EP2235244B1 - Procédé de fabrication d'un article textile comprenant un fil discontinu et article textile - Google Patents

Procédé de fabrication d'un article textile comprenant un fil discontinu et article textile Download PDF

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Publication number
EP2235244B1
EP2235244B1 EP09700898A EP09700898A EP2235244B1 EP 2235244 B1 EP2235244 B1 EP 2235244B1 EP 09700898 A EP09700898 A EP 09700898A EP 09700898 A EP09700898 A EP 09700898A EP 2235244 B1 EP2235244 B1 EP 2235244B1
Authority
EP
European Patent Office
Prior art keywords
staple fibers
staple
range
shrinkage
fiber yarn
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Not-in-force
Application number
EP09700898A
Other languages
German (de)
English (en)
Other versions
EP2235244A1 (fr
Inventor
Regine Maria Zumloh-Nebe
Christoph Jörg HAHN
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Teijin Aramid GmbH
Original Assignee
Teijin Aramid GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Teijin Aramid GmbH filed Critical Teijin Aramid GmbH
Priority to EP09700898A priority Critical patent/EP2235244B1/fr
Publication of EP2235244A1 publication Critical patent/EP2235244A1/fr
Application granted granted Critical
Publication of EP2235244B1 publication Critical patent/EP2235244B1/fr
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04—Blended or other yarns or threads containing components made from different materials
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/44—Yarns or threads characterised by the purpose for which they are designed
    • D02G3/442—Cut or abrasion resistant yarns or threads
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D19/00—Gloves
    • A41D19/015—Protective gloves
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04—Blended or other yarns or threads containing components made from different materials
    • D02G3/045—Blended or other yarns or threads containing components made from different materials all components being made from artificial or synthetic material
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04—Blended or other yarns or threads containing components made from different materials
    • D02G3/047—Blended or other yarns or threads containing components made from different materials including aramid fibres
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D10B2321/02—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • D10B2331/021—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides aromatic polyamides, e.g. aramides
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/06—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyethers
    • D10B2331/061—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyethers polyetherketones, polyetheretherketones, e.g. PEEK
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/10—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyurethanes

Definitions

  • the present invention relates to a method for producing a textile article and a textile article.
  • Staple fiber yarn textile articles made from aramid staple fibers are made EP-B 1 099 088 known.
  • Such articles, such as gloves, have high abrasion resistance and high cut resistance, but are correspondingly expensive because of the high quality aramid fibers processed therein.
  • a method according to the preamble of claim 1 is made WO-A-02/052077 known.
  • the document teaches that in a staple fiber yarn up to 40% by weight of the high-cut pile fibers can be replaced by synthetic staple fibers.
  • EP-A-1 862 572 Teaches a weight ratio of g5: 5 to 50:50 without any statements about abrasion resistance.
  • the present invention has the object to provide textile articles available that can be offered cheaper, but without losing abrasion resistance.
  • the textile article according to the invention has an abrasion resistance which is similar to or even higher than that of a suitably produced textile article whose staple fiber yarn consists exclusively of first staple fibers
  • the article according to the invention in view of its content of first staple fibers of high-tenacity filaments, due to the Ratio A: B in the range of 5:95 to 45:55 is always smaller than the proportion of the second staple fibers, yet has a cut resistance, which is surprising in comparison with a comparative article made exclusively from the first staple fibers of high strength filaments is low.
  • the textile article produced by this method belongs to the present invention.
  • the present invention makes textile articles accessible for the first time, which - because the second staple fibers contained in the article according to the invention are significantly cheaper than the first staple fibers - can be offered correspondingly more favorably.
  • the staple fiber yarn comprises at least one twine, wherein the twine comprises a mixture of first and second staple fibers.
  • twine comprises a mixture of first and second staple fibers.
  • the staple fiber yarn comprises at least one twine comprising first staple fibers made from high tenacity filaments having a tenacity of at least 80 cN / tex. Below a tear strength of 80 cN / tex, the cut resistance of the textile article made of the staple fiber yarn is too low.
  • the first staple fibers of the staple fiber yarn are made of high tenacity filaments having a tenacity of at least 120 cN / tex, more preferably at least 150 cN / tex, and most preferably 190 cN / tex.
  • the first staple fibers can be made by tearing corresponding high strength filaments, resulting in first staple fibers having a length distribution due to the tearing process.
  • the first staple fibers may be made by cutting corresponding high strength filaments, resulting in first staple fibers having a uniform length, preferably in the range of 10 mm to 200 mm, and more preferably in the range of 30 to 60 mm.
  • the first staple fibers are selected from at least one of the groups comprising aramid staple fibers, polybenzoxazole staple fibers, and polybenzothiazole staple fibers. In the context of the present invention, this means that the first staple fibers are selected either from aramid staple fibers only or only from polybenzoxazole staple fibers or only from polybenzothiazole staple fibers.
  • the first staple fibers can also consist of a mixture of aramid staple fibers with polybenzoxazole and / or polybenzothiazole staple fibers.
  • aramid staple fibers mean staple fibers made from aramids, i. are prepared from aromatic polyamides wherein at least 85% of the amide (-CO-NH-) bonds are bonded directly to two aromatic rings.
  • An aromatic polyamide particularly preferred for the present invention is poly-para-phenylene terephthalamide, a homopolymer resulting from the mol: mol polymerization of para-phenylenediamine and terephthalic acid dichloride.
  • copolymers which, in addition to para-phenylenediamine and terephthalic acid dichloride, contain small amounts of other diamines and / or other dicarboxylic acid chlorides incorporated in the polymer chain.
  • the other diamines and / or other dicarboxylic acid chlorides may be incorporated in the polymer chain in a proportion of up to 10 mol%.
  • first staple fibers used therein e.g. also the aramid staple fibers, as good as new staple fibers.
  • first staple fibers e.g. also aramid staple fibers, from up to 100 wt .-% recycled staple fibers are used.
  • polybenzoxazole staple fibers and polybenzothiazole staple fibers mean staple fibers made from polybenzoxazoles or from polybenzothiazoles, ie from polymers having the structural units shown below, wherein the aromatic groups attached to the nitrogen are preferably carbocyclic, as shown in the structural units. However, said groups may also be heterocyclic. Further, the nitrogen-bonded aromatic groups are preferable six-membered rings as shown in the structural units. However, said groups may also be formed as fused or unfused polycyclic systems.
  • the staple fiber yarn has first staple fibers with a titre in the range from 0.1 dtex to 10 dtex, more preferably in the range from 0.5 dtex to 5 dtex and in particular in the range from 0.5 dtex to 2.5 dtex ,
  • the staple fiber yarn has second staple fibers which have a shrinkage in the range of 5% to 50%. Below a shrinkage of 5%, the cut resistance of the textile article produced from the staple fiber yarn according to the invention is too low. Above a shrinkage of 50%, the shrunken textile article is too stiff and offers too little wearing comfort.
  • the second staple fibers have a shrinkage in the range of 7% to 40%, more preferably in the range of 8% to 35% and most preferably in the range of 9% to 30%.
  • the second staple fibers can be produced by tearing corresponding filaments with the shrinkage required according to the invention, resulting in second staple fibers having a length distribution caused by the tearing process.
  • the second staple fibers can be made by cutting corresponding filaments with the shrinkage required by the invention, resulting in second staple fibers having a uniform length, preferably in the range of 10 mm to 200 mm, and more preferably in the range of 30 to 60 mm.
  • the second staple fibers are staple thermoplastic fibers, which are preferably selected from at least one of the groups comprising polyacrylonitrile staple fibers and polyetheretherketone staple fibers.
  • the second staple fibers in a further preferred embodiment may consist of a mixture of polyacrylonitrile staple fibers with polyetheretherketone staple fibers, with an increasing proportion of polyetheretherketone staple fibers the heat resistance of the textile article according to the invention produced from the staple fiber yarn according to the invention increases.
  • polyacrylonitrile staple fibers mean staple fibers made from a polymer containing at least 85% by weight of acrylonitrile units the remainder being up to 15% by weight of ethylenic monomers copolymerizable individually or in admixture with acrylonitrile, such as esters of acrylic acid and methacrylic acid (methyl acrylate, ethyl acrylate, methyl methacrylate, ethyl methacrylate, etc.), vinyl acetate, Vinyl chloride, vinylidene chloride, acrylamide, methacrylamide or methacrylonitrile.
  • esters of acrylic acid and methacrylic acid methyl acrylate, ethyl acrylate, methyl methacrylate, ethyl methacrylate, etc.
  • vinyl acetate Vinyl chloride, vinylidene chloride, acrylamide, methacrylamide or methacrylonitrile.
  • polyetheretherketone staple fibers mean staple fibers made from a polymer in which phenyl radicals are linked via ether or keto groups in a sequence in which two ether linkages are followed by a keto linkage.
  • the staple fiber yarn has second staple fibers with a titre in the range from 0.1 dtex to 20 dtex, more preferably in the range from 0.5 dtex to 5 dtex and in particular in the range from 0.9 dtex to 2.5 dtex ,
  • the staple fiber yarn comprises at least one thread, preferably two or three or four threads.
  • A: B is in the range of 10:90 to 40:60.
  • the shrinkage is carried out by heating the staple fiber yarn at a shrinkage temperature T s which is above the glass transition temperature T g and below the melting temperature T m of the material constituting the second staple fibers.
  • the shrinkage can be carried out in a dry, steam-saturated or wet atmosphere, ie as hot air, Stattdampf- or cooking shrinkage.
  • the Staple yarn during shrinkage are on a coil, which is located in one of the aforementioned atmospheres.
  • the staple fiber yarn may be unwound from the spool and passed through one of the stated atmospheres.
  • the textile article according to the invention containing the staple fiber yarn is introduced into one of the said atmospheres and the shrinkage of the staple fiber yarn is initiated in the temperature range mentioned.
  • the shrinkage in the process according to the invention for the production of a textile article is carried out at a shrinkage temperature T s which lies in the range T g ⁇ T s ⁇ T m .
  • T s extends in a range from 100 ° C. to 150 ° C., in particular in a range from 110 ° C. to 140 ° C., for which reason the ranges mentioned in the process according to the invention preferred or particularly preferred.
  • a shrinkage time t s in the range from 20 seconds to 700 seconds, in particular from 30 seconds, is sufficient for a large number of the materials forming the second staple fibers, in particular for thermoplastic polymers 240 seconds and most preferably from 50 seconds to 180 seconds.
  • the use of the staple fiber yarn in the process according to the invention for producing a textile article may be in the form of any of the known processes by which textile articles are produced from staple fiber yarns, but preferably by knitting, knitting, braiding or weaving.
  • the knitting is preferably effected with a needle spacing of 7 gg to 18 gg (1 gg means 1 needle per 2.54 cm) and a row density in the range of 3 per cm to 12 per cm and in sticks in the range of 3 per cm to 12 per cm.
  • the staple fiber yarn may be made of a single twist, e.g. a knitting, knitting, braiding or weaving device are supplied.
  • a staple fiber yarn of two or three or four plys may also be fed to one of said devices, wherein the two, three or four plys may be fed in parallel to the device.
  • the two, three or four threads may first be twisted around each other and then fed to the apparatus which manufactures the textile article of the invention.
  • the object underlying the present invention is finally achieved by a textile article which has been produced by the process according to the invention.
  • the textile article according to the invention is a glove, an apron, a trouser, a jacket, a cuff, a hose, a hose wrap or a vandalism resistant article.
  • first staple fibers 50 mm p-aramid staple fibers (Type 1072 from Teijin Aramid) made by cutting p-aramid filament yarn (Type 1012 from Teijin Aramid) with a filament titer of 1.7 dtex are provided.
  • polyacrylonitrile staple fibers As the second staple fibers, 50 mm-long polyacrylonitrile staple fibers (type SHK1.3 / 50 from Dyvertex) made by cutting polyacrylonitrile filament yarn having a filament titer of 1.3 dtex are provided.
  • the polyacrylonitrile staple fibers have a shrinkage of 19.1% measured according to DIN 53866, part 3 (March 1979) with a shrinking time of 15 minutes, a shrinking temperature of 190 ° C. and a preloading of 240 mg.
  • a staple fiber yarn is made, which consists of a thread with Nm 28/1 (36 tex). Four of these threads are twisted around each other, fed to a knitting machine and knitted into a glove, the needle spacing being 7 gg (7 needles per 2.54 cm), the stitch density of the glove before shrinking in row 3.5 per cm and in sticks 3, 5 per cm.
  • Example 1b is carried out as Example 1a with the difference that in the manufacture of the glove a yarn with Nm 28/1 (36 tex) is fed to the knitting machine, the needle spacing is 13 gg (13 needles per 2.54 cm) and the stitch density of the glove before shrinking in row 8 per cm and in sticks 6 per cm.
  • 50 mm p-aramid staple fibers (type 1072 from Teijin Aramid) are prepared by cutting p-aramid filament yarn (type 1012 from Teijin Aramid) with a filament titer of 1.7 dtex.
  • Staple fibers are made of a staple fiber yarn, which consists of a twisted yarn with Nm 28/1 (36 dtex). Four of these threads are twisted around each other, fed into a knitting machine and knitted into a glove, the needle spacing being 7gg (7 needles per 2.54 cm), the mesh density in the row 3.5 per cm and in sticks 3.5 per cm.
  • Comparative Example C2 is carried out as Comparative Example C1, with the difference that a yarn is fed to the knitting machine, the needle spacing being 13 gg and the mesh density in row 8 per cm and in bars 6 per cm.
  • a / B means the weight ratio of p-aramid staple fibers: polyacrylonitrile staple fibers in the staple fiber yarn of the invention, gg the needle pitch of the knitting machine, NESI uncut or shrunk the lowest single cut index, ie, the cut resistance before or after shrinking and TZ unhardened or shrunk as the number of revolutions Abrasion resistance before or after shrinking specified until the formation of the hole.
  • Example 1a shows that the glove according to the invention, which was produced and shrunk with the staple fiber yarn according to the invention, has only 11% lower cut resistance and 81% higher abrasion resistance than the comparison glove, although in the staple fiber yarn of the invention Glove 70% of the p-aramid staple fibers were replaced by polyacrylonitrile staple fibers.
  • Example 1b shows that the glove according to the invention, which was produced and shrunk with the staple fiber yarn according to the invention, although a 33% lower cut resistance but has virtually the same abrasion resistance as the comparison glove, although 70% of the p-aramid staple fibers were replaced by polyacrylonitrile staple fibers in the staple fiber yarn of the glove of the present invention.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Knitting Of Fabric (AREA)
  • Artificial Filaments (AREA)
  • Woven Fabrics (AREA)

Claims (17)

  1. Procédé de fabrication d'un article textile, avec utilisation d'un fil de fibres coupées comportant au moins un fil retors, le fil retors comprenant un mélange de premières fibres coupées et de deuxièmes fibres coupées, les premières fibres coupées étant fabriquées à partir de filaments très résistants qui présentent une résistance à la rupture d'au moins 80 cN/tex, les deuxièmes fibres coupées présentant une rétraction se situant dans la plage de 5 % à 50 %,
    le procédé comportant une opération de rétraction et la rétraction
    - soit étant exécutée sur le fil de fibres coupées, après quoi l'article est fabriqué à partir du fil de fibres coupées rétractées,
    - soit étant exécutée sur l'article renfermant le fil de fibres coupées non rétractées, caractérisé en ce que le rapport de poids entre les premières fibres coupées et les deuxièmes fibres coupées dans le fil retors A au moins unique est de A/B, et A/B se situant dans la plage comprise entre 5/95 et 45/55.
  2. Procédé selon la revendication 1 caractérisé en ce que les premières fibres coupées sont fabriquées à partir de filaments très résistants qui présentent une résistance à la rupture d'au moins 120 cN/tex.
  3. Procédé selon la revendication 1 ou 2 caractérisé en ce que les premières fibres coupées sont choisies dans au moins un des groupes comprenant les fibres coupées d'aramide, les fibres coupées de polybenzoazol et les fibres coupées de polybenzothioazol.
  4. Procédé selon une ou plusieurs des revendications 1 à 3, caractérisé en ce que les premières fibres coupées ont un titre se situant dans la plage comprise entre 0,1 dtex et 10 dtex.
  5. Procédé selon une ou plusieurs des revendications 1 à 4, caractérisé en ce que les deuxièmes fibres coupées présentent une rétraction qui se situe dans la plage comprise entre 7 % et 40 %.
  6. Procédé selon une ou plusieurs des revendications 1 à 5, caractérisé en ce que les deuxièmes fibres coupées sont des fibres coupées thermoplastiques.
  7. Procédé selon la revendication 6 caractérisé en ce que les fibres coupées thermoplastiques sont choisies dans au moins un des groupes comprenant les fibres coupées de polyacrylonitrile et les fibres coupées de polyétheréthercétone.
  8. Procédé selon une ou plusieurs des revendications 4 à 7, caractérisé en ce que les deuxièmes fibres coupées ont un titre qui se situe dans la plage comprise entre 0,1 dtex et 20 dtex.
  9. Procédé selon une ou plusieurs des revendications 1 à 8, caractérisé en ce que le fil de fibres coupées présente deux, trois, ou quatre fils retors.
  10. Procédé selon la revendication 9 caractérisé en ce que chacun des fils retors a un titre se situant dans la plage comprise entre 100 dtex et 10 000 dtex.
  11. Procédé selon une ou plusieurs des revendications 1 à 10, caractérisé en ce que le rapport de poids A/B entre les premières fibres coupées et les deuxièmes fibres coupées se situe dans la plage comprise entre 10/90 et 40/60.
  12. Procédé selon une ou plusieurs des revendications 1 à 11, caractérisé en ce que la rétraction est exécutée à une température de rétraction ts qui se situe dans la plage comprise entre 100°C et 150°C.
  13. Procédé selon une ou plusieurs des revendications 1 à 12, caractérisé en ce que la rétraction est exécutée pendant un temps de rétraction ts compris entre 20 secondes et 700 secondes.
  14. Procédé selon une ou plusieurs des revendications 1 à 13, caractérisé en ce que l'on utilise une technique de tricotage à mailles cueillies ou à mailles jetées, une technique de tressage ou une technique de tissage.
  15. Procédé selon la revendication 14 caractérisé en ce que le tricotage est effectué avec un écart d'aiguilles compris entre 7 gg et 18 gg et une densité de mailles dans le sens des rangées se situant dans la plage comprise entre 3 par cm et 12 par cm et avec une densité de mailles dans le sens des colonnes se situant dans la plage comprise entre 3 par cm et 12 par cm.
  16. Article textile fabriqué selon le procédé d'une ou de plusieurs des revendications 1 à 15.
  17. Article textile selon la revendication 16 caractérisé en ce que l'article est un gant, un tablier, un pantalon, une veste, une manchette, un tube, une enveloppe de tube ou un article résistant au vandalisme.
EP09700898A 2008-01-10 2009-01-05 Procédé de fabrication d'un article textile comprenant un fil discontinu et article textile Not-in-force EP2235244B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP09700898A EP2235244B1 (fr) 2008-01-10 2009-01-05 Procédé de fabrication d'un article textile comprenant un fil discontinu et article textile

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP08000338 2008-01-10
PCT/EP2009/050021 WO2009087123A1 (fr) 2008-01-10 2009-01-05 Fil discontinu, procédé de fabrication d'un article textile et article textile
EP09700898A EP2235244B1 (fr) 2008-01-10 2009-01-05 Procédé de fabrication d'un article textile comprenant un fil discontinu et article textile

Publications (2)

Publication Number Publication Date
EP2235244A1 EP2235244A1 (fr) 2010-10-06
EP2235244B1 true EP2235244B1 (fr) 2012-09-26

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EP09700898A Not-in-force EP2235244B1 (fr) 2008-01-10 2009-01-05 Procédé de fabrication d'un article textile comprenant un fil discontinu et article textile

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US (1) US8297081B2 (fr)
EP (1) EP2235244B1 (fr)
JP (1) JP5366225B2 (fr)
KR (1) KR20100106578A (fr)
CN (1) CN101918629B (fr)
ES (1) ES2396122T3 (fr)
WO (1) WO2009087123A1 (fr)

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PL2707527T3 (pl) * 2011-05-10 2019-01-31 Dsm Ip Assets B.V. Przędza, sposób wytwarzania przędzy i wytwory zawierające przędzę
US20140113122A1 (en) * 2012-10-19 2014-04-24 Springfield Llc Woven Flame-Resistant Garment Fabric, and Garment Made Therefrom
CN104047083B (zh) * 2013-03-15 2018-03-27 东丽纤维研究所（中国）有限公司 一种含尼龙的短纤纱线及其生产方法和用途
CN103225155B (zh) * 2013-04-16 2014-11-26 南通纺织职业技术学院 丙纶短纤矿物过滤帆布
CN106757598B (zh) * 2017-01-22 2019-08-02 吉林大学 一种聚醚醚酮短纤纱及其制备方法
FR3093668B1 (fr) * 2019-03-11 2021-04-02 Saint Gobain Performance Plastics France Procede de preparation d’un produit en matiere polymerique
US12320042B2 (en) 2019-09-04 2025-06-03 Milliken & Company Flame-resistant fabric
US20210324548A1 (en) * 2020-04-17 2021-10-21 Universal Fibers, Inc. Sharp color effect yarn
US11761124B1 (en) 2021-09-09 2023-09-19 Milliken & Company Elastic flame-resistant fabric

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US6829881B1 (en) 1998-08-07 2004-12-14 Teijin Twaron Gmbh Cut-resistant articles of aramid microfilaments
US6602600B2 (en) 2000-12-22 2003-08-05 E. I. Du Pont De Nemours And Company Yarn and fabric having improved abrasion resistance
EP1552045B1 (fr) * 2002-10-10 2006-08-30 DSM IP Assets B.V. Procede de fabrication d'un produit de type monofilament
US20050025963A1 (en) * 2003-07-28 2005-02-03 Reiyao Zhu Flame retardant fiber blends comprising modacrylic fibers and fabrics and garments made therefrom
US7065950B2 (en) * 2004-03-18 2006-06-27 E. I. Du Pont De Nemours And Company Modacrylic/aramid fiber blends for arc and flame protection
EP1862572A1 (fr) * 2006-06-02 2007-12-05 DSMIP Assets B.V. Fil résistant à la coupure

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ES2396122T3 (es) 2013-02-19
CN101918629A (zh) 2010-12-15
JP5366225B2 (ja) 2013-12-11
US8297081B2 (en) 2012-10-30
CN101918629B (zh) 2013-04-10
WO2009087123A1 (fr) 2009-07-16
EP2235244A1 (fr) 2010-10-06
JP2011509357A (ja) 2011-03-24
US20100281923A1 (en) 2010-11-11
KR20100106578A (ko) 2010-10-01

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