EP2051929A1 - Procédé de fabrication de structures mems - Google Patents
Procédé de fabrication de structures memsInfo
- Publication number
- EP2051929A1 EP2051929A1 EP07729426A EP07729426A EP2051929A1 EP 2051929 A1 EP2051929 A1 EP 2051929A1 EP 07729426 A EP07729426 A EP 07729426A EP 07729426 A EP07729426 A EP 07729426A EP 2051929 A1 EP2051929 A1 EP 2051929A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- layer
- sacrificial
- silicon
- monocrystalline
- structuring
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000034 method Methods 0.000 title claims abstract description 37
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 11
- 239000010410 layer Substances 0.000 claims abstract description 105
- 239000002346 layers by function Substances 0.000 claims abstract description 28
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 17
- 239000010703 silicon Substances 0.000 claims abstract description 17
- LEVVHYCKPQWKOP-UHFFFAOYSA-N [Si].[Ge] Chemical compound [Si].[Ge] LEVVHYCKPQWKOP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910000577 Silicon-germanium Inorganic materials 0.000 claims abstract description 8
- 238000000151 deposition Methods 0.000 claims description 20
- 239000000463 material Substances 0.000 claims description 16
- 229910021421 monocrystalline silicon Inorganic materials 0.000 claims description 16
- 230000008021 deposition Effects 0.000 claims description 15
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 7
- 238000011065 in-situ storage Methods 0.000 claims description 3
- 239000011810 insulating material Substances 0.000 claims description 2
- 238000004949 mass spectrometry Methods 0.000 claims description 2
- 238000012544 monitoring process Methods 0.000 claims description 2
- 238000001637 plasma atomic emission spectroscopy Methods 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 235000012431 wafers Nutrition 0.000 description 18
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 13
- 238000005530 etching Methods 0.000 description 10
- 229910052732 germanium Inorganic materials 0.000 description 10
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 10
- 238000009792 diffusion process Methods 0.000 description 6
- 229910052814 silicon oxide Inorganic materials 0.000 description 5
- 230000001133 acceleration Effects 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 239000002019 doping agent Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000004888 barrier function Effects 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 241000282326 Felis catus Species 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 210000000078 claw Anatomy 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000000407 epitaxy Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- VPAYJEUHKVESSD-UHFFFAOYSA-N trifluoroiodomethane Chemical compound FC(F)(F)I VPAYJEUHKVESSD-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B81—MICROSTRUCTURAL TECHNOLOGY
- B81C—PROCESSES OR APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OR TREATMENT OF MICROSTRUCTURAL DEVICES OR SYSTEMS
- B81C1/00—Manufacture or treatment of devices or systems in or on a substrate
- B81C1/00642—Manufacture or treatment of devices or systems in or on a substrate for improving the physical properties of a device
- B81C1/00714—Treatment for improving the physical properties not provided for in groups B81C1/0065 - B81C1/00706
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B81—MICROSTRUCTURAL TECHNOLOGY
- B81C—PROCESSES OR APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OR TREATMENT OF MICROSTRUCTURAL DEVICES OR SYSTEMS
- B81C2201/00—Manufacture or treatment of microstructural devices or systems
- B81C2201/01—Manufacture or treatment of microstructural devices or systems in or on a substrate
- B81C2201/0101—Shaping material; Structuring the bulk substrate or layers on the substrate; Film patterning
- B81C2201/0102—Surface micromachining
- B81C2201/0105—Sacrificial layer
- B81C2201/0109—Sacrificial layers not provided for in B81C2201/0107 - B81C2201/0108
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B81—MICROSTRUCTURAL TECHNOLOGY
- B81C—PROCESSES OR APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OR TREATMENT OF MICROSTRUCTURAL DEVICES OR SYSTEMS
- B81C2201/00—Manufacture or treatment of microstructural devices or systems
- B81C2201/01—Manufacture or treatment of microstructural devices or systems in or on a substrate
- B81C2201/0174—Manufacture or treatment of microstructural devices or systems in or on a substrate for making multi-layered devices, film deposition or growing
- B81C2201/0176—Chemical vapour Deposition
- B81C2201/0177—Epitaxy, i.e. homo-epitaxy, hetero-epitaxy, GaAs-epitaxy
Definitions
- the invention relates to a method for the production of MEMS structures (Micro Electro Mechanical Systems) based on silicon, preferably multi-layer depositable MEMS structures.
- MEMS structures Micro Electro Mechanical Systems
- silicon preferably multi-layer depositable MEMS structures.
- such structures essentially comprise a conductive functional layer containing fixed and movable regions. Movable regions are usually fixed during production by a so-called sacrificial layer, which is selectively removed at the end of the production process by methods known from micromechanical or semiconductor technology.
- Another disadvantage of said methods is the generally quite sensitive compensation of stress gradients by the driving in of the dopants.
- the success of this compensation depends sensitively on the avoidance of later thermal overloads of the doped layers, which is why, when a desired integration of a plurality of sensor elements into a chip is required, the sensor elements must be displaced laterally in order to thermally decouple them during manufacture. This increases the space requirements and costs of the MEMS structure and the finished component.
- the object of the invention is to provide a method which allows the production of complex MEMS structures with high efficiency in a small space and avoids the disadvantages of the prior art.
- the inventive method is based on the deposition of largely monocrystalline functional and sacrificial layers. Obviously, the associated omission of the grain boundaries effectively impedes the diffusion of germanium. This makes it possible to use sacrificial layers of silicon germanium without having to apply an additional barrier to germanium in order to limit its diffusion.
- the method is used to produce MEMS structures with at least one functional layer made of silicon, which contains structures which are released by removing a sacrificial layer.
- at least one sacrificial layer and at least one functional layer are deposited such that they grow up monocrystalline, wherein the sacrificial layer consists of a silicon-germanium mixed layer.
- a plurality of functional layers and sacrificial layers are deposited on top of each other, wherein all functional layers and all sacrificial layers are deposited in such a way that they grow up monocrystalline, and the sacrificial layers each consist of a silicon-germanium mixed layer.
- the multiple separation is possible because of the relatively high Growth rates claimed the heating of the entire assembly only a relatively short period in which a diffusion of germanium, which is also hampered by lack of grain boundaries, can be neglected.
- the removal of the sacrificial material by CIF3 gas phase cats takes place.
- process parameters are advantageously adjusted at least temporarily so that the epitaxial growth takes place at a growth rate of at least 3 ⁇ m / min.
- the change between silicon layers and silicon-germanium mixed layers facilitates by monitoring the plasma emission and / or species detectable by mass spectroscopy the avoidance of false etching depths and thus the occurrence of faulty structuring.
- the steps of depositing and structuring a sacrificial layer and depositing and structuring a functional layer can be repeated several times before completion with a capping layer.
- FIG. 2 shows an SOI wafer with a structured starting layer
- FIG. 3 shows an SOI wafer with an additional first structured sacrificial layer
- 4 shows an SOI wafer with a first structured functional layer
- 5 shows an SOI wafer with a second structured functional layer
- FIG. 6 shows an SOI wafer with a closed cap layer
- FIG. 7 shows an SOI wafer with a completely exposed functional structure
- FIG. and FIG. 8 shows a SOI wafer with a sealed and contacted MEMS structure.
- FIG. 1 shows an unstructured SOI wafer as starting material for the production of multi-layer depositable
- Such a wafer consists of a thick silicon layer 1, which also serves as a mechanical carrier, on which a silicon oxide layer is deposited as the insulating layer 2.
- a silicon oxide layer is deposited as the insulating layer 2.
- the insulating layer 2 On the insulating layer 2 there is a monocrystalline starting layer 3 made of silicon.
- SOI wafers it is possible to produce by individual structuring individual electrically isolated regions, which can serve as a starting layer for later epitaxial growth of other layers.
- FIG. 2 shows an SOI wafer with a structured starting layer 3.
- the structuring takes place by means of an etching step. Vorlie- In addition, several regions of the starting layer 3 are electrically insulated from one another, since the etched trenches 4 extend to the insulating layer 2. The individual areas of the starting layer 3 thus exposed form the bases of the later MEMS structures.
- the silicon layer must have a certain conductance value for this purpose.
- the conductance can be adjusted by doping the silicon.
- the conductance of the start layer 3 is maintained by in-situ doping during the deposition of further layers. Subsequent doping and thermal overload of individual structural areas can be avoided.
- the starting layer 3 is structured from monocrystalline silicon
- sacrificial material is deposited in the form of monocrystalline silicon germanium.
- the area of the silicon regions remaining after the structuring of the starting layer 3 serves for the growth of an initially closed sacrificial layer 5 as a starting layer in order to allow epitaxial growth.
- CMP step chemical mechanical polishing
- the polished sacrificial layer 5 is then patterned by an etching step in order to produce contact holes 6 to individual regions of the starting layer 3, which can serve as a base or conductor track.
- the plasma emission can be monitored during this process step. Disappear emission lines, the one Indicate the presence of germanium, a structuring of the sacrificial layer 5 can be read and the etching process is stopped.
- FIG. 4 shows an SOI wafer with a first structured functional layer 7 of monocrystalline silicon. This is first epitaxially deposited on the sacrificial layer 5 and then patterned in a trench process. Since there is no layer that causes an etch stop and too much overcutting could cause unwanted connections between conductive areas, the etch depth should always be monitored in this process step. This can be done, for example, by a mass spectrometer, to which the exhaust gases of the trencher are supplied. If germanium is detected, the etching process is stopped. As a result of this step, there is a structured functional layer 7, the regions of which partially protrude on the sacrificial layer and are partially in electrically conductive connection with regions of the starting layer 3.
- the steps of the deposition and structuring of a sacrificial layer which can be read in FIGS. 3 and 4 and the deposition and structuring of a functional layer can be repeated several times in order to place a plurality of structures one above the other until a desired functional structure is formed.
- acceleration sensors can be superimposed on a chip whose detection directions are offset by 90 °, which leads to two-axis acceleration sensors without enlarging the chip surface.
- cascaded structures can be realized.
- rotation rate sensors can be produced whose detection structures (acceleration sensors) are arranged on or under a vibrator (oscillator).
- FIG. 5 shows an SOI wafer having a second structured functional layer 8 of monocrystalline silicon and a second sacrificial layer 9 of monocrystalline silicon. Germanium. It is important that the structuring takes place in such a way that the zones which are filled by the sacrificial material in each case form interconnected areas which can be reached through the last silicon layer.
- FIG. 6 shows an SOI wafer with a closed cap layer 10.
- a last sacrificial layer 11 made of monocrystalline silicon germanium, which is broken at points at which contact has to be made later.
- the application of the last sacrificial layer 11, its structuring and the application of the cap layer 10 take place after the functional structure has been completely formed.
- accesses 12 are structured in the cap layer 10, via which the entire sacrificial material can be leached out by C1F 3 gas phase salts in one step. This produces the mechanical functionality of the functional structures.
- FIG. 8 shows a detail of an SOI wafer with a sealed and contacted MEMS structure. By way of example, it has four mechanically deflectable structures 15, 16, 17, 18, two of which are arranged one above the other.
- the accesses required in the cap layer 10 for dissolving out the sacrificial material were hermetically sealed in the present case by plasma-assisted nonconformal deposition of an oxide 19 at low temperature, for example based on silane or TEOS.
- the plasma-assisted oxide deposition can be ensured by appropriate adjustment of the plasma parameters in coordination with the geometric boundary conditions of the access in the cap layer 10 that no too deep penetration of the plasma takes place in the structural cavities of the arrangement.
- the processing of bond pads 20 onto structures 13, which serve to make contact is preferably carried out with the aid of sputtering technology.
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Micromachines (AREA)
- Pressure Sensors (AREA)
Abstract
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102006032195A DE102006032195A1 (de) | 2006-07-12 | 2006-07-12 | Verfahren zur Herstellung von MEMS-Strukturen |
| PCT/EP2007/054988 WO2008006641A1 (fr) | 2006-07-12 | 2007-05-23 | Procédé de fabrication de structures mems |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP2051929A1 true EP2051929A1 (fr) | 2009-04-29 |
Family
ID=38458788
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP07729426A Withdrawn EP2051929A1 (fr) | 2006-07-12 | 2007-05-23 | Procédé de fabrication de structures mems |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US20100297781A1 (fr) |
| EP (1) | EP2051929A1 (fr) |
| JP (1) | JP2009542452A (fr) |
| DE (1) | DE102006032195A1 (fr) |
| WO (1) | WO2008006641A1 (fr) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2932923B1 (fr) | 2008-06-23 | 2011-03-25 | Commissariat Energie Atomique | Substrat heterogene comportant une couche sacrificielle et son procede de realisation. |
| FR2932788A1 (fr) * | 2008-06-23 | 2009-12-25 | Commissariat Energie Atomique | Procede de fabrication d'un composant electromecanique mems / nems. |
| DE102009029202B4 (de) | 2009-09-04 | 2017-05-24 | Robert Bosch Gmbh | Verfahren zum Herstellen eines mikromechanischen Systems |
| WO2011154363A2 (fr) * | 2010-06-07 | 2011-12-15 | Commissariat à l'énergie atomique et aux énergies alternatives | Dispositif d'analyse comportant un réseau mems et/ou nems |
| US8633088B2 (en) | 2012-04-30 | 2014-01-21 | Freescale Semiconductor, Inc. | Glass frit wafer bond protective structure |
| DE102013212118B4 (de) * | 2013-06-25 | 2025-06-26 | Robert Bosch Gmbh | Sensorsystem mit zwei Inertialsensoren |
| DE102015206996B4 (de) | 2015-04-17 | 2025-05-22 | Robert Bosch Gmbh | Verfahren zum Herstellen von mikroelektromechanischen Strukturen in einer Schichtenfolge und ein entsprechendes elektronisches Bauelement mit einer mikroelektromechanischen Struktur |
| CN112666236A (zh) * | 2020-04-17 | 2021-04-16 | 华中科技大学 | 一种传感器集成芯片及其制备 |
| IT202000011755A1 (it) * | 2020-05-20 | 2021-11-20 | St Microelectronics Srl | Procedimento di fabbricazione di un dispositivo micro-elettro-meccanico, in particolare sensore di movimento con comando/rilevazione di tipo capacitivo, e relativo dispositivo mems |
| DE102021213259A1 (de) | 2021-11-25 | 2023-05-25 | Robert Bosch Gesellschaft mit beschränkter Haftung | Verfahren zur Herstellung eines Cavity SOI Substrats und mikromechanischen Strukturen darin |
| DE102022208514A1 (de) | 2022-08-17 | 2024-02-22 | Robert Bosch Gesellschaft mit beschränkter Haftung | Verfahren zur Herstellung von mikroelektromechanischen Strukturen |
| DE102023102347A1 (de) | 2023-01-31 | 2024-08-01 | Carl Zeiss Smt Gmbh | Optisches Bauelement |
| DE102023206603A1 (de) | 2023-07-12 | 2025-01-16 | Robert Bosch Gesellschaft mit beschränkter Haftung | Verfahren zum Verarbeiten eines Halbleiter-Wafers und Montageschablone |
| US20250033951A1 (en) * | 2023-07-28 | 2025-01-30 | Lawrence Semiconductor Research Laboratory, Inc. | Anchor structure |
| DE102023123480A1 (de) | 2023-08-31 | 2025-03-06 | Carl Zeiss Smt Gmbh | Verlagerungseinrichtung und optisches Bauelement |
| DE102023211098A1 (de) | 2023-11-10 | 2025-05-15 | Robert Bosch Gesellschaft mit beschränkter Haftung | Verfahren zum Transferieren von Chips eines Wafers und entsprechende Vorrichtung |
| US20250187901A1 (en) * | 2023-12-08 | 2025-06-12 | Lawrence Semiconductor Research Laboratory, Inc. | Micro-electro-mechanical systems (mems) having vertical stops and anchor structures |
| DE102024200570A1 (de) | 2024-01-23 | 2025-07-24 | Robert Bosch Gesellschaft mit beschränkter Haftung | Verfahren zur Herstellung von MEMS-Baugruppen |
| DE102024201175A1 (de) * | 2024-02-09 | 2025-08-14 | Robert Bosch Gesellschaft mit beschränkter Haftung | Verfahren zum Herstellen eines gekoppelten Wafers |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10017976A1 (de) * | 2000-04-11 | 2001-10-18 | Bosch Gmbh Robert | Mikromechanisches Bauelement und entsprechendes Herstellungsverfahren |
| DE10065013B4 (de) * | 2000-12-23 | 2009-12-24 | Robert Bosch Gmbh | Verfahren zum Herstellen eines mikromechanischen Bauelements |
| US6790699B2 (en) * | 2002-07-10 | 2004-09-14 | Robert Bosch Gmbh | Method for manufacturing a semiconductor device |
| US6808953B2 (en) * | 2002-12-31 | 2004-10-26 | Robert Bosch Gmbh | Gap tuning for surface micromachined structures in an epitaxial reactor |
| US7075160B2 (en) * | 2003-06-04 | 2006-07-11 | Robert Bosch Gmbh | Microelectromechanical systems and devices having thin film encapsulated mechanical structures |
| FR2857952B1 (fr) * | 2003-07-25 | 2005-12-16 | St Microelectronics Sa | Resonateur electromecanique et procede de fabrication d'un tel resonateur |
| US7902008B2 (en) * | 2005-08-03 | 2011-03-08 | Globalfoundries Inc. | Methods for fabricating a stressed MOS device |
-
2006
- 2006-07-12 DE DE102006032195A patent/DE102006032195A1/de not_active Withdrawn
-
2007
- 2007-05-23 JP JP2009518807A patent/JP2009542452A/ja not_active Withdrawn
- 2007-05-23 US US12/308,530 patent/US20100297781A1/en not_active Abandoned
- 2007-05-23 EP EP07729426A patent/EP2051929A1/fr not_active Withdrawn
- 2007-05-23 WO PCT/EP2007/054988 patent/WO2008006641A1/fr not_active Ceased
Non-Patent Citations (1)
| Title |
|---|
| See references of WO2008006641A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2009542452A (ja) | 2009-12-03 |
| WO2008006641A1 (fr) | 2008-01-17 |
| DE102006032195A1 (de) | 2008-01-24 |
| US20100297781A1 (en) | 2010-11-25 |
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