EP2087072A4 - Système catalytique permettant de convertir les combustibles liquides en gaz de synthèse - Google Patents

Système catalytique permettant de convertir les combustibles liquides en gaz de synthèse

Info

Publication number
EP2087072A4
EP2087072A4 EP07861577A EP07861577A EP2087072A4 EP 2087072 A4 EP2087072 A4 EP 2087072A4 EP 07861577 A EP07861577 A EP 07861577A EP 07861577 A EP07861577 A EP 07861577A EP 2087072 A4 EP2087072 A4 EP 2087072A4
Authority
EP
European Patent Office
Prior art keywords
syngas
catalytic system
liquid fuels
converting liquid
converting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP07861577A
Other languages
German (de)
English (en)
Other versions
EP2087072A2 (fr
Inventor
Maxim Lyubovsky
Subir Roychoudhury
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Precision Combustion Inc
Original Assignee
Precision Combustion Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Precision Combustion Inc filed Critical Precision Combustion Inc
Publication of EP2087072A2 publication Critical patent/EP2087072A2/fr
Publication of EP2087072A4 publication Critical patent/EP2087072A4/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/382—Processes with two or more reaction steps, of which at least one is catalytic, e.g. steam reforming and partial oxidation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20—Mixing gases with liquids
    • B01F23/21—Mixing gases with liquids by introducing liquids into gaseous media
    • B01F23/213—Mixing gases with liquids by introducing liquids into gaseous media by spraying or atomising of the liquids
    • B01F23/2132—Mixing gases with liquids by introducing liquids into gaseous media by spraying or atomising of the liquids using nozzles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0207—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly horizontal
    • B01J8/0214—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly horizontal in a cylindrical annular shaped bed
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0207—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly horizontal
    • B01J8/0221—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly horizontal in a cylindrical shaped bed
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0278—Feeding reactive fluids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0285—Heating or cooling the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • B01J8/0403—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal
    • B01J8/0423—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal through two or more otherwise shaped beds
    • B01J8/0426—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal through two or more otherwise shaped beds the beds being superimposed one above the other
    • B01J8/043—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal through two or more otherwise shaped beds the beds being superimposed one above the other in combination with one cylindrical annular shaped bed
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/386—Catalytic partial combustion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00203—Coils
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/0053—Controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00628—Controlling the composition of the reactive mixture
    • B01J2208/00646—Means for starting up the reaction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00716—Means for reactor start-up
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0261—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0455—Purification by non-catalytic desulfurisation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0485—Composition of the impurity the impurity being a sulfur compound
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0872—Methods of cooling
    • C01B2203/0888—Methods of cooling by evaporation of a fluid
    • C01B2203/0894—Generation of steam
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1276—Mixing of different feed components

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Hydrogen, Water And Hydrids (AREA)
EP07861577A 2006-11-03 2007-10-30 Système catalytique permettant de convertir les combustibles liquides en gaz de synthèse Withdrawn EP2087072A4 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/592,825 US20070151154A1 (en) 2005-11-04 2006-11-03 Catalytic system for converting liquid fuels into syngas
PCT/US2007/022891 WO2008057335A2 (fr) 2006-11-03 2007-10-30 Système catalytique permettant de convertir les combustibles liquides en gaz de synthèse

Publications (2)

Publication Number Publication Date
EP2087072A2 EP2087072A2 (fr) 2009-08-12
EP2087072A4 true EP2087072A4 (fr) 2011-08-17

Family

ID=39365026

Family Applications (1)

Application Number Title Priority Date Filing Date
EP07861577A Withdrawn EP2087072A4 (fr) 2006-11-03 2007-10-30 Système catalytique permettant de convertir les combustibles liquides en gaz de synthèse

Country Status (4)

Country Link
US (1) US20070151154A1 (fr)
EP (1) EP2087072A4 (fr)
CA (1) CA2667692C (fr)
WO (1) WO2008057335A2 (fr)

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US7810317B2 (en) * 2002-03-27 2010-10-12 Precision Combustion, Inc. Catalytic burner utilizing electrosprayed fuels
US7976594B2 (en) 2003-07-31 2011-07-12 Precision Combustion, Inc. Method and system for vaporization of liquid fuels
US8795398B2 (en) 2003-07-31 2014-08-05 Precision Combustion, Inc. Apparatus for vaporizing and reforming liquid fuels
US8557189B2 (en) * 2005-11-04 2013-10-15 Precision Combustion, Inc. Catalytic system for converting liquid fuels into syngas
US8444951B2 (en) * 2005-11-04 2013-05-21 Precision Combustion, Inc. Catalytic process and system for converting liquid fuels into syngas
US8479508B2 (en) * 2006-02-28 2013-07-09 Precision Combustion, Inc. Catalytic burner apparatus for stirling engine
US7913484B2 (en) * 2006-02-28 2011-03-29 Precision Combustion, Inc. Catalytic burner apparatus for stirling engine
US8387380B2 (en) * 2006-02-28 2013-03-05 Precision Combustion, Inc. Catalytic burner apparatus for Stirling Engine
US8337757B2 (en) 2008-02-07 2012-12-25 Precision Combustion, Inc. Reactor control method
US20090252661A1 (en) * 2008-04-07 2009-10-08 Subir Roychoudhury Fuel reformer
US9601261B2 (en) * 2008-09-27 2017-03-21 Witricity Corporation Wireless energy transfer using repeater resonators
US8439990B2 (en) * 2009-07-21 2013-05-14 Precision Combustion, Inc. Reactor flow control apparatus
US8739550B2 (en) * 2009-09-30 2014-06-03 Precision Combustion, Inc. Two stage combustor with reformer
US10690340B2 (en) 2010-01-06 2020-06-23 Precision Combustion, Inc. Flameless cooking appliance
US8562700B2 (en) 2010-08-30 2013-10-22 The United States Of America As Represented By The Secretary Of The Army Multi-functional compact fuel converter and a process for converting liquid fuel
US8784515B2 (en) 2010-10-14 2014-07-22 Precision Combustion, Inc. In-situ coke removal
WO2012106048A1 (fr) 2011-02-01 2012-08-09 Precision Combustion, Inc. Appareil et procédé pour vaporiser un combustible liquide
DE102013214313A1 (de) * 2013-07-22 2015-01-22 Bayerische Motoren Werke Aktiengesellschaft Reaktor zur Freisetzung von Wasserstoff aus flüssiger Verbindung
DE102013214314A1 (de) * 2013-07-22 2015-01-22 Bayerische Motoren Werke Aktiengesellschaft Reaktor zur Freisetzung von Wasserstoff aus einer flüssigen Verbindung
WO2015028540A1 (fr) * 2013-08-29 2015-03-05 Basf Se Dispositif et procédé de production d'acétylène et de gaz de synthèse
US10060344B1 (en) 2014-08-18 2018-08-28 Precision Combustion, Inc. Spark-ignited internal combustion engine modified for multi-fuel operation
CN107191978B (zh) * 2017-07-27 2023-03-14 重庆宙盾新能源技术开发有限公司 一种燃料灶
CN107246632B (zh) * 2017-07-27 2023-10-13 重庆宙盾新能源技术开发有限公司 一种醇基燃料灶
CN111322612A (zh) * 2018-12-14 2020-06-23 中国科学院大连化学物理研究所 一种低燃料消耗快速启动催化燃烧器的方法及其催化燃烧器

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US20020083646A1 (en) * 2000-12-05 2002-07-04 Deshpande Vijay A. Fuel processor for producing a hydrogen rich gas
US20020172630A1 (en) * 2001-03-23 2002-11-21 Shabbir Ahmed Fuel processor and method for generating hydrogen for fuel cells
US20030072700A1 (en) * 2001-10-15 2003-04-17 Goebel Steven G Reactor system including auto ignition and carbon suppression foam
US20030129108A1 (en) * 2002-01-10 2003-07-10 Burch Steven D. Fuel processor thermal management system
US20050028445A1 (en) * 2003-07-31 2005-02-10 Subir Roychoudhury Method and system for catalytic gasification of liquid fuels
US20050274107A1 (en) * 2004-06-14 2005-12-15 Ke Liu Reforming unvaporized, atomized hydrocarbon fuel

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US8557189B2 (en) * 2005-11-04 2013-10-15 Precision Combustion, Inc. Catalytic system for converting liquid fuels into syngas
US20080169449A1 (en) * 2006-09-08 2008-07-17 Eltron Research Inc. Catalytic membrane reactor and method for production of synthesis gas
US8337757B2 (en) * 2008-02-07 2012-12-25 Precision Combustion, Inc. Reactor control method
US20090252661A1 (en) * 2008-04-07 2009-10-08 Subir Roychoudhury Fuel reformer

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Publication number Priority date Publication date Assignee Title
US20020083646A1 (en) * 2000-12-05 2002-07-04 Deshpande Vijay A. Fuel processor for producing a hydrogen rich gas
US20020172630A1 (en) * 2001-03-23 2002-11-21 Shabbir Ahmed Fuel processor and method for generating hydrogen for fuel cells
US20030072700A1 (en) * 2001-10-15 2003-04-17 Goebel Steven G Reactor system including auto ignition and carbon suppression foam
US20030129108A1 (en) * 2002-01-10 2003-07-10 Burch Steven D. Fuel processor thermal management system
US20050028445A1 (en) * 2003-07-31 2005-02-10 Subir Roychoudhury Method and system for catalytic gasification of liquid fuels
US20050274107A1 (en) * 2004-06-14 2005-12-15 Ke Liu Reforming unvaporized, atomized hydrocarbon fuel

Also Published As

Publication number Publication date
WO2008057335A2 (fr) 2008-05-15
WO2008057335A3 (fr) 2008-09-25
CA2667692C (fr) 2015-07-21
US20070151154A1 (en) 2007-07-05
EP2087072A2 (fr) 2009-08-12
CA2667692A1 (fr) 2008-05-15

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