EP2018123A1 - Dispositif pour produire des ondes de choc - Google Patents
Dispositif pour produire des ondes de chocInfo
- Publication number
- EP2018123A1 EP2018123A1 EP07725076A EP07725076A EP2018123A1 EP 2018123 A1 EP2018123 A1 EP 2018123A1 EP 07725076 A EP07725076 A EP 07725076A EP 07725076 A EP07725076 A EP 07725076A EP 2018123 A1 EP2018123 A1 EP 2018123A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- liquid
- electrodes
- molecules
- shock waves
- housing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 230000035939 shock Effects 0.000 title claims abstract description 21
- 239000001257 hydrogen Substances 0.000 claims abstract description 36
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 36
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000007788 liquid Substances 0.000 claims abstract description 16
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000001301 oxygen Substances 0.000 claims abstract description 12
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 12
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 29
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 18
- 229910052763 palladium Inorganic materials 0.000 claims description 8
- 239000002245 particle Substances 0.000 claims description 7
- 230000004888 barrier function Effects 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 5
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims description 4
- 239000011859 microparticle Substances 0.000 claims description 4
- 239000002105 nanoparticle Substances 0.000 claims description 4
- 239000011324 bead Substances 0.000 claims description 2
- 239000012530 fluid Substances 0.000 claims description 2
- 229910017464 nitrogen compound Inorganic materials 0.000 claims description 2
- 150000002830 nitrogen compounds Chemical class 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 229920003002 synthetic resin Polymers 0.000 claims description 2
- 239000000057 synthetic resin Substances 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims 1
- 150000007513 acids Chemical class 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 abstract description 9
- -1 hydroxide ions Chemical class 0.000 abstract description 4
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract description 3
- 239000007789 gas Substances 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 6
- 150000002431 hydrogen Chemical class 0.000 description 5
- 208000000913 Kidney Calculi Diseases 0.000 description 3
- 206010029148 Nephrolithiasis Diseases 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 2
- 230000010355 oscillation Effects 0.000 description 2
- 210000002435 tendon Anatomy 0.000 description 2
- 208000010392 Bone Fractures Diseases 0.000 description 1
- SQUHHTBVTRBESD-UHFFFAOYSA-N Hexa-Ac-myo-Inositol Natural products CC(=O)OC1C(OC(C)=O)C(OC(C)=O)C(OC(C)=O)C(OC(C)=O)C1OC(C)=O SQUHHTBVTRBESD-UHFFFAOYSA-N 0.000 description 1
- 208000000491 Tendinopathy Diseases 0.000 description 1
- 208000023835 Tendon disease Diseases 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000013467 fragmentation Methods 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- 230000035876 healing Effects 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- CDAISMWEOUEBRE-GPIVLXJGSA-N inositol Chemical compound O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@H](O)[C@@H]1O CDAISMWEOUEBRE-GPIVLXJGSA-N 0.000 description 1
- 229960000367 inositol Drugs 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 230000000399 orthopedic effect Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- CDAISMWEOUEBRE-UHFFFAOYSA-N scyllo-inosotol Natural products OC1C(O)C(O)C(O)C(O)C1O CDAISMWEOUEBRE-UHFFFAOYSA-N 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 208000013515 tendinosis Diseases 0.000 description 1
- 230000029663 wound healing Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61B—DIAGNOSIS; SURGERY; IDENTIFICATION
- A61B17/00—Surgical instruments, devices or methods
- A61B17/22—Implements for squeezing-off ulcers or the like on inner organs of the body; Implements for scraping-out cavities of body organs, e.g. bones; for invasive removal or destruction of calculus using mechanical vibrations; for removing obstructions in blood vessels, not otherwise provided for
- A61B17/22004—Implements for squeezing-off ulcers or the like on inner organs of the body; Implements for scraping-out cavities of body organs, e.g. bones; for invasive removal or destruction of calculus using mechanical vibrations; for removing obstructions in blood vessels, not otherwise provided for using mechanical vibrations, e.g. ultrasonic shock waves
- A61B17/22012—Implements for squeezing-off ulcers or the like on inner organs of the body; Implements for scraping-out cavities of body organs, e.g. bones; for invasive removal or destruction of calculus using mechanical vibrations; for removing obstructions in blood vessels, not otherwise provided for using mechanical vibrations, e.g. ultrasonic shock waves in direct contact with, or very close to, the obstruction or concrement
- A61B17/22022—Implements for squeezing-off ulcers or the like on inner organs of the body; Implements for scraping-out cavities of body organs, e.g. bones; for invasive removal or destruction of calculus using mechanical vibrations; for removing obstructions in blood vessels, not otherwise provided for using mechanical vibrations, e.g. ultrasonic shock waves in direct contact with, or very close to, the obstruction or concrement using electric discharge
-
- G—PHYSICS
- G10—MUSICAL INSTRUMENTS; ACOUSTICS
- G10K—SOUND-PRODUCING DEVICES; METHODS OR DEVICES FOR PROTECTING AGAINST, OR FOR DAMPING, NOISE OR OTHER ACOUSTIC WAVES IN GENERAL; ACOUSTICS NOT OTHERWISE PROVIDED FOR
- G10K15/00—Acoustics not otherwise provided for
- G10K15/04—Sound-producing devices
- G10K15/06—Sound-producing devices using electric discharge
Definitions
- the invention relates to a device for generating shock waves, in particular for medical application according to the preamble of claims 1 and 4.
- Such devices are used in medical technology, for example in urology as Nierensteinzertrümmerer, in orthopedics in non-healing bone fractures or tendon tendinosis tendons or more generally for the promotion of wound healing for decades.
- the electrodes, between which shock waves are generated by spark discharge are subject to considerable wear.
- the discharge current oscillates between the capacitor, an inductive resistor and the electrode tips (surge circuit) several times. Repeatedly reversing the voltage at the electrode tips and reversing the electron flow direction between the tips. During several oscillation cycles, impact ionization of the water occurs between the tips and their surroundings. This impact ionization leads to partial decomposition of the water into hydrogen, oxygen and hydroxide ions. These are significantly responsible for the formation of the plasma bubble between the
- DE 197 18 512 C1 discloses a method and a device which proposes to mix in the liquid a catalyst by which the electrolytic formation of gas is completely or partially suppressed when the high voltage is applied to the electrodes and which catalytically transforms all or part of the gas produced during the application of the high voltage to the electrodes and during the electrical breakdown into its initial state
- the object of the invention is therefore to provide a device of the type mentioned above, by means of the efficiency and the lifetime the device is considerably increased compared to the previously known, in which the formation of hydrogen, oxygen and hydroxide ions between the electrode tips is not hindered. Rather, it is the object of the invention to provide a device which prevents the escape of hydrogen, stores it and completely facilitates the re-reaction in water molecules.
- the hydrogen storage can be added to the water both in dissolved or suspended form as well as in colloidal suspension. This is possible even as sediment, since this is swirled again in the reaction space by shaking the volume or by the fluid turbulence generated by the shock wave itself
- Another way to bind the free hydrogen molecules is to apply the hydrogen storage on the surface of the housing surrounding the electrodes. Also in the vicinity of the electrodes, support materials, e.g. fine reticular structures containing hydrogen storage on the surface.
- the hydrogen storage may consist of bound or unbound nanoparticles or microparticles, of films or sponge-like layers on surfaces. Common to this hydrogen storage is that the released by the Stossionisation hydrogen atoms that are reacted to hydrogen molecules are held in the liquid and that thus reacts the free oxygen molecules present in the liquid with the hydrogen stored in the hydrogen storage and water molecules is formed.
- an inventive embodiment is shown, which will be explained in more detail below.
- the sole figure shows a device for generating shock waves with a pair of electrodes in a housing in which water and a storage medium is embedded.
- shock waves 2 should be generated, which can be used for a medical application, for example, for the kidney stone fragmentation.
- the device 1 consists of a sound-permeable housing 3, in which a pair of electrodes 4 are arranged opposite to each other. Inside the housing 3 water 5 is filled. Between the opposing electrodes 4, a high voltage is applied, at the breakthrough of which a plasma bubble is generated which in turn generates a shock wave 2 in water.
- the shock waves 2 pass through the housing 3 to the outside and are aligned by a focusing device, not shown, such that, for example, a kidney stone can be smashed in the human body.
- a plurality of hydrogen storage 11 are present in the water 5. Furthermore, the inside of the housing 3 may be covered with a storage layer 16 in order to keep the hydrogen molecules 6 inside the housing 3 and thus in the water 5.
- the storage medium 11 can for example consist of a synthetic resin bead 12 whose surface is formed of nano- or microparticles. At these surface structures, a nitrogen compound 13 is provided, at the free end of each of which a palladium particle 14 is attached.
- the palladium particles 14 have a metallized outer layer through which the existing in the water 5 Hydrogen molecules 6 are bound. Accordingly, three chemical reactions take place between the metallized outer layer of the palladium particles 14 and the hydrogen molecules 7 present in the water 5:
- the storage layer 16 which may be formed as a film, sponge, grid or mesh, may consist of various layers, on the surface of a hydrogen storage, such as palladium particles 14, adhere or are bonded.
- the outer surfaces of the electrodes 4 and / or the material of the electrode insulation 17 may be covered with the storage layer 16. It is particularly advantageous if the barrier layer 16 is arranged directly in the region of the spark gap occurring between the electrodes 4, because this ensures that the oxygen molecules 7 react directly with the hydrogen molecules 6 in the area of the spark formation and therefore arise outside the plasma bubble. Due to the chemical fact that hydrogen molecules 6 are extremely difficult to store and to retain in the envelope, it is intended to additionally introduce chemical substances into the water 5 through which hydrogen molecules 6 are additionally made available. For example, hydrazine molecules 15 or dilute organic or inorganic acids or salts can be provided, through which hydrogen 6, for example in the form of hydronium ions, is released to the water 5. This is necessary in order to ensure that the oxygen molecules 7 formed by the stoistisation always have enough reaction partners to form water molecules 5.
Landscapes
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Surgery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Medical Informatics (AREA)
- General Health & Medical Sciences (AREA)
- Vascular Medicine (AREA)
- Orthopedic Medicine & Surgery (AREA)
- Biomedical Technology (AREA)
- Heart & Thoracic Surgery (AREA)
- Mechanical Engineering (AREA)
- Molecular Biology (AREA)
- Animal Behavior & Ethology (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Physics & Mathematics (AREA)
- Acoustics & Sound (AREA)
- Multimedia (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Surgical Instruments (AREA)
- External Artificial Organs (AREA)
Abstract
La présente invention concerne un dispositif (1) pour produire des ondes de choc (2) destinées en particulier à des applications médicales, le dispositif comprenant un boîtier (3) perméable aux ondes de choc (2); au moins une paire d'électrodes (4) disposées à l'intérieur du boîtier (3), entre lesquelles une tension respective destinée à la production des ondes de choc (2) peut être régulée; et un liquide (5) qui entoure les électrodes (4) et est constitué en partie ou en intégralité d'une pluralité de molécules d'eau (H<SUB>2</SUB>O). L'invention a pour objet d'améliorer le rendement et la durée de vie du dispositif (1) de façon conséquente par rapport à l'état de la technique, sans altérer la formation d'ions hydrogène, oxygène et hydroxyde entre les pointes des électrodes (4). L'objet de l'invention est plutôt la conception d'un dispositif (1) qui empêche le dégagement d'hydrogène (6), assure son stockage et permet la réaction inverse complète pour donner des molécules d'eau.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102006022416A DE102006022416A1 (de) | 2006-05-13 | 2006-05-13 | Vorrichtung zur Erzeugung von Stoßwellen |
| PCT/EP2007/004155 WO2007131702A1 (fr) | 2006-05-13 | 2007-05-10 | Dispositif pour produire des ondes de choc |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP2018123A1 true EP2018123A1 (fr) | 2009-01-28 |
Family
ID=38515821
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP07725076A Withdrawn EP2018123A1 (fr) | 2006-05-13 | 2007-05-10 | Dispositif pour produire des ondes de choc |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US20090326421A1 (fr) |
| EP (1) | EP2018123A1 (fr) |
| DE (1) | DE102006022416A1 (fr) |
| WO (1) | WO2007131702A1 (fr) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102016003854A1 (de) | 2016-03-26 | 2017-09-28 | Gerd Straßmann | Optimierung der Schalldruckwellentherapie eines Tumors |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9198825B2 (en) * | 2012-06-22 | 2015-12-01 | Sanuwave, Inc. | Increase electrode life in devices used for extracorporeal shockwave therapy (ESWT) |
| CA2890401C (fr) * | 2015-01-21 | 2015-11-03 | Vln Advanced Technologies Inc. | Appareil de decharge electrique pour generer de puissants jets d'eau cavitants et impulsionnels a basse frequence |
| CN116077987B (zh) * | 2023-02-07 | 2023-09-26 | 泰兴金江化学工业有限公司 | 一种具有原料可控的乙酸乙酯的生产加工设备 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4651311A (en) * | 1984-12-05 | 1987-03-17 | Southwest Research Institute | Electrodeless spark discharge acoustic pulse transducer for borehole operation |
| DE3918190A1 (de) * | 1989-06-03 | 1990-12-06 | Dornier Gmbh | Wasserstoff-eliminator |
| GB9003390D0 (en) * | 1990-02-14 | 1990-04-11 | Univ Manchester | Method of generating energy |
| EP0590177B1 (fr) * | 1992-09-28 | 1996-12-18 | Hmt High Medical Technologies Entwicklungs- Und Vertriebs Ag | Dispositif générateur d'ondes de choc pour la destruction à distance des concrétions dans le corps vivant |
| DE19718512C1 (de) * | 1997-05-02 | 1998-06-25 | Hmt Ag | Verfahren und Vorrichtung zum Erzeugen von Stoßwellen für medizinische Anwendungen |
| DE10150385B4 (de) * | 2001-10-11 | 2005-12-08 | Ballard Power Systems Ag | Brennstoffzellensystem |
-
2006
- 2006-05-13 DE DE102006022416A patent/DE102006022416A1/de not_active Withdrawn
-
2007
- 2007-05-10 EP EP07725076A patent/EP2018123A1/fr not_active Withdrawn
- 2007-05-10 WO PCT/EP2007/004155 patent/WO2007131702A1/fr not_active Ceased
- 2007-05-10 US US12/226,253 patent/US20090326421A1/en not_active Abandoned
Non-Patent Citations (1)
| Title |
|---|
| See references of WO2007131702A1 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102016003854A1 (de) | 2016-03-26 | 2017-09-28 | Gerd Straßmann | Optimierung der Schalldruckwellentherapie eines Tumors |
Also Published As
| Publication number | Publication date |
|---|---|
| US20090326421A1 (en) | 2009-12-31 |
| DE102006022416A1 (de) | 2007-11-22 |
| WO2007131702A1 (fr) | 2007-11-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| 17P | Request for examination filed |
Effective date: 20080730 |
|
| AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC MT NL PL PT RO SE SI SK TR |
|
| AX | Request for extension of the european patent |
Extension state: AL BA HR MK RS |
|
| DAX | Request for extension of the european patent (deleted) | ||
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
|
| 18D | Application deemed to be withdrawn |
Effective date: 20121201 |