EP2170110A2 - Degradable cigarette filters - Google Patents
Degradable cigarette filtersInfo
- Publication number
- EP2170110A2 EP2170110A2 EP08826746A EP08826746A EP2170110A2 EP 2170110 A2 EP2170110 A2 EP 2170110A2 EP 08826746 A EP08826746 A EP 08826746A EP 08826746 A EP08826746 A EP 08826746A EP 2170110 A2 EP2170110 A2 EP 2170110A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- fibers
- cigarette filter
- filter according
- biodegradable
- cross
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES OF CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter tips or filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces of cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/08—Use of materials for tobacco smoke filters of organic materials as carrier or major constituent
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES OF CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter tips or filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces of cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/062—Use of materials for tobacco smoke filters characterised by structural features
- A24D3/063—Use of materials for tobacco smoke filters characterised by structural features of the fibers
- A24D3/064—Use of materials for tobacco smoke filters characterised by structural features of the fibers having non-circular cross-section
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES OF CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter tips or filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces of cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/067—Use of materials for tobacco smoke filters characterised by functional properties
- A24D3/068—Biodegradable or disintegrable
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES OF CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter tips or filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces of cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/16—Use of materials for tobacco smoke filters of inorganic materials
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES OF CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter tips or filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces of cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/16—Use of materials for tobacco smoke filters of inorganic materials
- A24D3/163—Carbon
Definitions
- the present invention relates to degradable cigarette filters, and more particularly to shaped fibers made from degradable materials and the use of such shaped fibers in cigarette filters.
- Conventional cigarette filter plugs are made of cellulose acetate fibers bonded to each other by triacetin. After smoking, the spent filters are sometimes discarded in the environment. The cellulose acetate filaments therein tend to degrade slower than tobacco and/or the paper parts of the cigarettes, often contributing to the litter in the environment. To reduce such litter, there is a need to replace cellulose acetate filaments in cigarette filters with materials that degrade faster than cellulose acetate in the environment. At the same time, there is also a need to retain the filtration chemistry, smoke characteristics and consumer acceptability from the cellulose acetate triacetin systems.
- a cigarette filter produced from biodegradable materials formed into fibers with designed cross sectional shapes.
- Another object of the present invention is a cigarette filter of biodegradable shaped fibers with increased surface area and reduced overall material per filter.
- Still another object of the present invention is a cigarette filter of biodegradable shaped fibers having micro cavities therein for retaining flavorants and adsorbents for favor delivery and selective filtration.
- a biodegradable cigarette filter comprises shaped fibers of PHBV.
- the fibers may have designed shapes in cross section that include Y, V, C, Triad, 4-DG and JC shapes.
- the shaped fiber may include micro cavities with adsorbents and/or flavorants in the cavities.
- Figure 1 is a cross sectional view of a shaped biodegradable fiber having a Y shape
- Figure 2 is a cross sectional view of a shaped biodegradable fiber having a V shape
- Figure 3 is a cross sectional view of a shaped biodegradable fiber having a C shape
- Figure 4 is a cross sectional view of a shaped biodegradable fiber having a Triad shape
- Figure 5 is a cross sectional view of a shaped biodegradable fiber having a 4-DG shape
- Figure 6 is a cross sectional view of a shaped biodegradable fiber having a JC shape.
- the cigarette filters of the present invention may be made of sheets, films, fiber bands, yarns, or non-wovens from biodegradable materials such as paper (wood pulps), wool, cellulose acetate with lower acetylating levels, starch, and starch based polymer composites, cotton, polyactic acid, polyvinyl alcohol, polyhyroxyalkanoates, polyesters, polyesteramides, polycaprolactones, un-stabilized polypropylene, micro-glass materials, and their combinations.
- the biodegradable materials can be spun into fibers by melt spinning, dry spinning, wet spinning, electro spinning or any other known process into fibers.
- PHBV Polyhydroxybutyrate-co-hydroxyvalerate
- aliphatic aromatic polyester such as Ecoflex, PBS (poly butylenes succinate), d-, 1-, and dl- PLA (polyactic acid) and starch composites
- Ecoflex poly butylenes succinate
- d-, 1-, and dl- PLA polyactic acid
- starch composites have been successfully spun into round cross section fibers by melt spinning process.
- the filter fibers herein have improved cross sectional shapes. These shaped fibers are formed into filters and used in reduced litter cigarettes.
- the cross section of the fibers may be controlled by the shapes of the die used in the spinning processes.
- the cross section of the fibers may be modified to Y, V, C, Triad, 4-DG, or JC by using appropriate dies in the melt spinning process.
- Other fiber cross sections that have been reported in the literature such as those in U.S. Patent 6,907,895 are included herein by reference.
- single or multi-strands of these shaped fibers from single or multiple components may be drawn and crimped into tow bands, or the strands of these shaped fibers made of faster degradable materials can be combined with cellulose acetate fibers to form a joint tow bands during the cigarette filter making process.
- nonwovens from the above fibers can be produced from melt-blown, spun bonded, needle punched/felt, wet-laid, air-laid and other processes and then processed into cigarette filters by processes of rolling, folding or shredding.
- Appropriate amounts of a bonding/hardening agent may be applied onto the fibers in the filters as needed for firmness and smoke subjective adjustment.
- Adsorbents such as carbon granules and flavorants such as menthol can be impregnated into the micro cavities of the shaped fibers as well.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biodiversity & Conservation Biology (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
- Artificial Filaments (AREA)
- Nonwoven Fabrics (AREA)
- Filtering Materials (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US95329607P | 2007-08-01 | 2007-08-01 | |
| PCT/IB2008/002793 WO2009016513A2 (en) | 2007-08-01 | 2008-07-31 | Degradable cigarette filters |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP2170110A2 true EP2170110A2 (en) | 2010-04-07 |
Family
ID=40304985
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP08826746A Withdrawn EP2170110A2 (en) | 2007-08-01 | 2008-07-31 | Degradable cigarette filters |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US20090032037A1 (pt) |
| EP (1) | EP2170110A2 (pt) |
| JP (1) | JP2010535024A (pt) |
| KR (1) | KR20100045412A (pt) |
| CN (1) | CN101742932A (pt) |
| AU (1) | AU2008281436A1 (pt) |
| BR (1) | BRPI0815065A2 (pt) |
| CO (1) | CO6160279A2 (pt) |
| EA (1) | EA201070199A1 (pt) |
| MX (1) | MX2010001248A (pt) |
| WO (1) | WO2009016513A2 (pt) |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7479098B2 (en) | 2005-09-23 | 2009-01-20 | R. J. Reynolds Tobacco Company | Equipment for insertion of objects into smoking articles |
| CN103222684B (zh) * | 2008-05-21 | 2015-11-18 | R.J.雷诺兹烟草公司 | 用于形成吸烟制品的滤嘴组件的设备和相关方法以及由其制造的吸烟制品 |
| US8613284B2 (en) * | 2008-05-21 | 2013-12-24 | R.J. Reynolds Tobacco Company | Cigarette filter comprising a degradable fiber |
| US8079369B2 (en) | 2008-05-21 | 2011-12-20 | R.J. Reynolds Tobacco Company | Method of forming a cigarette filter rod member |
| US8375958B2 (en) * | 2008-05-21 | 2013-02-19 | R.J. Reynolds Tobacco Company | Cigarette filter comprising a carbonaceous fiber |
| US8991403B2 (en) * | 2009-06-02 | 2015-03-31 | R.J. Reynolds Tobacco Company | Thermal treatment process for tobacco materials |
| US8944072B2 (en) * | 2009-06-02 | 2015-02-03 | R.J. Reynolds Tobacco Company | Thermal treatment process for tobacco materials |
| GB2474694B (en) * | 2009-10-23 | 2011-11-02 | Innovia Films Ltd | Biodegradable composites |
| CN102080276B (zh) * | 2009-11-30 | 2014-05-14 | 合肥中科绿色家电科技有限公司 | 可生物降解的烟用纤维材料及香烟过滤嘴 |
| US20120318286A1 (en) * | 2010-03-31 | 2012-12-20 | Greenbutts Llc | Biodegradable cigarette filter and methods for making same |
| WO2012012053A1 (en) | 2010-06-30 | 2012-01-26 | R.J. Reynolds Tobacco Company | Biodegradable cigarette filter |
| US20120000480A1 (en) | 2010-06-30 | 2012-01-05 | Sebastian Andries D | Biodegradable cigarette filter |
| US20120017925A1 (en) * | 2010-06-30 | 2012-01-26 | Sebastian Andries D | Degradable cigarette filter |
| WO2012129038A1 (en) | 2011-03-15 | 2012-09-27 | Altria Client Services Inc. | Biodegradable cigar tip |
| GB201105455D0 (en) | 2011-03-31 | 2011-05-18 | British American Tobacco Co | Blends of a polylactic acid and a water soluble polymer |
| US9289012B2 (en) | 2011-07-29 | 2016-03-22 | R. J. Reynolds Tobacco Company | Plasticizer composition for degradable polyester filter tow |
| US8973588B2 (en) | 2011-07-29 | 2015-03-10 | R.J. Reynolds Tobacco Company | Plasticizer composition for degradable polyester filter tow |
| KR102031068B1 (ko) * | 2011-09-09 | 2019-10-15 | 필립모리스 프로덕츠 에스.에이. | 중합체 인서트를 포함하는 흡연 물품 필터 |
| CN102691121B (zh) * | 2012-06-14 | 2014-09-03 | 江苏天圣达集团无锡新合纤有限公司 | 一种皮芯型结构的聚乳酸/聚丙烯烟用复合丝束及其制备方法 |
| JP2015525079A (ja) * | 2012-07-25 | 2015-09-03 | セラニーズ アセテート,エルエルシー | 3弧孔を含む紡糸口金およびそれから製造された3弧フィラメント |
| WO2014018446A1 (en) * | 2012-07-25 | 2014-01-30 | Celanese Acetate Llc | Spinneret comprising tri-arc holes and tri-arc filaments produced therefrom |
| US8790556B2 (en) | 2012-07-25 | 2014-07-29 | Celanese Acetate Llc | Process of making tri-arc filaments |
| US9119419B2 (en) * | 2012-10-10 | 2015-09-01 | R.J. Reynolds Tobacco Company | Filter material for a filter element of a smoking article, and associated system and method |
| RU2668858C1 (ru) | 2013-12-20 | 2018-10-03 | Филип Моррис Продактс С.А. | Фильтр курительного изделия, содержащий разлагаемый компонент фильтра |
| GB201400990D0 (en) | 2014-01-21 | 2014-03-05 | British American Tobacco Co | Filter materials and filters made therefrom |
| GB2512502B (en) * | 2014-02-25 | 2015-03-11 | Cambridge Silicon Radio Ltd | Device authentication |
| WO2015178995A1 (en) | 2014-05-23 | 2015-11-26 | Greenbutts Llc | Biodegradable cigarette filter tow and method of manufacture |
| US10524500B2 (en) | 2016-06-10 | 2020-01-07 | R.J. Reynolds Tobacco Company | Staple fiber blend for use in the manufacture of cigarette filter elements |
| KR20210029155A (ko) * | 2018-07-13 | 2021-03-15 | 주식회사 다이셀 | 전자 담배 팁용의 토우 밴드, 전자 담배용 팁, 및 전자 담배 팁용의 토우 밴드의 제조 방법 |
| CN113660868A (zh) * | 2019-04-05 | 2021-11-16 | 日本烟草国际股份有限公司 | 具有环境优化型过滤器的气溶胶产生装置 |
| US20210015170A1 (en) * | 2019-07-15 | 2021-01-21 | Bio-On S.P.A. | Aerosol-generating articles suitable for use in aerosol-generating devices |
| CN110477450B (zh) * | 2019-08-28 | 2023-07-11 | 深圳市智叶科技有限公司 | 一种电子烟用过滤嘴及其制备方法 |
| CN111548772A (zh) * | 2020-05-29 | 2020-08-18 | 南通大学 | 一种多壁碳纳米管复合定形相变材料及其制备方法和应用 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5292783A (en) * | 1990-11-30 | 1994-03-08 | Eastman Kodak Company | Aliphatic-aromatic copolyesters and cellulose ester/polymer blends |
| DE4136694C2 (de) * | 1991-11-07 | 1996-10-10 | Inventa Ag | Stärkefaser oder Stärke-modifizierte Faser, Verfahren zu ihrer Herstellung sowie ihre Verwendung |
| US5538019A (en) * | 1993-11-03 | 1996-07-23 | Schweitzer-Mauduit International, Inc. | Spunbond cigarette filter |
| US5947126A (en) * | 1997-05-29 | 1999-09-07 | Eastman Chemical Co. | Environmentally disintegratable tobacco smoke filter rod |
| MY128157A (en) * | 2000-04-20 | 2007-01-31 | Philip Morris Prod | High efficiency cigarette filters having shaped micro cavity fibers impregnated with adsorbent or absorbent materials |
| MY138902A (en) * | 2000-04-20 | 2009-08-28 | Philip Morris Prod | "cigarette filters of shaped micro cavity fibers impregnated with flavorant materials" |
| US6946506B2 (en) * | 2001-05-10 | 2005-09-20 | The Procter & Gamble Company | Fibers comprising starch and biodegradable polymers |
| US6907895B2 (en) * | 2001-09-19 | 2005-06-21 | The United States Of America As Represented By The Secretary Of Commerce | Method for microfluidic flow manipulation |
| US6913784B2 (en) * | 2001-11-30 | 2005-07-05 | Philip Morris Usa Inc. | Continuous process for impregnating solid adsorbent particles into shaped micro-cavity fibers and fiber filters |
| US6919105B2 (en) * | 2003-01-06 | 2005-07-19 | Philip Morris Usa Inc. | Continuous process for retaining solid adsorbent particles on shaped micro-cavity fibers |
| US7767134B2 (en) * | 2005-06-29 | 2010-08-03 | Philip Morris Usa Inc. | Templated carbon monolithic tubes with shaped micro-channels and method for making the same |
| US8602036B2 (en) * | 2006-08-03 | 2013-12-10 | Philip Morris Usa Inc. | Smoking articles enhanced to deliver additives incorporated within electrospun microfibers and nonofibers, and related methods |
-
2008
- 2008-07-31 MX MX2010001248A patent/MX2010001248A/es not_active Application Discontinuation
- 2008-07-31 CN CN200880024688A patent/CN101742932A/zh active Pending
- 2008-07-31 KR KR1020097027544A patent/KR20100045412A/ko not_active Withdrawn
- 2008-07-31 WO PCT/IB2008/002793 patent/WO2009016513A2/en not_active Ceased
- 2008-07-31 US US12/183,470 patent/US20090032037A1/en not_active Abandoned
- 2008-07-31 AU AU2008281436A patent/AU2008281436A1/en not_active Abandoned
- 2008-07-31 JP JP2010518776A patent/JP2010535024A/ja active Pending
- 2008-07-31 BR BRPI0815065-6A2A patent/BRPI0815065A2/pt not_active Application Discontinuation
- 2008-07-31 EA EA201070199A patent/EA201070199A1/ru unknown
- 2008-07-31 EP EP08826746A patent/EP2170110A2/en not_active Withdrawn
-
2010
- 2010-03-01 CO CO10024065A patent/CO6160279A2/es unknown
Non-Patent Citations (1)
| Title |
|---|
| See references of WO2009016513A2 * |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2009016513A2 (en) | 2009-02-05 |
| KR20100045412A (ko) | 2010-05-03 |
| CO6160279A2 (es) | 2010-05-20 |
| MX2010001248A (es) | 2010-03-01 |
| WO2009016513A8 (en) | 2009-03-19 |
| BRPI0815065A2 (pt) | 2015-02-10 |
| AU2008281436A1 (en) | 2009-02-05 |
| US20090032037A1 (en) | 2009-02-05 |
| WO2009016513A3 (en) | 2009-09-24 |
| EA201070199A1 (ru) | 2010-06-30 |
| CN101742932A (zh) | 2010-06-16 |
| JP2010535024A (ja) | 2010-11-18 |
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Legal Events
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