EP2061596A1 - Catalyseurs à base de précurseurs vpo présentant une granulométrie définie, leur production et leur utilisation - Google Patents

Catalyseurs à base de précurseurs vpo présentant une granulométrie définie, leur production et leur utilisation

Info

Publication number
EP2061596A1
EP2061596A1 EP07788271A EP07788271A EP2061596A1 EP 2061596 A1 EP2061596 A1 EP 2061596A1 EP 07788271 A EP07788271 A EP 07788271A EP 07788271 A EP07788271 A EP 07788271A EP 2061596 A1 EP2061596 A1 EP 2061596A1
Authority
EP
European Patent Office
Prior art keywords
catalyst
precursor
vpo
agglomerates
additive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP07788271A
Other languages
German (de)
English (en)
Inventor
Andreas Raichle
Cornelia Dobner
Gunter Scherhag
Thomas Grassler
Andreas Kern
Martin Karches
Peter Walzel
Karsten Monse
Gerhard Schaldach
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to EP07788271A priority Critical patent/EP2061596A1/fr
Publication of EP2061596A1 publication Critical patent/EP2061596A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/34—Mechanical properties
    • B01J35/38—Abrasion or attrition resistance
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0045—Drying a slurry, e.g. spray drying
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/20—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state
    • B01J35/23—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state in a colloidal state
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/34—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation
    • B01J37/341—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation making use of electric or magnetic fields, wave energy or particle radiation
    • B01J37/343—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation making use of electric or magnetic fields, wave energy or particle radiation of ultrasonic wave energy

Definitions

  • the promoter components are added before, during or after the reaction of the vanadium pentoxide in the presence of the reducing organic solvent or with the phosphorus compound. Alternatively, it is possible to add it after completion of the precipitation (preferably at reduced temperature) and, if appropriate, a renewed heating.
  • the content of promoters is generally in total in the finished catalyst generally not more than about 5 wt .-%, each calculated as oxide.
  • the proportion of crystalline vanadyl pyrophosphate can be adjusted.
  • the catalysts of the invention can be used for the gas phase oxidation of hydrocarbons, in particular for the production of maleic anhydride by gas phase oxidation of hydrocarbons having at least four carbon atoms.
  • the process according to the invention can be carried out at a pressure below normal pressure (for example up to 0.05 MPa abs) or above normal pressure (for example up to 10 MPa abs). Preference is given to a pressure of 0.1 to 1.0 MPa abs, more preferably 0.15 to 0.7 MPa abs.
  • Catalyst precursor D-1 was prepared as in Example A-1, with the difference that instead of VPO precursor A, the significantly coarser VPO precursor D was used.
  • the catalyst prepared in this way was examined for its abrasion resistance (compare abrasion test) and its catalytic performance (see catalytic tests). The corresponding values are summarized in Table 5.
  • the preparation of the catalyst 3 was carried out as described in Example 1, with the difference that instead of the catalyst precursor A-1, the catalyst precursor A-2 was used.
  • the catalyst prepared in this way was examined for its abrasion resistance (compare abrasion test) and its catalytic performance (see catalytic tests). The corresponding values are summarized in Table 5. Due to the coarser SiO 2 species used, the catalyst shows a still acceptable, but not optimal abrasion resistance.
  • the preparation of the catalyst 5 was carried out as described in Example 1, with the difference that instead of the catalyst precursor A-1, the catalyst precursor C-1 was used.
  • the catalyst prepared in this way was examined for its abrasion resistance (compare abrasion test) and its catalytic performance (see catalytic tests). The corresponding values are summarized in Table 5. With good abrasion resistance, the yield of MSA achievable with this catalyst is clearly below the target value due to the encapsulation with SiC "2.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)

Abstract

L'invention concerne un précurseur de catalyseur ou un catalyseur et un procédé de production correspondant par : a) production d'une suspension contenant un précurseur à base de vanadium, phosphore et oxygène (précurseur VPO) dont les particules primaires dispersées par des ultrasons dans une solution aqueuse présentent un diamètre moyen (d<SUB>50</SUB> <SUB>,</SUB>
EP07788271A 2006-08-23 2007-08-07 Catalyseurs à base de précurseurs vpo présentant une granulométrie définie, leur production et leur utilisation Withdrawn EP2061596A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP07788271A EP2061596A1 (fr) 2006-08-23 2007-08-07 Catalyseurs à base de précurseurs vpo présentant une granulométrie définie, leur production et leur utilisation

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP06119373 2006-08-23
PCT/EP2007/058167 WO2008022911A1 (fr) 2006-08-23 2007-08-07 Catalyseurs à base de précurseurs vpo présentant une granulométrie définie, leur production et leur utilisation
EP07788271A EP2061596A1 (fr) 2006-08-23 2007-08-07 Catalyseurs à base de précurseurs vpo présentant une granulométrie définie, leur production et leur utilisation

Publications (1)

Publication Number Publication Date
EP2061596A1 true EP2061596A1 (fr) 2009-05-27

Family

ID=38596633

Family Applications (1)

Application Number Title Priority Date Filing Date
EP07788271A Withdrawn EP2061596A1 (fr) 2006-08-23 2007-08-07 Catalyseurs à base de précurseurs vpo présentant une granulométrie définie, leur production et leur utilisation

Country Status (2)

Country Link
EP (1) EP2061596A1 (fr)
WO (1) WO2008022911A1 (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1852413A1 (fr) 2006-04-27 2007-11-07 Basf Aktiengesellschaft Procédé d'oxydation en pase gazeeuse utilisant un couche modérateur
ES2343443T3 (es) 2006-05-19 2010-07-30 Basf Se Obtencion de anhidrido de acido ftalico a traves de la oxidacion en fase gaseosa de o-xileno en un reactor principal y un postreactor.
WO2007135104A1 (fr) 2006-05-19 2007-11-29 Basf Se Production d'anhydride phtalique par oxydation en phase gazeuse d'o-xylol
BRPI0720411A2 (pt) 2006-12-21 2013-12-31 Basf Se Processo para oxidação em fase gasosa, e, sistema catalisador para a realização de processos de oxidação em fase gasosa
WO2009124946A1 (fr) 2008-04-07 2009-10-15 Basf Se Procédé de démarrage d'un réacteur d'oxydation en phase gazeuse
CN116060061B (zh) * 2021-10-31 2024-05-31 中国石油化工股份有限公司 一种钒磷氧催化剂前驱体粉末及由其制备的催化剂

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4677084A (en) * 1985-11-27 1987-06-30 E. I. Du Pont De Nemours And Company Attrition resistant catalysts, catalyst precursors and catalyst supports and process for preparing same
JP2895142B2 (ja) * 1989-02-23 1999-05-24 三井化学株式会社 触媒先駆体および対応する触媒の製造法
US5302566A (en) * 1993-01-25 1994-04-12 E. I. Du Pont De Nemours And Company Process for preparing attrition resistant catalysts
JPH078800A (ja) * 1993-06-29 1995-01-13 Mitsubishi Chem Corp バナジウム及びリンを含む酸化物流動触媒の製造法
US6878668B1 (en) * 1999-07-14 2005-04-12 E. I. Du Pont De Nemours And Company Process for manufacture of an attrition resistant catalyst

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO2008022911A1 *

Also Published As

Publication number Publication date
WO2008022911A1 (fr) 2008-02-28

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