EP1964992B1 - Panneau isolant pour isoler l'extérieur de bâtiments - Google Patents

Panneau isolant pour isoler l'extérieur de bâtiments Download PDF

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Publication number
EP1964992B1
EP1964992B1 EP07004316A EP07004316A EP1964992B1 EP 1964992 B1 EP1964992 B1 EP 1964992B1 EP 07004316 A EP07004316 A EP 07004316A EP 07004316 A EP07004316 A EP 07004316A EP 1964992 B1 EP1964992 B1 EP 1964992B1
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EP
European Patent Office
Prior art keywords
coating
main body
insulating panel
open
pored
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Not-in-force
Application number
EP07004316A
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German (de)
English (en)
Other versions
EP1964992A1 (fr
Inventor
Daniel Jenni
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
swisspor Management AG
Original Assignee
swisspor Management AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by swisspor Management AG filed Critical swisspor Management AG
Priority to AT07004316T priority Critical patent/ATE468449T1/de
Priority to EP07004316A priority patent/EP1964992B1/fr
Priority to DE502007003840T priority patent/DE502007003840D1/de
Publication of EP1964992A1 publication Critical patent/EP1964992A1/fr
Application granted granted Critical
Publication of EP1964992B1 publication Critical patent/EP1964992B1/fr
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62Insulation or other protection; Elements or use of specified material therefor
    • E04B1/74Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
    • E04B1/76Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only
    • E04B1/762Exterior insulation of exterior walls

Definitions

  • the present invention relates to an insulation board for the external thermal insulation of buildings, the use of the insulation board for the external thermal insulation of buildings and a method for producing the insulating board according to the preambles of the independent claims.
  • a thermal barrier coating is first made from individual insulation panels on the outside of the building, e.g. on the facade and / or on the building roof, and then on the outside weather protection attached, e.g. in the form of a plaster layer applied to the thermal barrier coating or a ventilated protective facade made of wood or cement boards.
  • a plaster layer applied to the thermal barrier coating or a ventilated protective facade made of wood or cement boards.
  • insulation boards made of a plastic foam material often results in the problem that the prepared from the insulation boards thermal insulation layer over a longer period alternately intense sunlight and strong cold may be exposed before attaching the weather protection, resulting in relatively strong thermal dimensional changes of the insulation boards and can lead to a detachment of the same from the substrate with glued insulation boards.
  • the insulation panels are processed in intense sunlight, there is also the problem that they can contract after gluing and it can come to open plate joints, which can form cold bridges.
  • very bright board materials e.g.
  • EPS expanded polystyrene
  • the unprotected thermal insulation layer can also create a dazzling effect, which must be avoided.
  • an insulation board which is suitable for the external insulation of buildings, and which has a plate-shaped base body made of a plastic material.
  • a first aspect of the invention relates to an insulation board for the external thermal insulation of buildings.
  • the insulation board has a plate-shaped body made of a plastic foam material.
  • that outer side of the insulating board, which forms the outer side of this outer thermal insulation when using the same for creating an external thermal insulation of a building substantially over its entire planar extent a surface which alternately of first open-pore areas, which are formed by the outer surface of the body , and of second, open and / or closed-cell areas, which are formed by a arranged on the body, a plurality of particular irregular openings having continuous coating or a plurality of individual, arranged on the body and spaced-apart punctiform coatings is formed ,
  • insulation boards with a base body made of a plastic foam material which have the same good properties in terms of thermal insulation and adhesion for cementitious adhesives or plasters such as open-pore uncoated insulation panels of a corresponding plastic foam material, but have a significantly lower thermal expansion behavior in direct sunlight. It is also possible to optimize these with respect to their reflection properties.
  • cut slabs can be made from one Carbon black, graphite or aluminum powder pigmented expanded polystyrene foam, which have excellent thermal insulation properties but tend to increase thermal expansion in intensive, direct sunlight, on one of its two outer sides, ie on one of its two large surfaces, with a coating of white, having a plurality of perforations, extruded polystyrene (XPS) are provided, which can be significantly reduced their thermal length change, with virtually unchanged properties in terms of thermal insulation and adhesion to cementitious adhesives and plaster layers.
  • XPS extruded polystyrene
  • the second areas are arranged on the outside of the base body and fixedly connected to this continuous coating, wherein the coating has a plurality of regular or irregular openings, such that it spans the surface of the body reticulated.
  • the average area per aperture is preferably less than 20 mm 2. It is also preferred if the coating per square centimeter on average has more than four openings.
  • Such embodiments of the insulating panel have proven to be particularly advantageous and also have an increased flexural rigidity, which may be desirable depending on the use.
  • the second areas are formed by a plurality of individual spot coatings arranged on the body and spaced from one another, such that the coatings form a preferably substantially uniform spot pattern on the surface of the body, the average area per punctiform coating is preferably less than 20 mm 2. It is also preferred that On average, more than four punctiform coatings are present per square centimeter of surface area.
  • Such embodiments of the insulation board have virtually the same flexural rigidity as uncoated plates of a corresponding plastic foam material, which may be advantageous depending on the application.
  • the coating is a material application preferably applied by printing, preferably paint application.
  • this material application by spraying e.g. of paint, with or without stencil, to apply to the open-pore outside of the body.
  • the coating consists of a thermoplastic plastic material, in particular of extruded polystyrene. Such materials can be easily connected by transient liquefaction with the open-pored surface of the body.
  • both the base body and the coating are made of thermoplastic materials and are fused together. This results in a solid, cohesive bond between the base body and the coating.
  • the coating is formed of a plastic material which consists of the same plastic base component as the plastic foam material of the base body, in particular of a polystyrene, polyurethane or polyisocyanurate. This results in optimum material compatibility and recyclability.
  • the main body of the insulating panel consists of an expanded or extruded polystyrene foam and the coating of an extruded polystyrene.
  • the coating consists of a material, preferably of a plastic material, which has a better reflectivity for infrared radiation than the plastic foam material of the base body.
  • the coating consists of a material, in particular of a plastic material, which is lighter than the plastic foam material of the base body.
  • the base body of the insulating panel of a pigmented plastic foam material preferably from a pigmented with soot particles, graphite particles or aluminum particles plastic foam material, preferably of expanded or extruded polystyrene.
  • plastic foam materials have very good thermal insulation properties.
  • a second aspect of the invention relates to the use of the insulating board according to the first aspect of the invention for the external thermal insulation of buildings. In such uses, the benefits of the invention are particularly evident.
  • a third aspect of the invention relates to a method for producing an insulating board according to the first aspect of the invention.
  • a plate-shaped base body made of a plastic foam material is provided, in which at least that outer surface, which is disposed away from the building when the insulating board to be formed with this base body is intended to be used, has an open-pored surface.
  • this open-pored outer surface is provided substantially over its entire planar extent with a continuous coating having a plurality of regular or irregular openings or with a plurality of individual, spaced-apart punctiform coatings, such that the outer surface thus coated has a surface in which open-pore regions formed by the outer surface of the main body alternate with open-pored and / or closed-pore regions formed by the coating.
  • the inventive method makes it possible for the first time to produce insulating panels of a plastic foam material, which are comparable in thermal insulation and / or reflection properties with regard to their thermal insulation properties and adhesive strength for cement-bound adhesive or plasters with insulation boards, which are formed exclusively of this plastic foam material Sunshine clearly different from these.
  • the coating takes place under or by printing a material, preferably a paint, on the open-pored outer surface of the body. It is also intended to apply this material by spraying, with or without stencil.
  • a material preferably a paint
  • the coating takes place by contacting or by contacting a thermoplastic material in the at least partially molten state with the open-pored outer surface of the base body, resulting in the advantage that liquid material can penetrate into the open-pored surface of the body and after solidification of the same gives a good bond between the coating and the base body.
  • the coating takes place with a melting or by melting a film, preferably of expanded polystyrene (XPS), on the open-pore outer surface of the body.
  • XPS expanded polystyrene
  • the coating takes place by melting or by melting individual plastic particles previously arranged on the open-pored outer surface of the insulating board, so that a multiplicity of individual, spaced-apart spot coatings are formed on the open-pored outer surface.
  • the melting of the film or of the plastic particles takes place by pressing them with a heated surface against the open-pored outer surface of the main body. In this way, short application times can be achieved and ensure a defined dimensioning of the insulation boards thus produced, and there is a strong bond between the coating and the body surface.
  • the film material, the Film thickness, the temperature of the heated surface and the Anpressdauer the film with the heated surface to the open-pored outer surface selected such that the film receives a plurality of holes during melting on the open-pored outer surface.
  • the coating is carried out by or under a preferably drop-shaped spraying of molten plastic material on the open-pored outer surface of the body.
  • molten plastic material on the open-pored outer surface of the body.
  • the coating of the base body by or contacting a thermoplastic material in the at least partially molten state with the open-pore outer surface of the body is preferably when a base body made of a thermoplastic foam material is used and the coating of a thermoplastic Material is formed, wherein the coating and the base body are fused together. As a result, these are materially interconnected.
  • the coating is formed from a plastic material which is formed from the same plastic base component as the plastic foam material of the main body, preferably from a polystyrene, polyurethane or polyisocyanurate. These materials are well established in the field of building exterior thermal insulation and there is also the advantage of good material compatibility and recyclability.
  • a base body of a pigmented, expanded or extruded Polystyrene foam provided and the coating formed from an extruded polystyrene.
  • the coating is formed of a material, in particular of a plastic material, which has a better reflectivity for infrared radiation than the plastic foam material of the base body, so that the heating of the plastic foam material in direct sunlight and thus a thermal expansion of the inventive Insulating board opposite an insulation board, which consists exclusively of the plastic foam material of the body, is significantly reduced.
  • the coating is formed of a material, in particular of a plastic material, which is lighter than the plastic foam material of the base body.
  • a base body made of a pigmented plastic foam material is provided, preferably of a plastic foam material pigmented with carbon black, graphite particles or aluminum particles.
  • plastic foam materials can be insulation boards provide excellent thermal insulation.
  • the insulation board consists of a plate-shaped, square base body (1) made of graphite pigmented expanded polystyrene foam (shown in black), in the present case from the material "Lambda” the Swiss company swisspor, on one of its two large-scale outsides the entire areal extent of this outer side is provided with a continuous, net-like coating (2) of a non-pigmented, white, extruded polystyrene (shown in white).
  • the coating (2) is fused to the surface of the base body (1) and thereby firmly connected thereto.
  • This insulating board was prepared by pressing while melting a continuous, paper-thin, extruded and unpigmented polystyrene film (eg available from the German company Linpack) with a hot plate having a surface temperature of 184 ° C to the open-pore outer surface of the cut body (1), wherein the polystyrene film was merged with the formation of openings with the surface of the base body (1).
  • the contact time was 0.3 seconds in the present case.
  • Fig. 2 shows another preferred embodiment of the inventive insulation board for the external thermal insulation of buildings, also in a perspective plan view.
  • the Insulating board here from a plate-shaped, square base body (1) made of expanded polystyrene foam pigmented with aluminum powder (shown in black), on one of its two large outer sides over the entire areal extent of this outside a plurality of individual and spaced punctual coatings (3) of white polystyrene (shown in white), which form a substantially uniform Püpfelmuster.
  • the coatings (3) are each fused to the surface of the base body (1) and thereby firmly connected thereto. In the areas not covered by the coatings (3), the surface of the base body (1), which is open-pored in these areas, is accessible.
  • This insulating board was prepared by pressing with melting a plurality of previously isolated on the open-pored outer surface of the body (1) particles of white polystyrene with a heated surface to the open-pored outer surface of the cut body (1), wherein the polystyrene particles to form the individual coatings (3) were fused with the surface of the base body (1).

Landscapes

  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Acoustics & Sound (AREA)
  • Electromagnetism (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Building Environments (AREA)
  • Laminated Bodies (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Claims (28)

  1. Plaque calorifuge pour l'isolation de la chaleur extérieure de bâtiments, comportant un corps de base (1) en forme de plaque fabriqué à partir d'un matériau alvéolaire synthétique, caractérisée en ce que le côté extérieur de la plaque calorifuge prévu pour former le côté extérieur d'une isolation de la chaleur extérieure à établir avec la plaque calorifuge présente essentiellement sur la totalité de son extension plane une surface qui est formée en alternance par des premières zones poreuses formées par la face extérieure du corps de base (1) et par des secondes zones formées par une couche de recouvrement (2) adjacente disposée sur le corps de base (1), présentant une pluralité d'alésages ou formées par une pluralité de diverses couches de recouvrement (3) disposées sur le corps de base (1) et espacées les unes des autres ponctuellement.
  2. Plaque calorifuge selon la revendication 1, caractérisée en ce que les secondes zones sont formées par une couche de recouvrement (2) adjacente disposée sur le corps de base (1), présentant une pluralité d'alésages de telle sorte que la couche de recouvrement (2) recouvre comme un treillis la surface du corps de base (1), la surface moyenne par alésage étant en particulier inférieure à 20 mm2.
  3. Plaque calorifuge selon l'une quelconque des revendications précédentes, caractérisée en ce que les secondes zones sont formées par une couche de recouvrement (2) disposée sur le corps de base (1) présentant une pluralité d'alésages de telle sorte que la couche de recouvrement (2) recouvre comme un treillis la surface du corps de base (1), la couche de recouvrement (2) présentant en particulier plus de quatre alésages en moyenne par centimètre carré.
  4. Plaque calorifuge selon la revendication 1, caractérisée en ce que les secondes zones sont formées par une pluralité de diverses couches de recouvrement (3) disposées sur le corps de base (1), ponctuellement espacées les unes des autres de telle sorte que les couches de recouvrement (3) forment une forme mouchetée en particulier essentiellement homogène sur la surface du corps de base (1), la surface moyenne par couche de recouvrement ponctuelle étant en particulier inférieure à 20 mm2.
  5. Plaque calorifuge selon la revendication 1 ou la revendication 4, caractérisée en ce que les secondes zones sont formées par une pluralité de diverses couches de recouvrement (3) disposées sur le corps de base (1) espacées ponctuellement les unes des autres de telle sorte que les couches de recouvrement (3) forment une forme mouchetée en particulier essentiellement homogène sur la surface du corps de base (1), plus de quatre couches de recouvrement (3) ponctuelles étant en moyenne présentes en particulier par centimètre carré.
  6. Plaque calorifuge selon l'une quelconque des revendications précédentes, caractérisée en ce que la couche de recouvrement (2, 3) est une couche de matériau appliquée en particulier par impression, en particulier une couche de couleur.
  7. Plaque calorifuge selon l'une quelconque des revendications précédentes, caractérisée en ce que la couche de recouvrement (2, 3) se compose d'un matériau synthétique thermoplastique, en particulier d'un polystyrène extrudé.
  8. Plaque calorifuge selon l'une quelconque des revendications précédentes, caractérisée en ce que le corps de base (1) et la couche de recouvrement (2, 3) se composent d'un matériau thermoplastique et sont fondus l'un avec l'autre.
  9. Plaque calorifuge selon la revendication 8, caractérisée en ce que la couche de recouvrement (2, 3) se compose d'un matériau synthétique, lequel est formé à partir de composants de base synthétiques identiques comme le matériau alvéolaire synthétique du corps de base (1), en particulier d'un polystyrène, d'un polyuréthane ou d'un polyisocyanurate.
  10. Plaque calorifuge selon la revendication 9, caractérisée en ce que le corps de base (1) se compose d'une mousse de polystyrène expansée ou extrudée, et en ce que la couche de recouvrement (2, 3) se compose d'un polystyrène extrudé.
  11. Plaque calorifuge selon l'une quelconque des revendications précédentes, caractérisée en ce que la couche de recouvrement (2, 3) se compose d'un matériau, en particulier d'un matériau synthétique, lequel présente de meilleures propriétés pour réfléchir le rayonnement infrarouge que le matériau alvéolaire synthétique du corps de base (1).
  12. Plaque calorifuge selon l'une quelconque des revendications précédentes, caractérisée en ce que la couche de recouvrement (2, 3) se compose d'un matériau, en particulier d'un matériau synthétique, lequel est plus clair que le matériau alvéolaire synthétique du corps de base (1).
  13. Plaque calorifuge selon l'une quelconque des revendications précédentes, caractérisée en ce que le corps de base (1) se compose d'un matériau alvéolaire synthétique pigmenté, en particulier d'un matériau alvéolaire synthétique pigmenté de particules de noir de carbone, de graphite ou d'aluminium.
  14. Utilisation d'une plaque calorifuge selon l'une quelconque des revendications précédentes pour l'isolation de la chaleur extérieure de bâtiments.
  15. Procédé de fabrication de la plaque calorifuge selon l'une quelconque des revendications 1 à 13, comportant les étapes suivantes :
    a) mise à disposition d'un corps de base (1) en forme de plaque fabriqué en un matériau alvéolaire synthétique présentant une face extérieure poreuse,
    b) recouvrement de la face extérieure poreuse, essentiellement sur toute son extension plane, d'une couche de recouvrement (2) adjacente présentant une pluralité d'alésages en particulier irréguliers ou d'une pluralité de diverses couches de recouvrement (3) ponctuellement espacées les unes des autres de telle sorte que la face extérieure recouverte obtienne une surface, pour laquelle des zones poreuses formées par la face extérieure du corps de base (1) et des zones formées par la couche de recouvrement (2, 3) alternent.
  16. Procédé selon la revendication 15, caractérisée en ce que le recouvrement se produit par impression d'un matériau, en particulier d'une couche de couleur, sur la face extérieure poreuse du corps de base (1).
  17. Procédé selon l'une quelconque des revendications 15 à 16, caractérisé en ce que le recouvrement se produit par mise en contact d'un matériau synthétique thermoplastique se trouvant dans un état au moins partiellement fondu avec la face extérieure poreuse du corps de base (1).
  18. Procédé selon la revendication 17, caractérisé en ce que le recouvrement se produit en faisant fondre une feuille, en particulier une feuille en polystyrène expansé, sur la face extérieure poreuse.
  19. Procédé selon la revendication 17, caractérisé en ce que le recouvrement se produit en faisant fondre diverses particules synthétiques disposées au préalable sur la face extérieure poreuse de la plaque calorifuge.
  20. Procédé selon l'une quelconque des revendications 18 à 19, caractérisé en ce que la fonte de la feuille ou de particules synthétiques se produit en serrant ces dernières grâce à une face chauffée contre la face extérieure poreuse du corps de base (1).
  21. Procédé selon la revendication 18 ou la revendication 20, caractérisé en ce qu'on utilise une feuille d'une seule pièce, et en ce qu'on choisit le matériau de la feuille, la résistance de la feuille, la température de la face chauffée et la durée du temps de pressage contre la face extérieure poreuse de telle sorte que la feuille, lors de la fonte, obtienne une pluralité de trous sur la face extérieure poreuse.
  22. Procédé selon l'une quelconque des revendications 15 à 21, caractérisé en ce que le recouvrement se produit en injectant en particulier sous forme de gouttes un matériau synthétique fondu sur la face extérieure poreuse du corps de base (1).
  23. Procédé selon l'une quelconque des revendications 15 à 22, caractérisé en ce qu'un corps de base (1) fabriqué à partir d'un matériau alvéolaire synthétique thermoplastique est mis à disposition, et en ce que la couche de recouvrement (2, 3) est formée à partir d'un matériau thermoplastique, la couche de recouvrement (2, 3) et le corps de base (1) étant fondus l'un avec l'autre.
  24. Procédé selon la revendication 23, caractérisé en ce que la couche de recouvrement (2, 3) est formée à partir d'un matériau synthétique, lequel est formé à partir de composants de base synthétiques identiques comme le matériau alvéolaire synthétique du corps de base (1), en particulier à partir d'un polystyrène, d'un polyuréthane ou d'un polyisocyanurate.
  25. Procédé selon la revendication 24, caractérisé en ce qu'un corps de base (1) fabriqué à partir d'une mousse en polystyrène expansée ou extrudée est mis à disposition, et en ce que la couche de revêtement (2, 3) est formée à partir d'un polystyrène extrudé.
  26. Procédé selon l'une quelconque des revendications 15 à 25, caractérisé en ce que la couche de recouvrement (2, 3) est formée à partir d'un matériau, en particulier d'un matériau synthétique, lequel présente de meilleures propriétés pour réfléchir le rayonnement infrarouge que celles du matériau alvéolaire synthétique du corps de base (1).
  27. Procédé selon l'une quelconque des revendications 15 à 26, caractérisé en ce que la couche de recouvrement (2, 3) est formée à partir d'un matériau, en particulier d'un matériau synthétique, lequel est plus clair que le matériau alvéolaire synthétique du corps de base (1).
  28. Procédé selon l'une quelconque des revendications 15 à 27, caractérisé en ce qu'un corps de base (1) fabriqué à partir d'un matériau alvéolaire synthétique pigmenté, en particulier à partir d'un matériau alvéolaire synthétique pigmenté avec des particules de noir de carbone, des particules de graphite ou des particules d'aluminium est mis à disposition.
EP07004316A 2007-03-02 2007-03-02 Panneau isolant pour isoler l'extérieur de bâtiments Not-in-force EP1964992B1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
AT07004316T ATE468449T1 (de) 2007-03-02 2007-03-02 Dämmplatte für die aussenwärmedämmung von gebäuden
EP07004316A EP1964992B1 (fr) 2007-03-02 2007-03-02 Panneau isolant pour isoler l'extérieur de bâtiments
DE502007003840T DE502007003840D1 (de) 2007-03-02 2007-03-02 Dämmplatte für die Aussenwärmedämmung von Gebäuden

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP07004316A EP1964992B1 (fr) 2007-03-02 2007-03-02 Panneau isolant pour isoler l'extérieur de bâtiments

Publications (2)

Publication Number Publication Date
EP1964992A1 EP1964992A1 (fr) 2008-09-03
EP1964992B1 true EP1964992B1 (fr) 2010-05-19

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Family Applications (1)

Application Number Title Priority Date Filing Date
EP07004316A Not-in-force EP1964992B1 (fr) 2007-03-02 2007-03-02 Panneau isolant pour isoler l'extérieur de bâtiments

Country Status (3)

Country Link
EP (1) EP1964992B1 (fr)
AT (1) ATE468449T1 (fr)
DE (1) DE502007003840D1 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ITPG20100014A1 (it) * 2010-02-25 2010-05-27 Sulpol Srl Lastra isolante in polistirene espanso con inserto
DE102010020394A1 (de) 2010-05-12 2011-11-17 Puren Gmbh Hochhaus-Wärmedämm-Verbundsystem

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH517223A (de) * 1970-11-03 1971-12-31 Hebgen Heinrich Dämmplatte aus geschlossenzelligem Kunststoff-Hartschaum
DE8226114U1 (de) * 1982-09-16 1983-02-10 Deitermann, Wolfgang, 4354 Datteln Daemmplatte zur herstellung einer waermedaemmschicht
DE10151334A1 (de) * 2001-10-22 2003-04-30 Fagerdala Benelux S A Extudierter offenzelliger Kunststoffschaum mit verzögerter Rückstellung

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Publication number Publication date
EP1964992A1 (fr) 2008-09-03
ATE468449T1 (de) 2010-06-15
DE502007003840D1 (de) 2010-07-01

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