EP2007946A2 - Procédé pour réaliser une couche antidérapante - Google Patents

Procédé pour réaliser une couche antidérapante

Info

Publication number
EP2007946A2
EP2007946A2 EP07710521A EP07710521A EP2007946A2 EP 2007946 A2 EP2007946 A2 EP 2007946A2 EP 07710521 A EP07710521 A EP 07710521A EP 07710521 A EP07710521 A EP 07710521A EP 2007946 A2 EP2007946 A2 EP 2007946A2
Authority
EP
European Patent Office
Prior art keywords
carrier
layer
cover layer
sheet
slip
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP07710521A
Other languages
German (de)
English (en)
Other versions
EP2007946B1 (fr
Inventor
Friedrich Kerber
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to PL07710521T priority Critical patent/PL2007946T3/pl
Priority to SI200730294T priority patent/SI2007946T1/sl
Publication of EP2007946A2 publication Critical patent/EP2007946A2/fr
Application granted granted Critical
Publication of EP2007946B1 publication Critical patent/EP2007946B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/02—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain a matt or rough surface
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
    • D06N7/0092—Non-continuous polymer coating on the fibrous substrate, e.g. plastic dots on fabrics
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/66—Coatings characterised by a special visual effect, e.g. patterned, textured
    • D21H19/68—Coatings characterised by a special visual effect, e.g. patterned, textured uneven, broken, discontinuous
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2201/00—Polymeric substrate or laminate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2202/00—Metallic substrate
    • B05D2202/20—Metallic substrate based on light metals
    • B05D2202/25—Metallic substrate based on light metals based on Al
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2203/00—Other substrates
    • B05D2203/22—Paper or cardboard
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2252/00—Sheets
    • B05D2252/02—Sheets of indefinite length
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/10—Properties of the materials having mechanical properties
    • D06N2209/106—Roughness, anti-slip, abrasiveness
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/80—Paper comprising more than one coating
    • D21H19/82—Paper comprising more than one coating superposed
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/28—Colorants ; Pigments or opacifying agents
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
    • D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
    • D21H23/22—Addition to the formed paper
    • D21H23/52—Addition to the formed paper by contacting paper with a device carrying the material
    • D21H23/56—Rolls

Definitions

  • the invention relates to a process for the production of an antislip coating on a roll-formable or sheet-shaped carrier, in particular for improving the processing properties of the carrier for subsequent processing steps, wherein a cover layer of slip-resistant material is applied to at least one of the two surfaces of the carrier Preamble of claim 1.
  • the invention further relates to a sheet-like or sheet-like material consisting of a carrier, as well as an applied on at least one of the two surfaces of the carrier cover layer of slip-resistant material, in particular for improving the processing properties of the carrier for subsequent processing steps, according to the preamble of claim.
  • Processes and materials of this type are in particular used when web or sheet-shaped materials are fed to subsequent automated plant sections, in which further processing takes place.
  • a printing process can be involved, in which the carrier is provided with a single- or multi-colored printing layer.
  • An example of an application would be, for example, the production of a packaging material, for which at first a carrier, for example a paper web, is unwound from a supply roll and printed in one or more colors before it is finally fed to further processing steps such as cutting or gluing operations, or even just storage.
  • a carrier for example a paper web
  • the paper web has certain processing properties, such as a surface texture, which ensures good handling in mostly automated transport and processing processes.
  • Friction coefficient or slip angle is called to increase the carrier.
  • Various anti-slip materials are known, such as paints, which are applied in liquid or pasty form on one or both surfaces of the carrier and must subsequently harden or dry out before further processing of the carrier can take place.
  • the entire surface of the carrier to be coated is provided with a covering layer. This also appears advantageous because this cover layer protects underlying print layers from abrasion of paint, and also gives the material an optically appealing gloss.
  • the anti-slip materials used for the coating are expensive, so that the advantage of improved processing properties is associated with higher costs.
  • paints applied over the entire surface can often be very poorly adhered to planned splices, since the adhesive can be poorly connected to the covering layer. Therefore, it is often attempted to provide the wearer at the planned splice with a cover layer.
  • the drying time required after application of the cover layer reduces the overall processing speed. Measures for a faster drying, such as an increase in the drying temperature, in turn entail higher energy expenditure.
  • a plastic sheet which comprises a planar, flexible plastic carrier, and a plastic coating applied to the coating of plastic, wherein the B coating forms a structured surface.
  • Claim 1 relates to a method for producing a slip-resistant coating on a roll-formable or arcuate carrier for improving the frictional processing properties of the carrier for subsequent processing steps, such as cutting, punching or folding processes, subsequent transport operations, or a subsequent storage, wherein At least one of the two surfaces of the carrier, a cover layer of slip-resistant material is applied.
  • lacquer is used as cover layer, which is applied only over partial surfaces of the surface of the support. It has surprisingly been found that the slip angle of a material compared to a full-surface coating with the cover layer is substantially higher if the coating of the surface is not entirely. Thus, not only the slip angle can be increased, which is often a multiple request of the packaging industry, for example, but at the same time also expensive material for the production of the covering layer can be saved.
  • the subsequent processing steps mentioned in claim 1 may be steps for processing the coated carrier, such as cutting, punching or folding processes, transport processes or even only the preparation of a favorable for future access storage.
  • the cover layer is applied in a grid shape.
  • the slip-resistant material can be applied to the surface of the carrier in the form of a grid.
  • the masking ratio is also referred to below as a "percentage of the grid" in the context of a grid.
  • Claim 3 exploits the observation that by varying the cover ratio of the slip angle of the material can be selectively changed. Namely, according to claim 3, the ratio between the partial areas covered by the covering layer and the total area of the respective surface of the carrier is selected depending on the desired friction value (slip angle) of the surface. Thus, the friction value of the web or sheet material can be adjusted to the respective subsequent processing operation.
  • Claim 4 provides that the layer thickness of the covering layer is selected as a function of the desired friction value of the surface. If, for example, the impression of a closed covering layer is necessary for the sake of gloss, then one can choose the covering ratio higher, but at the same time reduce the layer thickness. So you can get the visual impression of a closed cover layer, but still achieve a significant saving due to the reduced thickness.
  • Claim 5 refers to an application of the method according to the invention in the context of a printing operation, in which before the application of the cover layer is a one- or multi-color printing on the surface of the carrier.
  • Claim 6 proposes to use as support paper, cardboard, textiles, aluminum foils, plastic films or composite films of at least two of the aforementioned materials.
  • Claim 7 refers to a web or sheet material consisting of a carrier, as well as one applied to at least one of the two surfaces of the carrier Covering layer of slip-resistant material for improving the wear-related processing properties of the carrier for subsequent processing steps, such as cutting, punching or folding processes, subsequent transport operations, or a subsequent storage, it being provided according to the invention that the covering layer is a lacquer layer which is only over Partial surfaces of the surface of the carrier is applied.
  • Claim 8 provides that the cover layer is applied in a grid pattern.
  • Claim 10 additionally proposes that the layer thickness of the cover layer is selected as a function of the desired friction value of the surface. In fact, it is shown in practice that the thickness of the covering layer also has an influence on its coefficient of friction.
  • Claim 11 in turn relates to an application of the material according to the invention in the context of a printing operation, in which the carrier is provided with a single- or multi-colored printing layer, the. the cover layer is at least partially covered.
  • the carrier paper cardboard, a textile material, an aluminum foil, a plastic film, or a composite foil of at least two of the aforementioned materials.
  • FIG. 1 shows a schematic cross section along the line AA of FIG. 4 of a section of a material according to the invention consisting of a carrier, a printed layer and a cover layer,
  • FIG. 2 is a schematic representation of the material of FIG. 1 seen from above for a first covering ratio
  • Fig. 3 is a schematic representation of the material of Fig. 1 seen from above for a second Abdeckiser
  • Fig. 4 is a schematic representation of the material of Fig. 1 seen from above for a third covering ratio.
  • the carrier 1 shows a schematic representation of a material according to the invention, which consists of a carrier 1, optionally a printing layer 2, as well as a covering layer 3.
  • the carrier 1 may be, for example, a paper web, a paper sheet, a cardboard, a textile, an aluminum foil, a plastic foil, a composite foil of at least two of the aforementioned materials or the like.
  • the carrier 1 is unwound from a roll or arcuate, and is thus suitable to be fed in the course of automated processing processes subsequent processing steps.
  • the print layer 2 can also consist of several color layers, for example if several color planes are applied in the course of printing on the carrier 1.
  • the carrier 1 is provided with a cover layer 3 of anti-slip material to the coefficient of friction of the To increase carrier 1.
  • Fig. 1 is shown approximately that only the upwardly oriented surface of the carrier 1 and the print layer 2, is provided with a cover layer 3, but not the downwardly oriented surface of the carrier 1.
  • both surfaces of the Support 1 may be provided with a print layer 2 and / or a cover layer 3.
  • anti-slip materials such as paints, which are applied in liquid or pasty form on one or both surfaces of the carrier 1, and subsequently harden or dry before further processing of the carrier 1 can take place.
  • paints are colorless, glossy or matt-drying materials, which are applied either as a printing varnish by the printing press, or as an aqueous-based dispersion varnish by a separate printing varnish on the support 1 and the print layer 2.
  • varnishing usually represents the last printing phase and not only improves the appearance of a printed product but also increases the abrasion resistance of the printing inks of the printing layer 2, especially with matt paper. Last but not least, these varnishes also have an antislip effect.
  • the entire surface of the carrier 1 to be coated is provided with a covering layer 3 in order to achieve the best possible friction properties.
  • the cover layer 3 also has the purpose of protecting the underlying print layer 2 from abrasion of paint.
  • the covering layer 3 is applied only over partial surfaces of the surface of the carrier 1.
  • the slip angle of a material is significantly higher in comparison to a full-surface coating with the cover layer 3, if the coating of the surface is not entirely done.
  • the application of the cover layer 3 is approximately grid-shaped, wherein the shape of the grid is in principle immaterial.
  • different raster forms than prove suitable, wherein the selection of the optimum grid shape represents a common task for the skilled person.
  • FIGS. 2 to 4 a simple example of a grid is shown, which consists of individual grid points 4, which are arranged in a regular arrangement over the surface 5 of the carrier 1 and the printing layer 2.
  • a raster point 4 is a printable image element which can be applied at different distances from each other or in different sizes.
  • the grid shown by way of example in FIGS. 2 to 4 would correspond approximately to a frequency-modulated raster, that is to say a raster in which the surface 5 is divided into raster dots 4 of the same size, the variation of the percentage of the raster, ie the coverage ratio, over the number the points in the area (the frequency) takes place.
  • the screen dots 4 could also be arranged stochastically.
  • the surface 5 could also be divided into a fixed number of screen dots 4 (eg "24th screen ⁇ : 24x24 dots per cm 2 ), and the variation of the percentage of the screen over the size of the dots (the amplitude) should take place , in which case one also speaks of an amplitude-modulated raster.
  • FIGS. 2 to 4 schematically show a raster form, each with different percentage values.
  • FIG. 2 shows approximately a grid with a comparatively low covering ratio. If, for example, 30% of the total area of the surface 5 is covered by screen dots 4, this is also referred to as a "30% screen.”
  • the number of screen dots 4 has been increased and represents, for example, a "50% screen”
  • FIG. 4 schematically represents a "70% grid".
  • all other types of screen forms and covering ratios are also conceivable.
  • the slip-resistant material can be applied to the surface 5 of the support 1 in the form of a grid.
  • the Choice of the optimum printing method will depend on the properties of the substrate 1 or the printing layer 2, the requirements of the subsequent processing steps, the nature of the anti-slip material, or simply the cost issue.
  • the person skilled in the art will thus opt for different high-speed, flat, gravure or through-printing methods, such as flexographic printing, offset printing, screen printing or even thermal printing processes.
  • the subject invention can be realized in any case with all these printing methods.
  • this carrier 1 has, after printing with the printing layer 2, a certain friction value (slip angle). This slip angle is smaller than the slip angle that results in full-surface painting with the cover layer 3.
  • Full-surface, grid-shaped painting with the cover layer 3 is a "100% grid.”
  • the slip angle initially increases from such a full-area coating of the substrate 1 or the print layer 2 when the percentage of the 4), with a further reduction of the cover ratio, a maximum value of the slip angle, which is greater than the slip angle in the case of full-area coating, is finally passed through, for example at a 50% grid (FIG After passing through this maximum value, the expected behavior finally sets in that the slip angle decreases the smaller one selects the partial surfaces of the surface 5 of the carrier 1 provided with the covering layer 3. At a certain covering ratio, ultimately the same slip angle arises as with completely covered surface a. With a 24iger grid that would be approx at a 30% grid the case (schematic in Fig.
  • the slip angle of the painted printing unit can be selectively changed. It is only necessary to choose the ratio between the partial areas covered by the covering layer 3 and the total area of the relevant surface 5 of the carrier 1 as a function of the desired friction value (slip angle) of the surface 5.
  • the friction value of the sheet or sheet material according to the invention can be adapted to the respective subsequent processing operation.
  • the method according to the invention or the material according to the invention it is thus possible to reduce the amount of slip-resistant material used for the coating, which results in a considerable cost reduction.
  • bonding operations are easier to carry out because, due to the raster, the adhesive, e.g. Glue, a compound to the carrier 1, e.g. Paper, build, and so can achieve the necessary adhesive properties. This in turn leads to lower costs, as well as lower complaints and spoilage.
  • the required drying time can be reduced, which increases the overall processing speed. Measures for faster drying, such as an increase in the drying temperature or the like, are no longer or to a reduced extent necessary.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Laminated Bodies (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Printing Methods (AREA)
  • Wrappers (AREA)
  • Paper (AREA)

Abstract

L'invention concerne un procédé pour réaliser une couche antidérapante sur un support (1) en forme de feuille ou pouvant être déroulé sur un cylindre, afin d'améliorer les aptitudes au traitement déterminées par frottement dudit support (1) pour des opérations de traitement ultérieures telles que des processus de coupe, d'estampage ou de pliage, des opérations de transport ultérieures ou un stockage ultérieur, une couche de couverture (3) en matériau antidérapant étant appliquée sur au moins une des deux surfaces (5) du support (1). Selon l'invention, la couche de couverture (3) est du vernis appliqué seulement sur des parties de la surface (5) du support (1). L'invention porte également sur un matériau en bande ou en feuille composé d'un support (1) et d'une couche de couverture (3) en matériau antidérapant appliquée sur au moins une des deux surfaces (5) du support (1), cette couche de couverture (3) étant une couche de vernis appliquée seulement sur des parties de la surface (5) du support (1).
EP07710521A 2006-03-16 2007-03-16 Procédé pour réaliser une couche antidérapante Active EP2007946B1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
PL07710521T PL2007946T3 (pl) 2006-03-16 2007-03-16 Sposób wytwarzania powłoki antypoślizgowej
SI200730294T SI2007946T1 (sl) 2006-03-16 2007-03-16 Postopek za izdelavo protidrsnega presloja

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
AT0044006A AT503396B1 (de) 2006-03-16 2006-03-16 Verfahren zur herstellung einer rutschhemmenden beschichtung
PCT/AT2007/000131 WO2007104069A2 (fr) 2006-03-16 2007-03-16 Procédé pour réaliser une couche antidérapante

Publications (2)

Publication Number Publication Date
EP2007946A2 true EP2007946A2 (fr) 2008-12-31
EP2007946B1 EP2007946B1 (fr) 2010-05-12

Family

ID=38509822

Family Applications (1)

Application Number Title Priority Date Filing Date
EP07710521A Active EP2007946B1 (fr) 2006-03-16 2007-03-16 Procédé pour réaliser une couche antidérapante

Country Status (15)

Country Link
US (1) US20090065141A1 (fr)
EP (1) EP2007946B1 (fr)
AT (3) AT503396B1 (fr)
CA (1) CA2642878A1 (fr)
DE (1) DE502007003740D1 (fr)
DK (1) DK2007946T3 (fr)
EA (1) EA013193B1 (fr)
ES (1) ES2346093T3 (fr)
HR (1) HRP20100435T1 (fr)
MX (1) MX2008011799A (fr)
NO (1) NO20084264L (fr)
PL (1) PL2007946T3 (fr)
SI (1) SI2007946T1 (fr)
UA (1) UA86732C2 (fr)
WO (1) WO2007104069A2 (fr)

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DE102011117302A1 (de) * 2011-11-01 2013-05-02 Focke & Co. (Gmbh & Co. Kg) Packung, insbesondere Zigarettenpackung
US20130216712A1 (en) * 2012-02-17 2013-08-22 Oskar MERZ Method for producing a non-slip coating
FR3007045B1 (fr) * 2013-06-12 2015-09-04 Endupack Feuille antiderapante
DE102014109548A1 (de) * 2014-07-08 2016-01-14 Thyssenkrupp Ag Bandbeschichtungsverfahren zur Herstellung eines Halbzeugs mit einer Oberflächenstruktur
US10687642B2 (en) 2016-02-05 2020-06-23 Havi Global Solutions, Llc Microstructured packaging surfaces for enhanced grip
AU2017214665B2 (en) 2016-02-05 2019-08-22 Havi Global Solutions, Llc Micro-structured surface with improved insulation and condensation resistance
BR112018070338B1 (pt) 2016-04-07 2022-10-18 Havi Global Solutions, Llc Recipiente flexível para reter fluido

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Also Published As

Publication number Publication date
SI2007946T1 (sl) 2010-08-31
EA200801827A1 (ru) 2009-02-27
AT503396A1 (de) 2007-10-15
MX2008011799A (es) 2008-12-10
US20090065141A1 (en) 2009-03-12
ATE467720T1 (de) 2010-05-15
AT503396B1 (de) 2008-05-15
WO2007104069A3 (fr) 2007-12-21
NO20084264L (no) 2008-12-15
UA86732C2 (ru) 2009-05-12
EP2007946B1 (fr) 2010-05-12
DE502007003740D1 (de) 2010-06-24
EA013193B1 (ru) 2010-02-26
PL2007946T3 (pl) 2010-10-29
ES2346093T3 (es) 2010-10-08
AT10897U1 (de) 2009-12-15
WO2007104069A2 (fr) 2007-09-20
DK2007946T3 (da) 2010-07-19
CA2642878A1 (fr) 2007-09-20
HRP20100435T1 (hr) 2010-09-30

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