and freezing point depression product.
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Lubricants (AREA)
- Paints Or Removers (AREA)
- Laminated Bodies (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US69754105P | 2005-07-11 | 2005-07-11 | |
| US11/456,520 US20070021310A1 (en) | 2005-07-11 | 2006-07-10 | Corrosion Prevention and Friction Reduction Coating and Low Temperature Process |
| PCT/US2006/026737 WO2007008802A2 (en) | 2005-07-11 | 2006-07-11 | Corrosion prevention and friction reduction coating and low temperature process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1904355A2 true EP1904355A2 (de) | 2008-04-02 |
| EP1904355A4 EP1904355A4 (de) | 2010-04-28 |
Family
ID=37637829
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP06786777A Withdrawn EP1904355A4 (de) | 2005-07-11 | 2006-07-11 | Rostschutz- und reibminderungsbeschichtung und niedertemperaturverfahren |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US20070021310A1 (de) |
| EP (1) | EP1904355A4 (de) |
| JP (1) | JP2009500516A (de) |
| KR (1) | KR20080033386A (de) |
| BR (1) | BRPI0613038A2 (de) |
| CA (1) | CA2615163A1 (de) |
| WO (1) | WO2007008802A2 (de) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101133078B1 (ko) | 2009-09-16 | 2012-04-04 | 부산대학교 산학협력단 | 마찰저항 저감 코팅 조성물 |
| US9447340B2 (en) | 2012-03-15 | 2016-09-20 | William E. Olliges | Hexylene glycol fuel additive containing boric acid for inhibiting phase separation and corrosion in Ethanol Blended Fuels |
| US9447348B2 (en) | 2012-03-15 | 2016-09-20 | William E. Olliges | Use of hexylene glycol additive containing boric acid for reducing friction and corrosion in internal combustion engine crankcases |
| US9212329B2 (en) | 2012-03-15 | 2015-12-15 | William E. Olliges | Use of hexylene glycol fuel additive containing boric oxide |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3087936A (en) * | 1961-08-18 | 1963-04-30 | Lubrizol Corp | Reaction product of an aliphatic olefinpolymer-succinic acid producing compound with an amine and reacting the resulting product with a boron compound |
| US4851145A (en) * | 1986-06-30 | 1989-07-25 | S.A. Texaco Petroleum Nv | Corrosion-inhibited antifreeze/coolant composition |
| JPH03255197A (ja) * | 1990-03-05 | 1991-11-14 | Nichiyu Kagaku Kogyo Kk | 鉄道分岐切変えポイント面用の自己潤滑剤組成物およびシート |
| CA2138275C (en) * | 1992-06-16 | 1999-12-14 | Ali Erdemir | Improved lubrication from mixture of boric acid with oils and greases |
| DK12497A (da) * | 1996-02-12 | 1997-08-13 | Ciba Geigy Ag | Korrisionsinhiberende overtrækssammensætninger til metaller |
| US6331509B1 (en) * | 1997-01-31 | 2001-12-18 | Elisha Technologies Co Llc | Corrosion resistant lubricants, greases, and gels |
| US5958847A (en) * | 1997-12-19 | 1999-09-28 | United Technologies Corporation | Environmentally compatible solid film lubricant |
| US6641923B2 (en) * | 2001-07-31 | 2003-11-04 | Ppg Industries Ohio, Inc. | Weldable coating compositions having improved intercoat adhesion |
-
2006
- 2006-07-10 US US11/456,520 patent/US20070021310A1/en not_active Abandoned
- 2006-07-11 EP EP06786777A patent/EP1904355A4/de not_active Withdrawn
- 2006-07-11 BR BRPI0613038-0A patent/BRPI0613038A2/pt not_active IP Right Cessation
- 2006-07-11 CA CA002615163A patent/CA2615163A1/en not_active Abandoned
- 2006-07-11 JP JP2008521499A patent/JP2009500516A/ja not_active Withdrawn
- 2006-07-11 WO PCT/US2006/026737 patent/WO2007008802A2/en not_active Ceased
- 2006-07-11 KR KR1020087003327A patent/KR20080033386A/ko not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| WO2007008802A3 (en) | 2007-05-03 |
| EP1904355A4 (de) | 2010-04-28 |
| JP2009500516A (ja) | 2009-01-08 |
| BRPI0613038A2 (pt) | 2010-12-14 |
| WO2007008802A2 (en) | 2007-01-18 |
| KR20080033386A (ko) | 2008-04-16 |
| CA2615163A1 (en) | 2007-01-18 |
| US20070021310A1 (en) | 2007-01-25 |
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