EP2137475A2 - Verfahren zur kühlung einer kryogenen austauschleitung - Google Patents

Verfahren zur kühlung einer kryogenen austauschleitung

Info

Publication number
EP2137475A2
EP2137475A2 EP08788101A EP08788101A EP2137475A2 EP 2137475 A2 EP2137475 A2 EP 2137475A2 EP 08788101 A EP08788101 A EP 08788101A EP 08788101 A EP08788101 A EP 08788101A EP 2137475 A2 EP2137475 A2 EP 2137475A2
Authority
EP
European Patent Office
Prior art keywords
expansion means
fraction
exchange line
fluid
valve
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP08788101A
Other languages
English (en)
French (fr)
Other versions
EP2137475B1 (de
Inventor
Philippe Court
Antoine Hernandez
Christian Monereau
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Original Assignee
Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Air Liquide SA, LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude filed Critical Air Liquide SA
Publication of EP2137475A2 publication Critical patent/EP2137475A2/de
Application granted granted Critical
Publication of EP2137475B1 publication Critical patent/EP2137475B1/de
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/06Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation
    • F25J3/0695Start-up or control of the process; Details of the apparatus used
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/0002Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
    • F25J1/0022Hydrocarbons, e.g. natural gas
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/003Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
    • F25J1/0047Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle
    • F25J1/0052Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle by vaporising a liquid refrigerant stream
    • F25J1/0055Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle by vaporising a liquid refrigerant stream originating from an incorporated cascade
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0243Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
    • F25J1/0244Operation; Control and regulation; Instrumentation
    • F25J1/0245Different modes, i.e. 'runs', of operation; Process control
    • F25J1/0247Different modes, i.e. 'runs', of operation; Process control start-up of the process
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0295Start-up or control of the process; Details of the apparatus used, e.g. sieve plates, packings
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/06Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation
    • F25J3/0605Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the feed stream
    • F25J3/062Refinery gas, cracking gas, coke oven gas, gaseous mixtures containing aliphatic unsaturated CnHm or gaseous mixtures of undefined nature
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/06Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation
    • F25J3/063Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the separated product stream
    • F25J3/0635Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the separated product stream separation of CnHm with 1 carbon atom or more
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/06Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation
    • F25J3/063Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the separated product stream
    • F25J3/064Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the separated product stream separation of CnHm with 2 carbon atoms or more
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/06Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation
    • F25J3/063Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the separated product stream
    • F25J3/0655Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the separated product stream separation of hydrogen
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2210/00Processes characterised by the type or other details of the feed stream
    • F25J2210/42Nitrogen
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2240/00Processes or apparatus involving steps for expanding of process streams
    • F25J2240/40Expansion without extracting work, i.e. isenthalpic throttling, e.g. JT valve, regulating valve or venturi, or isentropic nozzle, e.g. Laval
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2245/00Processes or apparatus involving steps for recycling of process streams
    • F25J2245/02Recycle of a stream in general, e.g. a by-pass stream
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2270/00Refrigeration techniques used
    • F25J2270/04Internal refrigeration with work-producing gas expansion loop
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2270/00Refrigeration techniques used
    • F25J2270/18External refrigeration with incorporated cascade loop
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2270/00Refrigeration techniques used
    • F25J2270/90External refrigeration, e.g. conventional closed-loop mechanical refrigeration unit using Freon or NH3, unspecified external refrigeration
    • F25J2270/904External refrigeration, e.g. conventional closed-loop mechanical refrigeration unit using Freon or NH3, unspecified external refrigeration by liquid or gaseous cryogen in an open loop
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2280/00Control of the process or apparatus
    • F25J2280/10Control for or during start-up and cooling down of the installation

Definitions

  • the present invention relates to an exchange line and a method for cooling such a line of exchange.
  • cryogenics to fractionate a gas stream into at least two fluids of different composition, generally into a fluid said to be light, that is to say composed essentially of the most volatile constituents and into a so-called heavy fluid consisting essentially of the most easily condensable constituents.
  • the mixture to be fractionated is cooled in an exchanger or in a set of exchangers called the exchange line until obtaining a diphasic liquid / vapor mixture extracted from said exchange line and separated into a liquid-vapor separation device.
  • the steam can be cooled again until a new diphasic state is obtained and fractionated a second time.
  • liquid-vapor separator will be used to encompass all equipment generating at least one liquid outlet and one gas outlet from at least one two-phase supply.
  • This equipment can be of the vertical or horizontal gravity separator type, equipped or not with a mist eliminator, of the cyclone type, or of a distillation column ...
  • the liquid outlet may contain a small amount of bubbles driven by the speed of the liquid as the vapor outlet may contain liquid droplets or aerosols without departing from the scope of the invention.
  • Other applications include recovering a methane-rich fluid and a methane-depleted fluid from a source rich in various hydrocarbons. In this way, it is also possible to obtain several fluids such as a fraction rich in methane, a fraction rich in ethane or ethylene, and a C3 + fraction.
  • This type of process makes it possible in particular to recover hydrogen with a purity of approximately 95% from a mixture of hydrogen and hydrocarbons, to eliminate a part of the nitrogen contained in gas rich in hydrocarbons. hydrocarbons. It also makes it possible to recover a fraction very rich in CO2 and a waste gas containing lighter constituents such as N 2 , Argon, O 2 ...
  • This fractionation may not be a goal in itself but only a means to provide cooling capacity for liquefying another fluid such as natural gas.
  • the various separated fluids are recombined after heating, recompressed and reinjected into the exchange line. This is called a refrigeration cycle.
  • the exchangers may be of the coil type, tube exchanger and shell or preferably of the plate heat exchanger type.
  • numerous improvements have been made to the exchange waves and the introduction of fluids, in particular two-phase fluids, into these exchangers in order to optimize the heat transfer.
  • This example relates to obtaining hydrogen under pressure at a purity of 95% from a gaseous mixture under pressure containing approximately 70% of hydrogen, 18% methane and 12% heavier hydrocarbons.
  • the mixture to be separated 1 is introduced at ambient temperature and under a pressure of 40 bar absolute into the plate heat exchanger 10 to be cooled via the exchange passages 11.
  • the fluid 1 At a first temperature level depending on the composition of the hydrocarbons, heavier and pressure, generally from -40 to -120 ° C., the fluid 1, then two-phase, is extracted from the exchanger and separated into its vapor fraction 2 and its liquid fraction 3 in the liquid-gas separator 30.
  • the liquid fraction 3 is released via the expansion valve 50 to low pressure and revaporized in the exchange line via the exchange passages 13.
  • the vapor phase 2 enriched in hydrogen and methane is again cooled in the exchanger 20 via the passages 22, partially condensed and extracted to - 160 ° C.
  • the vapor fraction 4 from the separator 40 constitutes the production of hydrogen at 95% molar content. It is then reheated in the passages 24 and 14 of the exchangers 20 and 10.
  • the liquid fraction 5 consisting mainly of methane is expanded at low pressure in the valve 60, revaporized in the exchanger 20 (passages 24) and reheated in the exchanger 10 (passages 14).
  • the fluids 6 and 7 associated respectively with the exchangers 20 and 10 may optionally be used as a refrigerating auxiliary. It may be external fluids such as liquid nitrogen from a storage or a nearby air separation device, or a fluid internal to the process, such as a fraction of the hydrogen produced, partially heated and then expanded in an expansion turbine and reinjected at the cold end of the exchanger 20.
  • expansion valves 50 and 60 serve to relax liquids with a high pressure, here 40 bar abs., Until low pressure. It is therefore small valves.
  • the procedure for obtaining the normal operating conditions here a first cut-off temperature between the exchangers 10 and 20 of -80 ° C. for example and a cold end temperature of -80 ° C., is called the cold-setting of the exchange line. 160 ° c to obtain the required purity from equipment at room temperature or ambient, if the exchange line has not had time to reach the ambient temperature.
  • the problem of a cooling using the only free expansion of the gas to be treated in the expansion valves 50, 60 and possibly 70 is that the total flow expanded is very low and therefore the cooling capacity obtained is itself very low.
  • this cooling capacity is intended to cool the exchange line, ancillary equipment such as separators, to compensate for heat losses, ie exchanges with the outside environment ... Such cooling can take place. dozens of hours and even possibly not to achieve the desired operating point.
  • cooling supply circuits 6 and 7 for example to hasten the cold setting.
  • These passages 26 and 27 can be used permanently or only temporarily during the cooling phases.
  • liquid nitrogen at low or preferably medium pressure to accelerate the achievement of target temperature levels.
  • brazed aluminum plate heat exchangers which to date constitute the bulk of the exchange lines of cryogenic gas separation or liquefaction units.
  • a method of cryogenic separation, refrigeration or liquefaction of a fluid by means of an exchange line comprising:
  • phase separator The separation of said two-phase fluid into at least one vapor fraction and a liquid fraction in a phase separator
  • At least one of the first and second expansion means is a valve
  • the first and the second detent means are installed in parallel; steam is sent from the phase separator to a third expansion means and, during the cooling of said exchange line, at least a fraction of the steam is expanded in a second expansion means in parallel with the third means of relaxation;
  • the CV of the second expansion means equals 3 times the CV, preferably 5 times the CV of the first expansion means;
  • the CV of the second expansion means equals 3 times the CV, preferably 5 times the CV of the third expansion means;
  • the second expansion means is manually controlled or the pressure of the supply gas is regulated;
  • the cryogenic separation is a process for separating hydrocarbons or producing hydrogen, preferably of 90 to 98% purity or production of CO2, preferably of greater than 95% purity, still more preferably greater than 98% or a process for removing nitrogen or argon from a heavier fraction or the liquefaction is liquefaction of natural gas.
  • This figure shows the modifications made to the cold end of the exchange line described above. These modifications can also be made at the first separator pot 30 and more generally at each expansion of a liquid fraction.
  • the invention consists in adding to the diagram corresponding to the normal operation in steady state mode, a so-called chilling expansion valve used only (or mainly) during start-up of the unit.
  • this valve is twofold. It first allows to relax a large flow of gas thus considerably increasing the cooling capacity produced by the unit itself, that is to say that it reduces the cold time and normally allows it alone to achieve the required levels of temperature.
  • this valve allows first to partially cool the equipment and to limit all the thermal shocks but especially to rebalance the exchange line by circulating large flows in the revaporization passages 25 and 13.
  • This new valve must therefore allow to relax a large fraction of the high pressure gas, here the fluid 2, and to introduce this expanded fluid into the passages 25 devolved normally to the liquid fraction 5.
  • This valve will preferably be installed in bypass of the expansion valve 60. It will then be about 10 times larger. This is the valve 61 of Figure 2.
  • valve 81 It is also possible to add a valve between the fluid 2, that is to say between the outlet of the exchanger and the separator pot 40, and the inlet of the passages 25: this is then the valve 81.
  • the additional expansion valve 61, 71 or 81 may pass a flow of an order of magnitude at least 10 times greater than that able to be expanded in the valve 60 or 70.
  • This additional valve will be gradually closed as and when cold, especially since liquid will appear at the outlet of the exchanger.
  • HIC human operator controlled
  • PIC high pressure
  • valves it is not possible with the vast majority of commercial valves to have both a valve to pass a large gas flow, ie to have a CV at full opening 10 or more and then regulate with an opening corresponding to a CV of about 0.3. It is conventional to use a valve in an opening range of a factor 5, preferably 3, ie for example with a CV of 0.1 to 0.5 or 0.1 to 0.3 but not beyond.
  • a factor of 5 (or 3) usually makes it possible to perform the nominal run and the reduced (reduced flow) steps without any particular regulation problem.
  • the expansion valve 60 makes it possible to maintain the level liquid in the separator pot 40. It therefore controls the liquid flow expanded and revaporized in the exchange line. This flow being the main refrigeration supply of the exchanger 20, it is understood that its regulation is critical. It would be totally impossible with an oversized valve, let alone with a valve 10 times larger than necessary.

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Separation By Low-Temperature Treatments (AREA)
EP08788101.7A 2007-04-13 2008-04-02 Verfahren zur kühlung einer kryogenen austauschleitung Active EP2137475B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0754462A FR2914990B1 (fr) 2007-04-13 2007-04-13 Procede de mise en froid d'une ligne d'echange cryogenique.
PCT/FR2008/050575 WO2008139085A2 (fr) 2007-04-13 2008-04-02 Procédé de mise en froid d'une ligne d'échange cryogénique

Publications (2)

Publication Number Publication Date
EP2137475A2 true EP2137475A2 (de) 2009-12-30
EP2137475B1 EP2137475B1 (de) 2018-06-27

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
EP08788101.7A Active EP2137475B1 (de) 2007-04-13 2008-04-02 Verfahren zur kühlung einer kryogenen austauschleitung

Country Status (5)

Country Link
US (1) US20100126215A1 (de)
EP (1) EP2137475B1 (de)
CN (1) CN102099647A (de)
FR (1) FR2914990B1 (de)
WO (1) WO2008139085A2 (de)

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US20100313598A1 (en) * 2009-06-16 2010-12-16 Daly Phillip F Separation of a Fluid Mixture Using Self-Cooling of the Mixture
EP2407741A1 (de) * 2010-07-14 2012-01-18 Alstom Technology Ltd Energieeffiziente Herstellung von CO2 aus Verbrennungsabgasen mittels einstufiger Expansion und Pumpen zur Verdampfung unter erhöhtem Druck
IN2014CN00681A (de) * 2011-07-01 2015-04-03 Brooks Automation Inc
US11428463B2 (en) * 2013-03-15 2022-08-30 Chart Energy & Chemicals, Inc. Mixed refrigerant system and method
CA2971646C (en) * 2014-12-29 2023-05-23 Shell Internationale Research Maatschappij B.V. Method and apparatus for cooling down a cryogenic heat exchanger and method of liquefying a hydrocarbon stream
US10281203B2 (en) * 2016-08-05 2019-05-07 L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Method for liquefaction of industrial gas by integration of methanol plant and air separation unit
US10288346B2 (en) * 2016-08-05 2019-05-14 L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Method for liquefaction of industrial gas by integration of methanol plant and air separation unit
CN113227690A (zh) * 2019-01-25 2021-08-06 乔治洛德方法研究和开发液化空气有限公司 用于供应处于压力下的备用气体的方法和设备
FR3099559B1 (fr) * 2019-08-01 2021-07-16 Air Liquide Procédé de liquéfaction de gaz naturel avec configuration d’échangeur améliorée
WO2022003128A1 (de) * 2020-07-02 2022-01-06 Christian Blank Gasgemisch-zerlegungsanlage sowie verfahren zum abtrennen von wenigstens einem hauptfluid aus einem gasgemisch

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WO2008139085A2 (fr) 2008-11-20
US20100126215A1 (en) 2010-05-27
EP2137475B1 (de) 2018-06-27
FR2914990A1 (fr) 2008-10-17
CN102099647A (zh) 2011-06-15
FR2914990B1 (fr) 2010-02-26
WO2008139085A3 (fr) 2013-02-28

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