EP2087029A2 - Mit wärmemittel versetzter silikonschaum und verwendung des schaums - Google Patents

Mit wärmemittel versetzter silikonschaum und verwendung des schaums

Info

Publication number
EP2087029A2
EP2087029A2 EP07866481A EP07866481A EP2087029A2 EP 2087029 A2 EP2087029 A2 EP 2087029A2 EP 07866481 A EP07866481 A EP 07866481A EP 07866481 A EP07866481 A EP 07866481A EP 2087029 A2 EP2087029 A2 EP 2087029A2
Authority
EP
European Patent Office
Prior art keywords
silicone foam
foam according
resin
silicone
agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP07866481A
Other languages
English (en)
French (fr)
Inventor
Thierry Guenard
Jean-Claude Boulanger
Annick Boccara
Claude Boccara
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SNCF Mobilites
FOTIA COMPOSITE
Original Assignee
SNCF Mobilites
FOTIA COMPOSITE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SNCF Mobilites, FOTIA COMPOSITE filed Critical SNCF Mobilites
Publication of EP2087029A2 publication Critical patent/EP2087029A2/de
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0014Use of organic additives
    • C08J9/0038Use of organic additives containing phosphorus
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0066Use of inorganic compounding ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/32Phosphorus-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/36Silica
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04Polysiloxanes
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62CFIRE-FIGHTING
    • A62C99/00Subject matter not provided for in other groups of this subclass
    • A62C99/0009Methods of extinguishing or preventing the spread of fire by cooling down or suffocating the flames
    • A62C99/0045Methods of extinguishing or preventing the spread of fire by cooling down or suffocating the flames using solid substances, e.g. sand, ashes; using substances forming a crust
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60RVEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
    • B60R13/00Elements for body-finishing, identifying, or decorating; Arrangements or adaptations for advertising purposes
    • B60R13/08Insulating elements, e.g. for sound insulation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2383/00Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
    • C08J2383/04Polysiloxanes

Definitions

  • the French patent application 05 05 848 relates to a corrosion protection treatment process for hollow bodies, in particular in the railway field, using a cellular foam, support of an anti-corrosion agent and flame retardant or thermal insulation.
  • treatment foam it is envisaged in this application to consider a silicone foam. It is also contemplated a composition of PCT / BE 95/00 106, that is to say an inorganic resin comprising an aqueous solution of a metal phosphate of aluminum, zirconium, magnesium, zinc, calcium or iron, an oxy-boron compound and a wollastonite compound.
  • US H 1976 H also relates to an expanded corrosion-resistant plastic polymer for hollow bodies, more specifically a closed-cell foam and more specifically a diisocyanate resin.
  • DE 103 35 746 relates to a liquid cold corrosion resin for hollow bodies, which is foamed with the aid of a gas.
  • the invention of the present application also relates to corrosion protection of hollow bodies, but not exclusively. In its greater generality, it relates in fact to a thermal protection material, a barrier material and, in fact, a particular silicone foam.
  • the invention relates first of all to a silicone foam, comprising a mixture of silica, a polyorganosiloxane resin and a polyorganosiloxane hardener, added with a thermal insulator.
  • the silicone foam under the action of fire, transforms itself into silica. It is a self-extinguishing material.
  • foam applications of the invention are excessively numerous and varied, whether for use in filling or partitioning.
  • thermal insulation of the ammonium polyphosphate is considered.
  • the foam contains the resin and the hardener in equal amounts by weight.
  • the foam contains less than 10% by weight of thermal insulation, preferably about 5% by weight of the resin.
  • the resin and hardener are products marketed by Rhodia under the protected names Rhodorsil RT foam 3240 A and B, respectively ®.
  • the foam of the invention may contain an adhesion promoter, in this case raminopropyltriethoxysilane-3, in an amount of about 1 to 3% by weight of the resin, preferably the agent marketed by the company Wacker- Chemie under the protected name Geniosil GF 93 ® '
  • the foam of the invention may also contain, as an anticorrosive agent, in an amount of approximately 1% of the weight of the resin, a calcium soap, preferably the product marketed by Lockhart Chemical under the protected name Lockguard S 8855 ® . -
  • the foam of the invention may also contain a soundproofing agent, preferably barium sulfate, preferably in an amount of about 3 to 15% by weight of the resin.
  • the resin and its hardener are in liquid form, as are the adhesion promoter Geniosil and the anti-corrosion agent Lockguard ®, while the barium sulfate and the ammonium polyphosphate are powdered.
  • the above-mentioned resin and functional charges can be first mixed in a mixer, with trial and error determination until the desired proportions are achieved.
  • the primary mixture thus obtained is then mixed and homogenized with the resin just before injecting, pouring or filling the final mixture product into the body to be treated or at the place of application, before the mixing reaction takes place. continues exothermically and the foam is not properly formed and is properly spread and applied. By cooling then, a skin effect occurs which contributes to the seal and contributes to ensuring an anti-corrosion function due to the absence of cells on the surface.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Acoustics & Sound (AREA)
  • Mechanical Engineering (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
EP07866481A 2006-10-31 2007-10-31 Mit wärmemittel versetzter silikonschaum und verwendung des schaums Withdrawn EP2087029A2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0609566A FR2907787B1 (fr) 2006-10-31 2006-10-31 Mousse silicone additionnee d'un agent thermique et utilisations de la mousse
PCT/FR2007/001814 WO2008059142A2 (fr) 2006-10-31 2007-10-31 Mousse silicone additionnée d'un agent thermique et utilisations de la mousse

Publications (1)

Publication Number Publication Date
EP2087029A2 true EP2087029A2 (de) 2009-08-12

Family

ID=38229349

Family Applications (1)

Application Number Title Priority Date Filing Date
EP07866481A Withdrawn EP2087029A2 (de) 2006-10-31 2007-10-31 Mit wärmemittel versetzter silikonschaum und verwendung des schaums

Country Status (9)

Country Link
US (1) US20110021648A1 (de)
EP (1) EP2087029A2 (de)
JP (1) JP2010508381A (de)
KR (1) KR20090106460A (de)
CN (1) CN101558108A (de)
BR (1) BRPI0716293A2 (de)
FR (1) FR2907787B1 (de)
MA (1) MA30958B1 (de)
WO (1) WO2008059142A2 (de)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8056953B2 (en) 2008-06-13 2011-11-15 Itt Manufacturing Enterprises, Inc. Thermal barrier system
US20160179140A1 (en) * 2014-12-20 2016-06-23 Intel Corporation Chassis Design for Wireless-Charging Coil Integration for Computing Systems

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2318195A1 (fr) * 1975-07-14 1977-02-11 Dow Corning Composition et procede pour la fabrication d'eponges et mousses de caoutchouc de silicone
FR2593184A1 (fr) * 1986-01-21 1987-07-24 Rhone Poulenc Spec Chim Agent porophore pour composition organopolysiloxane transformable en mousse

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1240403A (en) * 1969-02-03 1971-07-21 Ass Elect Ind Improvements in or relating to electrical insulating compositions
US4433069A (en) * 1983-01-03 1984-02-21 Dow Corning Corporation Method for preparing flame resistant polysiloxane foams and foams prepared thereby
JPS6243435A (ja) * 1985-08-20 1987-02-25 Shin Etsu Chem Co Ltd 耐火性シリコ−ン発泡体組成物
DE3602888A1 (de) * 1986-01-31 1987-08-06 Bayer Ag Intumeszierende polysiloxan-formmassen
US4686244A (en) * 1986-12-17 1987-08-11 Dow Corning Corporation Intumescent foamable compositions
US4978705A (en) * 1987-12-24 1990-12-18 Dow Corning Corporation Silicone rubber containing alkali metal salts of phosphoric acid and phosphorous acid and compositions therefor
JPH0427052A (ja) * 1990-05-21 1992-01-30 Matsushita Electric Works Ltd 遮音材
DE4120561A1 (de) * 1991-06-21 1992-12-24 Hilti Ag Haft-, dicht- und klebemasse auf silikonbasis
US5183873A (en) * 1991-10-21 1993-02-02 Wacker Silicones Corporation Room temperature stable organopolysiloxane compositions
JP3523950B2 (ja) * 1995-12-04 2004-04-26 タイホー工業株式会社 車両塗装面用処理剤
JP3600884B2 (ja) * 1996-05-15 2004-12-15 株式会社カネカ 発泡性樹脂組成物、及びこれを用いた発泡体とその製造方法
RU2111982C1 (ru) * 1996-05-20 1998-05-27 Общественное объединение "Евразийское физическое общество" Способ получения вспениваемых кремнийорганических композиций
DE19620816A1 (de) * 1996-05-23 1997-11-27 Wacker Chemie Gmbh Zu flammabweisende Elastomere vernetzbare Organopolysiloxanmassen
USH1976H1 (en) * 1999-07-30 2001-08-07 The United States Of America As Represented By The Secretary Of The Navy Corrosion control in hollow frame structures
DE10007977B4 (de) * 2000-02-22 2004-07-29 Hilti Ag Additivmischung zur Erhöhung der Brandfestigkeit von Kunststoff-Formkörpern, Kunststoff-Formkörper und Zweikomponentensystem zu ihrer Herstellung

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2318195A1 (fr) * 1975-07-14 1977-02-11 Dow Corning Composition et procede pour la fabrication d'eponges et mousses de caoutchouc de silicone
FR2593184A1 (fr) * 1986-01-21 1987-07-24 Rhone Poulenc Spec Chim Agent porophore pour composition organopolysiloxane transformable en mousse

Also Published As

Publication number Publication date
CN101558108A (zh) 2009-10-14
FR2907787B1 (fr) 2010-05-21
BRPI0716293A2 (pt) 2013-12-31
WO2008059142A3 (fr) 2008-08-07
JP2010508381A (ja) 2010-03-18
US20110021648A1 (en) 2011-01-27
FR2907787A1 (fr) 2008-05-02
KR20090106460A (ko) 2009-10-09
WO2008059142A2 (fr) 2008-05-22
MA30958B1 (fr) 2009-12-01

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