EP2193108A2 - Verfahren zur herstellung von portlandhüttenzementen und hochofenzement - Google Patents
Verfahren zur herstellung von portlandhüttenzementen und hochofenzementInfo
- Publication number
- EP2193108A2 EP2193108A2 EP08802548A EP08802548A EP2193108A2 EP 2193108 A2 EP2193108 A2 EP 2193108A2 EP 08802548 A EP08802548 A EP 08802548A EP 08802548 A EP08802548 A EP 08802548A EP 2193108 A2 EP2193108 A2 EP 2193108A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- mill
- cement
- entry
- grinding
- classifier
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000004568 cement Substances 0.000 title claims abstract description 34
- 238000000034 method Methods 0.000 title claims abstract description 17
- 239000002893 slag Substances 0.000 title claims abstract description 12
- 239000011400 blast furnace cement Substances 0.000 title claims abstract description 8
- 238000004519 manufacturing process Methods 0.000 title abstract description 7
- 238000000227 grinding Methods 0.000 claims abstract description 35
- 239000011398 Portland cement Substances 0.000 claims abstract description 16
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims abstract description 13
- 239000004576 sand Substances 0.000 claims abstract description 5
- 239000000463 material Substances 0.000 claims description 14
- 229910021653 sulphate ion Inorganic materials 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims 2
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 claims 1
- 238000005056 compaction Methods 0.000 claims 1
- 238000002161 passivation Methods 0.000 claims 1
- 239000000843 powder Substances 0.000 abstract 1
- 235000013339 cereals Nutrition 0.000 description 6
- 235000013312 flour Nutrition 0.000 description 5
- 229910052602 gypsum Inorganic materials 0.000 description 3
- 239000010440 gypsum Substances 0.000 description 3
- 238000003801 milling Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000004088 simulation Methods 0.000 description 2
- 230000032258 transport Effects 0.000 description 2
- 241000237858 Gastropoda Species 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 235000008429 bread Nutrition 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 235000012054 meals Nutrition 0.000 description 1
- 238000012821 model calculation Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
- B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
- B02C23/00—Auxiliary methods or auxiliary devices or accessories specially adapted for crushing or disintegrating not provided for in preceding groups or not specially adapted to apparatus covered by a single preceding group
- B02C23/08—Separating or sorting of material, associated with crushing or disintegrating
- B02C23/10—Separating or sorting of material, associated with crushing or disintegrating with separator arranged in discharge path of crushing or disintegrating zone
- B02C23/12—Separating or sorting of material, associated with crushing or disintegrating with separator arranged in discharge path of crushing or disintegrating zone with return of oversize material to crushing or disintegrating zone
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
- B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
- B02C21/00—Disintegrating plant with or without drying of the material
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B7/00—Hydraulic cements
- C04B7/36—Manufacture of hydraulic cements in general
- C04B7/48—Clinker treatment
- C04B7/52—Grinding ; After-treatment of ground cement
- C04B7/527—Grinding ; After-treatment of ground cement obtaining cements characterised by fineness, e.g. by multi-modal particle size distribution
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/10—Compositions or ingredients thereof characterised by the absence or the very low content of a specific material
- C04B2111/1075—Chromium-free or very low chromium-content materials
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/10—Production of cement, e.g. improving or optimising the production methods; Cement grinding
Definitions
- the invention relates to a method for the production of Portland hut cements and blast furnace cement according to claim 1.
- Portland cement is known to be ground from clinker.
- the clinker is introduced together with a sulphate carrier, for example gypsum, in a cement mill, for example a good bed roller mill.
- a sulphate carrier for example gypsum
- CEM I 32.5 R the class of cement
- CEM I 42.5 R the class of cement
- CEM I 52.5 R the class of cement
- the latter is the one with the highest strength in the listed Portland cements
- it is also known to mill in two stages. Two-stage milling processes are also used to achieve higher mass flow rates coupled with significant energy savings. In a first milling stage, e.g.
- a good bed roller mill in circuit with a dynamic sifter.
- the discharge of the dynamic classifier is entered in the entry e.g. a ball mill as a second grinding step, which works in conjunction with another cyclic classifier in the circuit.
- the separated from the classifier finished product is discharged into appropriate reservoirs. Insufficiently comminuted regrind is thus guided to the entry of the second grinding stage.
- Mahlkugel supportiven results on the one hand from a different grinding resistance - for example from clinker about 12-16 kWh / t and of granulated slag about 18-22 kWh / t - and on the other hand from the upper grain size of the feed.
- Clinker is much coarser than, for example, granulated blastfurnace slag, which is very large grinding balls at the mill entry of a first grinding stage with 90 to 100 mm diameter required.
- a second grinding stage is able to work with balls of 30 to 20 mm diameter at the mill entry and 12 mm diameter at the discharge. It goes without saying that the ball diameter should decrease in the direction of the mill discharge.
- Portland cement is ground in one or two stages using one or two mills. With the help of one or two mills, a multi-component cement can also be produced. The components are ground either together or separately, in the latter case, a separate mixing stage is provided. For the grinding systems described a considerable amount of energy is required.
- a grinding plant which includes a pre-mill, in particular a good-bed roller mill, a first classifier for sighting in the Milled crushed material in a coarser and a finer fraction, a second classifier for sifting at least the finer fraction of the first classifier in coarse and fine material and a fine mill, in particular a ball mill, for grinding the coarse material of the second classifier has.
- the fine mill and the second classifier are connected via a conveying device which mechanically transports the material up to the second classifier.
- the invention has for its object to provide a method for the production of Portlandchristnzement and blast furnace cements, which can be carried out on energy-saving and the use value of the cement increasing manner.
- Portland cement clinker for grinding in a first mill the cement mill, registered.
- the Austragsgut the cement mill is given directly and / or via an intermediate reservoir in the entry of a dynamic classifier with preferably predetermined separation section.
- the coarse material of the dynamic classifier is given to the entry of a mill.
- granulated blastfurnace or granulated bread is additionally added.
- the material to be removed from the dynamic sifter is added to the feed of a second mill for fine grinding.
- the output material of the second mill is added to the entry of the dynamic classifier.
- Sulfate carrier is fed either to the entry of the first mill, the entry of the dynamic classifier or the entry of the second mill.
- the fines of the dynamic classifier are fed to a reservoir.
- this clinker flour with a fineness corresponding to the Portland cement is provided, this clinker flour together with a dried finely divided sulphate carrier will be added to the sifter.
- slag sand mills or cement mills can be considered.
- a vertical roller mill or a circulating ball mill can be used.
- Portland cement of the class CEM I 52.5 R from the classes CEM I 42.5 R or CEM I 32.5 R is grinded.
- a special cement of a high degree of fineness can also be obtained.
- the peculiarity of the method according to the invention is that the Portland cement is first fed to a dynamic sifter for a subsequent grinding, so that only the resulting classifier seed feeds the mill entry.
- Sulphate carrier can be ground together with clinker in the first mill.
- sulphate carrier is fed to the entry of the dynamic classifier.
- sulfate carrier is added to the entry of the second mill.
- an existing granulated blast-furnace sand mill which is better-greased for fine comminution, is used for refining, whose ball diameters are graduated, for example, from 40 mm to 17 mm.
- the process can be realized by a second stage for post-crushing in-use cement mill not at the entry of the mill, but according to the invention entry with, for example, a Vorzement (clinker flour plus finely divided sulfate carrier, dry) or with a Portland cement class CEM I 42.5 R or CEM I 32.5 R is charged.
- the possible ball diameters are between 25 mm and 12 mm or smaller. A higher energy efficiency is the result.
- FIG. 1 shows a block diagram of a two-stage grinding process according to the invention.
- FIG. 1 shows a two-stage grinding plant. From a clinker silo 20 and a sulphate carrier or gypsum silo 22, the materials to be milled are introduced into a first mill 24, which may be a ball mill, a good bed roller or a vertical roller mill. The output 25 of the mill 24 goes to the entry of a dynamic classifier 26. Its coarse grain returns at 28 to the entry of the first mill 24. The fines discharge 27 of the dynamic classifier 26 is based on a dynamic classifier 30. Alternatively, the discharging fines 27 of the classifier 26 in a silo 32, which is also connected to the entry of the dynamic classifier 30.
- a first mill 24 which may be a ball mill, a good bed roller or a vertical roller mill.
- the output 25 of the mill 24 goes to the entry of a dynamic classifier 26. Its coarse grain returns at 28 to the entry of the first mill 24.
- the fines discharge 27 of the dynamic classifier 26 is based on a dynamic class
- the coarse grain 39 from the dynamic classifier 30 enters the entry of the mill 40, which may be, for example, a ball mill, a vertical roller mill, or a stirred ball mill.
- the Kugelmühlengattierung is in this case for a fine and Feinstzerkleintation designed.
- the discharge of the mill 40 passes at 41 in the entry of the dynamic classifier 30.
- the fines of the dynamic classifier 30 is entered via the conveyor line 31 in a cement silo 42.
- This fine material is Portlandchristnzement or blast furnace cement high degree of fineness, which can be adjusted via the dynamic classifier 30 and the mill 40.
- the energy to be expended for the described process is significantly reduced in relation to conventional grinding plants.
- the balanced fine grinding mill for cement grinding consists of a single-chamber tubular ball mill 3.6 m Dmr. x 10.5m in length.
- Table 1 contains the essential parameters for the above embodiments.
- the required output data is taken from the recorded reference state (*), s. Table 1, column 2, and the Mahllesskennkurven the components, for example according to Zeisel or Bondtest.
- a predictive calculation model is used to calculate the grinding plant within the flowchart simulation.
- a suitable parameterized map is used to calculate the classifier flows: Particle size and unaddressed proportion as a function of feed fineness, load and classifier speed.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Food Science & Technology (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Crushing And Grinding (AREA)
- Disintegrating Or Milling (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102007046834A DE102007046834B4 (de) | 2007-09-29 | 2007-09-29 | Verfahren zur Herstellung von Hüttensandmehl enthaltenden Zementen |
| PCT/EP2008/008066 WO2009043510A2 (de) | 2007-09-29 | 2008-09-24 | Verfahren zur herstellung von portlandhüttenzementen und hochofenzement |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP2193108A2 true EP2193108A2 (de) | 2010-06-09 |
Family
ID=40070612
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP08802548A Withdrawn EP2193108A2 (de) | 2007-09-29 | 2008-09-24 | Verfahren zur herstellung von portlandhüttenzementen und hochofenzement |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US20100242805A1 (pt) |
| EP (1) | EP2193108A2 (pt) |
| AU (1) | AU2008306222A1 (pt) |
| BR (1) | BRPI0817617A2 (pt) |
| CA (1) | CA2701139A1 (pt) |
| DE (1) | DE102007046834B4 (pt) |
| MX (1) | MX2010003507A (pt) |
| WO (1) | WO2009043510A2 (pt) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102211358B (zh) * | 2010-12-30 | 2015-12-16 | 何玉成 | 一种级配砂料的制备方法及实施该方法的构造 |
| DE102011008967B4 (de) * | 2011-01-12 | 2014-10-30 | Khd Humboldt Wedag Gmbh | Anlage zur Herstellung von Zement mit zentraler Mahleinheit |
| CA2859455C (en) | 2011-12-16 | 2020-01-07 | Holcim Technology Ltd. | Grinding process and unit, and corresponding production process of a hydraulic binder |
| BR112014011302B1 (pt) * | 2011-12-22 | 2023-09-26 | Sika Technology Ag | Uso de uma mistura redutora de água |
| PL2980036T3 (pl) | 2014-07-28 | 2018-07-31 | Heidelbergcement Ag | Sposób mielenia klinkieru cementowego |
| CN106348629B (zh) * | 2016-08-25 | 2018-02-23 | 嘉华特种水泥股份有限公司 | 一种水泥粉磨制备工艺 |
| EP3326720B1 (de) | 2016-11-23 | 2021-11-03 | Loesche GmbH | Verfahren zum aufbereiten von mehrphasen-mineral-rohstoffen |
| DE102017115994A1 (de) | 2017-07-17 | 2019-01-17 | Thyssenkrupp Ag | Zweistufiger Mahlkreislauf und Verfahren zur Herstellung eines gemahlenen Produkts mittels einer zweistufigen Mahlung |
| DE102017117985A1 (de) | 2017-08-08 | 2019-02-14 | Thyssenkrupp Ag | Verfahren und Anlage zur Herstellung von Zement |
| IT201800020080A1 (it) * | 2018-12-18 | 2020-06-18 | Heidelbergcement Ag | Miscela cementizia per stampante 3D, a prestazioni migliorate, e relativo uso in detta stampante |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3490702A (en) * | 1966-10-24 | 1970-01-20 | D Ore Mills Inc | Method of accelerating production of portland cement and similar material |
| FR2329350A1 (fr) * | 1975-10-28 | 1977-05-27 | Inst Tsementnoi Promy | Broyeur a projection |
| DE3138342C2 (de) * | 1981-09-26 | 1983-10-06 | Portland-Zementwerk Wotan, H. Schneider Kg, 5531 Ahuette | Trockenverfahren zur Herstellung von Zement |
| DE3334235A1 (de) * | 1982-11-04 | 1984-05-10 | Heinz 4630 Bochum Jäger | Verfahren und vorrichtung zur energiesparenden herstellung eines feingutes, insbesondere zement |
| DE3843338A1 (de) * | 1988-12-22 | 1990-06-28 | Krupp Polysius Ag | Sichter |
| DE3905123A1 (de) * | 1989-02-20 | 1990-08-23 | Kloeckner Humboldt Deutz Ag | Sichter zum sichten von koernigem gut und mahlanlage mit einschaltung eines solchen sichters |
| IT1248066B (it) * | 1991-06-17 | 1995-01-05 | Italcementi Spa | Separatore dinamico per materiali polverulenti, in particolare cementoed impianto che lo comprende |
| DK0686065T3 (da) * | 1993-03-03 | 1998-02-02 | Slegten Sa | Styreproces til tørformalingsenhed, der fungerer i lukket kredsløb |
| DE4320025A1 (de) * | 1993-06-17 | 1994-12-22 | Krupp Polysius Ag | Mahlanlage und Verfahren zum Mahlen und Sichten von sprödem Mahlgut |
| DE19514971A1 (de) * | 1994-04-27 | 1995-11-02 | Heinz Jaeger | Verfahren und Anlage zur energiesparenden Herstellung eines Feingutes |
| DE19828326A1 (de) * | 1998-06-25 | 1999-12-30 | Alsen Ag | Hüttensandhaltiges Bindemittel, insbesondere Zement |
| EP0995726A1 (de) * | 1998-10-19 | 2000-04-26 | E. Schwenk Zementwerke KG | Verfahren und Vorrichtung zum Herstellen eines hydraulischen Bindemittels |
| CZ292488B6 (cs) * | 1999-03-18 | 2003-10-15 | Psp Engineering A. S. | Způsob mletí materiálů s rozdílnou zrnitostí |
| DE10119977A1 (de) * | 2001-04-24 | 2002-10-31 | Kloeckner Humboldt Wedag | Verfahren und Anlage zur Herstellung von Zementklinker |
-
2007
- 2007-09-29 DE DE102007046834A patent/DE102007046834B4/de not_active Withdrawn - After Issue
-
2008
- 2008-09-24 AU AU2008306222A patent/AU2008306222A1/en not_active Abandoned
- 2008-09-24 US US12/680,116 patent/US20100242805A1/en not_active Abandoned
- 2008-09-24 BR BRPI0817617 patent/BRPI0817617A2/pt not_active Application Discontinuation
- 2008-09-24 CA CA2701139A patent/CA2701139A1/en not_active Abandoned
- 2008-09-24 WO PCT/EP2008/008066 patent/WO2009043510A2/de not_active Ceased
- 2008-09-24 MX MX2010003507A patent/MX2010003507A/es unknown
- 2008-09-24 EP EP08802548A patent/EP2193108A2/de not_active Withdrawn
Non-Patent Citations (1)
| Title |
|---|
| See references of WO2009043510A2 * |
Also Published As
| Publication number | Publication date |
|---|---|
| DE102007046834A1 (de) | 2009-04-02 |
| DE102007046834B4 (de) | 2010-01-14 |
| MX2010003507A (es) | 2010-08-02 |
| CA2701139A1 (en) | 2009-04-09 |
| WO2009043510A2 (de) | 2009-04-09 |
| WO2009043510A3 (de) | 2009-06-18 |
| AU2008306222A1 (en) | 2009-04-09 |
| US20100242805A1 (en) | 2010-09-30 |
| BRPI0817617A2 (pt) | 2015-03-31 |
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