EP2087029A2 - Mit wärmemittel versetzter silikonschaum und verwendung des schaums - Google Patents
Mit wärmemittel versetzter silikonschaum und verwendung des schaumsInfo
- Publication number
- EP2087029A2 EP2087029A2 EP07866481A EP07866481A EP2087029A2 EP 2087029 A2 EP2087029 A2 EP 2087029A2 EP 07866481 A EP07866481 A EP 07866481A EP 07866481 A EP07866481 A EP 07866481A EP 2087029 A2 EP2087029 A2 EP 2087029A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- silicone foam
- foam according
- resin
- silicone
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000006260 foam Substances 0.000 title claims abstract description 18
- 229920002323 Silicone foam Polymers 0.000 title claims description 31
- 239000013514 silicone foam Substances 0.000 title claims description 31
- 239000011347 resin Substances 0.000 claims abstract description 21
- 229920005989 resin Polymers 0.000 claims abstract description 21
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000012212 insulator Substances 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims abstract description 6
- 239000004114 Ammonium polyphosphate Substances 0.000 claims abstract description 4
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims abstract description 4
- 229920001276 ammonium polyphosphate Polymers 0.000 claims abstract description 4
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 4
- 238000000638 solvent extraction Methods 0.000 claims abstract description 3
- 239000000945 filler Substances 0.000 claims abstract 2
- 239000004848 polyfunctional curative Substances 0.000 claims description 7
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical group [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 6
- 238000009413 insulation Methods 0.000 claims description 6
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 5
- 229910052791 calcium Inorganic materials 0.000 claims description 5
- 239000011575 calcium Substances 0.000 claims description 5
- 239000002318 adhesion promoter Substances 0.000 claims description 4
- 239000000344 soap Substances 0.000 claims description 4
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 claims description 2
- 238000003860 storage Methods 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims description 2
- 239000000853 adhesive Substances 0.000 claims 1
- 239000007767 bonding agent Substances 0.000 claims 1
- 229920001296 polysiloxane Polymers 0.000 claims 1
- 238000005260 corrosion Methods 0.000 description 7
- 230000007797 corrosion Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 230000004888 barrier function Effects 0.000 description 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 125000005442 diisocyanate group Chemical group 0.000 description 1
- 230000002500 effect on skin Effects 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910001463 metal phosphate Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0014—Use of organic additives
- C08J9/0038—Use of organic additives containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0066—Use of inorganic compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62C—FIRE-FIGHTING
- A62C99/00—Subject matter not provided for in other groups of this subclass
- A62C99/0009—Methods of extinguishing or preventing the spread of fire by cooling down or suffocating the flames
- A62C99/0045—Methods of extinguishing or preventing the spread of fire by cooling down or suffocating the flames using solid substances, e.g. sand, ashes; using substances forming a crust
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
- B60R13/00—Elements for body-finishing, identifying, or decorating; Arrangements or adaptations for advertising purposes
- B60R13/08—Insulating elements, e.g. for sound insulation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2383/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
- C08J2383/04—Polysiloxanes
Definitions
- the French patent application 05 05 848 relates to a corrosion protection treatment process for hollow bodies, in particular in the railway field, using a cellular foam, support of an anti-corrosion agent and flame retardant or thermal insulation.
- treatment foam it is envisaged in this application to consider a silicone foam. It is also contemplated a composition of PCT / BE 95/00 106, that is to say an inorganic resin comprising an aqueous solution of a metal phosphate of aluminum, zirconium, magnesium, zinc, calcium or iron, an oxy-boron compound and a wollastonite compound.
- US H 1976 H also relates to an expanded corrosion-resistant plastic polymer for hollow bodies, more specifically a closed-cell foam and more specifically a diisocyanate resin.
- DE 103 35 746 relates to a liquid cold corrosion resin for hollow bodies, which is foamed with the aid of a gas.
- the invention of the present application also relates to corrosion protection of hollow bodies, but not exclusively. In its greater generality, it relates in fact to a thermal protection material, a barrier material and, in fact, a particular silicone foam.
- the invention relates first of all to a silicone foam, comprising a mixture of silica, a polyorganosiloxane resin and a polyorganosiloxane hardener, added with a thermal insulator.
- the silicone foam under the action of fire, transforms itself into silica. It is a self-extinguishing material.
- foam applications of the invention are excessively numerous and varied, whether for use in filling or partitioning.
- thermal insulation of the ammonium polyphosphate is considered.
- the foam contains the resin and the hardener in equal amounts by weight.
- the foam contains less than 10% by weight of thermal insulation, preferably about 5% by weight of the resin.
- the resin and hardener are products marketed by Rhodia under the protected names Rhodorsil RT foam 3240 A and B, respectively ®.
- the foam of the invention may contain an adhesion promoter, in this case raminopropyltriethoxysilane-3, in an amount of about 1 to 3% by weight of the resin, preferably the agent marketed by the company Wacker- Chemie under the protected name Geniosil GF 93 ® '
- the foam of the invention may also contain, as an anticorrosive agent, in an amount of approximately 1% of the weight of the resin, a calcium soap, preferably the product marketed by Lockhart Chemical under the protected name Lockguard S 8855 ® . -
- the foam of the invention may also contain a soundproofing agent, preferably barium sulfate, preferably in an amount of about 3 to 15% by weight of the resin.
- the resin and its hardener are in liquid form, as are the adhesion promoter Geniosil and the anti-corrosion agent Lockguard ®, while the barium sulfate and the ammonium polyphosphate are powdered.
- the above-mentioned resin and functional charges can be first mixed in a mixer, with trial and error determination until the desired proportions are achieved.
- the primary mixture thus obtained is then mixed and homogenized with the resin just before injecting, pouring or filling the final mixture product into the body to be treated or at the place of application, before the mixing reaction takes place. continues exothermically and the foam is not properly formed and is properly spread and applied. By cooling then, a skin effect occurs which contributes to the seal and contributes to ensuring an anti-corrosion function due to the absence of cells on the surface.
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Acoustics & Sound (AREA)
- Mechanical Engineering (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0609566A FR2907787B1 (fr) | 2006-10-31 | 2006-10-31 | Mousse silicone additionnee d'un agent thermique et utilisations de la mousse |
| PCT/FR2007/001814 WO2008059142A2 (fr) | 2006-10-31 | 2007-10-31 | Mousse silicone additionnée d'un agent thermique et utilisations de la mousse |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP2087029A2 true EP2087029A2 (de) | 2009-08-12 |
Family
ID=38229349
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP07866481A Withdrawn EP2087029A2 (de) | 2006-10-31 | 2007-10-31 | Mit wärmemittel versetzter silikonschaum und verwendung des schaums |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US20110021648A1 (de) |
| EP (1) | EP2087029A2 (de) |
| JP (1) | JP2010508381A (de) |
| KR (1) | KR20090106460A (de) |
| CN (1) | CN101558108A (de) |
| BR (1) | BRPI0716293A2 (de) |
| FR (1) | FR2907787B1 (de) |
| MA (1) | MA30958B1 (de) |
| WO (1) | WO2008059142A2 (de) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8056953B2 (en) | 2008-06-13 | 2011-11-15 | Itt Manufacturing Enterprises, Inc. | Thermal barrier system |
| US20160179140A1 (en) * | 2014-12-20 | 2016-06-23 | Intel Corporation | Chassis Design for Wireless-Charging Coil Integration for Computing Systems |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2318195A1 (fr) * | 1975-07-14 | 1977-02-11 | Dow Corning | Composition et procede pour la fabrication d'eponges et mousses de caoutchouc de silicone |
| FR2593184A1 (fr) * | 1986-01-21 | 1987-07-24 | Rhone Poulenc Spec Chim | Agent porophore pour composition organopolysiloxane transformable en mousse |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1240403A (en) * | 1969-02-03 | 1971-07-21 | Ass Elect Ind | Improvements in or relating to electrical insulating compositions |
| US4433069A (en) * | 1983-01-03 | 1984-02-21 | Dow Corning Corporation | Method for preparing flame resistant polysiloxane foams and foams prepared thereby |
| JPS6243435A (ja) * | 1985-08-20 | 1987-02-25 | Shin Etsu Chem Co Ltd | 耐火性シリコ−ン発泡体組成物 |
| DE3602888A1 (de) * | 1986-01-31 | 1987-08-06 | Bayer Ag | Intumeszierende polysiloxan-formmassen |
| US4686244A (en) * | 1986-12-17 | 1987-08-11 | Dow Corning Corporation | Intumescent foamable compositions |
| US4978705A (en) * | 1987-12-24 | 1990-12-18 | Dow Corning Corporation | Silicone rubber containing alkali metal salts of phosphoric acid and phosphorous acid and compositions therefor |
| JPH0427052A (ja) * | 1990-05-21 | 1992-01-30 | Matsushita Electric Works Ltd | 遮音材 |
| DE4120561A1 (de) * | 1991-06-21 | 1992-12-24 | Hilti Ag | Haft-, dicht- und klebemasse auf silikonbasis |
| US5183873A (en) * | 1991-10-21 | 1993-02-02 | Wacker Silicones Corporation | Room temperature stable organopolysiloxane compositions |
| JP3523950B2 (ja) * | 1995-12-04 | 2004-04-26 | タイホー工業株式会社 | 車両塗装面用処理剤 |
| JP3600884B2 (ja) * | 1996-05-15 | 2004-12-15 | 株式会社カネカ | 発泡性樹脂組成物、及びこれを用いた発泡体とその製造方法 |
| RU2111982C1 (ru) * | 1996-05-20 | 1998-05-27 | Общественное объединение "Евразийское физическое общество" | Способ получения вспениваемых кремнийорганических композиций |
| DE19620816A1 (de) * | 1996-05-23 | 1997-11-27 | Wacker Chemie Gmbh | Zu flammabweisende Elastomere vernetzbare Organopolysiloxanmassen |
| USH1976H1 (en) * | 1999-07-30 | 2001-08-07 | The United States Of America As Represented By The Secretary Of The Navy | Corrosion control in hollow frame structures |
| DE10007977B4 (de) * | 2000-02-22 | 2004-07-29 | Hilti Ag | Additivmischung zur Erhöhung der Brandfestigkeit von Kunststoff-Formkörpern, Kunststoff-Formkörper und Zweikomponentensystem zu ihrer Herstellung |
-
2006
- 2006-10-31 FR FR0609566A patent/FR2907787B1/fr active Active
-
2007
- 2007-10-31 EP EP07866481A patent/EP2087029A2/de not_active Withdrawn
- 2007-10-31 US US12/447,681 patent/US20110021648A1/en not_active Abandoned
- 2007-10-31 JP JP2009533907A patent/JP2010508381A/ja active Pending
- 2007-10-31 CN CNA2007800406225A patent/CN101558108A/zh active Pending
- 2007-10-31 BR BRPI0716293-6A2A patent/BRPI0716293A2/pt not_active IP Right Cessation
- 2007-10-31 WO PCT/FR2007/001814 patent/WO2008059142A2/fr not_active Ceased
- 2007-10-31 KR KR1020097010202A patent/KR20090106460A/ko not_active Withdrawn
-
2009
- 2009-05-21 MA MA31903A patent/MA30958B1/fr unknown
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2318195A1 (fr) * | 1975-07-14 | 1977-02-11 | Dow Corning | Composition et procede pour la fabrication d'eponges et mousses de caoutchouc de silicone |
| FR2593184A1 (fr) * | 1986-01-21 | 1987-07-24 | Rhone Poulenc Spec Chim | Agent porophore pour composition organopolysiloxane transformable en mousse |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101558108A (zh) | 2009-10-14 |
| FR2907787B1 (fr) | 2010-05-21 |
| BRPI0716293A2 (pt) | 2013-12-31 |
| WO2008059142A3 (fr) | 2008-08-07 |
| JP2010508381A (ja) | 2010-03-18 |
| US20110021648A1 (en) | 2011-01-27 |
| FR2907787A1 (fr) | 2008-05-02 |
| KR20090106460A (ko) | 2009-10-09 |
| WO2008059142A2 (fr) | 2008-05-22 |
| MA30958B1 (fr) | 2009-12-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| 17P | Request for examination filed |
Effective date: 20090526 |
|
| AK | Designated contracting states |
Kind code of ref document: A2 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC MT NL PL PT RO SE SI SK TR |
|
| 17Q | First examination report despatched |
Effective date: 20090925 |
|
| DAX | Request for extension of the european patent (deleted) | ||
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
|
| 18D | Application deemed to be withdrawn |
Effective date: 20150130 |