EP1928953A2 - Zusammensetzung zur herstellung von polyester- und polyamidgarnen mit verbesserten feuchtigkeitsmanagementeigenschaften - Google Patents
Zusammensetzung zur herstellung von polyester- und polyamidgarnen mit verbesserten feuchtigkeitsmanagementeigenschaftenInfo
- Publication number
- EP1928953A2 EP1928953A2 EP06803016A EP06803016A EP1928953A2 EP 1928953 A2 EP1928953 A2 EP 1928953A2 EP 06803016 A EP06803016 A EP 06803016A EP 06803016 A EP06803016 A EP 06803016A EP 1928953 A2 EP1928953 A2 EP 1928953A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- polyamide
- poly
- composition
- thermoplastic
- terephthalate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 35
- 229920002647 polyamide Polymers 0.000 title claims abstract description 27
- 239000004952 Polyamide Substances 0.000 title claims abstract description 25
- 239000000835 fiber Substances 0.000 claims abstract description 22
- 229920000728 polyester Polymers 0.000 claims abstract description 18
- -1 poly(butylene terephthalate) Polymers 0.000 claims description 54
- 229920001169 thermoplastic Polymers 0.000 claims description 13
- 239000004416 thermosoftening plastic Substances 0.000 claims description 13
- 229920002302 Nylon 6,6 Polymers 0.000 claims description 12
- 229920002292 Nylon 6 Polymers 0.000 claims description 11
- 229920006149 polyester-amide block copolymer Polymers 0.000 claims description 10
- 229920000571 Nylon 11 Polymers 0.000 claims description 9
- 229920000299 Nylon 12 Polymers 0.000 claims description 9
- 229920006345 thermoplastic polyamide Polymers 0.000 claims description 9
- 150000004985 diamines Chemical class 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 6
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 6
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 6
- 229920000572 Nylon 6/12 Polymers 0.000 claims description 5
- ANDAQSIUDBVMNP-UHFFFAOYSA-N 12-(azepan-1-yl)-12-oxododecanamide Chemical compound NC(=O)CCCCCCCCCCC(=O)N1CCCCCC1 ANDAQSIUDBVMNP-UHFFFAOYSA-N 0.000 claims description 4
- 229920000305 Nylon 6,10 Polymers 0.000 claims description 4
- 239000012141 concentrate Substances 0.000 claims description 4
- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 4
- LLLVZDVNHNWSDS-UHFFFAOYSA-N 4-methylidene-3,5-dioxabicyclo[5.2.2]undeca-1(9),7,10-triene-2,6-dione Chemical compound C1(C2=CC=C(C(=O)OC(=C)O1)C=C2)=O LLLVZDVNHNWSDS-UHFFFAOYSA-N 0.000 claims description 3
- 229920000747 poly(lactic acid) Polymers 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 229920002215 polytrimethylene terephthalate Polymers 0.000 claims description 2
- 239000004753 textile Substances 0.000 abstract description 6
- 239000004594 Masterbatch (MB) Substances 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 238000009987 spinning Methods 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 150000001413 amino acids Chemical class 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 150000003951 lactams Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 239000012209 synthetic fiber Substances 0.000 description 2
- 239000004970 Chain extender Substances 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- 229920006397 acrylic thermoplastic Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 238000002788 crimping Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 238000005505 soilproofing Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/02—Polyalkylene oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/90—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyamides
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2377/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2467/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2477/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/12—Applications used for fibers
Definitions
- This invention relates generally to a composition and process for preparing articles having improved moisture management properties.
- the invention relates to a composition and process for
- polyester-based fibers and polyamide-based fibers that exhibit improved moisture management or wicking properties without detrimental
- the fibers of the invention may be any suitable material.
- Synthetic fibers have generally suffered from an inability to wick moisture efficiently. Improvements in the wicking properties of fibers are highly
- an efficient wicking fiber may provide
- improved wicking properties may assist in drying of the floor covering after shampooing and cleaning.
- improved wicking assists in
- compositions includes a polyester or polyamide, and one or more polyoxyalkyleneamines.
- the composition contains from about
- polyester or polyamide 97 to about 99.75 % by weight of polyester or polyamide and from about
- composition contains from about 98 to about 99.5 % by weight of
- polyester or polyamide from about 0.5% to 2 % by weight of polyoxyalkyleneamine.
- the polyoxyalkyleneamine may be added directly to the polyester or polyamide, or in the form of a thermoplastic concentrate or masterbatch by compounding it in a suitable thermoplastic carrier.
- suitable thermoplastic carriers are polyester or polyamide or mixtures thereof.
- polyamide includes those synthesized from lactams, alpha-omega amino acids, and pairs of diacids and diamines. Such polyamides include, but
- polycaprolactam [polyamide 6]
- polyamide 11 polyundecanolactam
- polyhexamethylene adipamide polyamide 66
- polyamide 12 poly(hexamethylene dodecanediamide
- polyamide 6,12 poly(hexamethylene sebacamide) [polyamide 6,10], poly(ethylene terephthalate), poly(butylene terephthalate), poly(trimethylene terephthalate). If the polyoxyalklenediamine is used in this masterbatch form, then the amount of polyester or polyamide in the above formulation is adjusted to take into account the amount of the thermoplastic carrier in the polyoxyalkylenediamine masterbatch.
- the preferred polyoxyalkyleneamine is poly(oxyethylene)diamine (POED)
- polyoxyalkyleneamine that can be used in the invention is poly(oxypropylene)diamine, also with a molecular weight of 2000.
- Polyesters include thermoplastic polyesters such as those synthesized from one or more diacids and one or more glycols. Such polyesters
- Polyamides include thermoplastic polyamides such as those synthesized
- polyamides from lactams, alpha-omega amino acids, and pairs of diacids and diamines.
- polyamides include, but are not limited to, polycaprolactam [polyamide 6], polyundecanolactam [polyamide 11],
- polyamide 6 polyhexamethylene adipamide
- polyamide 12 polylauryllactam
- polyamide 612 poly(hexamethylene dodecanediamide
- polyamide 610 poly(hexamethylene sebacamide)
- compositions used in the practice of the invention may contain
- antioxidants UV stabilizers, antiozonants, soilproofing agents,
- Fibers produced from the composition can be melt-spun using various additives
- the fibers can be spun using standard spinning machinery
- a range of denier per filament (dpf) may be
- the cross-sectional shape of the fibers may also be any of a wide range of
- melt-spun fibers including crimping
- the fibers may be any material that is used to make upholstery fabrics, carpets and other floorcoverings.
- the fibers may be any material that is used to make upholstery fabrics, carpets and other floorcoverings.
- the fibers may be any material that is used to make upholstery fabrics, carpets and other floorcoverings.
- the fibers may be any material that is used to make upholstery fabrics, carpets and other floorcoverings.
- polyolefins or acrylics or natural fibers such as wool or cotton, and
- a comparative (non-inventive) 150/34R yarn was spun and false-twist
- Example 2 textured in a similar manner to Example 1, except the POED masterbatch
- the water transport rate is measured according to a so-called vertical
- Table 1 shows the test results for Examples 1 to 3 for the vertical strip
- melt-extruder fiber spinning line to give a 1850/30Y undrawn yarn.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Artificial Filaments (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US71374805P | 2005-09-06 | 2005-09-06 | |
| PCT/US2006/034650 WO2007030494A2 (en) | 2005-09-06 | 2006-09-06 | Composition for producing poyester and polyamide yarns with improved moisture management properties |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP1928953A2 true EP1928953A2 (de) | 2008-06-11 |
Family
ID=37836400
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP06803016A Pending EP1928953A2 (de) | 2005-09-06 | 2006-09-06 | Zusammensetzung zur herstellung von polyester- und polyamidgarnen mit verbesserten feuchtigkeitsmanagementeigenschaften |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP1928953A2 (de) |
| JP (1) | JP2009507109A (de) |
| KR (1) | KR20080065611A (de) |
| CN (1) | CN101287795A (de) |
| AU (1) | AU2006287620A1 (de) |
| BR (1) | BRPI0614972A2 (de) |
| MX (1) | MX2008003159A (de) |
| WO (1) | WO2007030494A2 (de) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ITFI20130162A1 (it) * | 2013-07-04 | 2015-01-05 | Golden Lady Co Spa | "metodo per la produzione di un filo sintetico ad alta ripresa di umidita' e filo ottenuto" |
| PE20190865A1 (es) | 2016-08-02 | 2019-06-18 | Fitesa Germany Gmbh | Sistema y proceso para la preparacion de telas no tejidas de acido polilactico |
| US11441251B2 (en) | 2016-08-16 | 2022-09-13 | Fitesa Germany Gmbh | Nonwoven fabrics comprising polylactic acid having improved strength and toughness |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS575974A (en) * | 1980-06-06 | 1982-01-12 | Unitika Ltd | Production of polyester fiber with good adheherence with rubbers |
| US5582907A (en) * | 1994-07-28 | 1996-12-10 | Pall Corporation | Melt-blown fibrous web |
-
2006
- 2006-09-06 CN CNA2006800325100A patent/CN101287795A/zh active Pending
- 2006-09-06 MX MX2008003159A patent/MX2008003159A/es active IP Right Grant
- 2006-09-06 EP EP06803016A patent/EP1928953A2/de active Pending
- 2006-09-06 WO PCT/US2006/034650 patent/WO2007030494A2/en not_active Ceased
- 2006-09-06 JP JP2008529376A patent/JP2009507109A/ja active Pending
- 2006-09-06 AU AU2006287620A patent/AU2006287620A1/en not_active Abandoned
- 2006-09-06 BR BRPI0614972A patent/BRPI0614972A2/pt not_active IP Right Cessation
- 2006-09-06 KR KR1020087008396A patent/KR20080065611A/ko not_active Ceased
Non-Patent Citations (1)
| Title |
|---|
| See references of WO2007030494A2 * |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2009507109A (ja) | 2009-02-19 |
| AU2006287620A1 (en) | 2007-03-15 |
| BRPI0614972A2 (pt) | 2016-09-13 |
| WO2007030494A3 (en) | 2007-06-28 |
| KR20080065611A (ko) | 2008-07-14 |
| CN101287795A (zh) | 2008-10-15 |
| MX2008003159A (es) | 2008-10-06 |
| WO2007030494A2 (en) | 2007-03-15 |
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Legal Events
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| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
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| STAA | Information on the status of an ep patent application or granted ep patent |
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| 17P | Request for examination filed |
Effective date: 20080327 |
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