EP2454358B1 - Composition solide parfumée à bonne solubilité dans l'eau froide - Google Patents
Composition solide parfumée à bonne solubilité dans l'eau froide Download PDFInfo
- Publication number
- EP2454358B1 EP2454358B1 EP10730763.9A EP10730763A EP2454358B1 EP 2454358 B1 EP2454358 B1 EP 2454358B1 EP 10730763 A EP10730763 A EP 10730763A EP 2454358 B1 EP2454358 B1 EP 2454358B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- fragrance
- solid
- fabric
- saccharide
- transmitting composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Not-in-force
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- 239000007787 solid Substances 0.000 title claims description 42
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title description 15
- 150000001875 compounds Chemical class 0.000 claims description 68
- 150000001720 carbohydrates Chemical class 0.000 claims description 45
- -1 alkali metal salts Chemical class 0.000 claims description 41
- 239000004744 fabric Substances 0.000 claims description 33
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- 239000003112 inhibitor Substances 0.000 claims description 8
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical group O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 7
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- IUNMPGNGSSIWFP-UHFFFAOYSA-N dimethylaminopropylamine Chemical compound CN(C)CCCN IUNMPGNGSSIWFP-UHFFFAOYSA-N 0.000 description 4
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- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- FVDRFBGMOWJEOR-UHFFFAOYSA-N hexadecan-2-ol Chemical compound CCCCCCCCCCCCCCC(C)O FVDRFBGMOWJEOR-UHFFFAOYSA-N 0.000 description 4
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- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 4
- 239000008107 starch Substances 0.000 description 4
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 3
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 3
- 241001136792 Alle Species 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
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- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 3
- GZUXJHMPEANEGY-UHFFFAOYSA-N bromomethane Chemical compound BrC GZUXJHMPEANEGY-UHFFFAOYSA-N 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 239000000969 carrier Substances 0.000 description 3
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- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 3
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 3
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 3
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- SXQXMKMHOFIAHT-UHFFFAOYSA-N 1,1-dichloro-2-(2,2-dichloroethoxy)ethane Chemical compound ClC(Cl)COCC(Cl)Cl SXQXMKMHOFIAHT-UHFFFAOYSA-N 0.000 description 2
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- GGZKJFGVSZKFLD-UHFFFAOYSA-N 1-prop-1-enyl-1h-imidazol-1-ium;chloride Chemical compound [Cl-].CC=CN1C=C[NH+]=C1 GGZKJFGVSZKFLD-UHFFFAOYSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
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- KNUPSOXBESCJLY-UHFFFAOYSA-N 2-methoxy-1-phenylhexan-1-one Chemical compound CCCCC(OC)C(=O)C1=CC=CC=C1 KNUPSOXBESCJLY-UHFFFAOYSA-N 0.000 description 2
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- 235000015497 potassium bicarbonate Nutrition 0.000 description 1
- 229910000028 potassium bicarbonate Inorganic materials 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 235000011181 potassium carbonates Nutrition 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 1
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 1
- 229910052913 potassium silicate Inorganic materials 0.000 description 1
- LJCNRYVRMXRIQR-OLXYHTOASA-L potassium sodium L-tartrate Chemical compound [Na+].[K+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O LJCNRYVRMXRIQR-OLXYHTOASA-L 0.000 description 1
- 229940074439 potassium sodium tartrate Drugs 0.000 description 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
- 229910052939 potassium sulfate Inorganic materials 0.000 description 1
- 235000011151 potassium sulphates Nutrition 0.000 description 1
- 239000001944 prunus armeniaca kernel oil Substances 0.000 description 1
- 239000008171 pumpkin seed oil Substances 0.000 description 1
- MUPFEKGTMRGPLJ-ZQSKZDJDSA-N raffinose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO[C@@H]2[C@@H]([C@@H](O)[C@@H](O)[C@@H](CO)O2)O)O1 MUPFEKGTMRGPLJ-ZQSKZDJDSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910000275 saponite Inorganic materials 0.000 description 1
- 229910000276 sauconite Inorganic materials 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- HELHAJAZNSDZJO-OLXYHTOASA-L sodium L-tartrate Chemical compound [Na+].[Na+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O HELHAJAZNSDZJO-OLXYHTOASA-L 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 229960004249 sodium acetate Drugs 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 229960001790 sodium citrate Drugs 0.000 description 1
- 235000011083 sodium citrates Nutrition 0.000 description 1
- 235000011006 sodium potassium tartrate Nutrition 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 235000019794 sodium silicate Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000001433 sodium tartrate Substances 0.000 description 1
- 229960002167 sodium tartrate Drugs 0.000 description 1
- 235000011004 sodium tartrates Nutrition 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- 239000013042 solid detergent Substances 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- YYGNTYWPHWGJRM-AAJYLUCBSA-N squalene Chemical compound CC(C)=CCC\C(C)=C\CC\C(C)=C\CC\C=C(/C)CC\C=C(/C)CCC=C(C)C YYGNTYWPHWGJRM-AAJYLUCBSA-N 0.000 description 1
- 229940031439 squalene Drugs 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 229940012831 stearyl alcohol Drugs 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 125000000185 sucrose group Chemical group 0.000 description 1
- 239000002600 sunflower oil Substances 0.000 description 1
- 230000000475 sunscreen effect Effects 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 229940095064 tartrate Drugs 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- BORJONZPSTVSFP-UHFFFAOYSA-N tetradecyl 2-hydroxypropanoate Chemical compound CCCCCCCCCCCCCCOC(=O)C(C)O BORJONZPSTVSFP-UHFFFAOYSA-N 0.000 description 1
- USFMMZYROHDWPJ-UHFFFAOYSA-N trimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]azanium Chemical compound CC(=C)C(=O)OCC[N+](C)(C)C USFMMZYROHDWPJ-UHFFFAOYSA-N 0.000 description 1
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical group CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
- 150000004043 trisaccharides Chemical class 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 235000019154 vitamin C Nutrition 0.000 description 1
- 239000011718 vitamin C Substances 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 229940045997 vitamin a Drugs 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000010497 wheat germ oil Substances 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
- C11D3/502—Protected perfumes
- C11D3/505—Protected perfumes encapsulated or adsorbed on a carrier, e.g. zeolite or clay
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/221—Mono, di- or trisaccharides or derivatives thereof
Definitions
- the invention relates to a solid, fragrance-imparting composition and their use and preparation.
- cationic fabric softening compounds include, for example, methyl N- (2-hydroxyethyl) -N, N-di (tallowacyloxyethyl) ammonium compounds or N, N-dimethyl-N, N-di (tallowacyloxyethyl) ammonium compounds.
- a disadvantage of these conventional softeners is that they often leave unsightly deposits in the dispenser compartment of the washing machine.
- the conventional softeners do not prevent the deposition of limescale during the rinsing process on the laundry.
- solid fragrance-providing and fabric-care compositions having a crystalline look comprising a water-soluble carrier, a water-soluble polymer, a fabric-conditioning compound, and a perfume.
- fragrance-imparting and textile-care compositions are used in the main wash together with detergents or cleaners.
- Aesthetically appealing Solid fragrance-providing and textile-care compositions are obtained with polyalkylene glycols, in particular polyethylene glycol, as a water-soluble polymer.
- the WO 2005/00591 A1 describes particles of perfume and tripolyphosphate as carriers, which are coated with sugar and silica.
- the DE 102004020400 A1 discloses perfumed solids containing perfume and water-soluble inorganic carriers.
- the WO 97/11151 A1 describes vitreous particles containing inorganic-perfume enveloped in sugar.
- a solid fragrance-providing composition comprising a particulate, water-soluble carrier, a perfume, a fabric-care composition comprising a fabric softening compound, and an at least partially encapsulated saccharide, wherein the saccharide is selected from the group of the monosaccharides, the oligosaccharides and mixtures thereof and wherein the textile-care compound is powdery and at least partially present in and / or at least partially on the casing.
- this solid composition is easier and better to handle than liquid compositions, since no drops remain on the edge of the bottle, which lead to subsequent storage of the bottle to edges on the ground or to unsightly deposits in the region of the closure. The same applies in the event that some of the composition is accidentally spilled during dosing.
- the spilled composition can also be removed easier and cleaner.
- the water-soluble carrier is selected from the group consisting of inorganic alkali metal salts, organic alkali metal salts, inorganic alkaline earth metal salts, organic alkaline earth metal salts, organic acids, carbohydrates, silicates, urea and mixtures thereof.
- the amount of the water-soluble carrier is from 50 to 99% by weight, preferably from 75 to 95% by weight, based in each case on the total solid fragrance-imparting composition.
- the solid fragrance-providing composition further comprises an ingredient selected from the group of dyes, fillers, pearlescers, skin-care compounds and mixtures thereof.
- the fabric care composition comprises a fabric softening compound and may additionally be bleaches, bleach activators, enzymes, silicone oils, anti redeposition agents, optical brighteners, grayness inhibitors, anti-shrinkage agents, wrinkle inhibitors, color transfer inhibitors, antimicrobial agents, germicides, fungicides, antioxidants, antistatic agents, ironing aides, phobizers - And impregnating agents, swelling and slipping agents, UV absorbers and mixtures thereof may be selected.
- the solid, fragrance-imparting composition can be extended in a simple manner to further functionalities.
- the fabric care composition comprises a fabric softening compound. It is most preferred that the fabric softening compound is selected from quaternary ammonium compounds, polysiloxanes, textile softening clays, cationic polymers, and mixtures thereof.
- polysiloxanes and / or cationic polymers as a fabric care compound in the fragrance-providing composition is advantageous because they not only have a softening effect but also enhance the perfume impression on the laundry.
- softening clays as a textile-care compound in the fragrance-providing composition is advantageous, since these additionally have a water-softening effect and thus lime deposits on the laundry are prevented.
- a fragrance-providing composition may contain a combination of at least two fabric-care compounds.
- the choice of fabric softening compound also depends on the intended use of the fragrance-providing composition. Thus, it may be desirable for the solid, fragrance-promoting composition to be free of cationic, fabric softening compounds.
- the saccharide is sucrose.
- Sucrose has a high solubility at 2.4 g per 1 g of water at 20 ° C.
- the fragrance-providing composition contains 0.1 to 20 wt .-%, preferably 1 to 10 wt .-% and particularly preferably 2 to 7 wt .-% perfume.
- the fabric conditioning compound is powdered and at least partially present in and / or at least partially on the casing.
- a polysaccharide is present at least partially in and / or at least partially on the sheath.
- the water-soluble carrier have particle sizes in the range of 0.6 to 30 mm, in particular 0.8 to 7 mm and particularly preferably 1 to 3 mm.
- Fragrance-providing compositions having particle sizes in the range from 0.8 to 7 mm and particularly preferably in the range from 1 to 3 mm can be metered particularly well and in a targeted manner.
- the fragrance-providing composition may contain additional ingredients, preferably selected from the group consisting of dyes, perfume, fillers, pearlescers, skin-care compounds, and mixtures thereof.
- the invention also relates to the use of a solid fragrance-providing composition according to the invention for conditioning textile fabrics.
- the invention also relates to a process for the preparation of a solid fragrance-providing composition
- a solid fragrance-providing composition comprising a particulate, water-soluble carrier, a perfume, a fabric-care composition comprising a fabric softening compound, and an at least partially saccharide-containing casing the saccharide selected from the group of monosaccharides, oligosaccharides and mixtures thereof, wherein the perfume is applied to the water-soluble carrier, the saccharide is melted and placed on the particulate carrier such that it is at least partially enveloped and wherein the textile Caring compound is powdery and at least partially in the enclosure is present with saccharide or the wrapper is coated after solidification with the textile-care compound.
- the solid fragrance-providing composition contains as essential ingredients a particulate water-soluble carrier, a water-soluble saccharide and a perfume.
- An essential component of the fragrance-providing composition is the water-soluble carrier.
- This preferably includes inorganic alkali metal salts such as sodium chloride, potassium chloride, sodium sulfate, sodium carbonate, potassium sulfate, potassium carbonate, sodium bicarbonate, potassium bicarbonate or mixtures thereof, organic alkali metal salts such as sodium acetate, potassium acetate, sodium citrate, sodium tartrate or potassium sodium tartrate, inorganic alkaline earth metal salts such as calcium chloride or magnesium chloride, organic alkaline earth metal salts such as calcium lactate, carbohydrates, organic acids such as citric acid or tartaric acid, silicates such as water glass, sodium silicate or potassium silicate, urea and mixtures thereof.
- inorganic alkali metal salts such as sodium chloride, potassium chloride, sodium sulfate, sodium carbonate, potassium sulfate, potassium carbonate, sodium bicarbonate, potassium bicarbonate or mixtures thereof
- organic alkali metal salts such as sodium a
- the water-soluble carrier may in particular comprise a carbohydrate, which is for example selected from the group consisting of dextrose, fructose, galactose, isoglucose, glucose, sucrose, raffinose, isomalt and mixtures thereof.
- the carbohydrate used may be, for example, candy or hail sugar.
- Citric acid as a carrier has the advantage that the scent-imparting composition at the same time has a builder for lowering the water hardness.
- the water-soluble carrier may also contain mixtures of said materials.
- the water-soluble carrier is particulate and has particle sizes in the range of 0.6 to 30 mm, in particular 0.8 to 7 mm and particularly preferably 1 to 3 mm.
- Another ingredient of the fragrance-providing composition is the water-soluble saccharide which at least partially envelops the water-soluble carrier.
- the saccharide is selected from the group of monosaccharides, oligosaccharides and mixtures thereof.
- Monosaccharides are linear polyhydroxy aldehydes (aldoses) or polyhydroxy ketones (ketoses) and preferably comprise pentoses (C 5 H 10 O 5 ) and hexoses (C 6 H 12 O 6 ).
- Suitable pentoses are, for example, xylose, lyxose, ribose and arabinose.
- Suitable hexoses include, for example, glucose, galactose or mannose.
- oligosaccharides 2 to 10 monosaccharide molecules are combined to form larger molecules with the outflow of water, and accordingly comprise disaccharides, trisaccharides, etc.
- Suitable oligosaccharides are, for example, sucrose, lactose, maltose.
- the saccharide sucrose is particularly preferably used.
- the water-soluble saccharide may also contain a mixture of said mono- and / or oligosaccharides.
- fragrance-providing composition Another essential ingredient of the fragrance-providing composition is the perfume.
- perfume oils or fragrances individual fragrance compounds, e.g. the synthetic products of the ester, ether, aldehyde, ketone, alcohol and hydrocarbon type are used.
- mixtures of different fragrances are used, which together produce an attractive fragrance.
- perfume oils may also contain natural fragrance mixtures as are available from plant sources.
- the amount of perfume in the fragrance-transmitting composition is preferably between 0.1 and 20 wt .-%, particularly preferably between 1 and 10 wt .-% and most preferably between 2 and 7 wt .-%.
- the fragrance-providing composition contains a fabric care compound and may optionally contain other ingredients selected from the group of dyes, fillers, pearlescers, skin care compounds and mixtures thereof.
- a textile-care compound is understood to mean any compound which imparts a textile softening effect to fabrics treated therewith or another advantageous effect, such as crease resistance or the harmful or negative effects which result during cleaning and / or conditioning / or wearing, such as fading, graying, etc., reduced.
- the fabric care composition comprises a fabric softening compound and may include, for example, bleaches, bleach activators, enzymes, silicone oils, anti redeposition agents, optical brighteners, grayness inhibitors, anti-shrinkage agents, anti-crease agents, color transfer inhibitors, antimicrobial agents, germicides, fungicides, antioxidants, antistatic agents, ironing aids, phobizers - And impregnating, swelling and slip agents, UV absorbers and mixtures thereof.
- a fabric softening compound may include, for example, bleaches, bleach activators, enzymes, silicone oils, anti redeposition agents, optical brighteners, grayness inhibitors, anti-shrinkage agents, anti-crease agents, color transfer inhibitors, antimicrobial agents, germicides, fungicides, antioxidants, antistatic agents, ironing aids, phobizers - And impregnating, swelling and slip agents, UV absorbers and mixtures thereof.
- the fabric conditioning compound is a fabric softening compound and is, for example, a quaternary ammonium compound, a polysiloxane, a fabric softening clay, a cationic polymer or a blend of at least two of these fabric care agents Links. Accordingly, the fragrance-providing composition is preferably a fabric softening composition.
- esterquats Preferably usable quaternary ammonium compounds are esterquats. Suitable examples of ester quats are shown, for example, in formulas (I) and (II):
- R 4 is an aliphatic alk (en) yl radical having 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds and / or optionally with substituents;
- R 5 is H, OH or O (CO) R 7
- R 6 is, independently of R 5, H, OH or O (CO) R 8 , where R 7 and R 8 are each independently an aliphatic alk (ene) ylrest having 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds.
- m, n and p can each independently be 1, 2 or 3.
- X - may be either a halide, methosulfate, methophosphate or phosphate ion as well as mixtures of these anions.
- R 5 represents the group O (CO) R 7 .
- R 5 is the group O (CO)
- R 7 and R 4 and R 7 are alk (en) yl radicals having 16 to 18 carbon atoms.
- R 6 is also OH.
- R 12 , R 13 and R 14 are independently a C 1-4 alkyl, alkenyl or hydroxyalkyl group
- R 15 and R 16 are each independently selected C 8-28 alkyl group
- X - An anion and r is a number between 0 and 5.
- ester quats examples include methyl N- (2-hydroxyethyl) -N, N-di (tallowacyloxyethyl) ammonium methosulfate, bis (palmitoyloxyethyl) hydroxyethyl methyl ammonium methosulfate, 1,2-bis [tallowacyloxy] 3-trimethylammoniumpropane chloride, methyl N, N-bis (stearoyloxyethyl) -N- (2-hydroxyethyl) ammonium methosulfate or N, N-dimethyl-N, N-di (tallowacyloxyethyl) ammonium methosulfate.
- Polydimethylpolysiloxanes are known as efficient fabric care compounds.
- Suitable polydimethysiloxanes include DC-200 (ex Dow Corning), Baysilone® M 50, Baysilone® M 100, Baysilone® M 350, Baysilone® M 500, Baysilone® M 1000, Baysilone® M 1500, Baysilone® M 2000 or Baysilone® M 5000 (all ex GE Bayer Silicones).
- the polysiloxane contains the structural units a) and b).
- a particularly preferred polysiloxane has the following structure: (CH 3 ) 3 Si [O-Si (CH 3 ) 2 ] n - [O-Si (CH 3 ) ⁇ (CH 2 ) 3 -NH- (CH 2 ) 2 -NH 2 ⁇ ] x -OSi ( CH 3 ) 3 where the sum n + x is a number between 2 and 10,000.
- Suitable polysiloxanes having the structural units a) and b) are for example commercially available under the trade names DC2-8663, DC2-8035, DC2-8203, DC05-7022 or DC2-8566 (all ex Dow Corning). Also suitable according to the invention are, for example, those commercially available products available Dow Corning ® 7224, Dow Corning ® 929 Cationic Emulsion or Formasil 410 (GE Silicones).
- a suitable fabric softening clay is, for example, a smectite clay.
- Preferred smectite clays are beidellite clays, hectorite clays, laponite clays, montmorillonite clays, nontronite clays, saponite clays, sauconite clays, and mixtures thereof.
- Montmorillonite clays are the preferred softening clays.
- Bentonites contain mainly montmorillonites and can serve as a preferred source of fabric softening clay. The bentonites can be used as powder or crystals.
- Suitable bentonites are sold, for example, under the names Laundrosil® by Süd-Chemie or under the name Detercal by Laviosa.
- the scent-imparting composition contains a fabric softening compound and one or more other fabric-care compounds.
- the fragrance-providing composition is free of cationic fabric-care compounds.
- the fragrance-providing composition is free of quaternary ammonium compounds.
- the amount of fabric care compound in the fragrance-providing composition is 0.1 to 15 weight percent and preferably between 2 and 12 weight percent.
- the textile care compound is powdered and at least partially present in and / or at least partially on the enclosure.
- Preferred dyes In order to improve the aesthetic impression of the fragrance-transmitting, they can be colored with suitable dyes.
- Preferred dyes the selection of which presents no difficulty to the skilled person, have a high storage stability and insensitivity to the other ingredients of detergents or cleaning agents and to light and no pronounced substantivity to textile fibers so as not to stain them.
- the fragrance-providing composition may contain a filler, such as silica.
- the amount of filler may be between 0.1 and 10 wt .-% and is preferably 1 to 5 wt .-%.
- the fragrance-providing composition may also contain a pearlescing agent to increase gloss.
- suitable pearlescing agents are ethylene glycol mono- and distearate (for example Cutina AGS from Cognis) and PEG-3-distearate.
- the fragrance-providing composition may comprise a skin care compound.
- a skin-care compound is understood as meaning a compound or a mixture of compounds which, upon contact of a textile with the detergent, draw on the textile and give an advantage on contact of the textile with skin of the skin compared to a textile which does not interfere with the laundry detergent according to the invention. and detergent was treated.
- This advantage can be, for example, the transfer of the skin care compound from the textile on the skin, less water transfer from the skin to the textile, or less friction on the skin surface through the textile.
- the amount of skin-care compound is preferably between 0.01 and 10% by weight, preferably between 0.1 and 5% by weight and very particularly preferably between 0.3 and 3% by weight, based on the solid, fragrance-containing compound. mediating composition. It may be that the skin-nourishing compound additionally has a textile care effect.
- the water-soluble carrier is first charged with the perfume and other ingredients, if any.
- the saccharide is melted and placed on the particulate carrier such that it is at least partially enveloped.
- the solid odoriferous composition has complete coverage with the saccharide.
- binders anionic surfactants, including soaps, nonionic surfactants, cationic surfactants, betaines, urea (derivatives), water glass, polyethylene glycols, glycerol, starches and mixtures thereof.
- the amount of water and / or binder is preferably at most 20 wt .-%, based on the total wrapping material ("saccharide glaze").
- the saccharide wrapper may additionally contain water and / or binder.
- the use of binders in the coating leads to a homogenization and stabilization of the saccharide glazes.
- saccharide glaze is understood to mean the coating of saccharide and optionally water and / or binder, which has been applied to the perfume-loaded carrier.
- binder in the saccharide glaze also makes it less sensitive to mechanical stress and / or temperature influences.
- the solid fragrance-providing composition has a powdered textile care compound. This is at least partially present in the envelope with saccharide.
- the pulverulent textile-care compound is at least partially incorporated in the applied to the support, but not yet complete solidified molten casing with saccharide.
- the casing can be coated after solidification with the powdered textile-care compound.
- a mixture of the powdered textile-care compound and a polysaccharide is incorporated or the coating is coated with such a mixture.
- the carrier is initially placed in a preheated mixer. Subsequently, the carrier is exposed during the mixing process with perfume and optionally other ingredients. Subsequently, a saccharide-containing melt is uniformly applied to the perfumed carrier and allowed to solidify. If the solid, scent-imparting composition contains a powdered textile-care compound or a mixture of a powdered textile-care compound and a polysaccharide, the coated perfumed carrier particles are powdered with it, as long as the saccharide-containing melt has not yet completely solidified.
- the application of the perfume, the other ingredients and the saccharide-containing melt is preferably carried out by spraying or Aufdüsens so that they are preferably used in liquid, dissolved and / or dispersed form.
- the solid, fragrance-imparting composition is particularly suitable for perfuming or perfuming and conditioning of textile fabrics and is brought into contact with the textile fabrics for this purpose with the rinse of a conventional washing and cleaning process.
- the fragrance-providing composition can be incorporated into a detergent or cleaning agent.
- a solid detergent or cleaning agent with 0.1 to 20 wt .-%, preferably 1 to 10 wt .-%, of the fragrance-imparting composition according to the invention is mixed.
- the solid fragrance-providing composition is preferably used separately in the rinse cycle.
- Table 1 shows fragrance-providing compositions E2 and E3 according to the invention (all amounts are given in% by weight of active ingredient based on the composition).
- Table 1 V1 E2 E3 NaCl crystals (1 - 3 mm) 79 - Sucrose crystals (1 - 4 mm) - 69 - Citric acid crystals (1 - 3 mm) - 69 Bentonite (powder) - 10 10 Perfume 1 1 1 Saccharide-containing coating 20 20 20 20 20 20 20 20 20
- Table 2 shows the composition of the saccharide-containing casing (all amounts are given in% by weight of active ingredient based on the composition).
- Table 2 Sucrose powder 84.99 C 12 -C 18 ROH (7 EO) 5 dye 0.01 water 10
- the NaCl crystals were initially charged in a Lödige mixer preheated to 40 to 60 ° C.
- a saccharide-containing melt was prepared by dissolving the sucrose in hot water and adding the nonionic surfactant and the dye. Subsequently, first the perfume and then the saccharide-containing melt was sprayed on. After cooling the melt, a solid, fragrance-imparting composition was obtained with crystal-like appearance, which dissolves without residue in the rinse of a washing machine.
- fragrance-imparting composition E2 and E3 were additionally powdered after applying the saccharide-containing melt and before it was completely solidified with bentonite powder. Also in these cases solid, fragrance-transmitting compositions were obtained with crystal-like appearance, which dissolve without residue in the rinse of a washing machine. No deposits / residues were observed in the dispensing compartment of the washing machines.
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Dispersion Chemistry (AREA)
- Molecular Biology (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Cosmetics (AREA)
Claims (12)
- Composition odorante solide, comprenant un véhicule particulaire hydrosoluble, un parfum, un composé de soin des textiles, lequel comprend un composé adoucissant les textiles, et une enveloppe au moins partielle à base d'un saccharide, dans laquelle le saccharide est sélectionné dans le groupe constitué des monosaccharides, des oligosaccharides et de mélanges de ceux-ci et dans laquelle le composé de soin des textiles est pulvérulent et est présent au moins en partie dans et/ou au moins en partie sur l'enveloppe.
- Composition odorante solide selon la revendication 1, caractérisée en ce que le véhicule hydrosoluble est sélectionné dans le groupe constitué de sels inorganiques de métal alcalin, de sels organiques de métal alcalin, de sels inorganiques de métal alcalino-terreux, de sels organiques de métal alcalino-terreux, d'acides organiques, de glucides, de silicates, de l'urée et de mélanges de ceux-ci.
- Composition odorante solide selon la revendication 1 ou la revendication 2, caractérisée en ce que la quantité de véhicule hydrosoluble atteint une valeur de 50 à 99 % en poids, de préférence de 75 à 95 % en poids, rapporté respectivement à la composition odorante solide totale.
- Composition odorante solide selon l'une des revendications 1 à 3, caractérisée en ce que la composition odorante solide comprend en outre un ingrédient sélectionné dans le groupe des composés de soin des textiles, des colorants, des charges, des agents nacrants, des composés de soin de la peau et de mélanges de ceux-ci.
- Composition odorante solide selon l'une des revendications 1 à 4, caractérisée en ce que le composé de soin des textiles est sélectionné parmi des agents de blanchiment, des activateurs de blanchiment, des enzymes, des huiles siliconées, des agents d'antiredéposition, des azurants optiques, des inhibiteurs de grisaillement, des agents anti-rétrécissement, des agents d'infroissabilité, des inhibiteurs de transfert de couleur, des agents actifs antimicrobiens, des germicides, des fongicides, des antioxydants, des agents antistatiques, des auxiliaires de repassage, des agents hydrofuges et d'imprégnation, des agents antigonflement et antiglissants, des absorbeurs d'UV ainsi que des mélanges de ceux-ci.
- Composition odorante solide selon la revendication 1, caractérisée en ce que le composé adoucissant des textiles est sélectionné parmi des composés d'ammonium quaternaire, des polysiloxanes, des argiles adoucissant les textiles, des polymères cationiques et des mélanges de ceux-ci.
- Composition odorante solide selon l'une des revendications 1 à 6, caractérisée en ce que le saccharide est le saccharose.
- Composition odorante solide selon l'une des revendications 1 à 7, caractérisée en ce que la quantité de parfum atteint une valeur de 0,1 à 20 % en poids, de préférence de 1 à 10 % en poids et de manière particulièrement préférée de 2 à 7 % en poids.
- Composition odorante solide selon la revendication 1, caractérisée en ce qu'en plus du composé de soin des textiles est présent un polysaccharide au moins en partie dans et/ou au moins en partie sur l'enveloppe.
- Composition odorante solide selon l'une des revendications 1 à 9, caractérisée en ce que le véhicule hydrosoluble présente des tailles de particule comprises dans la gamme allant de 0,6 à 30 mm, en particulier de 0,8 à 7 mm et de manière particulièrement préférée de 1 à 3 mm.
- Utilisation de la composition solide selon l'une des revendications 1 à 10 pour le conditionnement de tissus textiles.
- Procédé pour la réalisation d'une composition odorante solide, comprenant un véhicule particulaire hydrosoluble, un parfum, un composé de soin des textiles, lequel comprend un composé adoucissant les textiles, et une enveloppe au moins partielle à base d'un saccharide, dans lequel le saccharide est sélectionné dans le groupe des monosaccharides, des oligosaccharides et de mélanges de ceux-ci, dans lequel le véhicule hydrosoluble est exposé au parfum, le saccharide est fondu et est fourni sur le véhicule particulaire de telle sorte que celui-ci soit au moins en partie enveloppé et dans lequel le composé de soin des textiles est pulvérulent et est présent au moins en partie dans l'enveloppe avec le saccharide ou l'enveloppe est revêtue après la solidification avec le composé de soin des textiles.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL10730763T PL2454358T3 (pl) | 2009-07-16 | 2010-07-02 | Stały, zapach przekazujący zestaw o dobrej rozpuszczalności w zimnej wodzie |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102009027756A DE102009027756A1 (de) | 2009-07-16 | 2009-07-16 | Feste, Duft-vermittelnde Zusammensetzung mit guter Kaltwasserlöslichkeit |
| PCT/EP2010/059464 WO2011006779A1 (fr) | 2009-07-16 | 2010-07-02 | Composition solide parfumée à bonne solubilité dans l'eau froide |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP2454358A1 EP2454358A1 (fr) | 2012-05-23 |
| EP2454358B1 true EP2454358B1 (fr) | 2017-01-18 |
Family
ID=42827364
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP10730763.9A Not-in-force EP2454358B1 (fr) | 2009-07-16 | 2010-07-02 | Composition solide parfumée à bonne solubilité dans l'eau froide |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US20120114720A1 (fr) |
| EP (1) | EP2454358B1 (fr) |
| DE (1) | DE102009027756A1 (fr) |
| ES (1) | ES2621462T3 (fr) |
| HU (1) | HUE032755T2 (fr) |
| PL (1) | PL2454358T3 (fr) |
| WO (1) | WO2011006779A1 (fr) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102017218992A1 (de) * | 2017-10-24 | 2019-04-25 | Henkel Ag & Co. Kgaa | Feste parfümhaltige Zusammensetzung |
| EP3743494B1 (fr) | 2018-01-26 | 2025-08-06 | Ecolab Usa Inc. | Tensioactif liquide solidifié à base d'oxyde d'amine avec un liant comprenant de l'urée et un support optionnel |
| WO2019148071A1 (fr) | 2018-01-26 | 2019-08-01 | Ecolab Usa Inc. | Tensioactifs anioniques liquides solidifiants |
| CA3089629A1 (fr) | 2018-01-26 | 2019-08-01 | Ecolab Usa Inc. | Solidification de tensioactifs liquides d'oxyde d'amine, de betaine et/ou de sultaine ayant un vehicule |
| BR112022022718A2 (pt) * | 2020-06-23 | 2023-02-23 | Unilever Ip Holdings B V | Composição para lavagem de roupas, método de formação de partículas e uso de uma composição |
| DE102022214278A1 (de) | 2022-12-22 | 2024-06-27 | Henkel Ag & Co. Kgaa | Feste Nachfüllportion einer Weichspülzusammensetzung |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010112345A1 (fr) * | 2009-03-31 | 2010-10-07 | Henkel Ag & Co. Kgaa | Système de libération de parfum, pour utilisation dans un séchoir |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9422924D0 (en) * | 1994-11-14 | 1995-01-04 | Unilever Plc | Detergent compositions |
| EP0859828B2 (fr) * | 1995-09-18 | 2006-06-14 | The Procter & Gamble Company | Systemes de liberation |
| WO2003000625A2 (fr) * | 2001-06-22 | 2003-01-03 | Genencor International, Inc. | Granules a grande resistance au choc |
| GB0315946D0 (en) * | 2003-07-08 | 2003-08-13 | Quest Int | Fabric freshener compositions |
| DE102004020400A1 (de) * | 2004-04-23 | 2005-11-17 | Henkel Kgaa | Parfümierte Feststoffe |
| DE102006016578A1 (de) | 2006-04-06 | 2007-10-11 | Henkel Kgaa | Feste, Textil-weichmachende Zusammensetzung mit einem wasserlöslichen Polymer |
-
2009
- 2009-07-16 DE DE102009027756A patent/DE102009027756A1/de not_active Withdrawn
-
2010
- 2010-07-02 PL PL10730763T patent/PL2454358T3/pl unknown
- 2010-07-02 WO PCT/EP2010/059464 patent/WO2011006779A1/fr not_active Ceased
- 2010-07-02 ES ES10730763.9T patent/ES2621462T3/es active Active
- 2010-07-02 HU HUE10730763A patent/HUE032755T2/en unknown
- 2010-07-02 EP EP10730763.9A patent/EP2454358B1/fr not_active Not-in-force
-
2012
- 2012-01-13 US US13/349,752 patent/US20120114720A1/en not_active Abandoned
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010112345A1 (fr) * | 2009-03-31 | 2010-10-07 | Henkel Ag & Co. Kgaa | Système de libération de parfum, pour utilisation dans un séchoir |
Also Published As
| Publication number | Publication date |
|---|---|
| DE102009027756A1 (de) | 2011-01-20 |
| HUE032755T2 (en) | 2017-10-30 |
| EP2454358A1 (fr) | 2012-05-23 |
| WO2011006779A1 (fr) | 2011-01-20 |
| US20120114720A1 (en) | 2012-05-10 |
| ES2621462T3 (es) | 2017-07-04 |
| PL2454358T3 (pl) | 2017-07-31 |
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