EP2021382A4 - Geträgerter antistatischer polymerisationskatalysator - Google Patents

Geträgerter antistatischer polymerisationskatalysator

Info

Publication number
EP2021382A4
EP2021382A4 EP07719662.4A EP07719662A EP2021382A4 EP 2021382 A4 EP2021382 A4 EP 2021382A4 EP 07719662 A EP07719662 A EP 07719662A EP 2021382 A4 EP2021382 A4 EP 2021382A4
Authority
EP
European Patent Office
Prior art keywords
supported catalyst
antistatic
polymerization
antistatic polymerization
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP07719662.4A
Other languages
English (en)
French (fr)
Other versions
EP2021382B1 (de
EP2021382A1 (de
Inventor
Ian Mckay
Dusan Jeremic
Paul Mesquita
Grant Berent Jacobsen
Sergio Mastroianni
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nova Chemicals International SA
Ineos Sales UK Ltd
Original Assignee
Nova Chemicals International SA
Ineos Sales UK Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nova Chemicals International SA, Ineos Sales UK Ltd filed Critical Nova Chemicals International SA
Publication of EP2021382A1 publication Critical patent/EP2021382A1/de
Publication of EP2021382A4 publication Critical patent/EP2021382A4/de
Application granted granted Critical
Publication of EP2021382B1 publication Critical patent/EP2021382B1/de
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/02—Anti-static agent incorporated into the catalyst
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerisation Methods In General (AREA)
EP07719662.4A 2006-05-30 2007-05-02 Geträgerter antistatischer polymerisationskatalysator Active EP2021382B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB0610668.6A GB0610668D0 (en) 2006-05-30 2006-05-30 Supported antistatic polymerization catalysts
PCT/CA2007/000737 WO2007137396A1 (en) 2006-05-30 2007-05-02 Supported antistatic polymerization catalyst

Publications (3)

Publication Number Publication Date
EP2021382A1 EP2021382A1 (de) 2009-02-11
EP2021382A4 true EP2021382A4 (de) 2014-01-01
EP2021382B1 EP2021382B1 (de) 2016-08-17

Family

ID=36694616

Family Applications (1)

Application Number Title Priority Date Filing Date
EP07719662.4A Active EP2021382B1 (de) 2006-05-30 2007-05-02 Geträgerter antistatischer polymerisationskatalysator

Country Status (8)

Country Link
US (1) US7476715B2 (de)
EP (1) EP2021382B1 (de)
JP (1) JP5562636B2 (de)
CN (2) CN101466742A (de)
CA (1) CA2587238C (de)
ES (1) ES2598483T3 (de)
GB (1) GB0610668D0 (de)
WO (1) WO2007137396A1 (de)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010080871A1 (en) 2009-01-08 2010-07-15 Univation Technologies, Llc Additive for gas phase polymerization processes
JP2012529507A (ja) * 2009-06-11 2012-11-22 ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット アルミノキサンの製造方法及びかくして製造されるアルミノキサンを含んでなる触媒
RU2549541C2 (ru) * 2009-07-28 2015-04-27 Юнивейшн Текнолоджиз, Ллк Способ полимеризации с использованием нанесенного катализатора с затрудненной геометрией
CA2739969C (en) 2011-05-11 2018-08-21 Nova Chemicals Corporation Improving reactor operability in a gas phase polymerization process
CA2749835C (en) 2011-08-23 2018-08-21 Nova Chemicals Corporation Feeding highly active phosphinimine catalysts to a gas phase reactor
CA2760264C (en) 2011-12-05 2018-08-21 Nova Chemicals Corporation Passivated supports for use with olefin polymerization catalysts
CA2798855C (en) 2012-06-21 2021-01-26 Nova Chemicals Corporation Ethylene copolymers having reverse comonomer incorporation
US9115233B2 (en) 2012-06-21 2015-08-25 Nova Chemicals (International) S.A. Ethylene copolymer compositions, film and polymerization processes
CA2797620C (en) 2012-12-03 2019-08-27 Nova Chemicals Corporation Controlling resin properties in a gas phase polymerization process
CA2800056A1 (en) 2012-12-24 2014-06-24 Nova Chemicals Corporation Polyethylene blend compositions
EP2842912A1 (de) 2013-08-26 2015-03-04 Basell Poliolefine Italia S.r.l. Verfahren zur Verbesserung der Funktionsfähigkeit eines Olefinpolymerisationsreaktors
CA2871463A1 (en) 2014-11-19 2016-05-19 Nova Chemicals Corporation Passivated supports: catalyst, process and product
CA2874344C (en) 2014-12-15 2021-08-31 Nova Chemicals Corporation Spheroidal catalyst for olefin polymerization
CA2891693C (en) 2015-05-21 2022-01-11 Nova Chemicals Corporation Controlling the placement of comonomer in an ethylene copolymer
CA2892552C (en) 2015-05-26 2022-02-15 Victoria Ker Process for polymerization in a fluidized bed reactor
CA2892882C (en) 2015-05-27 2022-03-22 Nova Chemicals Corporation Ethylene/1-butene copolymers with enhanced resin processability
KR101845625B1 (ko) * 2016-09-27 2018-04-05 롯데케미칼 주식회사 폴리올레핀 제조방법
KR20200059350A (ko) 2018-11-20 2020-05-29 롯데케미칼 주식회사 폴리에틸렌 중합용 촉매의 제조방법
KR102803225B1 (ko) * 2019-10-23 2025-04-30 주식회사 엘지화학 메탈로센계 담지 촉매의 제조 방법 및 이를 이용한 폴리올레핀의 제조 방법
KR102947655B1 (ko) 2020-12-01 2026-04-01 주식회사 엘지화학 메탈로센 담지 촉매 및 이를 이용한 올레핀 중합체의 제조방법

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006054048A1 (en) * 2004-11-18 2006-05-26 Ineos Europe Limited Supported polymerisation catalysts

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FR2660926B1 (fr) * 1990-04-11 1992-07-31 Bp Chemicals Snc Prepolymere d'alpha-olefine contenant un metal de transition et procede de polymerisation d'alpha-olefine en phase gazeuse mettant en óoeuvre le prepolymere.
US5194526A (en) * 1992-07-30 1993-03-16 Union Carbide Chemicals & Plastics Technology Corporation Process for producing sticky polymers
US5498581A (en) * 1994-06-01 1996-03-12 Phillips Petroleum Company Method for making and using a supported metallocene catalyst system
DE19615953A1 (de) * 1996-04-22 1997-10-23 Basf Ag Verfahren zur Herstellung von Polymerisaten von Alk-1-enen in Gegenwart eines geträgerten Metallocenkatalysatorsystems und eines Antistatikums
RU2190632C2 (ru) * 1996-05-17 2002-10-10 Дзе Дау Кемикал Компани Полиолефиновая сополимерная композиция, способ полимеризации (варианты), металлоценовый катализатор, пленка на основе композиции и смесь двух или более полимерных компонентов
GB9800245D0 (en) * 1998-01-07 1998-03-04 Bp Chem Int Ltd Novel polymers
US6245868B1 (en) * 1998-05-29 2001-06-12 Univation Technologies Catalyst delivery method, a catalyst feeder and their use in a polymerization process
ATE420902T1 (de) * 1999-05-05 2009-01-15 Ineos Europe Ltd Ethylencopolymere und daraus hergestellte filme
JP4895426B2 (ja) * 1999-05-07 2012-03-14 イネオス ユーロープ リミテッド 流動床反応器におけるオレフィンの気相（共）重合法
GB9918668D0 (en) * 1999-08-06 1999-10-13 Bp Chem Int Ltd Polymerisation catalysts
WO2001018067A1 (en) * 1999-09-09 2001-03-15 Bp Chemicals Limited Process for the continuous gas-phase (co-)polymerisation of olefins in a fluidised bed reactor
GB0017547D0 (en) * 2000-07-17 2000-09-06 Bp Chem Int Ltd Supported polymerisation catalysts
WO2002010227A1 (en) * 2000-08-02 2002-02-07 Univation Technologies, Llc Method for producing highly productive supported ionic catalyst for gas phase polymerization
US7244795B2 (en) * 2003-12-08 2007-07-17 Univation Technologies, Llc Polymerization process using metallocene catalyst systems

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006054048A1 (en) * 2004-11-18 2006-05-26 Ineos Europe Limited Supported polymerisation catalysts

Also Published As

Publication number Publication date
CN103360519A (zh) 2013-10-23
CA2587238A1 (en) 2007-11-30
JP5562636B2 (ja) 2014-07-30
CA2587238C (en) 2015-11-24
US7476715B2 (en) 2009-01-13
WO2007137396A1 (en) 2007-12-06
EP2021382B1 (de) 2016-08-17
ES2598483T3 (es) 2017-01-27
GB0610668D0 (en) 2006-07-12
CN101466742A (zh) 2009-06-24
JP2009538936A (ja) 2009-11-12
CN103360519B (zh) 2016-07-20
EP2021382A1 (de) 2009-02-11
US20070282085A1 (en) 2007-12-06

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