EP2199713A2 - Récipient et dispositif pour réfrigérations de marchandises directes ainsi que procédé de fabrication du récipient - Google Patents

Récipient et dispositif pour réfrigérations de marchandises directes ainsi que procédé de fabrication du récipient Download PDF

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Publication number
EP2199713A2
EP2199713A2 EP09015245A EP09015245A EP2199713A2 EP 2199713 A2 EP2199713 A2 EP 2199713A2 EP 09015245 A EP09015245 A EP 09015245A EP 09015245 A EP09015245 A EP 09015245A EP 2199713 A2 EP2199713 A2 EP 2199713A2
Authority
EP
European Patent Office
Prior art keywords
container
cooling
thermal conductivity
layer
heat
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP09015245A
Other languages
German (de)
English (en)
Other versions
EP2199713A3 (fr
EP2199713B1 (fr
Inventor
Bert-Olaf Grimm
Peter Zehnel
Kai Marschner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eppendorf SE
Original Assignee
Eppendorf SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eppendorf SE filed Critical Eppendorf SE
Priority to PL09015245T priority Critical patent/PL2199713T3/pl
Publication of EP2199713A2 publication Critical patent/EP2199713A2/fr
Publication of EP2199713A3 publication Critical patent/EP2199713A3/fr
Application granted granted Critical
Publication of EP2199713B1 publication Critical patent/EP2199713B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B04CENTRIFUGAL APPARATUS OR MACHINES FOR CARRYING-OUT PHYSICAL OR CHEMICAL PROCESSES
    • B04BCENTRIFUGES
    • B04B15/00Other accessories for centrifuges
    • B04B15/02Other accessories for centrifuges for cooling, heating, or heat insulating
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D19/00Arrangement or mounting of refrigeration units with respect to devices or objects to be refrigerated, e.g. infrared detectors
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D19/00Arrangement or mounting of refrigeration units with respect to devices or objects to be refrigerated, e.g. infrared detectors
    • F25D19/006Thermal coupling structure or interface
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D31/00Other cooling or freezing apparatus
    • F25D31/006Other cooling or freezing apparatus specially adapted for cooling receptacles, e.g. tanks
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D1/00Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators
    • F28D1/06Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with the heat-exchange conduits forming part of, or being attached to, the tank containing the body of fluid
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F13/00Arrangements for modifying heat-transfer, e.g. increasing, decreasing
    • F28F13/18Arrangements for modifying heat-transfer, e.g. increasing, decreasing by applying coatings, e.g. radiation-absorbing, radiation-reflecting; by surface treatment, e.g. polishing
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F13/00Arrangements for modifying heat-transfer, e.g. increasing, decreasing
    • F28F2013/005Thermal joints
    • F28F2013/006Heat conductive materials
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F2255/00Heat exchanger elements made of materials having special features or resulting from particular manufacturing processes
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F2270/00Thermal insulation; Thermal decoupling
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/49Method of mechanical manufacture
    • Y10T29/4935Heat exchanger or boiler making

Definitions

  • the present invention relates to a container according to the preamble of claim 1, a device according to the preamble of claim 5 and a method of manufacturing the container according to the preamble of claim 7.
  • the present invention relates to laboratory centrifuges, i. Centrifuges used, for example, in chemical, biological, biochemical or biotechnological laboratories.
  • the present invention can be advantageously used in large-scale centrifuges and mechanical stirring devices and all devices in which a good is to be cooled at least indirectly.
  • the invention is also in pure cooling devices, such as refrigerators and freezers and especially laboratory cooling and laboratory freezers, where a very deep cooling to be achieved, can be used.
  • the container forms the enclosure of the interior of the device in which the good is introduced.
  • the invention does not relate to cookware, frying pans or the like containers which serve to heat a good that can be arranged in the container.
  • the ambient air is passed directly through the centrifuge bowl at the centrifuge rotor, with the rotor acting as a kind of radial fan.
  • the centrifuge lid and / or centrifuge bowl has an inlet opening near the axis and an outlet opening arranged at a distance from the axis of rotation.
  • the centrifuge tank must have an outlet opening for it, which, however, also permits a material outlet.
  • Such boilers are thus not suitable for stirring devices or the like, in which materials are to be mixed directly and must therefore be formed closed all around.
  • a disadvantage of direct cooling results from the use of the ambient air as a coolant: the good can be cooled only to the maximum temperature of the ambient air.
  • indirect cooling the rotor is enclosed in the centrifuge vessel under the centrifuge lid and no cooling channel or the like is provided.
  • the air circulates therefore only within the centrifuge bowl. Cooling is now achieved by a second medium, which is passed on the outside of the boiler.
  • This can either be ambient air, which is conducted past the outside of the boiler, as is realized, for example, in the case of the centrifuge 5424 from Eppendorf AG.
  • a special coolant is routed past the boiler via conduits spiraling against the boiler, ie the side walls and the bottom plate of the boiler, to remove heat.
  • An advantage of indirect cooling is the better controllability of the temperature to be set compared to direct cooling.
  • the object of the present invention is to provide a container that allows efficient indirect cooling and is simple and inexpensive to produce.
  • the container should not only be used in centrifuges, but also stirring devices, cooling devices and the like can be found.
  • Container in the context of the present invention are all devices in which a good to be cooled can be arranged directly or indirectly via a separate enclosure and which can be cooled by means of indirect cooling via a standing in heat conductive contact cooling device.
  • the container according to the invention may be designed differently with respect to the outer shape. He can round or be kettle-shaped. In such a case, the container has a round bottom plate from which pulls up a side wall at the outer edge. The top of the container is closed by an openable lid.
  • the container is angular, ie designed rectangular or square. He then has a rectangular or square base plate, extending from the outer edge of each four sidewalls. The top of the container is closed with a top plate.
  • the container either at least one of the side walls is designed as an openable door or the top of the container, ie the upper plate is formed as an openable lid.
  • the upper plate is formed as an openable lid.
  • Heat conductive contact in the context of the present invention means that the contact must be such that the heat transfer can be carried out by heat conduction. So there must be a material contact, but this does not mean that this contact must exist directly - so between the two layers can also be arranged one or more intermediate layers.
  • heat-transferring contact means, for example, that the contact must be such that heat transfer can take place at least by one of the three principal heat transfer mechanisms, heat conduction, radiation or convection. It does not necessarily have to be a material contact.
  • Direct contact between two objects in the context of the present invention means that two objects at least partially abut each other directly and thus touch each other. When in the context of the present invention is generally referred to as “contact” or “contact point”, i. without the preceding words “heat conducting” or "heat transferring”, this always means a direct contact.
  • the container according to the invention comprises a container body which has at least two heat-conducting contact container layers with different thermal conductivity.
  • the two container layers create a large contact area that improves heat transfer during cooling. Due to the fact that the layer with higher thermal conductivity is arranged on the outside of the container to be cooled, the heat flow is increased in the direction of the cooling device, which only conducts heat in some areas in contact with the cooling surface of the container. This results in an overall increased cooling efficiency.
  • the thermal conductivities should differ by a factor greater than 10, preferably greater than 20, in particular greater than 100.
  • the layer with lower thermal conductivity is formed from a material comprising stainless steel, steel, ceramic, glass and / or plastic and the layer with higher thermal conductivity is made of a material aluminum, gold, carbon, including its modifications graphite, diamond, diamond-like carbon and carbon nanotubes, copper, magnesium, brass, silver and / or silicon or their alloys formed. Then a particularly efficient heat transfer can be ensured and the boiler is also easy to produce.
  • an embodiment of the layer with higher thermal conductivity than film is advantageous, for example, as a pyrolytic graphite foil (PGS), since this manufacturing technology is simply applied to the layer with lower thermal conductivity.
  • PPS pyrolytic graphite foil
  • nanolayers can be used, that is to say a layer which was produced using nanotechnology. In the following, such a layer is understood to consist of a "nanomaterial".
  • the layer with higher thermal conductivity has a small thickness of less than 1 mm, preferably less than 0.5 mm and in particular less than 0.2 mm. It should be noted that depending on the layer material, the heat flow at too thick layers decreases and the heat transfer may be disturbed in the case of layers that are too thin, so that there is an optimum with respect to the minimum thickness for each layer material, which the expert will find out routinely by means of tests and calculations.
  • a device for treatment in particular centrifuging, stirring, cooling or the like of a good, in particular a laboratory centrifuge, a refrigerator, a freezer, a laboratory refrigerator, a laboratory freezer, or the like, with a container and a region only with a cooled outer surface of the container in heat-conducting contact cooling means for indirect cooling of the arranged inside the container good, wherein the container is designed as the container according to the invention.
  • the container is surrounded by a tubular conduit, which is preferably wound helically around the container.
  • tubular includes round tubes as well as tubes with at least one flattened side, in particular also rectangular tubes.
  • On in some areas in the context of the present invention means that the contact area between the cooling device and the cooled outer surface of the container is smaller than the cooled outer surface of the container.
  • the cooling device can also be formed by a plurality of separately operating devices, but their total contact area should be smaller than the cooled container outer surface.
  • indirect heat transfer according to the invention can also be coupled with a direct heat transfer, for example, the known rotor air assisted centrifugal cooling.
  • the layer with higher thermal conductivity is disposed on the layer with lower thermal conductivity or vice versa.
  • this can be done by the one layer, preferably the one with the higher thermal conductivity aufplatiert on the other layer and then the container is formed or two separate layers are stacked, for example, as foils or sheets and the container, for example, by simultaneous forming, For example, deep drawing, the layers shaped.
  • the higher thermal conductivity layer is deposited on the lower thermal conductivity layer after the lower thermal conductivity layer has substantially the shape of the container, or vice versa, the lower thermal conductivity layer is applied to the higher thermal conductivity layer after the lower thermal conductivity layer Layer with higher thermal conductivity has essentially received the shape of the container. Then, the manufacturing process can be made more cost-effective, for example, the layer with higher thermal conductivity is galvanotechnically applied to the layer with low thermal conductivity or vice versa.
  • Q ⁇ the heat flow through the solid
  • the thermal conductivity, which is a material constant
  • A the size of the solid's cross-sectional area
  • s the thickness of the solid
  • ⁇ T the temperature difference between the input and output sides of the heat flow.
  • FIG. 1 This principle is explained purely schematically for a prior art known and partially illustrated centrifuge vessel with a boiler wall 1, which is in contact with a cooling line 2.
  • the possibilities are available to reduce the wall thickness s 1 and s 2 and / or the boiler wall 1 made of a material with a very high thermal conductivity ⁇ (eg copper or silver), however, the first possibility is technically limited by the functional design of the components and is usually exhausted and the second option is usually not possible for application reasons and the intended use, since for example copper or silver is not chemically inert are.
  • very high thermal conductivity
  • an additional heat conducting layer is provided on the outer wall of the boiler by the inventors, as in Fig. 2 again in a purely schematic for the resulting and illustrated by the arrows heat flow fragmentary is shown.
  • an additional Kotaktstelle is inserted with a large contact area.
  • Fig. 1 Unlike the centrifuge kettle after Fig. 1 here is thus adjacent to the interior of the boiler vessel defining inner layer 10 having the thickness of 10 s an additional external boiler layer 11 is applied with the thickness s 11 from good heat conducting material as a boiler outer wall.
  • the cooling line 12 has the thickness s 12 .
  • the principle according to the invention has been described herein with reference to two container layers with different thermal conductivity, it is clear that three or more layers can also be used. These may in particular be anti-corrosion, anti-contamination or the like layers. It is only important that the layer with higher thermal conductivity is arranged on the container outer surface to be cooled. However, one or more further layers can be arranged between the layer with higher and the layer with lower thermal conductivity as well as on the layer with lower thermal conductivity in order to adapt the container to particular conditions of use.
  • a laboratory centrifuge 5415R from Eppendorf AG which has as cooling line 2, 12 a spiral rectangular tube with a width of 9.5 mm, a height of 5.5 mm and a material thickness of 0.5 mm.
  • a serial centrifuge vessel 1 with a diameter of 185 mm, a height of 70 mm and a wall thickness of 1 mm (article No. 5426 123.101-00) from Eppendorf AG was used, which was made of V2A stainless steel (thermal conductivity about 15 W / m * K) and with thermal grease (thermal conductivity about 15 W / m * K) provided in the cooling line 2 was arranged to form the comparative example.
  • the standard stainless steel centrifuge vessel 10 (article No. 5426 123.101-00) from Eppendorf AG was provided with a 0.1 mm thick copper coating 11 (thermal conductivity about 350 W / m.sup.K), otherwise the experimental setup is the same, ie The centrifuge vessel was connected to the rectangular cooling line 12 by means of thermal paste (thermal conductivity also about 15 W / m * K).
  • the centrifuge 5415R was operated with a conventional rotor F45-24-11 from Eppendorf AG for one hour at a maximum of 13200 rpm. The minimum achievable sample temperature was measured with the temperature meter. The results are recorded in the table. ⁇ U> Table ⁇ / u> 5415R with centrifuge bowl without Cu coating 5415R with centrifuge bowl with Cu coating Room temperature [° C] 25 26 Sample temperature [° C] 3.9 0.4
  • the present invention allows much more efficient indirect cooling from the exterior of the container to the interior of the container.
  • the improvement of the heat conduction and the heat transfer of centrifuge boilers results in cooled centrifuges a reduction of the necessary performance of the refrigeration system. Due to the higher efficiency of the centrifuge, a higher rotational speed can be run for the same centrifuging product temperatures and / or the absorbed power of the cooling unit can be reduced with the same centrifuging product temperature and the same rotational speed.
  • the principle according to the invention is based on the finding that with indirect cooling of a container surface which is larger than the contact surface between the container and the cooling device, the cooling effect can be increased if the container has a layer with higher thermal conductivity in addition to the layer with low thermal conductivity and the layer with higher thermal conductivity is arranged on the container outer surface to be cooled and is in conductive contact with the cooling device.
  • the cooling capacity is better transferred to the interior of the container to be cooled there Good.
  • An alternative solution is to make the contact area between the cooling device and the cooled surface of the container at least equal to the cooled container surface. This can be realized by virtue of the fact that the cooling device is part of the layer of the container with greater thermal conductivity.
  • the second layer consists of a solid, such as copper or the like, and the cooling device is arranged directly in this layer.
  • the cooling device can also be arranged in a liquid, gel or the like which is in heat-conducting contact with the layer of lower thermal conductivity and which itself has a higher thermal conductivity.
  • the container has a layer which has, between itself and the layer with lower thermal conductivity, a cavity which can be filled with a liquid, gel or the like, in which the cooling device is arranged (the thermal conductivity of this further layer is insignificant, as it relates to FIG the cooling device is outside).
  • the container does not itself comprise the liquid, gel or the like, but it is provided with the cooling means housed therein in a device in which the container can be arranged to heat the liquid, gel or the like with the layer of low heat conductivity is in managerial contact.
  • the container in the sense of a bath itself preferably to the edge completely, are immersed in the liquid, gel or the like or the liquid, gel or the like is in contact only with a part of the container outer surface.
  • liquid, gel or the like and the layer with low thermal conductivity may also be arranged a further layer with higher thermal conductivity.
  • the liquid, gel or the like may be disposed with the cooling device within a copper sheath which is either integrated directly into the container or provided in the device, where then the container can be brought into direct contact with this copper sheath. This can also achieve the seal.
  • liquids and gels include both Newtonian fluids and non-Newtonian fluids, sols, dispersions, suspensions, as well as any combination of two or more of these listed substances.
  • a liquid or gel can be selected from the following group: water, ionic liquids, suspensions of carbon nanotubes, cooling brines, eutectics or eutectic mixtures and similar materials.
  • Antifrogen N, Antifrogen L and Antifrogen SOL) or potassium formate (Antifrogen KF) Furthermore, find ionic liquids, such as 1-ethyl-3-methylimidazolium chloride, 1-ethyl-3-methylimidazolium methanesulfonate, 1-butyl-3-methylimidazolium chloride , 1-butyl-3-methylimidazolium methanesulfonate, 1-Ethyl-2,3-dimethylimidazolium ethylsulfate (sold under the trademark Basionics® BASF SE, 67063 Ludwigshafen, DE) application. Also can be used polyalkylene glycol derivatives.
  • the advantage of this alternative solution is that the cooling device no longer has to be in direct contact with the container surface to be cooled, possibly mediated by the intermediary of a thermal compound. As a result, there are no such great demands on the accuracy of, for example, the winding geometry of a cooling tube with respect to the container outer contour, which reduces costs.

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Centrifugal Separators (AREA)
EP09015245.5A 2008-12-22 2009-12-09 Centrifugeuse de laboratoire Active EP2199713B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL09015245T PL2199713T3 (pl) 2008-12-22 2009-12-09 Wirówka laboratoryjna

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US13988008P 2008-12-22 2008-12-22
DE102008064178A DE102008064178A1 (de) 2008-12-22 2008-12-22 Behälter und Vorrichtung für mittelbare Gutkühlungen sowie Verfahren zur Herstellung des Behälters

Publications (3)

Publication Number Publication Date
EP2199713A2 true EP2199713A2 (fr) 2010-06-23
EP2199713A3 EP2199713A3 (fr) 2012-05-02
EP2199713B1 EP2199713B1 (fr) 2018-08-29

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ID=43334663

Family Applications (1)

Application Number Title Priority Date Filing Date
EP09015245.5A Active EP2199713B1 (fr) 2008-12-22 2009-12-09 Centrifugeuse de laboratoire

Country Status (4)

Country Link
US (2) US20100155037A1 (fr)
EP (1) EP2199713B1 (fr)
DE (1) DE102008064178A1 (fr)
PL (1) PL2199713T3 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111572980B (zh) * 2020-05-19 2021-07-13 西安交通大学 一种环保型深紫外杀菌智能配送箱
MX2022015370A (es) 2020-06-05 2023-01-16 Pepsico Inc Refrigerador para enfriar una bebida.

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5477704A (en) 1992-12-11 1995-12-26 Beckman Instruments, Inc. Refrigerant cooling assembly for centrifuges

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DE1806839A1 (de) * 1968-11-04 1970-09-17 Bauknecht Gmbh G Kuehlmoebel
HU177645B (en) * 1979-07-12 1981-11-28 Huetoegepgyar Setup for water tight insulating evaporator of the refrigerators in particular of the absorption machines
US4738113A (en) * 1985-10-18 1988-04-19 The Cola-Cola Company Combination cooler and freezer for refrigerating containers and food in outer space
IT1188061B (it) * 1985-11-15 1987-12-30 Armco Spa Scambiatore termico in particolare evaporatore e metodo per la sua fabbricazione
US4690669A (en) * 1985-11-27 1987-09-01 E. I. Du Pont De Nemours And Company Refrigerated centrifuge having a removable bowl
JPH0225045U (fr) * 1988-07-29 1990-02-19
US5504007A (en) * 1989-05-19 1996-04-02 Becton, Dickinson And Company Rapid thermal cycle apparatus
GB9702473D0 (en) 1997-02-07 1997-03-26 Junair Spraybooths Ltd Spraybooth
IT1291271B1 (it) * 1997-02-10 1998-12-30 Raco Spa Metodo per la realizzazione di evaporatore per impianti di refrigerazione e rispettivo evaporatore od apparato che lo
JP2000015142A (ja) * 1998-07-01 2000-01-18 Tomy Seiko:Kk 遠心分離機
JP4611750B2 (ja) * 2002-12-20 2011-01-12 コーニング インコーポレイテッド キャピラリー・アッセイ・デバイスおよび方法
KR20040069476A (ko) * 2003-01-29 2004-08-06 엘지전자 주식회사 직냉식 냉장고용 열교환기
DE202004014916U1 (de) * 2004-09-24 2004-12-30 Tall & Stout Industrial Corp., Banchiau Innentank-Konstruktion eines Trinkwasserspenders
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Publication number Priority date Publication date Assignee Title
US5477704A (en) 1992-12-11 1995-12-26 Beckman Instruments, Inc. Refrigerant cooling assembly for centrifuges

Also Published As

Publication number Publication date
EP2199713A3 (fr) 2012-05-02
US8845967B2 (en) 2014-09-30
PL2199713T3 (pl) 2019-03-29
US20100155037A1 (en) 2010-06-24
EP2199713B1 (fr) 2018-08-29
US20120264582A1 (en) 2012-10-18
DE102008064178A1 (de) 2010-07-01

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