EP2410978A2 - Compositions aqueuses pour le nettoyage des cheveux et de la peau - Google Patents

Compositions aqueuses pour le nettoyage des cheveux et de la peau

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Publication number
EP2410978A2
EP2410978A2 EP10706221A EP10706221A EP2410978A2 EP 2410978 A2 EP2410978 A2 EP 2410978A2 EP 10706221 A EP10706221 A EP 10706221A EP 10706221 A EP10706221 A EP 10706221A EP 2410978 A2 EP2410978 A2 EP 2410978A2
Authority
EP
European Patent Office
Prior art keywords
composition according
alkyl
composition
mass
alcohols
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP10706221A
Other languages
German (de)
English (en)
Inventor
Hans Henning Wenk
Sascha Herrwerth
Klaus Jenni
Christian Noethe
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Evonik Operations GmbH
Original Assignee
Evonik Goldschmidt GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Evonik Goldschmidt GmbH filed Critical Evonik Goldschmidt GmbH
Priority to EP10706221A priority Critical patent/EP2410978A2/fr
Publication of EP2410978A2 publication Critical patent/EP2410978A2/fr
Withdrawn legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2006—Monohydric alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2068—Ethers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures
    • A61K2800/596—Mixtures of surface active compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/123—Sulfonic acids or sulfuric acid esters; Salts thereof derived from carboxylic acids, e.g. sulfosuccinates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds

Definitions

  • Aqueous hair and skin cleansing compositions are provided.
  • the present invention relates to an aqueous composition containing at least one sulfosuccinate surfactant, at least one amphoteric surfactant, and at least one free, OH-functional compound, which correspond to the alcohol component of the esters of the sulfosuccinate surfactants used.
  • Such cleansing compositions should not only be mild to the skin and hair, but should also have other desirable properties, e.g. good storage stability and good foaming behavior. Also desirable are skin and hair conditioning properties.
  • EP 1771538 therefore proposes to use sulfosuccinate systems which, in addition to the sulfosuccinate surfactant and an amphoteric surfactant, have at least 4% by weight of sulfosuccinic acid or its salt.
  • sulfosuccinic acid or its salt By adding sulfosuccinic acid or its salt, an increase in viscosity during storage could be prevented.
  • sulfosuccinic acid or its salt is not suitable for adjusting the viscosity but only causes a once set viscosity does not change or only slowly after prolonged storage.
  • the presence of free acid leads to an increase in the electrolyte content, which adversely affects the surfactant system, for. For example, the solubility of non-polar substances is reduced.
  • EP 1771538 states that sulfosuccinic acid or its salts have only a marginal effect on the adjustment of the viscosity and thus can not be used as traditional viscosity regulators (thickeners).
  • Sulfosuccinate surfactant system by the addition of 1 to 20% by mass, based on the mass of sulfosuccinate surfactant, free, OH-functional compound, these being the Alcohol component of the esters of the sulfosuccinate surfactants used to obtain the sulfosuccinate surfactant, is easily adjustable.
  • the present invention therefore relates to aqueous compositions comprising:
  • Sulfosuccinat surfactants same, wherein the mass ratio of sulfosuccinate surfactant i) to free, OH-functional compound iii) of 100 to 1 to 100 to 20, preferably from 100 to 3 to 100 to 15, and preferably from 100 to 5 to 100 to 12 , as well as their use for the preparation of cleaning compositions or as cleaning compositions, in particular for the cleansing of skin and hair.
  • compositions which have corresponding compositions according to the invention.
  • compositions of the invention have the advantage that the viscosity of the composition is easily adjustable.
  • the addition of said OH-functional compound the effect of conventional thickeners can be improved and thus the required proportion of conventional thickening can be reduced.
  • Another advantage of the composition according to the invention is the improved foaming behavior, which is achieved by the presence of free, special OH-functional compounds.
  • the free OH-functional compounds are the same as the alcohol components of the esters of sulfosuccinate surfactants used, it should be understood that the free (not sulfosuccinic esterified) OH-functional compounds have a composition which the composition of the alcohol component of the esters of sulfosuccinates used substantially corresponds. If the alcohol component of the sulfosuccinates z. As a fatty alcohol ethoxylate with a certain molecular weight Alkoxylation distribution, the free OH functional compounds additionally present in the composition are also fatty alcohol ethoxylates having substantially the same molecular weight / alkoxylation distribution.
  • amphoteric surfactants of component ii) are not sulfosuccinate surfactants iii).
  • the free (non-sulfosuccinic acid), OH-functional compounds are not amphoteric surfactants ii) or sulfosuccinate surfactants i)
  • sulfosuccinate surfactant sulfosuccinic ester surfactant
  • OH-functional compounds these being the alcohol component the ester of sulfosuccinate surfactants used are the same, wherein the mass ratio of sulfosuccinate surfactant i) to free, OH-functional compound iii) from 100 to 1 to 100 to 20, preferably from 100 to 3 to 100 to 15 and preferably from 100 to 5 bis 100 to 12, contains.
  • the mass ratio of sulfosuccinate surfactant to amphoteric surfactant is preferably 4 to 1 to 1 to 4, preferably 3 to 1 to 1 to 3, and more preferably 2 to 1 to 1 to 2.
  • the sulfosuccinate surfactant is preferably a compound of formula (Ia) or (Ib) or a mixture thereof.
  • common Sulphosuccinates usually consist of a mixture of the two isomers, with the mass fraction of compounds of the formula (Ib) predominating.
  • R 1 hydrocarbon radical, preferably hydrocarbon radical having on average 1 to 25, preferably 8 to 22, preferably 10 to 14 carbon atoms.
  • R 1 is particularly preferably a branched or unbranched, preferably unbranched, alkyl radical, preferably having the stated number of carbon atoms,
  • M identical or different cations, preferably alkali metal ions, preferably potassium or sodium ions or ammonium ions or alkanolammonium ions, preferably mono-, di- or triethanolammonium ions.
  • the distribution of the building blocks marked by the index n can be determined by gas chromatography after hydrolysis (the values for n given in this section do not represent mean values but exact values).
  • Particularly preferred sulfosuccinate surfactant mixtures are those in which less than 2 mol% of compounds of the formula (Ia) or
  • the OH-functional compounds are preferably selected from the group comprising alcohols having 1 to 25, preferably 8 to 22, preferably 10 to 14 carbon atoms or polyether alcohols of these alcohols.
  • Preferred OH-functional compounds are mixtures containing less than 2 mol% of alcohols having 10 or fewer carbon atoms in the alkyl chain, 65 to 75 mol% of alcohols having 12 carbon atoms in the alkyl chain, 20 to 30 mol% of alcohols 14 carbon atoms in the alkyl chain and less than 2 mol% alcohols with 16 or more carbon atoms in the alkyl chain.
  • the OH-functional compounds preferably have polyether groups with an average of up to 10, preferably 0 to 10, preferably 1 to 6, particularly preferably 2.5 to 3.5 or 4.5 to 5.5, very particularly preferably about 3 alkoxy units, preferably ethylene oxide units, where n is an average
  • Compounds are in the form of mixtures in which the composition with respect to the alcohols with a different Number of blocks with the index n which corresponds to the preferred sulfosuccinate surfactant mixtures.
  • Preferred OH-functional compounds are mixtures of ethoxylated lauryl and myristyl alcohols, which preferably have in the polyether group on average from 1 to 6 ethylene oxide units.
  • Particularly preferred OH-functional compounds are selected from the group comprising lauryl alcohol, PEG-5-lauryl alcohol, a mixture of PEG-3-alkyl alcohols, PEG-3-lauryl alcohol or a mixture of PEG-3-alkyl alcohols
  • Alkyl chain from 65 to 75 mole% of alkyl alcohols having 12 carbon atoms in the alkyl chain, from 20 to 30 mole% of alkyl alcohols having 14 carbon atoms in the alkyl chain and less than 2 mole% of alkyl alcohols having 16 or more carbon atoms in the alkyl chain ,
  • the mixture of PEG-3 alkyl alcohols exclusively comprises PEG-3 alkyl alcohols based on alkyl alcohols having an even number of carbon atoms.
  • the OH-functional compounds can be different
  • the OH-functional compound passes by adding the same to the composition of the invention.
  • Composition has a value of 4 to 7, preferably 4.5 to 6 and particularly preferably 4.5 to 5.75.
  • a suitable acid buffer is used which has an acid buffer capacity of at least 0.01 mol of acid or H + ion, preferably at least 0.02 mol of acid and more preferably 0.03 mol of acid per 1 composition.
  • Suitable buffer systems are z. As those based on citric acid or polyacrylic acid, neutralized with sodium or ammonium hydroxide.
  • the present invention has a pH of 4 to 7, preferably 4.5 to 6, and more preferably> 4.5 to 5.75, and moreover preferably has an acid buffering capacity of 0.02 mole of acid per liter of composition.
  • amphoteric surfactants can be present in the composition according to the invention as amphoteric surfactants.
  • the composition according to the invention comprises an amphoteric surfactant selected from the group consisting of betaines, amphoacetates, amphodiacetates, hydroxysultaines, amine oxides, amphopropionates and mixtures thereof.
  • an amphoteric surfactant selected from the group consisting of betaines, amphoacetates, amphodiacetates, hydroxysultaines, amine oxides, amphopropionates and mixtures thereof.
  • Preferred betaines are those of the formulas (IIa) or (IIb)
  • R 3 is -N + (CH 3 ) 2 -CH 2 -COO " (IIa)
  • R 5 branched or unbranched, saturated or unsaturated, preferably unbranched alkyl radicals having 7 to 17 carbon atoms and R 3 is an alkyl or alkylamidoalkyl radical, where the alkyl radical may be branched or unbranched, preferably unbranched and preferably has from 8 to 18, carbon atoms ,
  • betaine preferably a C 8 -i8 alkylbetaine, the composition of the invention, or a C 8 -I alkylamidopropylbetaine 8 or a mixture thereof.
  • betaines selected from Oleylbetaine, caprylamidopropylbetaine, capramidopropylbetaine, laurylbetaine, laurylamidopropylbetaine,
  • Isostearylamidopropyl betaine coconut betaine, cocamidopropyl betaine, ricinoleamidopropyl betaine.
  • hydroxysulteins (formula (III)
  • CTFA hydroxysulteins
  • this term is understood to mean suifobetaines which contain a hydroxypropylsulfonate group.
  • Hydroxysultains can e.g. obtained by reaction of tertiary amines with epichlorohydrin and bisulfite, such as cocamidopropyl hydroxysultaines, coco-hydroxysultaines, lauramidopropyl hydroxysultaines or lauryl hydroxysultaines.
  • R 4 is -N + (CH 3 ) 2 -CH 2 -CH (OH) -CH 2 -SO 3 " (HIa)
  • R 4 is an alkyl or alkylamidoalkyl radical.
  • the alkyl radical may be branched or unbranched, preferably unbranched, and preferably has from 8 to 18, preferably from 10 to
  • Particularly preferred hydroxy sultaine are e.g.
  • Laurylhydroxysultaine tallowamidopropylhydroxysultaine, erucamidopropylhydroxysultaine, alkyletherhydroxypropylsultaine,
  • Cocoamidopropylhydroxysultaine cocoamidopropylhydroxysultaine, laurylamidopropylhydroxysultaine and cocoamidopropylhydroxysultaine and R 5 as defined above.
  • amphoteric surfactants is the group of compounds (and salts thereof) represented by formulas (IVa) and (IVb).
  • R 5 branched or unbranched, preferably unbranched
  • Alkyl radicals having 7 to 17 carbon atoms and R 6 H or CH 2 -COOH, preferably H.
  • Preferred compounds of formula IV are e.g. the reaction products of imidazoline derivatives with chloroacetic acid, in particular amphoacetates and amphodiacetates. Particularly preferred compounds of formula IV are cocoamphoacetates or lauroamphoacetates, as well as the corresponding diacetates. Preferred compounds of the formulas (IVa) and (IVb) are, in particular, sodium cocoamphoacetates, sodium lauroamphoacetates, disodium cocoamphodiacetate and disodium lauroamphodiacetate.
  • Suitable as amphoteric surfactants are also C 8 -i ⁇ Fettamphocarboxypropionate and C 8 -i ⁇ Fettamphopropionate or Fettamoinoxide, such as. B. lauryldimethylamine oxide.
  • compositions according to the invention particularly preferably contain as amphoteric surfactants betaines, amphoacetates, amphodiacetates or amphopropionates selected from N-alkyl-N, N-dimethylammonium glycinates (alkylbetaines), for example cocoalkyldimethylammoniumglycinate, N-acylaminopropyl-N, N-dimethylammoniumglycinate (amidopropylbetaine); Isspielnem coco acylaminopropyldimethylammoniumglyci-inat (CAPB), 2-alkyl-3-carboxylmethyl-3-hydroxyethylimidazoline each having 8 to 18 CA atoms in the alkyl or acyl group and Kokosacylaminoethylhydroxyethylcarboxymethylglycinat
  • betaines amphoacetates, amphodiacetates or amphopropionates selected from N-alkyl-N, N-
  • Composition optionally contain other surfactants.
  • surfactants may, for. As anionic surfactants, such as. B.
  • the composition of the invention one or more C10-22-, preferably Ci-2 -i4 alkyl ethoxy sulfate surfactants, which are preferably on average 1 to 10, preferably having 2 to 5 ethylene oxide units.
  • Preferred cationic surfactants are in particular quaternary ammonium compounds, in particular those provided with at least one linear and / or branched, saturated or unsaturated alkyl chain having 8 to 22 carbon atoms, such as.
  • B. Alkyltr imethylammoniumhalogenide such.
  • Further preferred cationic surfactants are, in particular monoalkylamidoquats, such as. B.
  • PEG / PPG-20/6 dimethicones PEG / PPG-20/20 dimethicones, bis-PEG / PPG-20/20 dimethicones, PEG-12 or PEG-14 dimethicones, PEG / PPG-14/4 or 4 / 12 or 20/20 or 18/18 or 17/18 or 15/15, polysiloxane-polyalkyl-polyether copolymers or corresponding derivatives, such as. B.
  • lauryl or cetyl dimethicone copolyols especially cetyl PEG / PPG-10/1 Dimethicone (ABIL® EM 90 (Evonik Degussa)), mixed esters of pentaerythritol, fatty acids, citric acid and fatty alcohol according to DE 11 65 574 and / or mixed esters of fatty acids 6 to 22 carbon atoms, methyl glucose and polyols, such as.
  • glycerol or polyglycerol citric acid esters such.
  • the anionic surfactants are preferably selected from surfactants containing water-solubilizing anionic groups, such as. As a carboxylate, sulfate, sulfonate or phosphate groups and a lipophilic radical.
  • Skin-compatible anionic surfactants are known to the skilled worker in large numbers and are available commercially. These may be alkyl sulfates or alkyl phosphates in the form of their alkali, ammonium or alkanolammonium salts, Alkyl ether sulfates, Alkylethercarboxylate, Acylsarkosinate and acylglutamates in the form of their alkali metal or ammonium salts.
  • Preferred optional surfactants are, in particular, alkyl ethoxy sulfates of the formula (V)
  • the mass ratio of optional surfactants, preferably alkyl ethoxy sulfate surfactants to sulfosuccinate surfactants is preferably from 1 to 4 to 2 to 1, preferably 1 to 2.5 to 1 to 1.5.
  • Particularly preferred optional surfactants are in particular
  • Alkyl ethoxy sulfates of the formula (V) are, in particular Ci O - 22 alkyl ethoxy sulfate surfactants which preferably have 1 to 5 ethylene oxide units.
  • the total content of surfactants is in the inventive
  • Composition preferably from 1 to 30, preferably 3 to 20 and particularly preferably from 6 to 15 mass%.
  • Such OH-functional compounds may, for. B. monohydric alkanols, such as. As isopropanol or ethanol, glycerol. These other OH-functional alkanols, such as. As isopropanol or ethanol, glycerol. These other OH-functional alkanols, such as. As isopropanol or ethanol, glycerol. These other OH-functional alkanols, such as. As isopropanol or ethanol, glycerol.
  • Compounds are preferably in a proportion of at least
  • composition of the invention may also comprise one or more conditioning agents. These may be selected from the silicone-based or non-silicone based conditioning agents.
  • the composition according to the invention comprises a silicone, preferably selected from the group consisting of organosilicones, amino-functional organosilicones, amino-functional organosilicone-polyether copolymers, quat-functional organosiloxanes, betaine-functional siloxanes and mixtures thereof, preferably in a concentration of 0 , 01- 5 mass%, particularly preferably 0.1-3 mass%.
  • the conditioning agents may be present as particles or as drops in the composition according to the invention. They may be liquid, semi-solid or solid, provided that they are substantially complete and uniform in nature
  • Disperse composition present.
  • the conditioning agents are present as liquid drops in the composition.
  • Silicone-based conditioning agents may e.g. B. selected from the group comprising: polydiorganosiloxanes, in particular polydimethylsiloxanes (dimethicone), polydimethylsiloxanes with hydroxyl end groups (Dimethiconol), silicone resins, such as. As described in WO 96/31188 and offered by General Electric under the designations GE SS4230 and GE SS4267, silicones (polysiloxanes) with a Refractive index, of at least 1.46 and at most 1.70, the z. B., aryl-containing substituents.
  • the proportion of silicone-based conditioning agent based on the composition of the invention is preferably 0.01 to 5, preferably 0.1 to 3 mass%.
  • non-silicone based conditioning agents are e.g.
  • organic quaternary compounds such as cetrimonium chloride, dicetyldimonium chloride, behentrimonium chloride, distearyldimonium chloride, beethentrimonium methosulfate, distearoylethyldimonium chloride, palmitamidopropyltrimonium chloride, guar hydroxypropyltrimonium chloride, hydroxypropylguar hydroxypropyltrimonium chloride, polyquaternium-10 or quaternium-80 or also amine derivatives such as e.g. Stearamidopropyl.
  • the proportion of non-silicone-based conditioning agent based on the composition of the invention is preferably 0.01 to 5, preferably 0.1 to 3 mass%.
  • EP 1771538 which belongs in its entirety to the disclosure content of the present invention.
  • composition according to the invention comprises one or more cationic polymers.
  • the cationic polymers have the advantage that they are also suitable as conditioning agents.
  • the proportion of the cationic polymers is preferably from 0.01 to 2, preferably 0.1 to 0.6 and particularly preferably from 0.15 to 0.45 mass%.
  • the cationic polymers contain cationic nitrogen-containing groups, such as. As quaternary ammonium or protonated amino groups.
  • cationic nitrogen-containing groups such as. As quaternary ammonium or protonated amino groups.
  • CTFA Cosmetic Ingredient Dictionary 6th edition, edited by Wenninger, JA and McEwen Jr, GN, (The Cosmetics, Toiletry, and Fragrance Association, 1995), the disclosures of which are incorporated herein by reference in their entirety.
  • Preferred cationic polymers are selected from the group comprising cationically modified starch, cationically modified cellulose, cationically modified galactomannans, such.
  • cationically modified polyacrylates such as guar, cationically modified polyacrylates such.
  • Suitable cationic cellulose polymers are available from Amerchol Corp. (Edison, N.J.,) B. in their product series POLYMER JR and LR distributed. Particularly suitable cationic cellulose polymers are, for. Polyquaternium 10 or Polyquaternium 24 available from Amerchol Corp. (Edison, N.J.,) under the trade name Polymer LM-200. A suitable and particularly preferred cationic guar derivative is, in particular, guar-dexypropyltrimonium chloride marketed by Rhodia Corporation under the name JAGUAR EXCEL or JAGUAR C13S. Other suitable cationic polymers may, for. For example, US 3,958,581 and EP 1771538 are taken.
  • the composition according to the invention preferably has a viscosity of from 10 to 20,000 mPas, preferably from 1,000 to 7,000 and more preferably from 2,000 to 4,500 mPas (determined using Brookfield LVF, spindle 3, 5 rpm, 25 ° C.). The adjustment of the viscosity, if necessary, for. Example, by adding one or more thickeners to the composition of the invention.
  • compositions one or more thickeners
  • Suitable thickeners are, for example, polysaccharides, in particular xanthan gum, guar, agar-agar, alginates and tyloses, carboxymethylcellulose, hydroxypropylmethylcellulose and hydroxyethylcellulose higher molecular weight polyethylene glycol mono- and di-esters of fatty acids, polyacrylates (eg Carbopol TM or Synthalen TM), polyacrylamides, polyvinyl alcohol and polyvinylpyrrolidone, surfactants such as ethoxylated fatty acid glycerides, esters of fatty acids with polyols such as pentaerythritol or trimethylolpropane, Fatty alcohol ethoxylates with restricted homolog distribution or alkyl oligoglucosides and electrolytes such as common salt and ammonium chloride.
  • polysaccharides in particular xanthan gum, guar, agar-agar, alginates and tyloses, carb
  • Particularly suitable thickeners are low molecular weight nonionic surfactants, such as cocoamides DEA / MEA and laureth-3, or polymeric, high molecular weight, associative, highly ethoxylated fatty derivatives, such as PEG-200 hydrogenated glyceryl palmates, PEG-120 methylglucose dioleate (Antil® 120 Plus) , PEG-55 Propylene Glycol Oleate, PEG-18 Glyceryl Oleate / Cocoate.
  • nonionic surfactants such as cocoamides DEA / MEA and laureth-3
  • polymeric, high molecular weight, associative, highly ethoxylated fatty derivatives such as PEG-200 hydrogenated glyceryl palmates, PEG-120 methylglucose dioleate (Antil® 120 Plus) , PEG-55 Propylene Glycol Oleate, PEG-18 Glyceryl Oleate / Cocoate.
  • thickener z As waxes, such as hydrogenated castor wax, beeswax or Microwachs, inorganic thickeners, such as.
  • silica, alumina or phyllosilicates eg hectorite, laponite, saponite
  • aerosils, phyllosilicates and / or metal salts of fatty acids such as.
  • zinc stearate can be used.
  • Preferred compounds of this class are, for. B. PEG-120 methyl glucose dioleate, z. B. sold under the trade name Antil ® 120 Plus by Evonik Goldschmidt GmbH, PEG-150 pentaerythrityl tetrastearate, the z. From Croda under the trade name
  • compositions which have a viscosity in the abovementioned range preferably have from 0.1 to 10, preferably from 0.5 to 8 and particularly preferably from 1 to 7,% by mass of thickeners, in particular the abovementioned thickeners and more preferably the hydrophobically modified, water-soluble nonionic polyols.
  • compositions according to the invention are those in which several of the aforementioned particularly advantageous additives are present simultaneously.
  • compositions according to the invention can be used for the preparation of or as cleansing or care compositions, in particular for the cleansing or care of skin and hair.
  • Another object of the present invention are accordingly skin and / or hair care or cleaning compositions having a composition of the invention.
  • compositions or compositions of the invention may contain conventional further constituents in conventional concentrations.
  • the other ingredients can z. B. be selected from emollients, emulsifiers, thickeners / viscosity regulators / stabilizers, UV
  • Sunscreen filters antioxidants, hydrotropes (or polyols), solids and fillers, film formers, pearlescing additives, deodorant and antiperspirant active ingredients, insect repellents, self-tanning agents, preservatives, conditioners, perfumes, dyes, biogenic agents, care additives, superfatting agents and solvents.
  • film formers pearlescing additives
  • deodorant and antiperspirant active ingredients insect repellents
  • self-tanning agents preservatives, conditioners, perfumes, dyes, biogenic agents, care additives, superfatting agents and solvents.
  • the sulphosuccinate solutions used were prepared on the basis of Comparative Example 1 of DE 44 14 863. Instead of Dehydol®, the OH-functional component used was an equivalent amount of ethoxylated fatty alcohol of the formula VI
  • compositions of Formulations are listed in Table 1 (data in mass% unless stated otherwise).
  • Texapon NSO IS, TEGO Betain F 50, and water were mixed with stirring and at 25 0 C with the SuIfosuccinatants (33% by mass aqueous. Solution), which has the content shown in Table 1 of fatty alcohol ethoxylate, was added.
  • the Antil® 120 Plus was added in the form of pellets and the mixture heated with stirring for 5 min (until complete dissolution of the pellets) to 50 0 C.
  • Example 1 Examples Ia to G according to the invention, Example Ih Comparative Example
  • FAEO fatty alcohol ethoxylate
  • Texapon ® NSO IS is a 28 wt .-% aqueous solution of
  • Tego ® Betain F50 is a 38% by weight solution of
  • Antil® 120 Plus is PEG-120 methylglucose dioleate, distributed by Evonik Goldschmidt GmbH.
  • Formulations were prepared analogously to Example 2 with different levels of fatty alcohol ethoxylate, but the
  • Formulations 4a, 4b and 4c (0.5% in water, 10 ° dH, 30 0 C, pH 6) were, similarly to Examples 2 and 3 were prepared (but without the addition of a thickener) and a SITA Foam Tester R-2000 ( Software: SITA-Foam DAC / DL; volume / measurement 300 ml; 1500 rpm; five-fold measurement). The foam volume was measured after 20 s.
  • the composition of the formulations used and the results can be seen in Table 4. It can be clearly seen that the addition of free, OH-functional compound leads to an increase in the foam volume and thus to a better foaming behavior.

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Abstract

La présente invention porte sur une composition aqueuse contenant : i) de 0,5 à 10% en masse d'au moins un tensio-actif de type sulfosuccinate, ii) de 0,5 à 10% en masse d'au moins un tensio-actif amphotène, et iii) des composés libres, à fonctionnalité OH, ces derniers étant équivalents aux composants alcools des esters du tensio-actif de type sulfosuccinate utilisé, le rapport en masse du tensio-actif de type sulfosuccinate ii) au composé libre à fonctionnalité OH, étant de 100:1 à 100:20. L'invention porte également sur l'utilisation d'une telle composition pour préparer des compositions nettoyantes ou pour servir de composition nettoyante, en particulier pour le nettoyage de la peau et des cheveux, ainsi que sur des produits pour le nettoyage de la peau et/ou des cheveux qui contiennent une telle composition.
EP10706221A 2009-03-27 2010-03-01 Compositions aqueuses pour le nettoyage des cheveux et de la peau Withdrawn EP2410978A2 (fr)

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EP09156406 2009-03-27
PCT/EP2010/052519 WO2010108756A2 (fr) 2009-03-27 2010-03-01 Compositions aqueuses pour le nettoyage des cheveux et de la peau
EP10706221A EP2410978A2 (fr) 2009-03-27 2010-03-01 Compositions aqueuses pour le nettoyage des cheveux et de la peau

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CN (1) CN102365079A (fr)
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WO (1) WO2010108756A2 (fr)

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DE102013218981A1 (de) 2013-09-20 2015-03-26 Evonik Industries Ag Raumtemperaturhärtendes Silikon-Polyester-Bindemittel
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WO2017223076A1 (fr) 2016-06-20 2017-12-28 Rita Corporation Composition tensioactive
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EP3399754A1 (fr) 2017-05-04 2018-11-07 Thomson Licensing Procédé et appareil permettant de réordonner l'ordre des modes les plus probables pour une prédiction intra
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WO2010108756A3 (fr) 2011-09-29
WO2010108756A2 (fr) 2010-09-30
JP2012521969A (ja) 2012-09-20
US20120021960A1 (en) 2012-01-26
BRPI1013486A2 (pt) 2016-04-05
CN102365079A (zh) 2012-02-29

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