EP2092090A1 - Solution de phosphatage à base de zr/ti utilisée pour passiver des surfaces composites métalliques - Google Patents

Solution de phosphatage à base de zr/ti utilisée pour passiver des surfaces composites métalliques

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Publication number
EP2092090A1
EP2092090A1 EP07820181A EP07820181A EP2092090A1 EP 2092090 A1 EP2092090 A1 EP 2092090A1 EP 07820181 A EP07820181 A EP 07820181A EP 07820181 A EP07820181 A EP 07820181A EP 2092090 A1 EP2092090 A1 EP 2092090A1
Authority
EP
European Patent Office
Prior art keywords
aqueous composition
zirconium
steel
titanium
aluminum
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP07820181A
Other languages
German (de)
English (en)
Other versions
EP2092090B1 (fr
Inventor
Jan-Willem Brouwer
Jens KRÖMER
Matthias Hamacher
Stephan Winkels
Frank-Oliver Pilarek
Marc Balzer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Priority to SI200731183T priority Critical patent/SI2092090T1/sl
Priority to PL07820181T priority patent/PL2092090T3/pl
Publication of EP2092090A1 publication Critical patent/EP2092090A1/fr
Application granted granted Critical
Publication of EP2092090B1 publication Critical patent/EP2092090B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
    • C23C22/08—Orthophosphates
    • C23C22/12—Orthophosphates containing zinc cations
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
    • C23C22/36—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates
    • C23C22/364—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates containing also manganese cations
    • C23C22/365—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates containing also manganese cations containing also zinc and nickel cations
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/78—Pretreatment of the material to be coated
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/14—Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12736—Al-base component
    • Y10T428/1275—Next to Group VIII or IB metal-base component
    • Y10T428/12757—Fe

Definitions

  • the present invention relates to an aqueous composition and a process for the corrosion-protective conversion treatment of metallic surfaces.
  • the aqueous composition is particularly suitable for treating various metallic materials joined together in composite structures, including steel or galvanized or alloy galvanized steel, and any combination of these materials, which composite structure is at least partially composed of aluminum or its alloys.
  • the metallic surfaces of the composite structure treated according to the invention can be coated homogeneously and with excellent adhesion properties in a subsequent dip-coating
  • the clear advantage of the aqueous composition according to the invention for the treatment of metallic surfaces is the selective coating of different metal surfaces with a crystalline phosphate layer in the case of steel or galvanized or alloy-galvanized steel surfaces and a non-crystalline one Conversion layer on the aluminum surfaces such that an excellent passivation of the metallic surfaces and a sufficient paint adhesion for after following applied paint results.
  • the application of the aqueous composition according to the invention therefore enables a one-step process for the anticorrosion pretreatment of metal surfaces assembled in a composite structure.
  • a suitable masking of the aluminum ions can be achieved by the addition of fluoride ions or fluoro complexes eg SiF 6 2 " as disclosed in US 5,683,357 Depending on the strength of the pickling attack by the additional introduction of fluoride ions, hexafluoroaluminates can be obtained from the bath solution In addition, the formation of a phosphate layer on the aluminum surface takes place only at high pickling rates, ie a relatively high concentration of free fluoride The control of defined bath parameters, in particular of the free fluoride content, is of considerable importance for a sufficient corrosion protection and a good lacquer adhesion An insufficient phosphating of the aluminum surfaces always requires a post-passivation in a subsequent process step n are optical defects after the coating primer caused by a inhomogeneously deposited phosphate layer basically not curable.
  • DE10322446 uses a conventional phosphating and supplements them with water-soluble zirconium and / or titanium compounds, wherein a certain amount, but not more than 5000 ppm, of free fluoride is present.
  • DE10322446 teaches that when phosphating solutions in which the total content of zirconium and / or titanium is in a range of 10 to 1000 ppm, preferably 50 to 250 ppm, post-passivation of both the phosphated metal surfaces and the aluminum surfaces can be waived.
  • the one-stage process of a conversion treatment of metallic surfaces which at least partially comprise aluminum surfaces is carried out with constantly high fluoride contents, which results in a high pickling rate and thus a massive input of aluminum. Ions in the bath solution conditionally. It is the associated technical effort in bath control and treatment, which inevitably results from increased sludge formation in the phosphating. Furthermore, sedimented aluminate particles may remain on the components treated in this way in the conversion, which after the deposition of the coating primer cause a negative visual impression of the painted components or also impair the paint adhesion and mechanical resistance of the paint.
  • the present invention therefore relates to an aqueous composition for the corrosion-protective conversion treatment of metallic surfaces, which Surface of steel or galvanized steel or alloy galvanized steel or aluminum and all combinations of these includes, the
  • (C) a total of 1 -200 ppm of one or more water-soluble compounds of zirconium and / or titanium based on the element zirconium and / or titanium contains, characterized in that in the aqueous composition additionally an amount of free fluoride 1-400 ppm, measured with a fluoride-sensitive electrode, is present.
  • the concentration of free fluoride ions should not be optimized independently of the concentration of the zirconium and / or titanium compounds.
  • a quotient ⁇ characteristic of the passivation properties of the aqueous composition could be identified in accordance with the following formula (I):
  • VMe / mM where F / mM and Me / mM represent the free fluoride (F) or reduced zirconium and / or titanium concentration (Me) reduced by the unit of concentration in mM (10 -3 mol / L).
  • F / mM and Me / mM represent the free fluoride (F) or reduced zirconium and / or titanium concentration (Me) reduced by the unit of concentration in mM (10 -3 mol / L).
  • the quotient ⁇ should be at least 4 or at least 6 in the case of an aqueous composition containing only titanium as component (c).
  • the quotient ⁇ according to formula (I) should not be less than
  • Optimum ranges for the quotient ⁇ , for which a homogeneous passivation of all metal surfaces in the context of the invention is achieved, and an acceptable pickling rate is maintained and an acceptable entry of aluminum ions into the bath solution takes place, are as follows:
  • quotient ⁇ should according to the invention for aqueous compositions containing as component (c) exclusively water-soluble compounds of
  • (ii) contain titanium, at least 6, preferably at least 6.5 and more preferably at least 7, but not more than 14 and preferably not more than 12;
  • the proportion of free fluoride in the aqueous composition according to the invention is determined potentiometrically with the aid of a fluoride-sensitive glass electrode.
  • a detailed description of the measuring method, the calibration and the experimental procedure for determining the free fluoride concentration can be found in the description of the embodiments of the present invention.
  • zirconium compounds in the different embodiments of the present invention gives technically better results than the use of titanium compounds and is therefore preferred.
  • complex fluoro acids or their salts can be used.
  • the aqueous composition according to the invention for corrosion-protective conversion treatment can be used in addition to
  • 1 to 200 ppm of one or more water-soluble compounds of zirconium and / or titanium based on the element zirconium and / or titanium also contain at least one of the following accelerators:
  • Such accelerators are known in the art as components of phosphating baths and serve the function of "hydrogen scavengers" by directly oxidizing and thereby reducing the hydrogen produced by the acid attack on the metallic surface Accelerator, which reduces the formation of gaseous hydrogen on the metal surface, much easier.
  • Corrosion protection and paint adhesion of the crystalline zinc phosphate layers produced with an aqueous composition according to the invention are, according to experience, improved if, in addition, one or more of the following cations is present: From 0.001 to 4 g / l of manganese (II),
  • the zinc concentration is preferably in the range between about 0.3 and about 2 g / l, and more preferably between about 0.8 and about 1.4 g / l.
  • Higher levels of zinc do not provide significant benefits to the conversion treatment with the aqueous composition of the present invention, but on the other hand cause increased sludge accumulation in the treatment bath.
  • high levels of zinc can occur in a working treatment bath when mainly galvanized surfaces are phosphated and thus additional zinc is introduced into the treatment bath as a result of the pickling process.
  • Aqueous conversion treatment compositions which contain both manganese and nickel ions in addition to zinc ions are known to the person skilled in the art of phosphating as trication-phosphating solutions and are also well suited for the purposes of the present invention.
  • usual share of up to 3 g / l nitrate facilitates the formation of a crystalline homogeneous and closed phosphate layer on the steel, galvanized and alloy-galvanized steel surfaces.
  • hexafluorosilicate anions can be added to the aqueous composition for anticorrosive conversion treatment since they are capable of complexing the trivalent aluminum cations introduced into the bath solution, so that the phosphating is optimized and the so-called "speckling" increased under the formation of a speckle on the surface Pickling rate associated with the deposition of amorphous, white zinc phosphate, is prevented on galvanized substrates.
  • Another important parameter of the aqueous composition for the conversion treatment according to the invention is its content of free acid and the total acid.
  • the aqueous treatment solution preferably has a free acid content, each staggered in accordance with an increasing preference, of at least 0; 0.2; 0.5; 0.8; 1 point but not more than 3; 2.5; 2; 1, 5 points.
  • a total acid content of the treatment solution each staggered according to an increasing preference, of at least 20; 21; 22 points but not more than 26; 25; 24 points available.
  • free acid is well known to those skilled in the phosphating art.
  • the pH of the aqueous treatment solution is preferably not less than 2.2 with increasing preference. 2.4; 2.6; 2.8 but not greater than 3.6; 3.5; 3.4; 3.3; 3.2.
  • aqueous composition according to the invention for the conversion treatment of composite materials assembled from metallic materials, which at least partially also comprise aluminum surfaces, takes place after cleaning and degreasing the surfaces by contacting the surfaces with the aqueous composition according to the invention, for example by spraying or dipping, at bath temperatures in the range of 20-65 0 C for a tailored to the convection in the Badstrom and for the composition of the composite structure to be treated typical time interval.
  • a rinsing process with city water or demineralized water
  • rinse water partial recycling of rinse water components can be made in the bath solution according to the invention.
  • the thus treated metallic surfaces of the composite structure can be provided with a base coat in a further step, preferably with an organic electrodeposition paint.
  • the at least 200 bis Contains 1500 ppm of fluorocomplexes of zirconium and / or titanium based on the elements zirconium and / or titanium and optionally 10 to 100 ppm of copper (II) ions.
  • the pH of such a post-passivation solution is in the range of 3.5 to 5.5.
  • a composite structure which has been converted in accordance with this method and which is composed of, inter alia, steel and / or galvanized and / or alloy-galvanized steel components and aluminum components has phosphating coating weights of 0.5 to 4.5 g on its metallic surfaces on which a crystalline zinc phosphate layer has been formed. m 2 up.
  • the metallic surfaces which can be treated with the aqueous composition according to the invention for forming a conversion layer are preferably steel, galvanized steel and alloy-galvanized steel as well as aluminum and alloys of aluminum with an alloying fraction of less than 50 atomic%, silicon being used as further alloying constituents.
  • Magnesium, copper, manganese, zinc, chromium, titanium and nickel come into question.
  • the metallic surface may either consist exclusively of a metallic material or be composed of any combination of said materials in a composite structure.
  • aqueous composition according to the invention and the corresponding sequence of processes for the conversion treatment of metallic surfaces was tested on cold rolled steel test sheets (CRS ST1405, Sidca), hot dip galvanized steel (HDG, Thyssen Co.) and aluminum (AC120).
  • Table 1 shows the sequence of processes for the treatment according to the invention of the sample sheets, as is in principle also customary in automotive body production.
  • the sheets are alkaline cleaned and degreased and prepared after a rinsing with a titanium phosphate-containing activating solution for the conversion treatment according to the invention.
  • commercially available products by the applicant were used: Ridoline® ® 1569 A, Ridosol ® 1270, FIXODINE ® 50 CF.
  • the free acid score is determined by diluting 10 ml bath sample to 50 ml and titrating to pH 3.6 with 0.1 N sodium hydroxide solution. The consumption of ml of sodium hydroxide gives the score. Accordingly, the content of total acid is determined by titrating to a pH of 8.5.
  • the content of free fluoride in the aqueous composition for conversion treatment according to the invention is detected by means of a potentiometric measuring chain (inoLab pH / ion Level 3, Fa. WTW).
  • the measuring chain contains a fluoride-sensitive glass electrode (F501, Fa. WTW) and a reference electrode (R503, Fa. WTW).
  • F501, Fa. WTW fluoride-sensitive glass electrode
  • R503, Fa. WTW reference electrode
  • For two-point calibration of both electrodes are immersed together in sequence in the calibration solutions with a content of 100 ppm and 1000 ppm prepared from the Titrisol ® fluoride standard of Fa. Merck without buffer addition.
  • the resulting measured values are correlated with the respective fluoride content "100" or "1000" and read into the measuring device.
  • the steepness of the glass electrode is then displayed in mV per decade of the fluoride ion content in ppm on the meter, typically between -55 and -60 mV.
  • the fluoride content in ppm can then be determined directly by immersing the two electrodes in the bath solution according to the invention cooled, however.
  • Table 1 Process for Conversion Treatment of Aluminum (AC 120), CRS ST1405 (Sidca) and HDG (Thyssen)
  • deionized water is also fed into the rinsing process, but this is partially recycled and continuously processed.
  • An enrichment of salts is tolerated to a certain extent, so that procedurally higher specific conductivity values than 1 ⁇ Scm "1 of the rinse water are common.
  • Table 2 shows the pickling rates for the substrate aluminum as a function of the concentration of free fluoride and zirconium for a process sequence according to Table 1. As expected, the pickling rate increases with each increase in fluoride concentration. Surprisingly, the pickling rate on aluminum is significantly reduced by the addition of 50 ppm, and in the case of a free fluoride concentration of 30 and 55 ppm, the pickling rate is reduced by 50% compared with an aqueous composition for conversion treatment containing no zirconium.
  • P passivation layer n.i.O .: not in order / i.O .: in order according to visual assessment of the degree of coverage
  • the ⁇ -value is lower than
  • P passivation layer niO: not OK / OK: in order according to optical evaluation of the degree of coverage, wherein a Pa 1
  • critical bath parameters for this change in the type of passivation is characterized by a ⁇ -value of less than 4.
  • Excessive layer weights of the zinc phosphate layer of> 4.5 g / m 2 indicate a low barrier effect of the phosphate layer characterize the transition from a zinc phosphating with the desired crystallinity to a pure Zr-based passivation with a decreasing ⁇ value.
  • P passivation layer niO: not OK / OK: in order according to optical evaluation of the degree of coverage, wherein a Pa 1
  • Zr zirconium coating in mg / m 2 determined by X-ray fluorescence analysis (RFA)
  • the respective sheet is in the Table 1, the identical process steps, cleaned, rinsed, activated, and then placed an aqueous treatment solution according to the invention in accordance with Table 1 in contact, which, however, either a) 0-70 ppm zirconium in the form of H 2 ZrF 6 or b) 0-70 ppm of titanium in the form of K 2 TiF 6 or c) in each case 0-30 ppm of zirconium and titanium in the form of H 2 ZrF 6 or K 2 TiF 6 .
  • Tables 8 to 10 contain, depending on the quotient ⁇ of the respectively used treatment solutions a) to c) an optical assessment of phosphating on cold-rolled steel, since the formation of a closed and homogeneous zinc phosphate layer is critical especially on this substrate.
  • the sample sheet is subdivided into a line grid in such a way that an optical individual evaluation of approximately 1 cm 2 square fields is made. The mean value of the covering degrees summed over all individual fields then yields, semi-quantitatively, the total coverage of the respective sheet with the phosphate layer as a percentage of the sheet metal surface examined, whereby this consists of at least 64 individual fields.
  • Coated and uncoated areas are distinguishable for the skilled person due to their different reflectivity and / or color. Phosphated areas appear dull gray on all metallic substrates, while uncoated areas appear metallic and passivated areas appear bluish to violet shimmering.
  • Table 8 :
  • V / R front / back; as the front side of the stirrer facing side of the sheet is called high Badshaw
  • V / R front / back; as the front side of the stirrer facing side of the sheet is called high Badshaw
  • V / R front / back; as the front side of the stirrer facing side of the sheet is called high Badshaw

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  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemical Treatment Of Metals (AREA)

Abstract

L'invention concerne une composition aqueuse et un procédé de traitement de conversion à effet anticorrosif de surfaces métalliques. Ladite composition aqueuse s'utilise tout particulièrement dans le traitement de différents matériaux métalliques, réunis dans des structures composites, notamment l'acier ou l'acier galvanisé ou galvanisé allié, ainsi que dans celui de toutes les combinaisons comprenant lesdits matériaux. La structure composite comprend au moins en partie de l'aluminium ou ses alliages. La composition aqueuse à base d'une solution de phosphatage contient, outre des composés de zircon et de titane solubles dans l'eau, une quantité selon l'invention de fluorure libre, dans un rapport qui permet le phosphatage de surfaces en acier et de surfaces en acier galvanisé et/ou galvanisé allié et présuppose à la fois de faibles taux d'attaque du substrat en aluminium avec passivation simultanée de la surface en aluminium. Les matériaux, éléments et structures composites métalliques correspondants, qui ont été soumis à un traitement de conversion, selon l'invention, s'utilisent dans la construction automobile, dans la fabrication de carrosseries, dans la construction navale, dans l'industrie du bâtiment, ainsi que dans la fabrication de gros appareils électroménagers.
EP07820181A 2006-11-08 2007-09-13 Solution de phosphatage à base de zr/ti utilisée pour passiver des surfaces composites métalliques Active EP2092090B1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
SI200731183T SI2092090T1 (sl) 2006-11-08 2007-09-13 Fosfatirna raztopina, ki vsebuje zr/ti za pasiviranje kovinskih kompozitnih povrĺ in
PL07820181T PL2092090T3 (pl) 2006-11-08 2007-09-13 Zawierający Zr/Ti roztwór fosforanujący do pasywacji powierzchni metalicznych kompozytów

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102006052919A DE102006052919A1 (de) 2006-11-08 2006-11-08 Zr-/Ti-haltige Phosphatierlösung zur Passivierung von Metallverbundoberflächen
PCT/EP2007/059628 WO2008055726A1 (fr) 2006-11-08 2007-09-13 Solution de phosphatage à base de zr/ti utilisée pour passiver des surfaces composites métalliques

Publications (2)

Publication Number Publication Date
EP2092090A1 true EP2092090A1 (fr) 2009-08-26
EP2092090B1 EP2092090B1 (fr) 2012-12-19

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EP07820181A Active EP2092090B1 (fr) 2006-11-08 2007-09-13 Solution de phosphatage à base de zr/ti utilisée pour passiver des surfaces composites métalliques

Country Status (14)

Country Link
US (2) US8801871B2 (fr)
EP (1) EP2092090B1 (fr)
JP (1) JP5406723B2 (fr)
KR (1) KR20090086405A (fr)
CN (1) CN101535528B (fr)
BR (1) BRPI0718578A2 (fr)
CA (1) CA2669042C (fr)
DE (1) DE102006052919A1 (fr)
ES (1) ES2398594T3 (fr)
PL (1) PL2092090T3 (fr)
RU (1) RU2464356C2 (fr)
SI (1) SI2092090T1 (fr)
WO (1) WO2008055726A1 (fr)
ZA (1) ZA200903169B (fr)

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WO2007134152A1 (fr) 2006-05-10 2007-11-22 Henkel Ag & Co. Kgaa. Composition améliorée comprenant du chrome trivalent s'utilisant pour former des couches anti-corrosion sur des surfaces métalliques
DE102008000600B4 (de) * 2008-03-11 2010-05-12 Chemetall Gmbh Verfahren zur Beschichtung von metallischen Oberflächen mit einem Passivierungsmittel, das Passivierungsmittel, die hiermit erzeugte Beschichtung und ihre Verwendung
JP5593532B2 (ja) * 2008-07-30 2014-09-24 ディップソール株式会社 亜鉛又は亜鉛合金めっき上にクロムフリー化成皮膜を形成するための化成処理水溶液及びそれより得られたクロムフリー化成皮膜
DE102009029334A1 (de) * 2009-09-10 2011-03-24 Henkel Ag & Co. Kgaa Zweistufiges Verfahren zur korrosionsschützenden Behandlung von Metalloberflächen
DE102009047522A1 (de) 2009-12-04 2011-06-09 Henkel Ag & Co. Kgaa Mehrstufiges Vorbehandlungsverfahren für metallische Bauteile mit Zink- und Eisenoberflächen
DE102009047523A1 (de) * 2009-12-04 2011-06-09 Henkel Ag & Co. Kgaa Mehrstufiges Vorbehandlungsverfahren für metallische Bauteile mit Zinnoberflächen
DE102010030697A1 (de) 2010-06-30 2012-01-05 Henkel Ag & Co. Kgaa Verfahren zur selektiven Phosphatierung einer Verbundmetallkonstruktion
JP5861249B2 (ja) * 2010-09-15 2016-02-16 Ｊｆｅスチール株式会社 容器用鋼板の製造方法
US20130230425A1 (en) * 2011-09-02 2013-09-05 Ppg Industries Ohio, Inc. Two-step zinc phosphating process
EP2631333A1 (fr) * 2012-02-24 2013-08-28 Henkel AG & Co. KGaA Prétraitement de surfaces en zinc avant une passivation
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DE102006052919A1 (de) 2008-05-15
US8801871B2 (en) 2014-08-12
ES2398594T3 (es) 2013-03-20
RU2009121446A (ru) 2010-12-20
PL2092090T3 (pl) 2013-05-31
JP5406723B2 (ja) 2014-02-05
WO2008055726A1 (fr) 2008-05-15
US8956468B2 (en) 2015-02-17
JP2010509499A (ja) 2010-03-25
RU2464356C2 (ru) 2012-10-20
KR20090086405A (ko) 2009-08-12
CA2669042C (fr) 2016-08-02
US20120177946A1 (en) 2012-07-12
US20090255608A1 (en) 2009-10-15
BRPI0718578A2 (pt) 2014-03-11
ZA200903169B (en) 2010-04-28
EP2092090B1 (fr) 2012-12-19
SI2092090T1 (sl) 2013-06-28
CN101535528A (zh) 2009-09-16
CA2669042A1 (fr) 2008-05-15
CN101535528B (zh) 2012-03-21

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