EP2352575A1 - Procédé de purification d'un gaz de fumée d'une installation métallurgique, et dispositif de purification des fumées - Google Patents
Procédé de purification d'un gaz de fumée d'une installation métallurgique, et dispositif de purification des fuméesInfo
- Publication number
- EP2352575A1 EP2352575A1 EP09744067A EP09744067A EP2352575A1 EP 2352575 A1 EP2352575 A1 EP 2352575A1 EP 09744067 A EP09744067 A EP 09744067A EP 09744067 A EP09744067 A EP 09744067A EP 2352575 A1 EP2352575 A1 EP 2352575A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- flue gas
- gas
- scrubber
- metallurgical plant
- dust collector
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title claims abstract description 63
- 239000003546 flue gas Substances 0.000 title claims abstract description 62
- 238000000034 method Methods 0.000 title claims abstract description 29
- 238000005201 scrubbing Methods 0.000 title abstract description 9
- 239000007789 gas Substances 0.000 claims abstract description 82
- 239000000428 dust Substances 0.000 claims abstract description 38
- 239000007788 liquid Substances 0.000 claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000002245 particle Substances 0.000 claims abstract description 13
- 238000004140 cleaning Methods 0.000 claims description 23
- 239000012719 wet electrostatic precipitator Substances 0.000 claims description 16
- 238000001816 cooling Methods 0.000 claims description 6
- 238000000746 purification Methods 0.000 claims description 6
- 238000011084 recovery Methods 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- 238000011010 flushing procedure Methods 0.000 claims 1
- 238000001914 filtration Methods 0.000 abstract 1
- 238000005406 washing Methods 0.000 description 9
- 239000012717 electrostatic precipitator Substances 0.000 description 5
- 229910000831 Steel Inorganic materials 0.000 description 4
- 230000003750 conditioning effect Effects 0.000 description 4
- 239000012718 dry electrostatic precipitator Substances 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- 230000001143 conditioned effect Effects 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 210000004602 germ cell Anatomy 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000009420 retrofitting Methods 0.000 description 1
- 238000010079 rubber tapping Methods 0.000 description 1
- 238000005549 size reduction Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000011882 ultra-fine particle Substances 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J15/00—Arrangements of devices for treating smoke or fumes
- F23J15/06—Arrangements of devices for treating smoke or fumes of coolers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D47/00—Separating dispersed particles from gases, air or vapours by liquid as separating agent
- B01D47/02—Separating dispersed particles from gases, air or vapours by liquid as separating agent by passing the gas or air or vapour over or through a liquid bath
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C—MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C3/00—Separating dispersed particles from gases or vapour, e.g. air, by electrostatic effect
- B03C3/017—Combinations of electrostatic separation with other processes, not otherwise provided for
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C—MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C3/00—Separating dispersed particles from gases or vapour, e.g. air, by electrostatic effect
- B03C3/02—Plant or installations having external electricity supply
- B03C3/16—Plant or installations having external electricity supply wet type
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J15/00—Arrangements of devices for treating smoke or fumes
- F23J15/02—Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
- F23J15/022—Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material for removing solid particulate material from the gasflow
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J15/00—Arrangements of devices for treating smoke or fumes
- F23J15/02—Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
- F23J15/022—Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material for removing solid particulate material from the gasflow
- F23J15/025—Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material for removing solid particulate material from the gasflow using filters
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J2217/00—Intercepting solids
- F23J2217/10—Intercepting solids by filters
- F23J2217/102—Intercepting solids by filters electrostatic
Definitions
- the invention relates to a method for purifying a flue gas of a metallurgical plant. Furthermore, the invention relates to a flue gas purification device.
- the flue gas produced in a metallurgical plant must be sufficiently dedusted before being discharged to the environment in order to avoid environmental pollution. It is known to use wet scrubbers (for example DE 1176099 B) for which various types are possible. With such gas scrubbers can be done dedusting of the flue gas.
- the BAUMCO scrubber is, as one skilled in the art knows, a typical representative of a wet dust removal system, as has been used, for example, in oxygen / air converters for decades.
- the purification of the exhaust gas is carried out in two stages, wherein in a first step in a so-called quencher of the coarse dust is precipitated by spraying water into the gas stream and in a second step, the fine cleaning by an eddy current mixture of gas and scrubber water in a special designed scrubber unit is performed.
- annular-gap scrubbers which are also known to the expert for a long time in the flue gas dedusting of metallurgical plants use, usually flows through hot water together with the hot gas in the co-current tube and deprives the hot gas sensible heat, whereby a large amount of steam is formed and the gas at least approximately until is enriched to its saturation limit with water vapor.
- entrained by the gas ultrafine particles are wetted to a large extent and serve in a subsequent stages in the stages of condensation of water as germ cells for drop formation.
- the particles are then eliminated together with the drops in the condensate.
- electrostatic precipitators are available in two types: In dry electrostatic precipitators, the high-pressure gas is cooled and conditioned in a conditioning tower by means of evaporation. The dust is then separated electrostatically. The separated dust falls dry in this process variant. The cleaning of the electrodes required in the separator takes place by mechanical tapping.
- the purified flue gas if it has a sufficiently high chemical calorific value, can be absorbed for further use: in the case of converter steelworks, a dry electrostatic filter is used, this is referred to as so-called e.g. Lurgi-Thyssen steel gas process.
- a dry electrostatic filter in this case, dry electrostatic precipitators in round design are used for emission control.
- this type of electric filter With this type of electric filter, the low amount of clean gas dust required in the useful gas is easily achieved, whereby this steel gas process offers decisive advantages over conventional scrubbing systems, in particular a lower energy requirement, a dry dust separation and low maintenance costs.
- wet electrostatic precipitators for flue gas cleaning.
- the exhaust gas is cooled in a first step to saturation temperature in a conditioning tower and then also electrostatically deposited.
- the electrodes are cleaned by rinsing.
- the present invention is therefore based on the object of developing a method of the type mentioned above and to provide a Rauchgastherapiesvor- direction, with which it is possible or easier to comply with strict limits for the dedusting of a flue gas. This should be possible in an energetically favorable mode of operation. In addition, the investment level should be kept as low as possible and the maintenance costs reduced by a simple design.
- the solution of this problem by the invention is characterized by the following process steps: a) introducing the flue gas into a gas scrubber, wherein the flue gas stream in the scrubber with a liquid, in particular with water, is brought into contact. By gravity and wetting with water dust particles are separated from the gas stream and rinsed with the wash water. b) feeding the flue gas pre-cleaned in the gas scrubber into a wet
- Electrostatic precipitator wherein the flue gas stream is further removed by electrostatic separation of particles from the flue gas.
- the flue gas is preferably passed directly from the gas scrubber into the electric dust collector.
- the flue gas can be cooled on its way from the metallurgical plant to the gas scrubber. It can be passed behind the electric dust collector in a fireplace, or if energetically usable gas extraction are supplied.
- the flue gas is preferably cooled in the gas scrubber.
- the cooling of the flue gas in the gas scrubber is preferably carried out to saturation temperature.
- the flue gas is cleaned in the gas scrubber so that it with a dust amount, e.g. less than 1.0 g / Nm3 to ensure a permanently satisfactory performance of the wet electrostatic precipitator.
- the electric dust collector has at least one collecting electrode, wherein the cleaning of the at least one collecting electrode preferably takes place by rinsing with a liquid, in particular with water.
- the melt metallurgical plant is preferably a converter, a blast furnace or an electric furnace.
- the proposed flue gas purification device of a metallurgical plant comprises a gas scrubber connected via a connecting line to the metallurgical plant and a wet electrostatic precipitator connected to the gas scrubber via a further connecting line.
- the connecting line between the metallurgical plant and the gas scrubber can be formed at least in sections as a cooling chimney. Behind the wet electrostatic filter, a chimney with a flaring device can be arranged. In a connecting line between the wet electrostatic precipitator and the fireplace can be arranged a fan. If a gas recovery is desired, a switching station can be arranged between fan and chimney.
- the basic idea of the invention therefore depends on the combination of two methods known per se.
- a gas scrubbing operation is coupled with an electrostatic dust removal operation. Both techniques are strengthened by the combination, i. the advantages of the respective procedures are used better and the respective weaknesses are no longer significant.
- the scrubber is no longer used for dedusting to clean gas dust content, but the pre-cleaning and conditioning of the exhaust stream. These are favorable conditions for trouble-free and efficient operation of the subsequent wet electrostatic precipitator.
- the gas scrubber thus only reduces the dust content in the flue gas to such an extent that reliable operation of the downstream electric dust collector can be ensured.
- the gas scrubber can therefore be operated with less pressure loss. Overall, this results in a lower energy consumption for the fan. Thus, the operating costs can be reduced.
- the following wet electrostatic filter is designed in its construction and operating mode to the pre-cleaned and conditioned gas stream. As a result, it can be built smaller than conventional wet electrostatic precipitators. Its installations and controls are optimized according to the new size.
- the electric dust collector takes over the cleaning of the flue gas to the final dust content of the clean gas.
- a further advantage is the simple cleaning of the electrodes of the wet electrostatic precipitator by rinsing.
- the service life of the electrodes in the electrostatic precipitator is achieved by pre-cleaning the gas in the scrubber. increased.
- the cleaning of the electrodes in the wet electrostatic precipitator is considerably easier than in the dry electrostatic precipitator. Smoldering fires are excluded in the wet electrostatic precipitator. The risk of explosion is reduced in the water-saturated flue gas.
- the size reduction of the electric dust collector which is made possible by the reduced gas temperature in the pre-cleaning, results in advantages in terms of investment volume.
- the preferred application of the proposed idea is the gas cleaning of steel works, in particular the cleaning of the exhaust gases of metallurgical vessels such as converters and electric furnace. This applies to the production of standard steels and stainless steels.
- FIG. 1 An embodiment of the invention is shown.
- the single figure shows schematically the structure of a flue gas cleaning device for a metallurgical plant.
- the illustrated flue gas cleaning device serves to purify the flue gas which originates from a metallurgical plant 1.
- the flue gas is conveyed via a connecting line 5 in the form of a chimney of the cleaning fed direction.
- the connecting line 5 is already designed as a cooling section for the flue gas to be cleaned.
- the pre-cooled gas is pre-cleaned in the gas scrubber 2, with a pure dust content of preferably less than 1 g / Nm3 (grams per standard cubic meter) is sought.
- the flue gas cleaning device consists essentially of two directly interconnected filter systems, namely a gas scrubber 2, which is connected via a connecting line 6 with an electric dust collector 3.
- the electric dust collector 3 is designed as a wet electrostatic precipitator.
- the water management 10 supplies the system with the supply and discharge of the water or washing liquid.
- Both the gas scrubber 2 and the wet electrostatic filter 3 operate in a known manner.
- the gas stream to be cleaned is brought into contact with a liquid stream to receive components of the gas stream in the liquid.
- the passing components of the gas stream may be solid, liquid or gaseous constituents.
- washing liquid pure solvents such as water but also suspensions can be used.
- the gas scrubber often has six areas: In the bottom of the gas scrubber, the scrubbing liquid is collected and withdrawn in the gas inlet, the gas is given and installed by a uniform load on the interior, in the contact section, the leaching of the gas stream in the constituents takes place in the washing liquid is added to the washing liquid and distributed, are entrained in the drip ne components of the washing liquid deposited and leaving the purified gas stream in the outlet, the gas scrubber.
- the scrubbing liquid is sprayed through the gas at high speed and in small drops.
- the gas must pass through the scrubbing liquid like through a curtain. If the drops of the washing liquid are fast enough, the particles in the gas stream can no longer escape the drop and fuse with them to larger drops. These larger drops can then be separated with the drip.
- the conditioning tower otherwise required for dry electrostatic precipitators is eliminated.
- the electric dust collector 3 can be made relatively small.
- the wet electrostatic precipitator 3 is equally a plant for the separation of particles from gases, which is based on the electrostatic principle.
- the separation in the electrostatic precipitator usually takes place in five phases: First, the generation of the electrical charges takes place, then the charging of the dust particles takes place in the electric field. Subsequently, the transport of the charged dust particles to the collecting electrode takes place. The dust particles then adhere to the collecting electrode. Finally, the cleaning of the dust layer from the electrodes is carried out by the washing liquid.
- the wet electrostatic filter can be made significantly smaller than would be the case if the upstream scrubber 2 were dispensed with. Furthermore, the wear of the electrodes is reduced by the abrasive dusts in that already precleaned gas is introduced.
- Another advantage of the proposed system in plants that are operated in batch mode - for example, a converter steelworks, is that during the process phase, in which hot dust-laden flue gas is produced, the Washing liquid is used for the gas scrubber. In the phase in which no flue gas is produced, the available washing liquid can be diverted into the wet electrostatic precipitator to clean the electrodes.
- the now purified gas stream is conducted via a connecting line 8 into a chimney 4, at the upper end of which a flaring device 7 is arranged.
- a gas switching station can be installed, which - depending on the process phase - diverts process gases with a chemical calorific value into a gas container.
- the transport of the gas is accomplished by a blower 9, which is integrated into the conduit 8. If gas recovery is desired, a switching station is arranged between the fan 9 and the chimney 4.
- the proposed hydro-hybrid filter system is therefore an advanced dedusting technology.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrostatic Separation (AREA)
- Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
Abstract
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102008052119 | 2008-10-20 | ||
| PCT/EP2009/007482 WO2010046071A1 (fr) | 2008-10-20 | 2009-10-19 | Procédé de purification d'un gaz de fumée d'une installation métallurgique, et dispositif de purification des fumées |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP2352575A1 true EP2352575A1 (fr) | 2011-08-10 |
Family
ID=41396006
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP09744067A Ceased EP2352575A1 (fr) | 2008-10-20 | 2009-10-19 | Procédé de purification d'un gaz de fumée d'une installation métallurgique, et dispositif de purification des fumées |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP2352575A1 (fr) |
| CN (1) | CN102202768A (fr) |
| TW (1) | TW201020020A (fr) |
| WO (1) | WO2010046071A1 (fr) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102580437A (zh) * | 2012-02-21 | 2012-07-18 | 中冶华天工程技术有限公司 | 转炉一次烟气双塔净化方法及转炉一次烟气净化塔 |
| CN103571984A (zh) * | 2012-08-01 | 2014-02-12 | 马西元 | 一种用原煤冶炼铁的方法 |
| DE102012224521A1 (de) | 2012-12-28 | 2014-07-03 | Sms Siemag Ag | Vorrichtung und Verfahren zum Reinigen von Rauchgas einer metallurgischen Anlage |
| DE102012224523A1 (de) | 2012-12-28 | 2014-07-03 | Sms Siemag Ag | Vorrichtung und Verfahren zum Reinigen von Rauchgas einer metallurgischen Anlage |
| CN104075335B (zh) * | 2014-07-22 | 2017-01-11 | 山东神华山大能源环境有限公司 | 一种利用耦合技术实现锅炉烟气达标排放的工艺及其装置 |
| DE102014223917A1 (de) | 2014-11-25 | 2016-05-25 | Sms Group Gmbh | Vorrichtung und Verfahren zum Reinigen von Rauchgas einer metallurgischen Anlage |
| KR101984814B1 (ko) * | 2017-08-31 | 2019-05-31 | 주식회사 에코에너젠 | Ipa를 포함하는 공정 배기 스트림의 처리 시스템 |
| AT16120U1 (de) * | 2018-01-19 | 2019-02-15 | Scheuch Gmbh | Vorrichtung zur Reinigung von mit Staub und organischen als auch anorganischen Verbindungen belasteten Abgasen aus der holzverarbeitenden Industrie |
| CN108837646A (zh) * | 2018-04-09 | 2018-11-20 | 张素平 | 一种空气净化装置 |
| CN108295588A (zh) * | 2018-04-10 | 2018-07-20 | 北京英华高科技有限公司 | 一种新型气体除尘净化设备 |
| CN109331601B (zh) * | 2018-12-04 | 2023-11-28 | 昊姆(上海)节能科技有限公司 | 热湿烟气脱白除尘装置及利用其的脱白除尘方法 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3820768A (en) * | 1971-07-19 | 1974-06-28 | Pennsylvania Engineering Corp | Steel conversion method and apparatus |
| US5980606A (en) * | 1996-03-22 | 1999-11-09 | Steel Technology Corporation | Method for reducing sulfuric content in the offgas of an iron smelting process |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004130213A (ja) * | 2002-10-10 | 2004-04-30 | Chiyoda Corp | 排ガス処理装置 |
| JP2004238236A (ja) * | 2003-02-05 | 2004-08-26 | Nippon Electric Glass Co Ltd | ガラス溶融方法およびガラス溶融設備 |
| JP3937356B1 (ja) * | 2006-03-29 | 2007-06-27 | 株式会社日立プラントテクノロジー | 排ガス処理方法および設備 |
| KR100817303B1 (ko) * | 2006-11-07 | 2008-03-27 | (주)플라즈마텍 | 혼산 배기 가스 처리 장치 및 방법 |
| JP2008202071A (ja) * | 2007-02-19 | 2008-09-04 | Nippon Steel Engineering Co Ltd | 高炉ガス清浄設備の操業方法 |
-
2009
- 2009-10-19 EP EP09744067A patent/EP2352575A1/fr not_active Ceased
- 2009-10-19 TW TW098135228A patent/TW201020020A/zh unknown
- 2009-10-19 WO PCT/EP2009/007482 patent/WO2010046071A1/fr not_active Ceased
- 2009-10-19 CN CN2009801423886A patent/CN102202768A/zh active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3820768A (en) * | 1971-07-19 | 1974-06-28 | Pennsylvania Engineering Corp | Steel conversion method and apparatus |
| US5980606A (en) * | 1996-03-22 | 1999-11-09 | Steel Technology Corporation | Method for reducing sulfuric content in the offgas of an iron smelting process |
Non-Patent Citations (1)
| Title |
|---|
| See also references of WO2010046071A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2010046071A1 (fr) | 2010-04-29 |
| TW201020020A (en) | 2010-06-01 |
| CN102202768A (zh) | 2011-09-28 |
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