EP2105530A1 - Verschleissanzeige eines Gewebes mittels Verwendung von Filamenten - Google Patents

Verschleissanzeige eines Gewebes mittels Verwendung von Filamenten Download PDF

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Publication number
EP2105530A1
EP2105530A1 EP09165880A EP09165880A EP2105530A1 EP 2105530 A1 EP2105530 A1 EP 2105530A1 EP 09165880 A EP09165880 A EP 09165880A EP 09165880 A EP09165880 A EP 09165880A EP 2105530 A1 EP2105530 A1 EP 2105530A1
Authority
EP
European Patent Office
Prior art keywords
fabric
filament
wear
guideline
filaments
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP09165880A
Other languages
English (en)
French (fr)
Other versions
EP2105530B1 (de
Inventor
Per Martinsson
Jerry O'connor
Anders Nilsson
David A. Dunn
Jan Bodbacka
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Albany International Corp
Original Assignee
Albany International Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Albany International Corp filed Critical Albany International Corp
Publication of EP2105530A1 publication Critical patent/EP2105530A1/de
Application granted granted Critical
Publication of EP2105530B1 publication Critical patent/EP2105530B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/22Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
    • D02G3/34Yarns or threads having slubs, knops, spirals, loops, tufts, or other irregular or decorative effects, i.e. effect yarns
    • D02G3/346Yarns or threads having slubs, knops, spirals, loops, tufts, or other irregular or decorative effects, i.e. effect yarns with coloured effects, i.e. by differential dyeing process
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/22Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
    • D02G3/36Cored or coated yarns or threads
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/283Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads synthetic polymer-based, e.g. polyamide or polyester fibres
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/292Conjugate, i.e. bi- or multicomponent, fibres or filaments
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/30Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the fibres or filaments
    • D03D15/37Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the fibres or filaments with specific cross-section or surface shape
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/54Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads coloured
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/547Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads with optical functions other than colour, e.g. comprising light-emitting fibres
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F1/00Wet end of machines for making continuous webs of paper
    • D21F1/0027Screen-cloths
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F1/00Wet end of machines for making continuous webs of paper
    • D21F1/36Guiding mechanisms
    • D21F1/365Guiding mechanisms for controlling the lateral position of the screen
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21GCALENDERS; ACCESSORIES FOR PAPER-MAKING MACHINES
    • D21G9/00Other accessories for paper-making machines
    • D21G9/0009Paper-making control systems
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/14Dyeability
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/16Physical properties antistatic; conductive
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/20Physical properties optical
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30Woven fabric [i.e., woven strand or strip material]
    • Y10T442/3065Including strand which is of specific structural definition
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30Woven fabric [i.e., woven strand or strip material]
    • Y10T442/3065Including strand which is of specific structural definition
    • Y10T442/3089Cross-sectional configuration of strand material is specified
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30Woven fabric [i.e., woven strand or strip material]
    • Y10T442/3065Including strand which is of specific structural definition
    • Y10T442/3089Cross-sectional configuration of strand material is specified
    • Y10T442/3114Cross-sectional configuration of the strand material is other than circular

Definitions

  • the present invention is directed towards means for detecting the wear level of, and creating guidelines on, papermaking and other industrial fabrics, particularly towards multilayered and conductive filaments used as such a means.
  • a cellulosic fibrous web is formed by depositing a fibrous slurry, that is, an aqueous dispersion of cellulose fibers, onto a moving forming fabric in the forming section of a paper machine. A large amount of water is drained from the slurry through the forming fabric, leaving the cellulosic fibrous web on the surface of the forming fabric.
  • a fibrous slurry that is, an aqueous dispersion of cellulose fibers
  • the newly formed cellulosic fibrous web proceeds from the forming section to a press section, which includes a series of press nips.
  • the cellulosic fibrous web passes through the press nips supported by a press fabric, or, as is often the case, between two such press fabrics.
  • the press nips the cellulosic fibrous web is subjected to compressive forces which squeeze water therefrom, and which adhere the cellulosic fibers in the web to one another to turn the cellulosic fibrous web into a paper sheet.
  • the water is accepted by the press fabric or fabrics and, ideally, does not return to the paper sheet.
  • the paper sheet finally proceeds to a dryer section, which includes at least one series of rotatable dryer drums or cylinders, which are internally heated by steam.
  • the newly formed paper sheet is directed in a serpentine path sequentially around each in the series of drums by a dryer fabric, which holds the paper sheet closely against the surfaces of the drums.
  • the heated drums reduce the water content of the paper sheet to a desirable level through evaporation.
  • the forming, press and dryer fabrics all take the form of endless loops on the paper machine and function in the manner of conveyors. It should further be appreciated that paper manufacture is a continuous process which proceeds at considerable speeds. That is to say, the fibrous slurry is continuously deposited onto the forming fabric in the forming section, while a newly manufactured paper sheet is continuously wound onto rolls after it exits from the dryer section.
  • the present invention is directed towards a fabric which includes multilayer filaments comprising a core yarn surrounded by one or more outside layers.
  • the core and the layers are visibly distinguishable from one another by, for example, their contrasting color, or reflectivity. This enables fabric wear to be monitored as abrasion gradually wears away successive layers of the filaments, eventually revealing the core yarns.
  • conductive monofilaments are woven into the wear side of a fabric to create another type of wear detection system. By measuring, for example, the resistance in the cross direction of the fabric, it is possible to determine the level of wear.
  • the multilayer filaments are used to create a visible guideline on the fabric in CD and/or MD directions.
  • the guideline is not removable by high-pressure showers or chemical cleaning, and is used for determining belt alignment, speed measurements, or as a trigger for an electronic guiding system.
  • a conductive filament having a contrasting color is used to create a permanent guideline on a fabric.
  • the color contrast or the electrical properties of the filaments can be used as a trigger for on-line speed measurements or as a trigger for an electronic guiding system.
  • a preferred embodiment of the present invention will be described in the context of filaments and fabrics woven therefrom used in papermaking. However, it should be noted that the invention is applicable to the fabrics used in other industrial settings where wear detection and guiding are of importance.
  • Fabric constructions include woven, spiral wound, knitted, extruded mesh, spiral coil, and other nonwoven fabrics. These fabrics may also include monofilament, plied monofilament, multifilament or plied multifilament yarns, and may be a single-layer weave, a multi-layer weave or laminated.
  • the filament can be the coils, the yarns used to connect the coils or the inserts (stuffers) that may be present in the coil interior void.
  • the yarns are typically extruded from any one of the synthetic polymeric resins, such as polyamide and polyester resins, used for this purpose by those of ordinary skill in the industrial fabric arts.
  • the filament 10 can comprise, for example, a core yarn 12 surrounded by a plurality of outside layers 14, 16, 18.
  • the core 12 and the surrounding layers 14, 16, 18 are visibly distinguishable from one another by, for example, their contrasting color, or reflectivity. This enables the wear of fabrics comprising such filaments 10 to be monitored as abrasion gradually wears away successive layers 14, 16, 18 of the filaments 10, eventually revealing the core yarns 12.
  • An example of the multilayered filament 10 exhibiting such wear is shown in Figure 2 (cross-sectional view and plan view).
  • the core 12 and the layers 14, 16, 18 can also be doped with dyes or other substances that will change their appearance.
  • the dye would then be detectable by a sensor when excited with an external energy source, for example, a light (e.g., laser, or UV) or ultra sound.
  • the filaments 10 can also comprise a light absorbing/transmitting core 12 and several transparent layers 14, 16, 18 having varying refractions n1, n2, n3.
  • An example of this multilayer optical filament 10 is shown in Figure 3 . In this case, the transmitted/reflected light from the filament 10 changes color depending on the wear level through the layers 14, 16, 18.
  • Figure 4 is a plan view of an unused fabric 20 (wear side) comprising at least some of the multilayered filaments 10, according to the teachings of the present invention.
  • Fabric 20 can be a structure woven from yarns 10 lying in the cross-machine direction (CD) and yarns 22 lying in the machine direction (MD), although it need not be woven to fall within the scope of the present invention, and could be a nonwoven structure.
  • CD yarns 10 which are multilayered filaments of the variety shown in Figures 1, 2 and 3 are depicted as weaving with MD yarns 22 in a plain weave.
  • the knuckles 24 on the surface of the fabric 20 are most susceptible to wear because they are formed where a yarn in one direction of the fabric 20 passes or crosses over one in the other direction, and are therefore elevated points on the surface of the fabric 20.
  • the same plan view of the fabric 20 will appear as shown in Figure 5 .
  • At least one or more of the outer layers 16, 18 of the CD multilayered filaments 10 are shown to be worn away to the point where an inner layer 14 or the core 12 is exposed to view.
  • the inner layer 14 or core 12 gives an indication of the wear of the fabric 20.
  • the CD yarns 10 can be conductive monofilaments woven into the wear side of fabric 20 to provide another means of wear detection.
  • a corresponding level of fabric wear is determined. That is, less cross sectional area of the conductive monofilaments corresponds to lower conductivity in the CD direction of the fabric 20.
  • the multilayer filaments 10 are used to create a visible guideline 30 on a fabric in the CD and/or MD directions.
  • This guideline 30 is used for determining belt alignment, on-line speed measurements, or as a trigger for an electronic guiding system.
  • the guideline 30 is not removable by high-pressure showers or chemical cleaning.
  • a conductive monofilament having a contrasting color can also be used to create the guideline 30 on the fabric.
  • the color contrast and/or the electrical properties of the monofilaments can be used as the trigger for on-line speed measurements or as the trigger for the electronic guiding system.
  • the filament used can be either round or non-round in cross section.
  • each filament can be the inventive filament, or at least one filament can have the inventive (e.g., conductive) property.
  • inventive e.g., conductive

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Woven Fabrics (AREA)
  • Paper (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Golf Clubs (AREA)
  • Treatment Of Fiber Materials (AREA)
  • Artificial Filaments (AREA)
EP09165880A 2003-06-27 2004-06-14 Verschleissanzeige eines Gewebes mittels Verwendung von Filamenten Expired - Lifetime EP2105530B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/608,630 US20040266296A1 (en) 2003-06-27 2003-06-27 Wear level indicating filaments and fabrics (and guideline applications)
EP04755174A EP1639194B1 (de) 2003-06-27 2004-06-14 Verschleissanzeige eines gewebes mittels verwendung von filamenten

Related Parent Applications (2)

Application Number Title Priority Date Filing Date
EP04755174A Division EP1639194B1 (de) 2003-06-27 2004-06-14 Verschleissanzeige eines gewebes mittels verwendung von filamenten
EP04755174.2 Division 2004-06-14

Publications (2)

Publication Number Publication Date
EP2105530A1 true EP2105530A1 (de) 2009-09-30
EP2105530B1 EP2105530B1 (de) 2012-06-27

Family

ID=33540627

Family Applications (2)

Application Number Title Priority Date Filing Date
EP04755174A Expired - Lifetime EP1639194B1 (de) 2003-06-27 2004-06-14 Verschleissanzeige eines gewebes mittels verwendung von filamenten
EP09165880A Expired - Lifetime EP2105530B1 (de) 2003-06-27 2004-06-14 Verschleissanzeige eines Gewebes mittels Verwendung von Filamenten

Family Applications Before (1)

Application Number Title Priority Date Filing Date
EP04755174A Expired - Lifetime EP1639194B1 (de) 2003-06-27 2004-06-14 Verschleissanzeige eines gewebes mittels verwendung von filamenten

Country Status (20)

Country Link
US (1) US20040266296A1 (de)
EP (2) EP1639194B1 (de)
JP (1) JP4643571B2 (de)
KR (1) KR101163991B1 (de)
CN (1) CN1813104B (de)
AT (1) ATE443791T1 (de)
AU (1) AU2004255728A1 (de)
BR (1) BRPI0412016B1 (de)
CA (2) CA2530472C (de)
DE (1) DE602004023290D1 (de)
ES (2) ES2389144T3 (de)
MX (1) MXPA05014228A (de)
NO (1) NO20060458L (de)
NZ (1) NZ544352A (de)
PL (1) PL1639194T3 (de)
PT (1) PT1639194E (de)
RU (1) RU2347020C2 (de)
TW (1) TW200514893A (de)
WO (1) WO2005005719A1 (de)
ZA (1) ZA200600046B (de)

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WO2016071262A1 (de) 2014-11-05 2016-05-12 Voith Patent Gmbh Bespannung mit indikatorlage

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AU2003293512A1 (en) * 2003-12-11 2005-07-14 Albany International Corp. Passive sensor system for detection or wear problems in paper machine clothing
US8728373B2 (en) * 2007-03-20 2014-05-20 Albany International Corp. Industrial fabric having a thermochromic sensor
US7883737B2 (en) * 2008-03-18 2011-02-08 General Electric Company Methods allowing for visual inspection of coated components for erosion damage
US20130000005A1 (en) * 2011-06-28 2013-01-03 Banom, Inc. Plaited glove
US8890672B2 (en) 2011-08-29 2014-11-18 Harnischfeger Technologies, Inc. Metal tooth detection and locating
US9382663B2 (en) 2012-11-13 2016-07-05 Georgia-Pacific Consumer Products Lp Apparatus, system, and process for determining characteristics of a surface of a papermaking fabric
US9062416B2 (en) 2012-11-13 2015-06-23 Georgia-Pacific Consumer Products Lp Apparatus, system, and process for determining characteristics of a surface of a papermaking fabric
CN104452007A (zh) * 2013-09-13 2015-03-25 常州科旭纺织有限公司 一种高性能包芯纱线及其应用
US9611625B2 (en) 2015-05-22 2017-04-04 Harnischfeger Technologies, Inc. Industrial machine component detection and performance control
CA3263786A1 (en) * 2015-11-12 2025-03-24 Joy Global Surface Mining Inc Methods and systems for detecting heavy machine wear
KR101859181B1 (ko) * 2016-06-02 2018-05-17 주식회사 덕성 다층 코팅 다색실 및 그 제조방법
US10994521B2 (en) 2018-08-02 2021-05-04 Gates Corporation Rubber product with wear indicating layers
CN110004528A (zh) * 2019-04-18 2019-07-12 宿迁市柯信纺织品股份有限公司 一种应用于纺织业梳棉工序的再处理方法
CN110284227A (zh) * 2019-06-27 2019-09-27 苏州峰佳达化纤纺织有限公司 一种高强高弹涤锦多层复合丝
US12281417B2 (en) * 2022-01-26 2025-04-22 Federal-Mogul Powertrain Llc Self-wrapping woven sleeve with wear indicator yarns and method of construction thereof

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CA2752532A1 (en) 2005-01-20
CA2530472C (en) 2012-08-07
AU2004255728A1 (en) 2005-01-20
BRPI0412016A (pt) 2006-08-15
KR20060026890A (ko) 2006-03-24
ES2333225T3 (es) 2010-02-18
CN1813104B (zh) 2010-08-18
TW200514893A (en) 2005-05-01
WO2005005719A1 (en) 2005-01-20
ES2389144T3 (es) 2012-10-23
EP1639194A1 (de) 2006-03-29
NO20060458L (no) 2006-03-27
EP1639194B1 (de) 2009-09-23
ATE443791T1 (de) 2009-10-15
KR101163991B1 (ko) 2012-07-20
PL1639194T3 (pl) 2010-02-26
PT1639194E (pt) 2009-12-07
CA2530472A1 (en) 2005-01-20
US20040266296A1 (en) 2004-12-30
RU2347020C2 (ru) 2009-02-20
DE602004023290D1 (de) 2009-11-05
BRPI0412016B1 (pt) 2014-12-16
NZ544352A (en) 2009-03-31
EP2105530B1 (de) 2012-06-27
JP4643571B2 (ja) 2011-03-02
JP2007520641A (ja) 2007-07-26
ZA200600046B (en) 2007-03-28
CN1813104A (zh) 2006-08-02
RU2005140048A (ru) 2006-07-27
MXPA05014228A (es) 2006-07-03

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