EP2562502A1 - Procédé et installation pour la fourniture d'un monoxyde de carbone gazeux par distillation cryogénique - Google Patents

Procédé et installation pour la fourniture d'un monoxyde de carbone gazeux par distillation cryogénique Download PDF

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Publication number
EP2562502A1
EP2562502A1 EP11306060A EP11306060A EP2562502A1 EP 2562502 A1 EP2562502 A1 EP 2562502A1 EP 11306060 A EP11306060 A EP 11306060A EP 11306060 A EP11306060 A EP 11306060A EP 2562502 A1 EP2562502 A1 EP 2562502A1
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EP
European Patent Office
Prior art keywords
carbon monoxide
liquefied
product
separation unit
conduit
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP11306060A
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German (de)
English (en)
Inventor
Emmanuelle BROCHERIOU
Bhadri PRASAD
Audrey RIVOAL
Marie-Pascal Victor
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Original Assignee
Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Air Liquide SA, LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude filed Critical Air Liquide SA
Priority to EP11306060A priority Critical patent/EP2562502A1/fr
Priority to PCT/EP2012/062020 priority patent/WO2012175635A2/fr
Priority to CN201280030991.7A priority patent/CN104011488B/zh
Publication of EP2562502A1 publication Critical patent/EP2562502A1/fr
Withdrawn legal-status Critical Current

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    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0204—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the feed stream
    • F25J3/0223—H2/CO mixtures, i.e. synthesis gas; Water gas or shifted synthesis gas
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0228—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
    • F25J3/0233—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of CnHm with 1 carbon atom or more
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0228—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
    • F25J3/0252—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of hydrogen
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0228—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
    • F25J3/0257—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of nitrogen
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0228—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
    • F25J3/0261—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of carbon monoxide
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2200/00—Processes or apparatus using separation by rectification
    • F25J2200/40—Features relating to the provision of boil-up in the bottom of a column
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2200/00—Processes or apparatus using separation by rectification
    • F25J2200/70—Refluxing the column with a condensed part of the feed stream, i.e. fractionator top is stripped or self-rectified
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2200/00—Processes or apparatus using separation by rectification
    • F25J2200/76—Refluxing the column with condensed overhead gas being cycled in a quasi-closed loop refrigeration cycle
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2205/00—Processes or apparatus using other separation and/or other processing means
    • F25J2205/30—Processes or apparatus using other separation and/or other processing means using a washing, e.g. "scrubbing" or bubble column for purification purposes
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2215/00—Processes characterised by the type or other details of the product stream
    • F25J2215/04—Recovery of liquid products
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2250/00—Details related to the use of reboiler-condensers
    • F25J2250/30—External or auxiliary boiler-condenser in general, e.g. without a specified fluid or one fluid is not a primary air component or an intermediate fluid
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2270/00—Refrigeration techniques used
    • F25J2270/02—Internal refrigeration with liquid vaporising loop
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2270/00—Refrigeration techniques used
    • F25J2270/04—Internal refrigeration with work-producing gas expansion loop
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2270/00—Refrigeration techniques used
    • F25J2270/08—Internal refrigeration by flash gas recovery loop
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2270/00—Refrigeration techniques used
    • F25J2270/24—Quasi-closed internal or closed external carbon monoxide refrigeration cycle
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2280/00—Control of the process or apparatus
    • F25J2280/02—Control in general, load changes, different modes ("runs"), measurements
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2280/00—Control of the process or apparatus
    • F25J2280/20—Control for stopping, deriming or defrosting after an emergency shut-down of the installation or for back up system

Definitions

  • This invention concerns processes and installations for providing gaseous carbon monoxide by cryogenic distillation.
  • it concerns the supply of carbon monoxide by vaporisation of liquid carbon monoxide when an industrial installation, such as a separation unit, requires a rapidly increasing amount of gaseous carbon monoxide product.
  • the CO liquid is removed before expansion and vaporized at the desired pressure (for example, that of the client's network).
  • the amount of gaseous carbon monoxide produced can increase by at least 1 % per minute.
  • an installation for supplying gaseous carbon monoxide by cryogenic distillation including:
  • Optional features include:
  • Figure 1 shows an apparatus for separating a mixture containing principally methane, carbon monoxide and hydrogen.
  • the mixture may also contain small amounts of nitrogen, carbon dioxide, humidity, higher hydrocarbons, methanol, etc.
  • This mixture is generally synthesis gas produced by a partial oxidation unit, a steam methane reformer, an auto thermal reformer, gasifier or any combination of these process schemes.
  • the mixture 1 is purified in a front end purification unit to remove impurities. Then the mixture is cooled to a cryogenic temperature in heat exchangers 3, 5 and sent to the bottom of a methane wash column 7 operating at a pressure between 10 and 60 bars. A methane wash stream 9 is fed to the top of column 7 and a hydrogen enriched stream 11 is removed from the top of the column. From the bottom of the column is removed a liquid stream 13 enriched in carbon monoxide.
  • Stream 13 is further treated before being sent to the stripping column 19 which operates at between 4 and 17 bars, at least one feed stream formed from stream 13 being sent to the top of stripping column 19. Alternatively if a methane stream is fed to the top of stripping column 19, the feed stream is fed thereto at a lower point.
  • the gas 21 from the top of the stripping column is warmed in the exchangers 5,3 and is used as fuel or burnt.
  • the liquid stream 23 from the bottom of the stripping column 19 is divided in two and may be further treated before being sent to the column 27. In particular, several feeds (liquid, dual phase, gaseous, in this case two liquid streams) at different levels may be provided to the column 27. Column 27 operates at between 1 and 10 bars, often around 2.5 bars.
  • methane rich liquid 29 at the bottom of the column and a carbon monoxide rich gas 31 at the top of the column.
  • Part of the methane rich liquid is pumped by pump 33 and sent to the top of the methane wash column 7 and the rest is removed as a purge stream.
  • the two portions of the methane rich liquid may be removed separately from the column.
  • the methane rich liquid is pumped by pump 33 and sent in part to the top of the methane wash column 7 and the remaining purge stream is warmed in heat exchangers 5, 3.
  • the carbon monoxide rich product stream 31 removed from the top of column 27 is warmed in a heat exchanger 52 and then in heat exchanger 3, compressed in a compressor 35 and is removed as a compressed product gas 37.
  • Refrigeration for the system is provided by a carbon monoxide cycle of which the compressor 35 forms part.
  • the carbon monoxide is compressed in compressor 35 to a pressure of between 10 and 60 bars.
  • Part of the compressed carbon monoxide 39 is further compressed in compressor 35A, then cooled in exchanger 3 to an intermediate temperature of the exchanger and then expanded in turbine 41.
  • the expanded carbon monoxide gas is warmed in the exchanger 3 and recycled to the compressor 35 at the entry thereof or an intermediate pressure thereof.
  • the unexpanded carbon monoxide 43 is divided into three parts, two of which, namely parts 51, 53, serve to reboil columns 9 and 11. Part 51 is sent to reboiler 55 of column 19 and part 53 is sent to the reboiler 57 of column 27.
  • Stream 53 is entirely sent to top condenser and/or CO liquid storage capacity 47 of column 27 via open expansion valve V3. During normal operation, all of stream 51 is also sent to top condenser and/or CO liquid storage capacity 47 via open expansion valve V2, valve V1 being closed.
  • the top condenser and/or CO storage liquid capacity 47 forms an integral part of the column 27 and additionally serves to provide reflux to the top of column 27 and to supply liquid carbon monoxide to cool an intermediate reboiler 49 of the methane wash column 7.
  • a further part 59 of the unexpanded carbon monoxide 43 is cooled in exchangers 3, 5 and sent to the top condenser or storage 47 via expansion valve V5.
  • part 59A of the carbon monoxide is sent via open valve V6, which is not an expansion valve, to vaporiser 54, replacing at least one of streams 51, 53 or in addition to at least one of these streams.
  • part 51A or all of the liquid 51 may be vaporised in a vaporiser 54 upstream of the top condenser and/or CO liquid capacity 47 by opening valve V1 and at least partially closing valve V2. Since valve is not an expansion valve, the carbon monoxide stream sent to vaporiser 54 is produced substantially at the outlet pressure of compressor 35A, less the pressure drop in the conduits.
  • the vaporiser 54 may either allow heat exchange with ambient air, water or steam if it is outside the cold box or may be within the cold box and may be constituted by the exchanger 5 or another heat exchanger.
  • the vaporised carbon monoxide produced 55 is sent to a point downstream of the compressor 35 to form part of the product gas 37.
  • valve V4 which is not an expansion valve and by at least partially closing valve V3 to allow stream 53A to flow to the vaporiser 54.
  • the liquid to be vaporised 51, 53 is available at high pressure, ie a pressure higher than that of condenser (or storage) 47, the gas produced, by vaporisation in vaporiser 54, can be directly mixed with the product gas 37.
  • Gaseous and liquid carbon monoxide are defined to be respectively a gas and a liquid containing at least 85% carbon monoxide, preferably at least 95% carbon monoxide.
  • cryogenic separation processes for mixtures containing carbon monoxide and at least one of hydrogen, nitrogen and methane as principal components, for example processes to separate mixtures of hydrogen, carbon monoxide and methane such as the partial condensation process or processes for separating mixtures containing carbon monoxide and nitrogen only as principal components or processes including a nitrogen wash unit.

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Separation By Low-Temperature Treatments (AREA)
EP11306060A 2011-06-24 2011-08-23 Procédé et installation pour la fourniture d'un monoxyde de carbone gazeux par distillation cryogénique Withdrawn EP2562502A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP11306060A EP2562502A1 (fr) 2011-06-24 2011-08-23 Procédé et installation pour la fourniture d'un monoxyde de carbone gazeux par distillation cryogénique
PCT/EP2012/062020 WO2012175635A2 (fr) 2011-06-24 2012-06-21 Procédé et installation de production d'oxyde carbonique gazeux par distillation cryogénique
CN201280030991.7A CN104011488B (zh) 2011-06-24 2012-06-21 通过低温蒸馏供应气态一氧化碳的方法和设备

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IN1810DE2011 2011-06-24
EP11306060A EP2562502A1 (fr) 2011-06-24 2011-08-23 Procédé et installation pour la fourniture d'un monoxyde de carbone gazeux par distillation cryogénique

Publications (1)

Publication Number Publication Date
EP2562502A1 true EP2562502A1 (fr) 2013-02-27

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EP11306060A Withdrawn EP2562502A1 (fr) 2011-06-24 2011-08-23 Procédé et installation pour la fourniture d'un monoxyde de carbone gazeux par distillation cryogénique

Country Status (3)

Country Link
EP (1) EP2562502A1 (fr)
CN (1) CN104011488B (fr)
WO (1) WO2012175635A2 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3133665A1 (fr) * 2022-03-21 2023-09-22 L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Procédé et appareil de séparation d’un mélange de monoxyde de carbone, de méthane et d’hydrogène

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3084453B1 (fr) * 2018-07-25 2020-11-27 Air Liquide Procede et appareil de separation cryogenique d'un melange de monoxyde de carbone, d'hydrogene et de methane pour la production de ch4

Citations (5)

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Publication number Priority date Publication date Assignee Title
DE3631332A1 (de) * 1986-09-15 1988-03-24 Linde Ag Verfahren zur verarbeitung eines brenn- oder synthesegases
JPS63163771A (ja) * 1986-12-26 1988-07-07 大同ほくさん株式会社 一酸化炭素分離精製装置
EP1245533A1 (fr) 2001-03-21 2002-10-02 L'air Liquide, S.A. à Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procédés Georges Claude Procédé et dispositif pour le traitement de gaz de synthèse et de gaz apparentés
EP1479989A1 (fr) 2003-05-19 2004-11-24 L'Air Liquide S. A. à Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procédés Georges Claude Procédé et installation pour la production de monoxyde de carbone gazeux et/ou d'un mélange contenant de monoxyde de carbone
DE102005003497A1 (de) * 2005-01-25 2006-07-27 Linde Ag Verfahren und Vorrichtung zur Zwischenspeicherung von Kohlenmonoxid in Synthesegasanlagen

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Publication number Priority date Publication date Assignee Title
FR2775275B1 (fr) * 1998-02-20 2000-05-19 Air Liquide Procede et installation pour la production combinee d'un melange de synthese d'ammoniac et de monoxyde de carbone
FR2847568B1 (fr) * 2002-11-25 2005-02-11 Air Liquide Procede et installation de production d'un melange krypton/xenon a partir d'air
FR2861165B1 (fr) * 2003-10-20 2005-12-16 Air Liquide Procede et appareil pour la production de monoxyde de carbone et/ou d'hydrogene et/ou d'un melange d'hydrogene et de monoxyde de carbone par distillation cryogenique
FR2910602B1 (fr) * 2006-12-21 2012-12-14 Air Liquide Procede et appareil de separation d'un melange comprenant au moins de l'hydrogene, de l'azote et du monoxyde de carbone par distillation cryogenique
FR2916523B1 (fr) * 2007-05-21 2014-12-12 Air Liquide Capacite de stockage, appareil et procede de production de monoxyde de carbone et/ou d'hydrogene par separation cryogenique integrant une telle capacite.

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3631332A1 (de) * 1986-09-15 1988-03-24 Linde Ag Verfahren zur verarbeitung eines brenn- oder synthesegases
JPS63163771A (ja) * 1986-12-26 1988-07-07 大同ほくさん株式会社 一酸化炭素分離精製装置
EP1245533A1 (fr) 2001-03-21 2002-10-02 L'air Liquide, S.A. à Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procédés Georges Claude Procédé et dispositif pour le traitement de gaz de synthèse et de gaz apparentés
EP1479989A1 (fr) 2003-05-19 2004-11-24 L'Air Liquide S. A. à Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procédés Georges Claude Procédé et installation pour la production de monoxyde de carbone gazeux et/ou d'un mélange contenant de monoxyde de carbone
DE102005003497A1 (de) * 2005-01-25 2006-07-27 Linde Ag Verfahren und Vorrichtung zur Zwischenspeicherung von Kohlenmonoxid in Synthesegasanlagen

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3133665A1 (fr) * 2022-03-21 2023-09-22 L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Procédé et appareil de séparation d’un mélange de monoxyde de carbone, de méthane et d’hydrogène
EP4249837A1 (fr) * 2022-03-21 2023-09-27 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Procédé de remplacement d'un premier appareil de séparation d'un mélange de monoxyde de carbone, de méthane et d'hydrogène

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WO2012175635A2 (fr) 2012-12-27
WO2012175635A3 (fr) 2015-08-20
CN104011488B (zh) 2016-03-02

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