EP2118040A2 - Mélange de substances pouvant être utilisé notamment en tant que granulat dans du béton - Google Patents
Mélange de substances pouvant être utilisé notamment en tant que granulat dans du bétonInfo
- Publication number
- EP2118040A2 EP2118040A2 EP08708497A EP08708497A EP2118040A2 EP 2118040 A2 EP2118040 A2 EP 2118040A2 EP 08708497 A EP08708497 A EP 08708497A EP 08708497 A EP08708497 A EP 08708497A EP 2118040 A2 EP2118040 A2 EP 2118040A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- mixture
- concrete
- cement
- preservative
- substances
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 83
- 239000004567 concrete Substances 0.000 title claims abstract description 73
- 239000004568 cement Substances 0.000 claims abstract description 20
- 239000000230 xanthan gum Substances 0.000 claims abstract description 10
- 235000010493 xanthan gum Nutrition 0.000 claims abstract description 10
- 229920001285 xanthan gum Polymers 0.000 claims abstract description 10
- 229940082509 xanthan gum Drugs 0.000 claims abstract description 10
- 239000004088 foaming agent Substances 0.000 claims abstract description 8
- 239000002562 thickening agent Substances 0.000 claims abstract description 8
- 229920003002 synthetic resin Polymers 0.000 claims abstract description 6
- 239000000057 synthetic resin Substances 0.000 claims abstract description 6
- 239000000126 substance Substances 0.000 claims description 24
- 239000000945 filler Substances 0.000 claims description 14
- 239000003755 preservative agent Substances 0.000 claims description 10
- 230000002335 preservative effect Effects 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 8
- 239000004576 sand Substances 0.000 claims description 8
- 229920000161 Locust bean gum Polymers 0.000 claims description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 6
- 239000000711 locust bean gum Substances 0.000 claims description 6
- 235000010420 locust bean gum Nutrition 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 5
- QAEKNCDIHIGLFI-UHFFFAOYSA-L cobalt(2+);2-ethylhexanoate Chemical compound [Co+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O QAEKNCDIHIGLFI-UHFFFAOYSA-L 0.000 claims description 4
- 239000004816 latex Substances 0.000 claims description 3
- 229920000126 latex Polymers 0.000 claims description 3
- 239000004014 plasticizer Substances 0.000 claims description 3
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 2
- CBOCVOKPQGJKKJ-UHFFFAOYSA-L Calcium formate Chemical compound [Ca+2].[O-]C=O.[O-]C=O CBOCVOKPQGJKKJ-UHFFFAOYSA-L 0.000 claims description 2
- 240000002989 Euphorbia neriifolia Species 0.000 claims description 2
- 229910001570 bauxite Inorganic materials 0.000 claims description 2
- 239000001110 calcium chloride Substances 0.000 claims description 2
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 2
- 239000004281 calcium formate Substances 0.000 claims description 2
- 229940044172 calcium formate Drugs 0.000 claims description 2
- 235000019255 calcium formate Nutrition 0.000 claims description 2
- 239000008262 pumice Substances 0.000 claims description 2
- 239000002689 soil Substances 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 12
- 239000004566 building material Substances 0.000 abstract description 6
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000010426 asphalt Substances 0.000 description 11
- 238000010276 construction Methods 0.000 description 10
- 239000006185 dispersion Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 3
- 239000002574 poison Substances 0.000 description 3
- 231100000614 poison Toxicity 0.000 description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 230000009969 flowable effect Effects 0.000 description 2
- 229920000609 methyl cellulose Polymers 0.000 description 2
- 239000001923 methylcellulose Substances 0.000 description 2
- 235000019353 potassium silicate Nutrition 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- -1 alkaline earth metal formate calcium formate Chemical class 0.000 description 1
- 238000009412 basement excavation Methods 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000003841 chloride salts Chemical class 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000009415 formwork Methods 0.000 description 1
- 239000000383 hazardous chemical Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 239000000546 pharmaceutical excipient Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
- C04B40/0042—Powdery mixtures
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Definitions
- the present invention relates to a mixture of substances for curing building materials, in particular concrete.
- bitumen The most common road building material is bitumen. Bitumen has the advantage that it is flexible enough to go with the ground something, so that the roads built with it get no cracks and / or edge projections. In addition, a bitumen coating proves to be extremely resistant to abrasion, so that roads with a bituminous coating last a long time.
- bitumen is its high price and lack of availability of this petroleum derivative in many parts of the world. Additionally, because of its lack of heat resistance, bitumen is a non-road building material in many countries of the southern and eastern hemisphere.
- bitumen road construction material An alternative to bitumen road construction material is the concrete. Concrete is a much cheaper material than bitumen and the materials needed for a concrete mix cement, water and a filler such as sand are at least more readily available from bitumen in much of the world. In addition, concrete does not soften even in extreme sunlight.
- the solidification of the substrate is a very complex process, in which usually the grown substrate must be replaced by a compressible material such as sand.
- a mixture of substances is known, which is added to a concrete mixture in order to increase its flexibility and reduce its shrinkage during curing.
- the substance mixture consists mainly of two components, of which one component consists predominantly of chloride salts and the other component is an alkali metal silicate (water glass), preferably sodium silicate.
- the two components are premixed and then added to the concrete mix of cement, water and sand for use in road construction, for example.
- DE 19649478 A1 describes an aqueous dispersion which can be used as aggregate for concrete mixtures.
- the concrete mixture described therein is preferably prepared by mixing cement, filler and optionally water with each other and then adding the dispersion according to the invention. Any other order of mixing the components is also possible.
- this dispersion is very advantageous because it is harmless to the environment and harmless to humans, increases the flexibility of the concrete and reduces the shrinkage of the concrete mix on curing.
- the disadvantage is that a dispersion has a relatively high mass due to the water content and thus leads to high transport costs.
- the product described therein is not suitable for admixture in cement, since this would only be possible if it would also be a dry, pulverförniges material.
- the mixture should continue to be suitable as a cement additive or as a mixture for other binders.
- the composition should have the best possible transport capabilities and it should allow the fillers are used in the concrete mix, which were previously considered cement poisons.
- This mixture is dry mixed as a powder.
- the water-containing locust bean gum As a viscous thickener, the water-containing locust bean gum has proved favorable.
- Xanthan Gum and locust bean gum have synergistic effects, as they both have a viscous effect on the concrete to be mixed with the excipient.
- the plasticizer preferably polycarboxylic ether (as a powder)
- the concrete mix is very thin and free-flowing.
- Xanthan Gum and locust bean gum can also be replaced with methylcellulose.
- the cement-compatible resin is also added as a powder (dispersion powder).
- Hostapur OSB has proven to be suitable as a foaming agent because it forms micro-pores.
- hardening accelerator it is possible to use all suitable accelerators, preferably calcium formate or calcium chloride.
- alumina-enamel cement can also be used as the hardening accelerator since this also leads to an exothermic reaction which accelerates the normal cement in the setting. Thor Preservative is especially good for preservatives.
- Another object of the invention is a concrete mixture containing: a. 0.01-0.5 kg, preferably 0.05-0.1 kg of the mixture of substances according to the invention per kg of cement, b. Cement, c. Filler d optionally water, the concrete mixture components are used in conventional amounts.
- the concrete mixture according to the invention is preferably prepared by mixing together the cement, the filler and optionally the water and then adding the substance mixture according to the invention. Any other order of mixing the components is also possible.
- the concrete mixture according to the invention is viscous, so it is stable viscous and not flowable, as long as no kinetic energy is added.
- the concrete mixture is pumped or shaken into a formwork, it becomes increasingly flowable and thus does not form any holes that reduce the flexural and compressive strength or cause optical disadvantages.
- the concrete of the invention has a very good water retention capacity, what vertext that the concrete reaches optimum hardness even in hot and very dry conditions.
- xanthan gum and locust bean gum prevent the formation of water ice crystals to -200 0 C, so that the concrete can be processed even at temperatures below zero . Even at very low temperatures, the concrete remains physically stable, does not shrink and does not become brittle or brittle.
- any material can be used that is available in the field of construction site or field of application.
- gravel, earth, sand or even asphalt are suitable.
- the concrete mixture according to the invention is mixed on site, after addition of water, the mixture is straightened and compacted with so-called Vibprowalzen. After a very short curing time, a wear layer of asphalt can then be applied as needed, but it can also be dispensed with, for example for farm roads.
- Xanthan Gum and locust bean gum can also be replaced with methylcellulose.
- Another object of the invention is the production of building materials, preferably plates or stones, from the concrete mixture according to the invention.
- the concrete mixture according to the invention can be used for any type of concrete construction, preferably for road, road construction and mounting, so that a further subject of the invention, this use and the corresponding concrete structures, preferably road, ways, and other mounting pads or structures ,
- a concrete mixture only has to be added to an adjuvant which does not have to be premixed in order to make the concrete more flexible to reduce the shrinkage during curing. This reduces freight and storage costs.
- the substance mixture according to the invention is not classified as a hazardous substance, so that it can be processed without protective measures.
- the mixture according to the invention is harmless to the environment, a concrete mixture according to the invention hardens very quickly, with the mixture of substances according to the invention, it is possible to produce a concrete mix with fillers, which were previously considered as cement poisons, as a filler in the concrete mix, the usual sands, but beyond also any type of soil, contaminated or uncontaminated, and / or materials such as bauxite, latent, volcanic ash, pumice and ash from incineration plants are used, with the concrete mixture according to the invention, building materials and concrete components of any kind, preferably road and pavement can be prepared by excavation of the worksite and / or sand or soil-like materials available in the construction site area are used as filler in the concrete mix instead of the usual fillers.
- composition of the invention composed as follows:
- the concrete mixture according to the invention and the conventional concrete mixture were respectively poured into wooden molds measuring 50 ⁇ 20 ⁇ 1 cm (length, width, depth), in which the concrete mixture was cured in each case.
- Each 10 plates were made.
- the concrete mixtures were each intimately premixed in a concrete mixer and then mixed in each case in a vat with 0.1 Lier of the mixture according to Example 1 and poured into the molds described in Example 1 into plates in which cured the concrete mixtures.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102007007421.4A DE102007007421B4 (de) | 2007-02-12 | 2007-02-12 | Stoffgemisch verwendbar als Zuschlagmittel für Beton |
| PCT/EP2008/051184 WO2008098843A2 (fr) | 2007-02-12 | 2008-01-31 | Mélange de substances pouvant être utilisé notamment en tant que granulat dans du béton |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP2118040A2 true EP2118040A2 (fr) | 2009-11-18 |
Family
ID=39597668
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP08708497A Withdrawn EP2118040A2 (fr) | 2007-02-12 | 2008-01-31 | Mélange de substances pouvant être utilisé notamment en tant que granulat dans du béton |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP2118040A2 (fr) |
| DE (1) | DE102007007421B4 (fr) |
| RU (1) | RU2433096C2 (fr) |
| UA (1) | UA93948C2 (fr) |
| WO (1) | WO2008098843A2 (fr) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102008038904A1 (de) * | 2008-08-13 | 2010-02-18 | Bauer, Wulf, Dr. | Dispersion für den Einsatz in einer Betonmischung |
| RU2678286C2 (ru) * | 2017-03-23 | 2019-01-24 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Кабардино-Балкарский государственный университет им. Х.М. Бербекова" (КБГУ) | Сырьевая смесь для изготовления пенобетона |
| RU2646925C1 (ru) * | 2017-03-27 | 2018-03-12 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Петербургский государственный университет путей сообщения Императора Александра I" | Комплексная добавка для пенобетонной смеси |
| RU2729086C1 (ru) * | 2019-10-21 | 2020-08-04 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Воронежский государственный технический университет" | Двухфазная смесь на основе цемента для композитов в технологии строительной 3D-печати |
| CN113319996B (zh) * | 2021-05-26 | 2022-08-26 | 付中 | 水泥复合板的生产方法和多层复合水泥板材的生产方法 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050092209A1 (en) * | 2003-10-30 | 2005-05-05 | Garner Van D. | Lime-free admixture compositions for hydraulic cements and methods thereof |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3628902A1 (de) * | 1986-08-26 | 1988-03-03 | Bayer Ag | Kationische kautschuklatices, verfahren zu ihrer herstellung und ihre verwendung |
| JPH07110775B2 (ja) * | 1987-06-30 | 1995-11-29 | 昭和電工株式会社 | 弾性モルタル組成物 |
| AU666706B2 (en) * | 1992-03-11 | 1996-02-22 | Gerhard Schilling | Flexibility enhancement agent and method of use |
| DE19649478A1 (de) * | 1995-12-22 | 1997-06-26 | Bauer Wulf Dr | Dispersionen und deren Einsatz in Betonmischungen |
| DE19607814A1 (de) * | 1996-03-01 | 1997-09-04 | Eckart Standard Bronzepulver | Porenbildendes Additiv für Mörtel und Putze |
| CN1295181C (zh) * | 2005-04-30 | 2007-01-17 | 王衡 | 一种高强弹性混凝土的复合添加剂 |
-
2007
- 2007-02-12 DE DE102007007421.4A patent/DE102007007421B4/de not_active Expired - Fee Related
-
2008
- 2008-01-31 UA UAA200909382A patent/UA93948C2/uk unknown
- 2008-01-31 WO PCT/EP2008/051184 patent/WO2008098843A2/fr not_active Ceased
- 2008-01-31 EP EP08708497A patent/EP2118040A2/fr not_active Withdrawn
- 2008-01-31 RU RU2009134179A patent/RU2433096C2/ru not_active IP Right Cessation
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050092209A1 (en) * | 2003-10-30 | 2005-05-05 | Garner Van D. | Lime-free admixture compositions for hydraulic cements and methods thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| UA93948C2 (uk) | 2011-03-25 |
| WO2008098843A2 (fr) | 2008-08-21 |
| DE102007007421B4 (de) | 2017-05-04 |
| WO2008098843A3 (fr) | 2008-10-16 |
| DE102007007421A1 (de) | 2008-08-14 |
| RU2433096C2 (ru) | 2011-11-10 |
| RU2009134179A (ru) | 2011-03-20 |
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