EP2148650A2 - Agents cosmétiques contenant des phéromones - Google Patents

Agents cosmétiques contenant des phéromones

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Publication number
EP2148650A2
EP2148650A2 EP08708851A EP08708851A EP2148650A2 EP 2148650 A2 EP2148650 A2 EP 2148650A2 EP 08708851 A EP08708851 A EP 08708851A EP 08708851 A EP08708851 A EP 08708851A EP 2148650 A2 EP2148650 A2 EP 2148650A2
Authority
EP
European Patent Office
Prior art keywords
group
composition according
formula
acid
alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
EP08708851A
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German (de)
English (en)
Inventor
Rolf Bayersdörfer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
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Publication date
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Publication of EP2148650A2 publication Critical patent/EP2148650A2/fr
Ceased legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/63—Steroids; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A61K8/8182—Copolymers of vinyl-pyrrolidones. Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q13/00—Formulations or additives for perfume preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring

Definitions

  • the present invention relates to cosmetic compositions containing certain pheromones and at least one film-forming and / or setting polymer, and the use of these agents for the treatment of keratinous fibers, in particular for the temporary deformation of these fibers.
  • all animal hairs e.g. Wool, horsehair, angora hair, furs, feathers and products or textiles made from them.
  • the keratinic fibers are human hairs.
  • Cosmetic products have become an indispensable part of modern life. They serve the cleaning, care and decorative change of the body, especially the skin and the hair, and thus ultimately the well-being of the user.
  • the cosmetic product contains a wide variety of ingredients, with a number of the active substances having an intrinsic odor that the user perceives as unpleasant.
  • cosmetic agents have long been added to individual fragrances or perfume mixtures, so-called perfume compositions. It is quite possible that a single perfume or a component of the perfume composition in pure form or high concentration has a smell that is perceived as unpleasant. However, if the respective components are used in optimized concentration and / or mixture, the desired pleasant odor experience results.
  • fragrances are a variety of different chemical compounds in question, which are often naturally occurring compounds that can be extracted from about plants. However, nature-identical and artificial fragrances also play a major role. Of particular interest are fragrances which, in addition to the fragrance-giving property, possess other desired properties, such as nourishing or antioxidant effects.
  • pheromones in perfume compositions and cosmetics has already been proposed.
  • the term pheromone is understood to mean, even in very low concentrations, effective signaling substances which serve to chemically communicate organisms of a species. Pheromones come in the communication Systems of almost all organisms from unicellular organisms to mammals and play a prominent role as a sex attractant.
  • cosmetic means which contain at least one film-forming and / or setting polymer in addition to the pheromone.
  • a first subject of the present invention is therefore cosmetic compositions comprising, in a cosmetically acceptable carrier a) 1 ⁇ 10 -7 to 1 ⁇ 10 -2 % by weight of at least one steroid selected from 16-androsteno-steroids of the formula (I)
  • R 1 represents an oxo group, a hydroxy group, a C 1 -C 6 -alkoxy, an acyloxy or a benzoyloxy group,
  • R 2 is hydrogen, hydroxy, dC 6 alkyl, hydroxyC 1 -C 6 alkyl, C 1 -
  • Ce-alkoxy-d-Ce-alkyl C 1 -C 6 -alkoxy, acyl, acyloxy, acyl-dC 6 alkyl or
  • R 4 is an oxo group, hydrogen, hydroxy, dC 6 alkyl, sulfate, 3-cyclopentylpropionate or acetate
  • R 5 is hydrogen or hydroxy
  • R 6 is hydrogen, a Ci-C6-Al ky Ig roup, a benzoyl, 3-Cyclopentylpropionat-, acetyl, C 1 -C 6 -ACyI- or a sulfate group, and the dotted line c represents an optional double bond and b) 0.1 to 30% by weight of at least one film-forming and / or setting polymer.
  • the use of the film-forming and / or setting polymer ensures that the pheromone is continuously released in only very low concentrations. As a result, on the one hand a perceived unpleasant odor is avoided, and on the other hand ensures that a long-lasting effect is achieved. In addition, the pheromone does not released by conventional environmental influences, such as wind and moisture or body heat and sweat prematurely.
  • Film-forming and / or setting polymers are often constituents of cosmetic agents for the temporary deformation of keratinic fibers, for example hair sprays, hair waxes, hair gels, hair waving, etc.
  • other polymers such as skin treatment agents, may also be used in such polymers.
  • the cosmetic agents according to the invention are agents for the treatment, in particular deformation of keratinic fibers, such as human hair.
  • the film-forming and / or setting polymers in this case, in addition to the task to regulate the pheromone release, the classical function as a holding and fixing ingredient.
  • the pheromone used are the abovementioned 16-androsten steroids of the formula (I) and / or estrogens of the formula (II).
  • the radical R 1 is an oxo group, ie an oxygen atom which, unlike the schematic representation of the attachment of the radical R 1 in formula (I), is attached to the ring system via a double bond, a hydroxy group, a C 1 -C 6 -alkoxy -, an acyloxy, or a benzolyoxy group and the radical R 2 is hydrogen, a hydroxy group, a C 1 -C 6 -alkyl, hydroxy-C 1 -C 6 -alkyl, C 1 -C 6 -alkoxy-C 1 -C 6 -alkyl , C 1 -C 6 -alkoxy, acyl, acyloxy, acyl-C 1 -C 6 -alkyl or acyloxy-C 1 -C 6 -alkyl group.
  • Suitable dC 6 -alkoxy groups include methoxy, ethoxy, propoxy, butoxy, pentoxy and hexyloxy.
  • Suitable acyloxy groups are in particular groups derived from the corresponding dC 6 -carboxylic acids, for example formyloxy, acetoxy or propionoxy.
  • C 1 -C 6 -alkyl groups are methyl, ethyl, propyl, isopropyl, butyl, isobutyl, tert-butyl, pentyl and hexyl, suitable hydroxy-C 1 -C 6 -alkyl groups hydroxymethyl, ⁇ -hydroxyethyl, ⁇ -hydroxyethyl, 1-hydroxypropyl, 2 Hydroxypropyl, 3-hydroxypropyl, 1-hydroxybutyl, 2-hydroxybutyl, 3-hydroxybutyl, A-hydroxybutyl, 1-hydroxypentyl, 2-hydroxypentyl, 3-hydroxypentyl, 4-hydroxypentyl, 5-hydroxy-pentyl, 1-hydroxyhexyl, 2- Hydroxyhexyl, 3-hydroxyhexyl, 4-hydroxyhexyl, 5-hydroxyhexyl and 6-hydroxyhexyl, suitable dC 6 -alkoxy-dC 6 -alkyl groups methoxymethyl, methoxyethoxy
  • the radical R 1 is an oxo group, a hydroxy group, a methoxy, an acetoxy, a proprionoxy or a Benzoyloxy distr, particularly preferably those whose radical R 1 is an oxo group or a hydroxy group.
  • the radical R 2 is hydrogen, a hydroxy group, a methyl, ethyl, n-propyl, iso-propyl, methoxy or ethoxy group, particularly preferably those , whose radical R 2 is hydrogen or a methyl group.
  • a most preferred pheromone is 4,16-androstadien-3-one, which is represented in formula.
  • Preferred Estrensteroide are compounds of formula (II), wherein R 4 is an oxo group, a hydroxy group or hydrogen.
  • Particularly preferred estrogens are compounds of the formula (II) in which R 4 , R 5 and R 6 have the abovementioned preferred meanings. Specifically, mention may be made of 1, 3,5 (10) -atratriene-3,17 ⁇ -diol, 1,3,5 (10) -atratriene-3,16 ⁇ , 17 ⁇ -triol, 1, 3,5 (10) -stratriene 3-ol-17-one and 1, 3,5 (10), 16-estratraven-3-ol. Very particular preference is 1, 3,5 (10), 16-Estratetraen-3-ol.
  • compositions according to the invention comprise a mixture of at least one 16-androstene steroid of the formula (I) and at least one estrogen steroid of the formula (II), where again 16-androstenoids of the formula (I) and estrogens of the formula (II) according to the above Embodiments are preferred and particularly preferred.
  • the composition comprises a mixture of 4,16-androstadien-3-one and 1,3,5 (10), 16-estratetraen-3-ol.
  • compositions of the invention contain the steroid or steroid mixture in an amount of 1 x 10 -7 to 1 x 10 -2 wt%, preferably in an amount of 1 x 10 -5 to 5 x 10 3 wt%, especially preferably in an amount of from 3 ⁇ 10 -4 to 1 ⁇ 10 3 % by weight, in each case based on the total cosmetic agent, wherein in the event that the cosmetic agent contains propellant, this is disregarded. If a mixture of different steroids is used, the amounts given refer to the sum of the steroids used, it being possible for the ratio of the various steroids with one another to be varied freely.
  • composition comprises a mixture of at least one 16-androstene steroid of the formula (I) and at least one estrogen steroid of the formula (II), 16-androstene steroid and estrogen steroid are preferably used in amounts such that the weight ratio of the sum of the 16-androstene steroids used Sum of Estrensteroide used is 1: 100 to 100: 1, preferably 1:10 to 10: 1.
  • compositions according to the invention also contain from 0.1 to 30% by weight, based on the total agent, of at least one film-forming and / or setting polymer. If the cosmetic contains propellant, it will be disregarded when calculating the appropriate proportions.
  • the film-forming and / or setting polymer is preferably contained in the composition in an amount of from 0.5 to 25% by weight, more preferably from 1 to 20% by weight, based on the total agent. Of course, several film-forming and / or setting polymers may be included.
  • film-forming and / or setting polymers may be both permanent and temporary cationic, anionic, nonionic or amphoteric.
  • the present invention also includes the recognition that when using at least two film-forming and / or setting polymers these can of course have different charges. It may be preferred according to the invention for an ionic film-forming and / or setting polymer to be used together with an amphoteric and / or nonionic film-forming and / or setting polymer. The use of at least two oppositely charged film-forming and / or setting polymers is also preferred. In the latter case, a particular embodiment may in turn additionally contain at least one further amphoteric and / or nonionic film-forming and / or setting polymer.
  • Film-forming polymers are polymers which leave a continuous film on the skin, the hair or the nails when drying.
  • Such film formers can be used in a wide variety of cosmetic products, such as for example face masks, make-up, hair fixatives, hair sprays, hair gels, hair waxes, hair treatments, shampoos or nail varnishes.
  • Particular preference is given to those polymers which have sufficient solubility in alcohol or water / alcohol mixtures in order to be present in completely completely dissolved form in the agent according to the invention.
  • the film-forming polymers may be of synthetic or natural origin.
  • film-forming polymers are understood as meaning polymers which, when used in 0.01 to 20% strength by weight aqueous, alcoholic or aqueous-alcoholic solution, are capable of depositing a transparent polymer film on the hair.
  • the film-forming polymers may be anionic, amphoteric, nonionic, permanent cationic or temporarily cationically charged.
  • Suitable synthetic, film-forming, hair-fixing polymers are homopolymers or copolymers which are composed of at least one of the following monomers: vinylpyrrolidone, vinylcaprolactam, vinyl esters such as vinyl acetate, vinyl alcohol, acrylamide, methacrylamide, alkyl and dialkylacrylamide, alkyl and dialkylmethacrylamide, alkyl acrylate, alkyl methacrylate, Propylene glycol or ethylene glycol, wherein the alkyl groups of these monomers are preferably C 1 - to C 7 alkyl groups, more preferably C 1 - to C 3 alkyl groups.
  • Examples include homopolymers of vinylcaprolactam, vinylpyrrolidone or N-vinylformannide.
  • Further suitable synthetic film-forming, hair-fixing polymers are copolymers of vinyl pyrrolidone and vinyl acetate, terpolymers of vinylpyrrolidone, vinyl acetate and vinyl propionate, polyacrylamides, for example, under the trade designations Akypomine ® P 191 by the company CHEM-Y, Emmerich or Sepigel ® 305 by the company Seppic be distributed; Polyvinyl alcohols, which are marketed under the trade names Elvanol.RTM ® from DuPont or Vinol ® 523/540 by Air Products as well as polyethylene glycol / polypropylene glycol copolymers, for example, Ucon ® Union Carbide sold under the trade names.
  • Suitable natural film-forming polymers are for example CeIIu losederivate, z.
  • Firming polymers contribute to the maintenance and / or build-up of the hair volume and hair fullness of the overall hairstyle.
  • These so-called setting polymers are at the same time film-forming polymers and therefore generally typical substances for shaping hair treatment compositions such as hair fixatives, hair foams, hair waxes, hair sprays.
  • the film formation can be quite selective and connect only a few fibers.
  • Substances which further impart hydrophobic properties to the hair are preferred because they reduce the tendency of the hair to absorb moisture, that is, water. As a result, the limp drooping of the strands of hair is reduced, thus ensuring a long-lasting hairstyle structure and preservation.
  • the test method for this is often the so-called curl retention test applied.
  • These polymeric substances can also be successfully incorporated into leave-on and rinse-off hair treatments or shampoos. Since polymers are often multifunctional, that is, show several applications-wise desirable effects, numerous polymers can be found in several groups on the mode of action, as well as in the CTFA Handbook. Because of the importance of polymers in particular, they should therefore be listed explicitly in the form of their INCI names. In this list of polymers preferably to be used according to the invention, it will be obvious, of course, that the above-mentioned film-forming polymers are again used.
  • Examples of common film-forming, setting polymers are acrylamide / ammonium acrylate copolymer, acrylamide / DMAPA acrylates / methoxy PEG methacrylate copolymer, Acrylamidopropyltrimonium Chloride / Acrylamide Copolymer, Acrylamidopropyltrimonium Chloride / Acrylates Copolymer, Acrylates / Acetoacetoxyethyl Methacrylate Copolymer, Acrylates / Acrylamide Copolymer, Acrylates / Ammonium Methacrylate Copolymer, Acrylates / t-Butylacrylamide Copolymer, Acrylates Copolymer, Acrylates / C1-2 Succinates / Hydroxy Acrylates Copolymer, Acrylates / Lauryl Acrylates / Stearyl Acrylates / Ethylamine Oxides Methacrylate Copolymer, Acrylates / Octylacrylamide Copolymer
  • a particularly uniform release of the pheromones and a long-lasting, stable effect can be achieved if the agent contains film-forming and / or setting polymers, which have proven to be particularly insensitive to environmental influences, in particular moisture.
  • film-forming and / or setting polymers are used.
  • the agent according to the invention therefore preferably comprises at least one film-forming and / or setting polymer selected from
  • Ci_ 2 alkyl succinates with hydroxyalkyl acrylates and one or more monomers selected from acrylic acid, methacrylic acid, acrylic acid esters and Methacryl Text ester.
  • composition according to the invention particularly preferably contains as film-forming and / or setting polymer an aminomethylpropanol salt of a copolymer of allyl methacrylate with one or more monomers selected from acrylic acid, methacrylic acid, acrylic ester and methacrylic acid ester.
  • the said Acrylklareestern and methacrylic acid esters to C-rC-i ⁇ alkyl acrylates and alkyl methacrylates dC 12 more preferably methyl acrylate, ethyl acrylate, propyl acrylate, methyl methacrylate, ethyl methacrylate, propyl methacrylate and mixtures thereof.
  • a preferred vinylpyrrolidone-vinyl acetate copolymer is the PVP / VA copolymer 60-40 W (INCI name: VP / VA copolymer, Aqua, Laurtrimonium Chloride).
  • the vinylpyrrolidone-vinylcaprolactam / dimethylaminopropylacrylamide copolymer used is preferably the copolymer obtainable from ISP under the name Aquaflex SF 40 and having the INCI name VP / vinyl caprolactam / DMAPA acrylates copolymer.
  • a preferred copolymer of the Octylacrylamids with t-butylaminoethyl methacrylate and two or more monomers selected from acrylic acid, methacrylic acid, acrylate and methacrylate esters, is that available from National Starch under the name Amphomer ® Copolymer with the INCI name octylacrylamide / acrylates butylaminoethyl methacrylate copolymer.
  • the agents according to the invention may furthermore contain all active substances, additives and auxiliaries known for such agents. Particular importance is attached to the care substances.
  • compositions according to the invention therefore preferably contain at least one silicone oil and / or one silicone gum.
  • Silicone oils or silicone gums which are suitable according to the invention are, in particular, dialkyl and alkylaryl siloxanes, for example dimethylpolysiloxane and methylphenylpolysiloxane, and also their alkoxylated, quaternized or else anionic derivatives. Preference is given to cyclic and linear polydialkylsiloxanes, their alkoxylated and / or aminated derivatives, dihydroxypoly-dimethylsiloxanes and polyphenylalkylsiloxanes.
  • Silicone oils cause a wide variety of effects. For example, at the same time they influence the dry and wet combability, the grip of dry and wet hair and the shine.
  • the term silicone oils is understood by the person skilled in the art as meaning several structures of silicon-organic compounds. Initially, these are understood to mean the dimethiconols (S1). These may be both linear and branched as well as cyclic or cyclic and branched. Linear dimethiconols can be represented by the following structural formula (S1-I):
  • Branched dimethiconols can be represented by the structural formula (S1-II): R 2
  • the radicals R 1 and R 2 are each independently hydrogen, a methyl radical, a C 2 to C 30 linear, saturated or unsaturated hydrocarbon radical, a phenyl radical and / or an aryl radical.
  • the groups represented by R 1 and R 2 include alkyl groups such as methyl, ethyl, propyl, isopropyl, butyl, isobutyl, pentyl, isopentyl, neopentyl, amyl, isoamyl, hexyl, isohexyl and the like; Alkenyl radicals such as vinyl, halovinyl, alkylvinyl, allyl, haloallyl, alkylallyl; Cycloalkyl radicals such as cyclobutyl, cyclopentyl, cyclohexyl and the like; Phenyl radicals, benzyl radicals, halohydrocarbon radicals such as 3-chloropropyl, A
  • the numbers x, y and z are integers and each run independently from 0 to 50,000.
  • the molecular weights of the dimethiconols are between 1,000 D and 10000000 D.
  • the viscosities are between 100 and 10,000,000 cPs measured at 25 0 C by means of a glass capillary viscometer according to Dow Corning Corporate Test Method CTM 0004 dated 20 July 1970.
  • Preferred viscosities are from 1000 to 5,000,000 cPs, most preferred viscosities are between 10,000 and 3,000,000 cps. The most preferred range is between 50,000 and 2,000,000 cps.
  • Examples of such products include the following commercial products: Botanisil NU-150M (Botanigenics), Dow Coming 1-1254 Fluid, Dow Corning 2-9023 Fluid, Dow Corning 2-9026 Fluid, Ultrapure Dimethiconol (Ultra Chemical), Unisil SF- R (Universal Preserve), X-21-5619 (Shin-Etsu Chemical Co.), Abil OSW 5 (Degussa Care Speciales), ACC DL-9430 Emulsion (Taylor Chemical Company), AEC Dimethiconol & Sodium Dodecylbenzenesulfonate (A & E Connock (Perfumery & Cosmetics) Ltd.), BC Dimethiconol Emulsion 95 (Basildon Chemical Company, Ltd.), Cosmetic Fluid 1401, Cosmetic Fluid 1403, Cosmetic Fluid 1501, Cosmetic Fluid 1401 DC (all aforementioned Chemsil Silicones, Inc.), Dow Corning 1401 Fluid, Dow Corning 1403 Fluid, Dow Corning 1501 Fluid, Dow Corning 1784 H
  • Dimethicones form the second group of silicones which may be present according to the invention. These may be both linear and branched as well as cyclic or cyclic and branched. Linear dimethicones can be represented by the following structural formula (S2-I):
  • Branched dimethicones can be represented by the structural formula (S2 - II):
  • the radicals R 1 and R 2 are each independently hydrogen, a methyl radical, a C 2 to C 30 linear, saturated or unsaturated hydrocarbon radical, a phenyl radical and / or an aryl radical.
  • the groups represented by R 1 and R 2 include alkyl groups such as methyl, ethyl, propyl, isopropyl, butyl, isobutyl, pentyl, isopentyl, neopentyl, amyl, isoamyl, hexyl, isohexyl and the like; Alkenyl radicals such as vinyl, halovinyl, alkylvinyl, allyl, haloallyl, alkylallyl; Cycloalkyl radicals such as cyclobutyl, cyclopentyl, cyclohexyl and the like; Phenyl radicals, benzyl radicals, halohydrocarbon radicals such as 3-chloropropyl, A
  • the numbers x, y and z are integers and each run independently from 0 to 50,000.
  • the molecular weights of Dimethicone lie between 1,000 D and 10000000 D.
  • the viscosities are between 100 and 10,000,000 cPs measured at 25 0 C by means of a glass capillary viscometer according to Dow Corning Corporate Test method CTM 0004 of 20 July 1970.
  • Preferred viscosities are between 1000 and 5000000 cPs, particularly preferred viscosities are between 10,000 and 3,000,000 cPs. Most preferably, the viscosity is in the range between 50,000 and 200,000 cps.
  • Dimethicone copolyols (S3) form another group of silicones that are suitable. Dimethicone copolyols can be represented by the following structural formulas:
  • Branched dimethicone copolyols can be represented by the structural formula (S3-IM):
  • the radicals R 1 and R 2 are each independently hydrogen, a methyl radical, a C 2 to C 30 linear, saturated or unsaturated hydrocarbon radical, a phenyl radical and / or an aryl radical.
  • the groups represented by R 1 and R 2 include alkyl groups such as methyl, ethyl, propyl, isopropyl, butyl, isobutyl, pentyl, isopentyl, neopentyl, amyl, isoamyl, hexyl, isohexyl and the like; Alkenyl radicals such as vinyl, halovinyl, alkylvinyl, allyl, haloallyl, alkylallyl; Cycloalkyl radicals such as cyclobutyl, cyclopentyl, cyclohexyl and the like; Phenyl radicals, benzyl radicals, halohydrocarbon radicals such as 3-chloropropyl, A
  • PE stands for a polyoxyalkylene radical.
  • preferred Polyoxyalkylene radicals are derived from ethylene oxide, propylene oxide and glycerol.
  • the numbers x, y and z are integers and each run independently from 0 to 50,000.
  • the molecular weights of Dimethicone lie between 1,000 D and 10000000 D.
  • the viscosities are between 100 and 10,000,000 cPs measured at 25 0 C by means of a glass capillary viscometer according to Dow Corning Corporate Test Method CTM 0004 dated 20 July 1970.
  • Preferred viscosities are 1000-5000000 cPs, most preferred viscosities are between 10,000 and 3,000,000 cps. The most preferred range is between 50,000 and 2,000,000 cps.
  • dimethicone copolyols are commercially available and are sold, for example, by Dow Corning under the name Dow Corning® 5330 Fluid.
  • the Dimethiconole, Dimethicone and / or Dimethiconcopolymere already be present as an emulsion.
  • the corresponding emulsion of dimethiconols, dimethicones and / or dimethicone copolyols can be prepared both after the preparation of the corresponding dimethiconols, dimethicones and / or dimethicone copolyols from these and the conventional methods of emulsification known to the person skilled in the art.
  • both cationic, anionic, nonionic or zwitterionic surfactants and emulsifiers can be used as auxiliaries for the preparation of the corresponding emulsions.
  • the emulsions of dimethiconols, dimethicones and / or dimethicone copolyols can also be prepared directly by an emulsion polymerization process.
  • Such methods are also well known to the person skilled in the art. For example, reference may be made to the Encyclopedia of Polymer Science and Engineering, Volume 15, Second Edition, pages 204 to 308, John Wiley & Sons, Inc. 1989. This reference is expressly incorporated herein by reference.
  • the droplet size of the emulsified particles is according to the invention 0.01 to 10000 microns, preferably 0.01 to 100 .mu.m, more preferably 0.01 to 20 microns and most preferably 0 , 01 to 10 ⁇ m.
  • the particle size is determined by the method of light scattering.
  • branched dimethiconols, dimethicones and / or dimethicone copolyols are used, it is to be understood that the branching is greater than a random branching, which occurs randomly due to impurities of the respective monomers.
  • branched dimethiconols, dimethicones and / or dimethicone copolyols are therefore to be understood as meaning that the degree of branching is greater than 0.01%.
  • Preferred is a Degree of branching greater than 0.1%, and most preferably greater than 0.5%.
  • the degree of branching is determined from the ratio of the unbranched monomers to the branching monomers, that is, the amount of tri- and tetrafunctional siloxanes. According to the invention, both low-branched and highly branched dimethiconols, dimethicones and / or dimethicone copolyols can be very particularly preferred.
  • Suitable silicones are furthermore amino-functional silicones (S4), in particular the silicones which are grouped under the INCI name amodimethicones. These are silicones which have at least one, optionally substituted, amino group.
  • Such silicones may e.g. by the formula (S4-I)
  • R in the above formula is a hydrocarbon or a hydrocarbon group having from 1 to about 6 carbon atoms
  • Q is a polar group of the general formula -R 1 Z wherein R 1 is a divalent linking group attached to hydrogen and Z is an organic, amino-functional radical containing at least one amino-functional group, carbon and hydrogen atoms, carbon, hydrogen and oxygen atoms or carbon, hydrogen and nitrogen atoms;
  • "a” assumes values in the range of about 0 to about 2
  • "b” assumes values in the range of about 1 to about 3
  • "a” + "b” is less than or equal to 3
  • "c” is a number in the range from about 1 to about 3
  • x is a number ranging from 1 to about 2,000, preferably from about 3 to about 50, and most preferably from about 3 to about 25
  • y is a number ranging from about 20 to about 10,000 , preferably from about 125 to about 10,000, and most preferably from about 150 to about 1,000
  • M is a suitable silicone
  • Non-limiting examples of the groups represented by R include alkyl groups such as methyl, ethyl, propyl, isopropyl, butyl, isobutyl, amyl, isoamyl, hexyl, isohexyl and the like; Alkenyl radicals such as vinyl, halovinyl, alkylvinyl, allyl, haloallyl, alkylallyl; Cycloalkyl radicals such as cyclobutyl, cyclopentyl, cyclohexyl and the like; Phenyl radicals, benzyl radicals, halohydrocarbon radicals such as 3-chloropropyl, A-bromobutyl, 3,3,3-trifluoropropyl, chlorocyclohexyl, bromophenyl, chlorophenyl and the like, as well as sulfur-containing radicals such as mercaptoethyl, mercaptopropyl, mercapto
  • R 1 examples include methylene, ethylene, propylene, hexamethylene, decamethylene, -CH 2 CH (CH 3 ) CH 2 -, phenylene, naphthylene, -CH 2 CH 2 SCH 2 CH 2 -, - CH 2 CH 2 OCH 2 -, -OCH 2 CH 2 -, -OCH 2 CH 2 CH 2 -, -CH 2 CH (CH 3 ) C (O) OCH 2 -, - (CH 2 ) 3 C (O) OCH 2 CH 2 -, - C 6 H 4 C 6 H 4 -, -C 6 H 4 CH 2 C 6 H 4 -; and - (CH 2 ) 3 C (O) SCH 2 CH 2 -.
  • Z is an organic, amino-functional radical containing at least one functional amino group.
  • a possible formula for Z is NH (CH 2 ) Z NH 2 , where z is an integer from 1 to 50.
  • Another possible formula for Z is -NH (CH 2 ) Z NH (CH 2 ) zz , in which both z and zz independently of one another represent an integer from 1 to 50, this structure comprising diamino ring structures, such as piperazinyl.
  • Z is particularly preferably a -NHCH 2 CH 2 NH 2 radical.
  • Z is -N (CH 2 ) Z NX 1 X 2 or -NX 1 X 2 , wherein each of X 1 and X 2 is independently selected from hydrogen and a hydrocarbon radical having from 1 to about 6 carbon atoms.
  • Q is a polar, amine-functional radical of the formula - CH 2 CH 2 CH 2 NHCH 2 CH 2 NH 2 .
  • the molar ratio of R 3 Q b SiO (. 4 a - b) / 2 units to the R 0 SiO (. 4 C) / 2 units is in the range of about 1: 2 to 1: 65, preferably from about From 1: 5 to about 1:65 and more preferably from about 1:15 to about 1: 20.
  • the various variable substituents in the above formula may be used for the various silicone components described in U.S. Pat Silicone blend exist, be different.
  • Preferred amino-functional silicones correspond to the formula (S4 - II)
  • G is -H, a phenyl group, -OH, -O-CH 3 , -CH 3 , -CH 2 CH 3 , -CH 2 CH 2 CH 3 ,
  • a is a number between 0 and 3, in particular 0;
  • b is a number between 0 and 1, in particular 1,
  • n and n are numbers whose sum (m + n) is between 1 and 2000, preferably between 50 and 150, where n is preferably values from 0 to 1999 and in particular from 49 to 149 and m preferably values from 1 to 2000, in particular from 1 to 10,
  • R ' is a monovalent radical selected from o -N (R ") - CH 2 -CH 2 - N (R 11 J o 2 -N (R 11 J 2 o -N + (FT) 3 A- o -N + H (FT) 2 A " o -N + H 2 (Fr) A " o -N (R ”) - CH 2 -CH 2 -N + R” H 2 A-, wherein each R "is identical or different radicals from the group -H, - phenyl, -benzyl, the Ci_ 20 -alkyl radicals, preferably -CH 3 , -CH 2 CH 3 , -CH 2 CH 2 CH 3 , -CH (CH 3 ) 2 , -CH 2 CH 2 CH 2 CH 3 , -CH 2 CH (CH 3 ) 2 ,
  • A- represents an anion, which is preferably selected from chloride, bromide, iodide or methosulfate.
  • Particularly preferred amino-functional silicones correspond to the formula (S4 - III)
  • m and n are numbers whose sum (m + n) is between 1 and 2000, preferably between 50 and 150, where n is preferably values from 0 to 1999 and in particular from 49 to 149 and m preferably values from 1 to 2000, in particular from 1 to 10.
  • silicones are referred to as trimethylsilylamodimethicones according to the INCI declaration.
  • R is -OH, -O-CH 3 or a -CH 3 group and m
  • n1 and n2 are numbers whose sum (m + n1 + n2) is between 1 and 2,000, preferably between 50 and 150, wherein the sum (n1 + n2) preferably assumes values from 0 to 1999 and in particular from 49 to 149 and m preferably values from 1 to 2000, in particular from 1 to 10.
  • silicones are referred to as amodimethicone according to the INCI nomenclature and are available for example in the form of an emulsion as a commercial product Dow Corning ® 949 in a mixture with a cationic and a nonionic surfactant.
  • those amino-functional silicones are used which have an amine number above 0.25 meq / g, preferably above 0.3 meq / g and especially preferably above 0.4 meq / g.
  • the amine number stands for the milliequivalents of amine per gram of the amino-functional silicone. It can be determined by titration and also expressed in mg KOH / g.
  • Suitable silicones are, for example, oligomeric polydimethylcyclosiloxanes (INCI name: cyclomethicone), in particular the tetrameric and the pentameric compound, which are available as commercial products DC 245 fluid, DC
  • Hexamethyl disiloxane (INCI name: Hexamethyldisiloxane), z. B. that under the
  • esters and partial esters of silicone-glycol copolymers such as those of the
  • Fancorsil ® LIM (INCI name:
  • anionic silicone oils such as the Dow Corning® 1784 product.
  • the agent according to the invention comprises at least two different silicone derivatives, more preferably a combination of a volatile and a nonvolatile silicone.
  • Volatile in the context of the invention are those silicones which have a volatility which is equal to or greater than the volatility of the cyclic, pentameric dimethylsiloxane.
  • Such combinations are also available as commercial products (eg, Dow Corning® 1401, Dow Corning® 1403, and Dow Corning® 1501, each containing mixtures of a cyclomethicone and a dimethiconol).
  • Preferred mixtures of different silicones are, for example, dimethicones and dimethiconols, linear dimethicones and cyclic dimethiconols.
  • a very particularly preferred mixture of silicones consists of at least one cyclic dimethiconol and / or dimethicone, at least one further noncyclic dimethicone and / or dimethiconol and at least one amino-functional silicone.
  • the mixing ratio is largely variable. However, all the silicones used for mixing are preferably used in a ratio of 5: 1 to 1: 5 in the case of a binary mixture. A ratio of 3: 1 to 1: 3 is particularly preferred. Very particularly preferred mixtures all contain in the Mixture contained silicones largely in a ratio of about 1: 1, in each case based on the amounts used in wt .-%.
  • the agents preferably contain the silicones in amounts of from 1 to 25% by weight, more preferably from 5 to 20% by weight and especially preferably from 7 to 15% by weight, based on the total agent.
  • composition according to the invention contains as care substance at least one protein hydrolyzate and / or one of its derivatives.
  • Protein hydrolysates are product mixtures obtained by acid, alkaline or enzymatically catalyzed degradation of proteins (proteins).
  • the term protein hydrolyzates also means total hydrolyzates as well as individual amino acids and their derivatives as well as mixtures of different amino acids.
  • polymers made up of amino acids and amino acid derivatives are understood by the term protein hydrolyzates. The latter include, for example, polyalanine, polyasparagine, polyserine, etc.
  • Further examples of compounds which can be used according to the invention are L-alanyl-L-proline, polyglycine, glycyl-L-glutamine or D / L-methionine-S-methylsulfonium chloride.
  • ⁇ -amino acids and their derivatives such as ⁇ -alanine, anthranilic acid or hippuric acid can also be used.
  • the molecular weight of the protein hydrolysates which can be used according to the invention is between 75, the molecular weight for glycine, and 200,000, preferably the molecular weight is 75 to 50,000 and very particularly preferably 75 to 20,000 daltons.
  • protein hydrolysates of both vegetable and animal or marine or synthetic origin can be used.
  • Animal protein hydrolysates are, for example, elastin, collagen, keratin, silk and milk protein protein hydrolysates, which may also be present in the form of salts.
  • Such products are, for example, under the trademarks Dehylan ® (Cognis), Promois® ® (Interorgana) Collapuron ® (Cognis), Nutrilan® ® (Cognis), Gelita-Sol ® (German Gelatinefabriken Stoess & Co), Lexein ® (Inolex) sericin (Pentapharm) and kerasol tm ® (Croda) sold.
  • Particularly interesting is the use of silk protein hydrolysates.
  • Protein hydrolysates of vegetable origin eg. B. soy, almond, pea, potato and wheat
  • protein hydrolysates Although the use of the protein hydrolysates is preferred as such, amino acid mixtures otherwise obtained may be used in their place, if appropriate. Also possible is the use of derivatives of protein hydrolysates, for example in the form of their fatty acid condensation products. Such products are marketed for example under the names Lamepon ® (Cognis), Lexein ® (Inolex), Crolastin ® (Croda), Crosilk ® (Croda) or Crotein ® (Croda).
  • agents according to the invention contain protein hydrolysates, they are used, for example, in concentrations of 0.01% by weight up to 20% by weight, preferably from 0.05% by weight up to 15% by weight and very particularly preferably in amounts of 0.05 wt .-% up to 5 wt .-%, each based on the total application preparation used.
  • the above-mentioned silicones and / or protein hydrolysates are preferably used, since their use has a particularly advantageous effect on the release and stability of the pheromones.
  • the agent may contain, for example, at least one cationic surfactant.
  • Cationic surfactants of the quaternary ammonium compounds, esterquats and amidoamines type are preferred according to the invention.
  • Preferred quaternary ammonium compounds are ammonium halides, in particular chlorides and bromides, such as alkyltrimethylammonium chlorides, dialkyldimethylammonium chlorides and trialkylmethylammonium chlorides, eg.
  • cetyltrimethylammonium chloride stearyltrimethylammonium chloride, distearyldimethyl ammonium chloride, lauryldimethylammonium chloride, Lauryldimethylbenzylammoniumchlorid and tricetylmethylammonium chloride, as well as those under the INCI names Quaternium-27 and Quaternium-83 known imidazolium compounds.
  • the long alkyl chains of the above-mentioned surfactants preferably have 10 to 18 carbon atoms.
  • Esterquats are known substances which contain both at least one ester function and at least one quaternary ammonium group as a structural element.
  • Preferred ester quats are quaternized ester salts of fatty acids with triethanolamine, quaternized ester salts of fatty acids with diethanolalkylamines and quaternized ester salts of fatty acids with 1,2-dihydroxypropyldialkylamines.
  • Such products are marketed under the trade names Stepantex® ®, ® and Dehyquart® Armocare® ®.
  • the alkylamidoamines are usually prepared by amidation of natural or synthetic fatty acids and fatty acid cuts with dialkylaminoamines.
  • An inventively particularly suitable compound from this group of substances under the name Tegoamid ® S 18 commercial stearamidopropyl dimethylamine is.
  • the cationic surfactants are contained in the compositions according to the invention preferably in amounts of from 0.05 to 10% by weight, based on the total application preparation. Amounts of 0.1 to 5 wt .-% are particularly preferred.
  • Nurturing polymers are also suitable as a care substance.
  • a first group of caring polymers are the cationic polymers.
  • Cationic polymers are to be understood as meaning polymers which have a group in the main and / or side chain which may be “temporary” or “permanent” cationic.
  • “permanently cationic” refers to those polymers which have a cationic group, irrespective of the pH of the agent. These are usually polymers containing a quaternary nitrogen atom, for example in the form of an ammonium group.
  • Preferred cationic groups are quaternary ammonium groups. In particular, such polymers in which the quaternary ammonium group over a C
  • R 1 -H or -CH 3
  • R 2, R 3 and R 4 are independently selected from CI_ 4 - alkyl, -alkenyl or -hydroxyalkyl groups
  • m 1, 2, 3 or 4
  • n a natural number
  • X ' is a physiologically acceptable organic or inorganic anion, as well as copolymers consisting essentially of the monomer units listed in formula (G1-I) and nonionic monomer units, are particularly preferred cationic polymers.
  • those are preferred according to the invention for which at least one of the following conditions applies:
  • R 1 is a methyl group
  • R 2 , R 3 and R 4 are methyl groups
  • m has the value 2.
  • Suitable physiologically acceptable counterions X ' are, for example, halide ions, sulfate ions, phosphate ions, methosulfate ions and organic ions such as lactate, citrate, tartrate and acetate ions. Preference is given to halide ions, in particular chloride.
  • a particularly suitable homopolymer is, if desired, crosslinked, poly (meth acryloyloxyethyltrimethylammonium chloride) with the INCI name Polyquaternium-37.
  • the crosslinking can be carried out with the aid of poly olefinically unsaturated compounds, for example divinylbenzene, tetraallyloxyethane, methylenebisacrylamide, diallyl ether, polyallylpolyglyceryl ethers, or allyl ethers of sugars or sugar derivatives such as erythritol, pentaerythritol, arabitol, mannitol, sorbitol, sucrose or glucose.
  • Methylenebisacrylamide is a preferred crosslinking agent.
  • the homopolymer is preferably used in the form of a non-aqueous polymer dispersion which should not have a polymer content of less than 30% by weight.
  • Such polymer dispersions are (under the names Salcare ® SC 95 about 50% polymer content, additional components: mineral oil (INCI name: Mineral Oil) and tridecyl-polyoxypropylene-polyoxyethylene-ether (INCI name: PPG-1 trideceth-6) ) and Salcare ® SC 96 (about 50% polymer content, additional components: mixture of diesters of propylene glycol (with a mixture of caprylic and capric acid INCI name: propylene glycol Dicaprylate / Dicaprate) and tridecyl polyoxypropylene-polyoxyethylene ether (INCI name: PPG-1-Trideceth-6)) are commercially available.
  • Copolymers with monomer units of the formula (G1-I) as the non-ionic monomer preferably acrylamide, methacrylamide, acrylic acid and methacrylic acid alkyl esters CI_ 4-C- ⁇ - 4 -alkyl.
  • the acrylamide is particularly preferred.
  • These copolymers can also be crosslinked, as described above in the case of the homopolymers.
  • a copolymer preferred according to the invention is the crosslinked acrylamide-methacryloyloxyethyltrimethylammonium chloride copolymer.
  • Such copolymers in which the monomers are present in a weight ratio of about 20:80, are commercially available as approximately 50% non-aqueous polymer dispersion 92 under the name Salcare ® SC.
  • cationic polymers are for example quaternised CeIIu lose-derivatives, such as are available under the names of Celquat ® and Polymer JR ® commercially.
  • the compounds Celquat ® H 100, Celquat ® L 200 and Polymer JR ® 400 are preferred quaternized cellulose derivatives, cationic alkyl polyglycosides according to DE-PS 44 13 686, cationized honey, for example the commercial product Honeyquat ® 50, cationic guar derivatives, such as in particular the products sold under the trade names Cosmedia® ® guar and Jaguar ® products,
  • Quaternary group polysiloxanes such as the commercially available products Q2-7224 (manufactured by Dow Corning, a stabilized trimethylsilylamodimethicone), Dow Corning® 929 emulsion (containing a hydroxylamino-modified silicone, also referred to as amodimethicones), SM -2059 (manufacturer: General Electric), SLM-55067 (manufacturer: Wacker) and Abil ® -Quat 3270 and 3272 (manufacturer: Th Goldschmidt.), diquaternary polydimethylsiloxanes, quaternium-80), polymeric dimethyldiallylammonium salts and their copolymers with esters and amides of acrylic acid and methacrylic acid.
  • Q2-7224 manufactured by Dow Corning, a stabilized trimethylsilylamodimethicone
  • Dow Corning® 929 emulsion containing a hydroxylamino-modified silicone, also referred
  • Copolymers of vinylpyrrolidone with quaternized derivatives of dialkylaminoalkyl acrylate and methacrylate such as diethyl sulfate quaternized vinylpyrrolidone-dimethylaminoethyl methacrylate copolymers.
  • Such compounds are sold under the names Gafquat ® 734 and Gafquat ® 755 commercially, Vinylpyrrolidone Vinylinnidazoliunnnnethochlorid-Copolynnere, such as those offered under the names Luviquat ® FC 370, FC 550, FC 905 and HM 552, quaternized polyvinyl alcohol, as well as by the names of Polyquaternium 2, Polyquaternium 17, Polyquaternium 18 and Polyquaternium 27, having quaternary Nitrogen atoms in the polymer backbone.
  • Can be used as cationic polymers are sold under the names Polyquaternium-24 (commercial product z. B. Quatrisoft ® LM 200), known polymers.
  • Gaffix ® VC 713 manufactured by ISP:
  • the copolymers of vinylpyrrolidone such as the commercial products Copolymer 845 (ISP manufacturer) are Gafquat ® ASCP 1011, Gafquat ® HS 110, Luviquat ® 8155 and Luviquat ® MS 370 available are.
  • cationic polymers which can be used according to the invention are the so-called "temporary cationic" polymers, which usually contain an amino group which is quaternary ammonium group and thus cationic at certain pH values ® CMF, Hydagen® ® HCMF, Kytamer ® PC and Chitolam ® NB / 101 are freely available commercially.
  • cationic polymers are cationic cellulose derivatives and chitosan and its derivatives, in particular the commercial products Polymer ® JR 400, Hydagen ® HCMF and Kytamer ® PC, cationic guar derivatives, cationic honey derivatives, in particular the commercial product Honeyquat ® 50, cationic Alkylpolyglycodside according to DE-PS 44 13 686 and polymers of the type Polyquaternium-37.
  • cationized protein hydrolysates are to be counted among the cationic polymers, wherein the underlying protein hydrolyzate from the animal, for example from collagen, milk or keratin, from the plant, for example from wheat, corn, rice, potatoes, soy or almonds, marine life forms, for example from fish collagen or algae, or biotechnologically derived protein hydrolysates.
  • the protein hydrolyzates on which the cationic derivatives according to the invention are based can be obtained from the corresponding proteins by chemical, in particular alkaline or acid hydrolysis, by enzymatic hydrolysis and / or a combination of both types of hydrolysis.
  • cationic protein hydrolyzates are to be understood as meaning quaternized amino acids and mixtures thereof.
  • the quaternization of the protein hydrolyzates or amino acids is often carried out using quaternary ammonium salts such as N, N-dimethyl-N- (n-alkyl) -N- (2-hydroxy-3-chloro-n-propyl) ammonium halides.
  • the cationic protein hydrolysates may also be further derivatized.
  • the cationic protein hydrolysates and derivatives according to the invention those mentioned under the INCI names in the "International Cosmetic Ingredient Dictionary and Handbook", (seventh edition 1997, The Cosmetic, Toiletry, and Fragrance Association 1101 17 th Street, NW, Suite 300 Cocodimonium Hydroxypropyl Hydrolyzed Casein, Cocodimonium Hydroxypropyl Hydrolyzed Collagen, Cocodimonium Hydroxypropyl Hydrolyzed Collagen, Cocodimonium Hydroxypropyl Hydrolyzed Hair Keratin, Cocodimonium Hydroxypropyl Hydrolyzed Keratin, Cocodimonium Hydroxypropyl Hydrolyzed Rice Protein, Cocodimonium Hydroxypropyl Hydrolyzed Soy Protein, Cocodimonium Hydroxypropyl Hydrolyzed Wheat Protein, Hydroxypropyl Arginine Lauryl / Myristyl Ether HCl, Hydroxypropy
  • amphoteric polymers are those polymers which are composed essentially
  • R 1 -CH CR 2 -CO-Z- (C n H 2n ) -N (+) R 3 R 4 R 5 A () (II) in R 1 and R 2 independently represent hydrogen or a methyl group and R 3 , R 4 and R 5 each independently represent an alkyl group having 1 to 4 carbon atoms, Z represents an NH group or an oxygen atom, n represents an integer of 2 to 5 and A is the anion of an organic or inorganic acid, and
  • These compounds can be used both directly and in salt form, which is obtained by neutralization of the polymers, for example with an alkali metal hydroxide, according to the invention.
  • Very particular preference is given to those polymers in which monomers of the type (a) are used in which R 3 , R 4 and R 5 are methyl groups, Z is an NH group and A () is a halide, methoxysulfate or ethoxysulfate ion is; Acrylamidopropyltrimethylammonium chloride is a particularly preferred monomer (a).
  • Acrylic acid is preferably used as monomer (b) for the stated polymers.
  • the agents according to the invention preferably contain the caring, cationic polymers in an amount of 0.01 to 5% by weight, in particular in an amount of 0.1 to 2% by weight, in each case based on the total application preparation.
  • the agent according to the invention may further comprise at least one vitamin, a provitamin, a vitamin precursor and / or one of their derivatives.
  • vitamins, pro-vitamins and vitamin precursors are preferred, which are usually assigned to groups A, B, C, E, F and H.
  • vitamin A includes retinol (vitamin A 1 ) and 3,4-didehydroretinol (vitamin A 2 ).
  • the ß-carotene is the provitamin of retinol.
  • vitamin A component for example, vitamin A acid and its esters, Vitamin A aldehyde and vitamin A alcohol and its esters such as the palmitate and the acetate into consideration.
  • the agents contain the vitamin A component preferably in amounts of 0.05-1% by weight, based on the total application preparation.
  • the vitamin B group or the vitamin B complex include vitamin B 1 (thiamine) vitamin B 2 (riboflavin)
  • Vitamin B 3 Under this name, the compounds nicotinic acid and nicotinamide (niacinamide) are often performed. Preferred according to the invention is the nicotinic acid amide, which is preferably contained in the agents according to the invention in amounts of from 0.05 to 1% by weight, based on the total application preparation. Vitamin B 5 (pantothenic acid, panthenol and pantolactone). Panthenol and / or pantolactone are preferably used in the context of this group. Derivatives of panthenol which can be used according to the invention are, in particular, the esters and ethers of panthenol and also cationically derivatized panthenols.
  • panthenol triacetate the panthenol monoethyl ether and its monoacetate and also the cationic panthenol derivatives disclosed in WO 92/13829.
  • the said compounds of the vitamin B 5 type are preferably present in the agents according to the invention in amounts of 0.05-10% by weight, based on the total application preparation. Amounts of 0.1-5 wt .-% are particularly preferred.
  • Vitamin B 6 (pyridoxine and pyridoxamine and pyridoxal).
  • the compounds of the vitamin B 6 type mentioned are preferably contained in the agents according to the invention in amounts of 0.01-5% by weight, based on the total application preparation. Levels of 0.05-1 wt% are particularly preferred.
  • Vitamin C (ascorbic acid). Vitamin C is used in the compositions according to the invention preferably in amounts of 0.1 to 3 wt .-%, based on the total application preparation. Use in the form of palmitic acid ester, glucosides or phosphates may be preferred. The use in combination with tocopherols may also be preferred.
  • Vitamin E tocopherols, especially ⁇ -tocopherol.
  • Tocopherol and its derivatives which include in particular the esters such as acetate, nicotinate, phosphate and succinate, are preferably present in the compositions according to the invention in amounts of 0.05-1% by weight, based on the total application preparation.
  • Vitamin F is usually understood as meaning essential fatty acids, in particular linoleic acid, linolenic acid and arachidonic acid.
  • Vitamin H is the compound (3aS, 4S, 6aR) -2-oxohexahydrothienol [3,4-c /] -imidazole-4-valeric acid, for which, however, the trivial name biotin has meanwhile prevailed.
  • Biotin is contained in the agents according to the invention preferably in amounts of 0.0001 to 1, 0 wt .-%, in particular in amounts of 0.001 to 0.01 wt .-%, each based on the total application preparation.
  • the agents according to the invention preferably contain vitamins, provitamins and vitamin precursors from groups A, B, C, E and H.
  • Panthenol, pantolactone, pyridoxine and its derivatives as well as nicotinic acid amide and biotin are particularly preferred.
  • compositions according to the invention may further contain at least one plant extract.
  • extracts are produced by extraction of the whole plant. However, in individual cases it may also be preferred to prepare the extracts exclusively from flowers and / or leaves of the plant.
  • extracts of green tea, almond, aloe vera, coconut, mango, apricot, lime, wheat, kiwi and melon are especially suitable.
  • alcohols and mixtures thereof can be used as extraction agent for the preparation of said plant extracts water.
  • the alcohols are lower alcohols such as ethanol and isopropanol, but especially polyhydric alcohols such as ethylene glycol and propylene glycol, both as sole extractant and in admixture with water, are preferred.
  • Plant extracts based on water / propylene glycol in a ratio of 1:10 to 10: 1 have proven to be particularly suitable.
  • the plant extracts can be used according to the invention both in pure and in diluted form. If they are used in diluted form, they usually contain about 2 to 80 wt .-% of active substance and as a solvent used in their extraction agent or extractant mixture.
  • compositions according to the invention mixtures of several, especially two, different plant extracts.
  • Ectoin or ectoine derivatives, allantoin, taurine and / or bisabolol are also suitable as care substances.
  • ectoine and ectoine derivatives means compounds of the formula (IV)
  • R 10 is a hydrogen atom, a branched or unbranched C 1 -C 4 -alkyl radical or a C 2 -C 4 -hydroxyalkyl radical,
  • R 11 represents a hydrogen atom, a grouping -COOR 14 or a grouping -
  • R 14 may be a hydrogen atom, a C 1 -C 4 -alkyl radical, an amino acid radical, a dipeptide or a tripeptide radical,
  • R 12 and R 13 are each, independently of one another, a hydrogen atom, a C 1 -C 4 -alkyl radical or a hydroxy group, with the proviso that both radicals may not simultaneously be a hydroxy group, and n is an integer from 1 to 3.
  • Suitable physiologically tolerated salts of the general compounds of the formula (IVa) or (IVb) are, for example, the alkali metal, alkaline earth metal, ammonium, triethylamine or tris (2-hydroxyethyl) amine salts and those which result from the reaction of compounds according to the formula (IVa) or (IVb) with inorganic and organic acids such as hydrochloric acid, phosphoric acid, sulfuric acid, branched or unbranched, substituted or unsubstituted (for example by one or more hydroxy groups) C 1 - C 4 - mono- or dicarboxylic acids, aromatic carboxylic acids and sulfonic acids such as acetic acid, citric acid, benzoic acid, maleic acid, fumaric acid, tartaric acid and p-toluenesulfonic acid.
  • inorganic and organic acids such as hydrochloric acid, phosphoric acid, sulfuric acid, branched or unbranched, substituted or unsubstit
  • physiologically acceptable salts are the Na, K, Mg and Ca and ammonium salts of the compounds of the formula (IVa) or (IVb), and the salts which are obtained by reacting compounds of the formula (IVa ) or (IVb) with hydrochloric acid, acetic acid, citric acid and benzoic acid.
  • Isomeric or stereoisomeric forms of the compounds of the formula (IVa) or (IVb) are understood according to the invention to mean all occurring optical isomers, diastereomers, racemates, zwitterions, cations or mixtures thereof.
  • amino acid the stereoisomeric forms, e.g. D and L forms, the following compounds understood:
  • arginine aspartic acid, glutamine, glutamic acid, ⁇ -alanine, ⁇ -aminobutyrate, N ⁇ -acetyllysine, N ⁇ -acetylornitine, N ⁇ -acetyldiaminobutyrate, N ⁇ -acetyldiaminobutyrate, histidine, isoleucine, leucine, methionine, phenylalanine, serine, Threonine and tyrosine.
  • L-amino acids are preferred.
  • Amino acid residues are derived from the corresponding amino acids. The following amino acid residues are preferred: Gly, Ala, Ser, Thr, VaI, ⁇ -Ala, ⁇ -aminobutyrate, Asp, Glu, Asn, AIn, N ⁇ -acetyllysine, N ⁇ -acetylornithine, N ⁇ -acetyldiaminobutyrate, N a -acetyldiaminobutyrate.
  • the short notation of the amino acids was carried out according to the usual notation.
  • the di- or tripeptide radicals are acid amides in their chemical nature and decompose on hydrolysis in 2 or 3 amino acids.
  • the amino acids in the di- or tripeptide moiety are linked together by amide bonds.
  • C 1 -C 4 -alkyl groups in the compounds of the formula (IV) are methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl and tert-butyl.
  • Preferred alkyl groups are methyl and ethyl, methyl is a particularly preferred alkyl group.
  • Preferred C 2 -C 4 -hydroxyalkyl groups are the groups 2-hydroxyethyl, 3-hydroxypropyl or 4-hydroxybutyl; 2-hydroxyethyl is a particularly preferred hydroxyalkyl group.
  • compositions of the invention contain these care substances preferably in amounts of 0.001 to 2, in particular from 0.01 to 0.5 wt .-%, each based on the total application preparation.
  • Mono- or oligosaccharides can also be used as a care substance in the compositions according to the invention.
  • Both monosaccharides and oligosaccharides such as cane sugar, lactose and raffinose, can be used.
  • the use of monosaccharides is preferred according to the invention.
  • those compounds which contain 5 or 6 carbon atoms are preferred.
  • Suitable pentoses and hexoses are, for example, ribose, arabinose, xylose, lyxose, allose, altrose, glucose, mannose, gulose, idose, galactose, talose, fucose and fructose.
  • Arabinose, glucose, galactose and fructose are preferably used carbohydrates; Very particular preference is given to using glucose which is suitable both in the D - (+) or L - (-) configuration or as a racemate.
  • sugars are gluconic acid, glucuronic acid, sugar acid, mannose and mucic acid.
  • Preferred sugar alcohols are sorbitol, mannitol and dulcitol.
  • Preferred glycosides are the methylglucosides. Since the mono- or oligosaccharides used are usually obtained from natural raw materials such as starch, they usually have the configurations corresponding to these raw materials (eg D-glucose, D-fructose and D-galactose).
  • the mono- or oligosaccharides are contained in the hair treatment compositions according to the invention preferably in an amount of 0.1 to 8 wt .-%, particularly preferably 1 to 5 wt .-%, based on the total application preparation.
  • the agent may further contain at least one lipid as a care substance.
  • Lipids suitable according to the invention are phospholipids, for example soya lecithin, egg lecithin and cephalins, and also the substances known under the INCI names linoleic amidopropyl PG-dimonium chlorides phosphates, cocamidopropyl PG-dimonium chlorides phosphates and stearamidopropyl PG-dimonium chlorides phosphates. These are sold, for example, by the company Mona under the trade names Phospholipid EFA® , Phospholipid PTC® and Phospholipid SV® .
  • the agents according to the invention preferably contain the lipids in amounts of from 0.01 to 10% by weight, in particular from 0.1 to 5% by weight, based on the total application preparation.
  • oil bodies are suitable as a care substance.
  • the natural and synthetic cosmetic oil bodies include, for example: vegetable oils.
  • vegetable oils examples include sunflower oil, olive oil, soybean oil, rapeseed oil, almond oil, jojoba oil, orange oil, wheat germ oil, peach kernel oil and the liquid portions of coconut oil.
  • triglyceride oils such as the liquid portions of beef tallow as well as synthetic triglyceride oils.
  • Ester oils are to be understood as meaning the esters of C 6 - C 30 fatty acids with C 2 - C 30 fatty alcohols. The monoesters of the fatty acids with alcohols having 2 to 24 carbon atoms are preferred.
  • fatty acid components used in the esters are caproic, caprylic, 2-ethylhexanoic, capric, lauric, isotridecanoic, myristic, palmitic, palmitoleic, stearic, isostearic, oleic, elaidic, petroselic, linoleic, linolenic Behenic acid and erucic acid and their technical mixtures which are obtained, for example, in the pressure splitting of natural fats and oils, in the oxidation of aldehydes from Roelen's oxo synthesis or the dimerization of unsaturated fatty acids.
  • fatty alcohol components in the ester oils are isopropyl alcohol, caproic alcohol, capryl alcohol, 2-ethylhexyl alcohol, capric alcohol, lauryl alcohol, isotridecyl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, linolyl alcohol, linolenyl alcohol, elaeostearyl alcohol, arachyl alcohol, Gadoleyl alcohol, behenyl alcohol, erucyl alcohol and brassidyl alcohol and their technical mixtures, for example, in the high-pressure hydrogenation of technical methyl esters based on fats and oils or aldehydes from the Roelen oxo synthesis and as a monomer fraction in the dimerization of unsaturated fatty alcohols incurred.
  • isopropyl myristate IPM Rilanit ®
  • isononanoic acid C16-18 alkyl ester Cetiol ® SN
  • 2-ethylhexyl palmitate Cegesoft ® 24
  • stearic acid-2-ethylhexyl ester Cetiol ® 868
  • cetyl oleate glycerol tricaprylate, Kokosfettalkohol- caprate / caprylate (Cetiol ® LC)
  • n-butyl stearate oleyl erucate
  • isopropyl palmitate IPP Rilanit ®
  • oleyl Oleate Cetiol ®
  • hexyl laurate Cetiol ® A
  • di-n-butyl adipate Cetiol ® B
  • myrist IPM Rilanit ®
  • Dicarboxylic acid esters such as di-n-butyl adipate, di- (2-ethylhexyl) adipate, di- (2-ethylhexyl) succinate and di-isotridecyl acelate
  • diol esters such as ethylene glycol dioleate, ethylene glycol diisotridecanoate, propylene glycol di (2- ethylhexanoate), propylene glycol diisostearate,
  • Fatty acid partial glycerides which are understood to mean monoglycerides, diglycerides and their technical mixtures. With the use of technical products production reasons may still contain small amounts of triglycerides.
  • the partial glycerides preferably follow the formula (D4-I), CH 2 O (CH 2 CH 2 O) m R 1 CHO (CH 2 CH 2 O) n R 2 (D4-I)
  • R 3 in the R 1 , R 2 and R 3 is independently of one another hydrogen or a linear or branched, saturated and / or unsaturated acyl radical having 6 to 22, preferably 12 to 18, Carbon atoms are provided with the proviso that at least one of these groups is an acyl radical and at least one of these groups is hydrogen.
  • the sum (m + n + q) is 0 or numbers from 1 to 100, preferably 0 or 5 to 25.
  • R 1 is an acyl radical and R 2 and R 3 are hydrogen and the sum (m + n + q) is 0.
  • Typical examples are mono- and / or diglycerides based on caproic, caprylic, 2-ethylhexanoic, capric, lauric, isotridecanoic, myristic, palmitic, palmitic, stearic, isostearic, oleic, elaidic, petroselic, linoleic, linolenic , Elaeostearic acid, arachidic acid, gadoleic acid, behenic acid and erucic acid and their technical mixtures.
  • oleic acid monoglycerides are used.
  • the amount used of the natural and synthetic cosmetic oil bodies in the compositions according to the invention is usually from 0.1 to 30% by weight, based on the total application preparation, preferably from 0.1 to 20% by weight, and in particular from 0.1 to 15% by weight. %.
  • the agent may further contain an enzyme as a conditioner.
  • enzymes according to the invention are selected from a group which is formed from proteases, lipases, transglutaminase, oxidases and peroxidases.
  • Pearl extracts are also suitable as a conditioner.
  • Pearls of mussels consist essentially of inorganic and organic calcium salts, trace elements and proteins. Pearls can be easily obtained from cultivated mussels. The cultivation of the mussels can be done in fresh water as well as in sea water. This can affect the ingredients of the beads. According to the invention, preference is given to a pearl extract which originates from shells cultivated in marine or salt water. The pearls consist to a large extent of aragonite (calcium carbonate), conchiolin and an albuminoid. The latter components are proteins. Also included in beads are magnesium and sodium salts, inorganic silicon compounds, and phosphates. To prepare the pearl extract, the beads are pulverized. Thereafter, the pulverized beads are extracted by the usual methods.
  • water, alcohols and mixtures thereof can be used. Underwater are understood to mean both demineralized water and seawater.
  • the alcohols are lower alcohols such as ethanol and isopropanol, but especially polyhydric alcohols such as glycerol, diglycerol, triglycerol, polyglycerol, ethylene glycol, propylene glycol and butylene glycol, both as sole extractant and in admixture with demineralized water or sea water, are preferred.
  • Pearl extracts based on water / glycerine mixtures have proven to be particularly suitable.
  • the pearl proteins can be largely in the native state or already partially or largely present as protein hydrolysates. Preference is given to a pearl extract in which conchiolin and albuminoid are already partially hydrolyzed.
  • the essential amino acids of these proteins are glutamic acid, serine, alanine, glycine, aspartic acid and phenylalanine.
  • the pearl extract is additionally enriched with at least one or more of these amino acids.
  • the pearl extract is enriched with glutamic acid, serine and leucine.
  • a preferred extract contains organic and / or inorganic calcium salts as well as magnesium and sodium salts, inorganic silicon compounds and / or phosphates.
  • a most preferred pearl extract contains at least 75%, preferably 85%, more preferably 90% and most preferably 95% of all ingredients of the naturally occurring pearls. Examples of pearl extracts usable according to the invention are the commercial products Pearl Protein Extract BG ® or Crodarom ® Pearl.
  • the above-described pearl extracts are preferably contained in an amount of at least 0.01 to 20% by weight.
  • amounts of the extract of 0.01 to 10% by weight, most preferably amounts of 0.01 to 5 wt.% Based on the total two-component agent used.
  • the agent according to the invention is present in a cosmetically acceptable carrier. It is preferably an aqueous, an alcoholic or an aqueous-alcoholic medium with preferably at least 10% by weight of water, based on the total preparation.
  • a cosmetically acceptable carrier it is possible in particular to include the lower alcohols having 1 to 4 carbon atoms usually used for cosmetic purposes, such as, for example, ethanol and isopropanol.
  • organic solvents or a mixture of solvents with a boiling point below 400 0 C in an amount of 0.1 to 15 weight percent may be included purchased from 1 to 10 wt percent on the total preparation is preferred.
  • Particularly suitable as additional co-solvents are unbranched or branched hydrocarbons such as pentane, hexane, isopentane and cyclic hydrocarbons such as cyclopentane and cyclohexane.
  • particularly preferred water-soluble solvents are glycerol, ethylene glycol and propylene glycol in an amount of up to 30 percent by weight based on the total preparation.
  • compositions according to the invention can be carried out in all forms customary for cosmetic compositions, for example in the form of solutions which can be applied to the hair, for example as hair tonic or pump or aerosol spray, in the form of creams, emulsions, waxes, gels or surfactant-containing effervescent solutions or other preparations suitable for application to the skin or hair.
  • the preparations preferably have a pH of from 2 to 11.
  • the pH range between 2 and 8 is particularly preferred.
  • the pH values in the context of this document refer to the pH at 25 ° C., unless otherwise stated.
  • the agents according to the invention are preferably hair treatment agents.
  • Hair creams and gels generally contain structurants and / or thickening polymers which serve to give the products the desired consistency.
  • Structurants and / or thickening polymers are typically used in an amount of 0.1 to 10 wt .-%, based on the total application formulation. Amounts of 0.5 to 5 wt .-%, in particular 0.5 to 3 wt .-% are preferred.
  • Corresponding hair treatment agents can also be formulated as a pump spray, aerosol spray, pump hair foam or aerosol hair foam.
  • Hair foams are understood to mean compositions which form a foam when they are removed from a suitable container. It may be necessary to add ingredients that promote foaming or stabilize foam once formed. In particular, surfactants and / or emulsifiers are suitable for this purpose. If the products according to the invention are an aerosol product, this necessarily contains a propellant.
  • Suitable blowing agents according to the invention are, for example, N 2 O, dimethyl ether, CO 2 , air and alkanes having 3 to 5 carbon atoms, such as propane, n-butane, isobutane, n-pentane and isopentane, and mixtures thereof. Preference is given to dimethyl ether, propane, n-butane, isobutane and mixtures thereof.
  • said alkanes, mixtures of said alkanes or mixtures of said alkanes with dimethyl ether are used as sole blowing agent.
  • the invention expressly also includes the concomitant use of propellants of the type of chlorofluorocarbons, but in particular of fluorocarbons.
  • the sizes of the aerosol droplets or of the foam bubbles and the respective size distribution can be set for a given spraying device.
  • blowing agent used varies depending on the specific composition of the composition, the packaging used and the desired product type, such as hair spray or hair foam.
  • aerosol foam products contain the propellant preferably in amounts of 1 to 35 wt .-%, based on the total product. Amounts of 2 to 30 wt .-%, in particular from 3 to 15 wt .-% are particularly preferred. Aerosol sprays generally contain larger amounts of propellant.
  • the blowing agent is used in this case in an amount of 30 to 98 wt .-%, based on the total product. Amounts of 40 to 95 wt .-%, in particular from 50 to 95 wt .-% are particularly preferred.
  • the aerosol products can be prepared in the usual way.
  • all constituents of the respective agent with the exception of the propellant, are introduced into a suitable pressure-resistant container. This is then closed with a valve.
  • the desired amount of blowing agent is introduced.
  • UV filters By adding a UV filter, both the agents themselves, as well as the treated parts of the body, preferably so the keratinic fibers are protected from harmful effects of UV radiation.
  • at least one UV filter is added to the agent.
  • the suitable UV filters are not subject to any general restrictions with regard to their structure and their physical properties. On the contrary, all UV filters which can be used in the cosmetics sector and whose absorption maximum lies in the UVA (315-400 nm), in the UVB (280-315 nm) or in the UVC ( ⁇ 280 nm) range are suitable. UV filters with an absorption maximum in the UVB range, in particular in the range from about 280 to about 300 nm, are particularly preferred.
  • the UV filters preferred according to the invention can be selected, for example, from substituted benzophenones, p-aminobenzoic acid esters, diphenylacrylic acid esters, cinnamic acid esters, salicylic acid esters, benzimidazoles and o-aminobenzoic acid esters.
  • UV filters which can be used according to the invention are 4-aminobenzoic acid, N, N, N-trimethyl-4- (2-oxoborn-3-ylidenemethyl) aniline methylsulfate, 3,3,5-trimethylcyclohexyl salicylate (homosalates), 2-hydroxy-4-methoxybenzophenone (benzophenone-3; Uvinul ® M 40, Uvasorb MET ®, ® Neo Heliopan BB, Eusolex ® 4360), 2-phenylbenzimidazole-5-sulfonic acid and potassium, sodium and triethanolamine salts ( Phenylbenzimidazole Sulfonic Acid; Parsol ® HS; Neo Heliopan Hydro ®), 3,3 '- (1, 4-phenylenedimethylene) bis (7,7-dimethyl-2-oxo-bicyclo [2.2.1] hept-1- yl-methane sulfonic acid) and salts thereof, 1- (4-tert-butylpheny
  • water-insoluble UV filters are those which dissolve in water at not more than 1% by weight, in particular not more than 0.1% by weight, at 20 ° C. Furthermore, these compounds should be soluble in common cosmetic oil components at room temperature to at least 0.1, in particular at least 1 wt .-%. The use of water-insoluble UV filters may therefore be preferred according to the invention.
  • UV filters which have a cationic group, in particular a quaternary ammonium group.
  • UV filters have the general structure U - Q.
  • the structural part U stands for a UV-absorbing group.
  • This group can in principle be derived from the known UV filters which can be used in the cosmetics sector, in which a group, generally a hydrogen atom, of the UV filter is replaced by a cationic group Q, in particular having a quaternary amino function ,
  • Compounds from which the structural part U can be derived are, for example, substituted benzophenones, p-aminobenzoic acid esters, diphenylacrylic acid esters, methylester esters, salicylic acid esters, benzimidazoles and o-aminobenzoic acid esters.
  • Structural parts U which are derived from cinnamic acid amide or from N, N-dimethylaminobenzoic acid amide are preferred according to the invention.
  • the structural parts U can in principle be chosen such that the absorption maximum of the UV filters can be in both the UVA (315-400 nm) and in the UVB (280-315 nm) or in the UVC ( ⁇ 280 nm) range. UV filters with an absorption maximum in the UVB range, in particular in the range from about 280 to about 300 nm, are particularly preferred.
  • the structural part U also as a function of structural part Q, is preferably selected so that the molar extinction coefficient of the UV filter at the absorption maximum is above 15,000, in particular above 20,000.
  • the structural part Q preferably contains, as a cationic group, a quaternary ammonium group.
  • This quaternary ammonium group can in principle be connected directly to the structural part U, so that the structural part U represents one of the four substituents of the positively charged nitrogen atom.
  • one of the four substituents on the positively charged nitrogen atom is a group, especially an alkylene group of 2 to 6 carbon atoms, which functions as a compound between the structural portion U and the positively charged nitrogen atom.
  • the group Q has the general structure - (CH 2 ) X -N + R 1 R 2 R 3 X ' , where x is an integer from 1 to 4, R 1 and R 2 independently of one another are Ci_ 4 Alkyl groups, R 3 is a Ci_ 22 alkyl group or a benzyl group and X 'is a physiologically acceptable anion.
  • x preferably represents the number 3
  • R 1 and R 2 each represent a methyl group and R 3 represents either a methyl group or a saturated or unsaturated, linear or branched hydrocarbon chain with 8 to 22, in particular 10 to 18, carbon atoms.
  • Physiologically acceptable anions are, for example, inorganic anions such as halides, in particular chloride, bromide and fluoride, sulfate ions and phosphate ions and organic anions such as lactate, citrate, acetate, tartrate, methosulfate and tosylate.
  • inorganic anions such as halides, in particular chloride, bromide and fluoride, sulfate ions and phosphate ions and organic anions such as lactate, citrate, acetate, tartrate, methosulfate and tosylate.
  • UV filters with cationic groups are the commercially available compounds cinnamic acid-trimethylammonium chloride (lncroquat ® UV-283) and dodecyl tosylate (Escalol ® HP 610).
  • the teaching of the invention also includes the use of a combination of several UV filters.
  • the combination of at least one water-insoluble UV filter with at least one UV filter with a cationic group is preferred.
  • the UV filters are usually contained in amounts of 0.01-5 wt .-%, based on the total application preparation. Amounts of 0.1-2.5 wt .-% are preferred.
  • the agent according to the invention is a hair treatment agent
  • this further contains one or more substantive dyes.
  • This allows the treated keratin fiber not only to be temporarily patterned when the agent is applied, but also dyed at the same time. This may be particularly desirable if only a temporary dyeing is desired, for example, with eye-catching fashion colors, which can be removed again by simple washing from the keratinic fiber.
  • Direct dyes are usually nitrophenylenediamines, nitroaminophenols, azo dyes, anthraquinones or indophenols.
  • Preferred substantive dyes are those having the international designations or trade names HC Yellow 2, HC Yellow 4, HC Yellow 5, HC Yellow 6, HC Yellow 12, Acid Yellow 1, Acid Yellow 10, Acid Yellow 23, Acid Yellow 36, HC Orange Disperse Orange 3, Acid Orange 7, HC Red 1, HC Red 3, HC Red 10, HC Red 11, HC Red 13, Acid Red 33, Acid Red 52, HC Red BN, Pigment Red 57: 1, HC Blue 2, HC Blue 11, HC Blue 12, Disperse Blue 3, Acid Blue 7, Acid Green 50, HC Violet 1, Disperse Violet 1, Disperse Violet 4, Acid Violet 43, Disperse Black 9, Acid Black 1, and Acid Black 52 known compounds as well as 1,4-diamino-2-nitrobenzene, 2-amino-4-nitrophenol, 1,4-bis- ( ⁇ -hydroxyethyl) -amino-2-nitrobenzene, 3-nitro
  • aromatic systems substituted with a quaternary nitrogen group such as Basic Yellow 57, Basic Red 76, Basic Blue 99, Basic Brown 16 and Basic Brown 17, as well as
  • Preferred cationic substantive dyes of group (c) are in particular the following compounds:
  • the compounds of the formulas (DZ1), (DZ3) and (DZ5) which are also known by the names Basic Yellow 87, Basic Orange 31 and Basic Red 51, are very particularly preferred cationic substantive dyes of group (c).
  • the cationic direct dyes which are sold under the trademark Arianor ®, according to the invention are also very particularly preferred cationic direct dyes.
  • the agents according to the invention according to this embodiment preferably contain the substantive dyes in an amount of 0.001 to 20 wt .-%, based on the total agent.
  • the agents of the invention may also contain naturally occurring dyes, such as those in henna red, henna neutral, henna black, chamomile flower, sandalwood, black tea, buckthorn bark, sage, bluewood, madder root, catechu, sedre and alkano root are included.
  • naturally occurring dyes such as those in henna red, henna neutral, henna black, chamomile flower, sandalwood, black tea, buckthorn bark, sage, bluewood, madder root, catechu, sedre and alkano root are included.
  • the substantive dyes each represent uniform compounds. Rather, in the inventive compositions, due to the production process for the individual dyes, in minor amounts, other components may be included, as far as they do not adversely affect the styling result or for other reasons, e.g. toxicological, must be excluded.
  • the agents may furthermore contain all active ingredients, additives and auxiliaries known for such preparations.
  • the agents contain at least one surfactant, wherein in principle both anionic and zwitterionic, ampholytic, nonionic and cationic surfactants are suitable. In many cases, however, it has proved to be advantageous to select the surfactants from anionic, zwitterionic or nonionic surfactants.
  • Thickeners such as agar-agar, guar gum, alginates, xanthan gum, gum arabic, karaya gum, locust bean gum, linseed gums, dextrans, cellulose derivatives, e.g. For example, methylcellulose, hydroxyalkylcellulose and carboxymethylcellulose, starch fractions and derivatives such as amylose, amylopectin and dextrins, clays such. Bentonite or fully synthetic hydrocolloids such as e.g. Polyvinyl alcohol, structurants such as maleic acid and lactic acid, perfume oils, dimethyl isosorbide and cyclodextrins,
  • Solvents and mediators such as ethanol, isopropanol, ethylene glycol, propylene glycol, glycerine and diethylene glycol, quaternized amines such as methyl-1-alkylamidoethyl-2-alkylimidazolinium methosulfate defoamers such as silicones, colorants for dyeing the agent,
  • Antidandruff active ingredients such as Piroctone Olamine, zinc Omadine and Climbazol, substances for adjusting the pH, such as conventional acids, in particular edible acids and bases, cholesterol,
  • Bodying agents such as sugar esters, polyol esters or polyol alkyl ethers, fats and waxes such as spermaceti, beeswax, montan wax and paraffins, fatty acid alkanolamides,
  • Complexing agents such as EDTA, NTA, ⁇ -alaninediacetic acid and phosphonic acids, swelling and penetrating agents such as glycerol, propylene glycol monoethyl ether, carbonates, bicarbonates, guanidines, ureas and primary, secondary and tertiary phosphates, opacifiers such as latex, styrene / PVP and styrene / acrylamide copolymers Pearlescing agents such as ethylene glycol mono- and distearate and PEG-3-distearate, preservatives,
  • Stabilizers for hydrogen peroxide and other oxidizing agents propellants such as propane-butane mixtures, N 2 O, dimethyl ether, CO 2 and air, antioxidants.
  • a second object of the invention is the use of the agents according to the invention for the treatment of keratinic fibers, wherein this treatment is preferably a temporary deformation.
  • compositions according to the invention necessarily contain a film-forming and / or setting polymer, this type of use is particularly advantageous.
  • the film-forming and / or setting polymers are used not only to regulate the effect of the pheromone used, but are also used to build and / or stabilize a desired hairstyle.
  • the styling gels E1 to E3 according to the invention were prepared according to the following table.
  • the formulation according to the invention for a styling foam E4 was prepared according to the following table.

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  • Health & Medical Sciences (AREA)
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  • General Health & Medical Sciences (AREA)
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  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
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Abstract

L'invention concerne des agents cosmétiques contenant 1 x 10-7 à 1 x 10-2 % en poids d'au moins un stéroïde sélectionné parmi certains 16-androstène stéroïdes, notamment 4,16-androstadiène-3-one, et parmi certains estrenstéroïdes, et 0,1 à 30 % en poids d'au moins un polymère filmogène et/ou de renforcement. L'invention porte également sur l'utilisation de ces agents pour traiter des fibres de kératine, notamment pour le modelage temporaire de ces fibres.
EP08708851A 2007-05-14 2008-02-11 Agents cosmétiques contenant des phéromones Ceased EP2148650A2 (fr)

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DE102007022916A DE102007022916A1 (de) 2007-05-14 2007-05-14 Pheromonhaltige kosmetische Mittel
PCT/EP2008/051590 WO2008138651A2 (fr) 2007-05-14 2008-02-11 Agents cosmétiques contenant des phéromones

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EP2148650A2 true EP2148650A2 (fr) 2010-02-03

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DE (1) DE102007022916A1 (fr)
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WO (1) WO2008138651A2 (fr)

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FR3104428B1 (fr) * 2019-12-13 2024-01-12 Oreal Dispositif aerosol de coloration a base de copolymere issu de la polymerisation d’au moins un monomere d’acide crotonique et d’au moins un monomere ester de vinyle et une amine organique

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5136093A (en) 1991-02-06 1992-08-04 Smith Ronald J Quaternized panthenol compounds and their use
US5278141A (en) 1992-03-24 1994-01-11 Erox Corporation Fragrance compositions containing human pheromones
US5272134A (en) * 1992-03-24 1993-12-21 Erox Corporation Fragrance compositions and other compositions which contain human pheromones
DE4413686C2 (de) 1994-04-20 1996-10-24 Henkel Kgaa Kationische Zuckertenside, Verfahren zu ihrer Herstellung und deren Verwendung
RU2160279C2 (ru) * 1994-09-29 2000-12-10 Ферин-Фармасьютикалз, Инк. Стероидное соединение
US5849280A (en) * 1996-08-06 1998-12-15 A-Veda Corporation Hair conditioning solid
AU7273898A (en) * 1997-04-30 1998-11-24 Human Pheromone Sciences, Inc. Method of fixing fragrances in fragrance composition and other compositions
DE19756454C1 (de) 1997-12-18 1999-06-17 Henkel Kgaa Verwendung von Glycerincarbonat
FR2785183B1 (fr) 1998-11-04 2002-04-05 Oreal COMPOSITION TINCTORIALE CONTENANT UN COLORANT DIRECT CATIONIQUE ET UNE PYRAZOLO-[1,5-a]- PYRIMIDINE A TITRE DE BASE D'OXYDATION, ET PROCEDES DE TEINTURE
US6544971B1 (en) * 2000-02-04 2003-04-08 Pherin Pharmaceuticals, Inc. Method of increasing alertness by administration of a vomeropherin, and vomeropherin-emitting alarm devices
AU2003255721A1 (en) 2002-07-18 2004-02-09 Quest International Services B.V. Perfume compositions
DE102004034265A1 (de) * 2004-07-15 2006-02-16 Wella Ag Haarstylinggel mit Lichtschutzwirkung für Haut und Haare
CA2618223A1 (fr) * 2005-08-09 2007-02-22 Soane Labs, Llc Formulations destinees a la tenue des cheveux
US8309539B2 (en) * 2005-09-09 2012-11-13 Pherin Pharmaceuticals, Inc. Acute treatment of social phobia
AU2006315121B2 (en) * 2005-11-17 2011-03-31 Colgate-Palmolive Company Malodor reducing compositions and methods
WO2008138547A2 (fr) * 2007-05-11 2008-11-20 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Préparation améliorée pour nourrissons, composition d'arôme utilisée dans ladite préparation en tant que composition de parfum et d'arôme, et procédé de fabrication de ladite composition d'arôme

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO2008138651A2 *

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RU2009145937A (ru) 2011-06-20
WO2008138651A3 (fr) 2009-06-11
WO2008138651A2 (fr) 2008-11-20
DE102007022916A1 (de) 2008-11-20
US20100120729A1 (en) 2010-05-13

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