EP2578202A2 - Metalllegierung zur fusion zahnärztlicher keramikartikel und zahnprothese - Google Patents

Metalllegierung zur fusion zahnärztlicher keramikartikel und zahnprothese Download PDF

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EP2578202A2
EP2578202A2 EP11786922.2A EP11786922A EP2578202A2 EP 2578202 A2 EP2578202 A2 EP 2578202A2 EP 11786922 A EP11786922 A EP 11786922A EP 2578202 A2 EP2578202 A2 EP 2578202A2
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weight
content
metal alloy
smaller
equal
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French (fr)
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Hyung-Seok Park
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Priority claimed from KR1020100117307A external-priority patent/KR101254289B1/ko
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61C—DENTISTRY; APPARATUS OR METHODS FOR ORAL OR DENTAL HYGIENE
    • A61C8/00—Means to be fixed to the jaw-bone for consolidating natural teeth or for fixing dental prostheses thereon; Dental implants; Implanting tools
    • A61C8/0012—Means to be fixed to the jaw-bone for consolidating natural teeth or for fixing dental prostheses thereon; Dental implants; Implanting tools characterised by the material or composition, e.g. ceramics, surface layer, metal alloy
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
    • A61K6/84—Preparations for artificial teeth, for filling teeth or for capping teeth comprising metals or alloys
    • A61K6/844—Noble metals
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C5/00—Alloys based on noble metals
    • C22C5/04—Alloys based on a platinum group metal
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/14—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of noble metals or alloys based thereon

Definitions

  • the present invention relates to metal alloys, and in particular, to metal alloys for dental porcelain fusing that is used in prosthetic appliance in dental clinics and dental prosthetic appliances using the same.
  • Metal alloys for dental porcelain fusing are used in mouths where various environmental changes of temperature, acidity, pressure, or the like in human bodies occur. Accordingly, they require not only excellent mechanical properties but also chemical stability and aesthetic appreciation. For example, since metal alloys for dental porcelain fusing are used in mouths, they should not corrode or discolor, and also should not be harmful for human bodies. In addition, since metal alloys for dental porcelain fusing endure a pressure caused by chewing food, they are required to have high mechanical properties.
  • gold-based alloys with high gold content are widely used for fusing with porcelain.
  • gold-based alloys are expensive.
  • alternative alloys that have similar properties to those of gold-based alloys and high economic properties are being developed. For example, a gold-palladium alloy, a silver-palladium alloy, a nickel-chromium alloy, or the like are being studied.
  • a dental metal alloy for dental porcelain fusing includes: gold (Au) in a content that is greater than 0 and equal to or smaller than 35 weight%; silver (Ag) in a content of 5 to 35 weight%; indium (In) in a content of 6 to 40 weight%; palladium (Pd) in a content of 30 to 70 weight%; and at least one element selected from the group consisting of boron (B), germanium (Ge), zirconium (Zr), silicon (Si) and iron (Fe) in a total content that is greater than 0 and equal to or smaller than 5.0 weight%.
  • the metal alloy may further include at least one element selected from the group consisting of zinc (Zn), tin (Sn), gallium (Ga), selenium (Se), carbon (C), antimony (Sb), and copper (Cu) in a total content of greater than 0 and equal to or smaller than 10.0%.
  • the metal alloy may further include at least one element selected from the group consisting of iridium (Ir), rhenium (Re), rhodium (Rh), ruthenium (Ru), lanthanum (La), osmium (Os), and bismuth (Bi) in a total content of greater than 0 and equal to or smaller than 2 weight%.
  • the metal alloy may further include at least one element selected from the group consisting of chromium (Cr), niobium (Nb), magnesium (Mg), titanium (Ti), cobalt (Co), aluminum (Al), vanadium (V), tantalum (Ta), molybdenum (Mo) and tungsten (W) in a total content of greater than 0 and equal to or smaller than 10.0 weight%.
  • a dental metal alloy for dental porcelain fusing includes: gold (Au) in a content that is greater than 0 and equal to or smaller than 35 weight%; silver (Ag) in a content of 5 to 35 weight%; indium (In) in a content of 12.0 to 35.0 weight%; at least one element selected from the group consisting of zinc (Zn), tin (Sn), gallium (Ga), selenium (Se), carbon (C), antimony (Sb), and copper (Cu) in a total content of greater than 0 and equal to or smaller than 10.0 weight%; at least one element selected from the group consisting of boron(B), germanium (Ge), zirconium (Zr), silicon (Si) and iron (Fe) in a total content of greater than 0 and equal to or smaller than 10.0 weight%; at least one element selected from the group consisting of chromium (Cr), niobium (Nb), magnesium (Mg), titanium (Ti), cobalt
  • indium may have a content of 12.0 to 26.0 weight%, and a melting point of 1030 to 1200°C.
  • indium (In) has a content of 20.3 to 30.0 weight%, and a melting point of 920 to 1040°C.
  • a metal alloy for dental porcelain fusing includes: gold (Au) in a content that is greater than 0 and equal to or smaller than 85 weight%; silver (Ag) in a content that is greater than 0 and equal to or smaller than 35 weight%; indium (In) in a content of 6 to 40 weight%; palladium (Pd) in a content of 5 to 70 weight%; at least one first element selected from the group consisting of boron (B), germanium (Ge), zirconium (Zr), silicon (Si) and iron (Fe) in a total content that is greater than 0 and equal to or smaller than 5.0 weight%; and at least one second element selected from the group consisting of chromium (Cr), niobium (Nb), magnesium (Mg), titanium (Ti), cobalt (Co), aluminum (Al), vanadium (V), tantalum (Ta), molybdenum (Mo) and tungsten (W) in a total content of
  • the at least one element may include silicon (Si) in a content that is greater than 0 and smaller than 1.0 weight%, and/or the at least one second element includes cobalt (Co) in a content of 0 to 5.0 weight%.
  • a calcination temperature of the metal alloy and ceramic porcelain is in a range of 900 to 980 °C.
  • the metal alloy may further include at least one third element selected from the group consisting of zinc (Zn), tin (Sn), gallium (Ga), selenium (Se), carbon (C), antimony (Sb), and copper (Cu) in a total content that is greater than 0 and equal to or smaller than 10.0 weight%.
  • the at least one element may include silicon (Si) in a content that is greater than 0 and smaller than 1.0 weight%
  • the at least one second element may include cobalt (Co) in a content of 0 to 5.0 weight%
  • at least one third element may include a copper (Cu) in a content that is greater than 0 and equal to or smaller than 5.0 weight%.
  • a dental prosthetic appliance may be manufactured by using at least one of the dental metal alloys described above.
  • a method of manufacturing a dental prosthetic appliance may include providing the dental metal alloy; pretreating the metal alloy to remove a metal oxide on a surface thereof; and fusing ceramic porcelain on the metal alloy at a calcination temperature range of 900 to 980°C.
  • Metal alloys for dental porcelain fusing according to some embodiments of the present invention have high economic properties due to high palladium and indium contents, and also have excellent mechanical properties, chemical stability, and high in-vivo compatibility due to the inclusion of other additional elements
  • Metal alloys for dental porcelain fusing have an appropriately controlled alloy component ratio of a palladium-indium-gold-silver based alloy, and thus, when calcined at high temperature with ceramic porcelain, deformation of the alloy may be prevented.
  • weight% is a percentage point of the weight of a component based on a total weight of the entire alloy.
  • ranges with respect to weight% when the expressions of 'greater than or smaller than' are used, a boundary value of a set range is not included, and when only the expression of 'range' is used, or the expression of 'equal to or greater than, or equal to or smaller than' are used, the boundary value of the range is included.
  • inevitable impurities may indicate typical impurities that may be introduced without any intension during metal alloys or prosthetic appliances are manufactured.
  • a dental metal alloy for dental porcelain fusing may be formed by mixing palladium (Pd) with gold (Au), silver (Ag), and a first adding element.
  • Palladium is a major element and may be provided as an alternative to gold and platinum, and is known as being harmless to human bodies.
  • a content of palladium may vary according to contents of gold, silver, and adding elements, and palladium may be selected together with gold, silver, and adding elements to exert appropriate performance of alloys for dental porcelain fusing. For example, for a decrease in costs, palladium may occupy the residual of an alloy and may be included in a range of 30 to 70 weight%.
  • a content of palladium may be 5% or more.
  • the metal alloy for dental porcelain fusing may include inevitable impurities that are originated from impurities of the elements or introduced without any intension in preparing alloys.
  • Gold may be added to improve erosion resistance, discoloration resistance, and elongation, and the content thereof may vary according to other elements, for example, the palladium content, and is not particularly limited. However, if a competitive price is required, the gold content may be restricted to 40 weight%, in particular, 35 weight% or less. In particular, when an alternative element content is high, the gold content may be restricted to 25 weight% or lower. In addition, a part of the gold may be replaced with platinum (Pt). In this case, a total content of gold and platinum may be 35 weight% or lower. Furthermore, platinum is expensive and has a high melting point, the platinum content in an alloy for molding may be restricted to 20 weight% or lower. However, if a competitive price is not required, the palladium content may be reduced and the gold content may be increased to about 85%.
  • Silver (Ag) may be added together with palladium to prevent formation of discolored product, fractures, hydrogen embrittlement, or a decrease in molding properties (greater than 0%). Furthermore, silver may be added in a content of at least 5 weight% to prevent formation of discolored structure and to improve elongation, and in consideration of yellowing, the silver content may be restricted to 35 weight% or lower. Under strict conditions, the silver content may be restricted to a range of 13 to 31 weight% to maintain the color of the alloy.
  • Indium (In) may be added to increase a binding force with porcelain and retain aesthetic appreciation.
  • a minimum indium content may be 3 weight%.
  • the alloy may be light yellow and a greater indium content leads to stronger yellow.
  • the greater indium content the alloy has a lower melting point and a higher thermal expansion coefficient. Accordingly, the indium content is restricted to 40% or lower, and may be appropriately determined according to the calcination temperature of the alloy.
  • the indium content may be further restricted to 35 weight% or less.
  • the calcination temperature range may vary according to ceramic powder. Roughly, a low temperature calcinations indicates a calcination temperature of about 800°C or lower, and a high temperature calcination indicates a calcination temperature of about 900 to 980°C.
  • the first adding element may include at least one element selected from the group consisting of boron (B), germanium (Ge), zirconium (Zr), silicon (Si) and iron (Fe).
  • the first adding element may offset a decrease in melting point and an increase in thermal expansion coefficient of the alloy due to the increased indium content.
  • the first adding element content may be in a range of 0.1 weight% to 10.0 weight% in consideration of an excess increase in melting point of the alloy and an excess decrease in thermal expansion coefficient of the alloy, and under strict conditions, the first adding element content may be restricted to 6.0 weight% or lower to suppress formation of an oxide, such as borax, and the oxide-induced discoloration of the alloy.
  • a dental metal alloy for dental porcelain fusing according to another embodiment of the present invention may be formed by mixing palladium (Pd) with gold (Au), silver (Ag), the first adding element, and a second adding element.
  • the metal alloy for dental porcelain fusing may include inevitable impurities that are originated from impurities of the elements or introduced without any intension in preparing alloys.
  • palladium (Pd), gold (Au), silver (Ag) and the first adding element will not described in detail herein because their description have been already presented above.
  • the metal alloy may further include at least one element selected from the group consisting of chromium (Cr), niobium (Nb), magnesium (Mg), titanium (Ti), cobalt (Co), aluminum (Al), vanadium (V), tantalum (Ta), molybdenum (Mo) and tungsten (W) in a total content of greater than 0 and equal to or smaller than 10.0 weight%.
  • the second adding element may offset a decrease in melting point and an increase in thermal expansion coefficient of the alloy due to the increased indium content.
  • the second adding element may allow the indium content to increase in the alloy, the alloy may be more distinctive yellow.
  • the second adding element may suppress an increase in deformation due to the increased indium content when the metal alloy is calcined with ceramic porcelain.
  • the indium contained in metal alloy may flow down together with ceramic porcelain when high temperature calcination is performed thereon with ceramic porcelain.
  • the metal alloy may be inappropriate for high temperature calcination.
  • the second adding element is combined with indium so that deformation of indium is suppressed during high temperature calcination, the indium content in metal alloy for high temperature calcination may increase.
  • the second adding element may be included in a content of 0.1 weight% or more to suppress deformation of indium.
  • the second adding element may be more strongly required as the calcination temperature increases.
  • the second adding element content may be restricted to 10.0 weight% or less.
  • the second adding element content may be restricted to 5.0 weight% or less.
  • a dental metal alloy for dental porcelain fusing according to another embodiment of the present invention may be formed by mixing palladium (Pd) with gold (Au), silver (Ag), the first adding element, and a third adding element.
  • the metal alloy for dental porcelain fusing may include inevitable impurities that are originated from impurities of the elements or introduced without any intension in preparing alloys.
  • palladium (Pd), gold (Au), silver (Ag) and the first adding element will not described in detail herein because their description have been already presented above.
  • the third adding element may include at least one element selected from the group consisting of zinc (Zn), tin (Sn), gallium (Ga), selenium (Se), carbon (C), antimony (Sb), and copper (Cu).
  • the third adding element may be added to preserve effects of an element that inhibits the embodiment of yellow alloy due to indium, for example, the second adding element. Furthermore, the third adding element may prevent discoloration of the first adding element.
  • the third adding element content increases, molding properties of the alloy may decrease, cytotoxicity may increase, a melting point may decrease, and an erosion resistance may decrease. Accordingly, a content of the third adding element may be restricted to 10.0 weight% or lower, and in the case of copper, to 5.0 weight% or lower.
  • a dental metal alloy for dental porcelain fusing according to another embodiment of the present invention may be formed by mixing palladium (Pd) with gold (Au), silver (Ag), the first adding element, and a fourth adding element.
  • the metal alloy for dental porcelain fusing may include inevitable impurities that are originated from impurities of the elements or introduced without any intension in preparing alloys.
  • palladium (Pd), gold (Au), silver (Ag) and the first adding element will not described in detail herein because their description have been already presented above.
  • the fourth adding element may include at least one element selected from the group consisting of iridium (Ir), rhenium (Re), rhodium (Rh), ruthenium (Ru), lanthanum (La), osmium (Os), and bismuth (Bi) in a total content of greater than 0 and equal to or smaller than 2 weight%.
  • the fourth adding element may improve molding properties, or may contribute grain refinement of the alloy, thereby increasing rigidity thereof. Accordingly, the fourth adding element content needs to be controlled in consideration of these properties. For example, when the fourth adding element content is greater than 2 weight%, the grain refinement effects may decrease. Accordingly, the fourth adding element content needs to be controlled to be 2 weight% or less.
  • a dental metal alloy for dental porcelain fusing according to another embodiment of the present invention may be formed by mixing palladium (Pd) with gold (Au), silver (Ag), the first adding element, and additionally, two or more of the second through fourth adding elements.
  • the metal alloy for dental porcelain fusing may include inevitable impurities that are originated from impurities of the elements or introduced without any intension in preparing alloys. Functions of the respective elements may be understood by referring to corresponding descriptions in the embodiments above.
  • the metal alloys for dental porcelain fusing according to embodiments of the present include lower expensive gold and platinum contents and instead, higher palladium and indium contents, and thus, have high price competitiveness.
  • excellent mechanical properties, chemical stability, and high in vivo compatibility may be obtained.
  • a dental prosthetic appliance according to an embodiment of the present invention may be prepared by using such metal alloys for dental porcelain fusing.
  • a dental prosthetic appliance may be formed by attaching ceramic porcelain onto such metal alloys.
  • a dental prosthetic appliance formed as described above may have not only excellent mechanical and chemical properties of the metal alloy and but also aesthetic appreciation of the ceramic porcelain, and thus, have high marketability.
  • Comparative Example and Experimental Examples are provided to promote understanding of the present invention.
  • Comparative Examples and Experimental Examples are presented for illustrative purpose only, and do not limit the scope of the present invention.
  • the inventors of the present application paid attention to a palladium-indium-based alloy as an alternative to expensive gold and platinum.
  • Table 1 shows composition ratios and physical properties of the palladium-indium-based alloy prepared according to Experimental Example I. Samples shown in Table 1 were prepared as follows: alloy components were dissolved and then injected into a graphite mold to form a mold product, and the mold product was extended by using a roller and then imprinted and cut to produce samples.
  • the greater indium content the lower melting point of the alloy. This is because the melting point of indium is much lower than those of gold and silver.
  • a melting point of the metal alloy for dental porcelain fusing needs to be 920°C or more, and accordingly, the indium content may be restricted to 40 weight% or less.
  • the indium content needs to be 6 weight% or more, and in particular to obtain more dark yellow, the indium content may be maintained to be 12 weight% or more.
  • the indium was added in a content range of 12 to 40 weight%.
  • Table 2 shows the alloy composition (weight%) and physical properties of Experimental Examples according to the present invention.
  • Experimental Example II Alloy element Physical characteristics Au Pd Ag Zn In Si Ge Zr Co Thermal expansion coefficient (10 -6 K -1 ) 1 10 45 17.5 0.5 27 0 16.96 2 10 45 17 0.5 27 0.5 14.90 3 10 45 16.5 0.5 27 1 12.94 4 10 45 15.5 0.5 27 2 8.80 5 10 45 17.5 0.5 27 0 16.96 6 10 45 17 0.5 27 0.5 16.04 7 10 45 16.5 0.5 27 1 15.13 8 10 45 15.5 0.5 27 2 13.19 9 10 45 17.5 0.5 27 0 16.96 10 10 45 17 0.5 27 0.5 16.41 11 10 45 16.5 0.5 27 1 15.66 12 10 45 15.5 0.5 27 2 14.36 13 10 45 17.5 0.5 27 2.5 16.81 14 10 45 17 0.5 27 0.5 2.5 14.81 15 10 45 16.5 0.5 27 1 2.5 14.96 16 10 45 15.5 0.5 27 2 2.5 14.31
  • the greater silicon (Si) content the lower thermal expansion coefficient of the metal alloy.
  • silver was less used.
  • the alloy prepared according to Experimental Example II-1 may be used for low temperature calcination
  • the alloy prepared according to Experimental Example II-2 may be used for high temperature calcination.
  • the alloys prepared according to Experimental Examples II-3 and II-4 may not be suitable for use as an alloy for fusing with porcelain due to their too low thermal expansion coefficients, when additional alloy elements are not used.
  • the silicon content may be restricted to less than 1 weight%. However, the silicon content may be further increased by adding other alloy elements.
  • the greater germanium (Ge) content the smaller thermal expansion coefficient of the metal alloy. Compared to the case with silicon, when germanium was added, the thermal expansion coefficient was relatively less decreased.
  • the alloys prepared according to Experimental Examples II-5 and II-6 may be used for low temperature calcination, and the alloy prepared according to Experimental Example II-7 may be used for high temperature calcination.
  • the alloy prepared according to Experimental Example II-8 may not be suitable for use as an alloy for fusing with porcelain due to its too low a thermal expansion coefficient, when additional alloy elements are not used.
  • the germanium content may be restricted to less than 2 weight%, for example, to a range of 1 weight% or lower. However, the germanium content may be further increased by adding other alloy elements.
  • the greater zirconium (Zr) content the smaller thermal expansion coefficient of the metal alloy. Compared to the case with germanium, when zirconium was added, the thermal expansion coefficient was relatively slightly less decreased.
  • the alloys prepared according to Experimental Examples II-9 and II-11 may be used for low temperature calcination, and the alloy prepared according to Experimental Example II-12 may be used for high temperature calcination. Considering these results, it is confirmed that the zirconium content is about 2 weight% or slightly greater than 2 weight%. Furthermore, for high temperature calcinations, the zirconium content may be greater than 1 weight%. However, the zirconium content may be changed by adding other alloy elements.
  • Table 3 shows composition (weight%) of the metal alloys prepared according to Experimental Example III.
  • Experimental Example III Group 1 Group 2 Group 3 Group 4 Group 5 Group 6 Group 7 Group 8 Pd Au Ag In Zn Ga B Ge Zr Si Fe Cr Nb Mg Ti Co Al Ta Mo Ir Ru 1 bal. 2 31 21.5 0.5 0.1 0.1 2 bal. 2 31 20.5 1.4 0.1 0.1 3 bal. 2 31 20.9 1.1 0.1 4 bal. 2 31 20.5 1.2 0.4 5 bal. 2 31 20.5 1 0.5 0.1 6 bal. 2 25 29.5 2.3 1 0.1 0.1 7 bal. 2 26 29.1 2.5 0.2 0.5 8 bal. 5 21 23.4 2 0.1 3 0.5 3.9 0.1 1 9 bal.
  • Samples shown in Table 3 were prepared as follows: alloy components were dissolved and then injected into a graphite mold to form a mold product, and the mold product was extended by using a roller and then imprinted and cut to produce samples.
  • the dissolving of alloy components may be performed with an appropriate reactor, for example, an induction chamber, and to prevent oxidation, the dissolving may be performed in vacuum conditions or while inert gas is injected.
  • a pressure inside the reactor may be controlled to be in a range of 10-4 to 10-3 torr, and in this state, argon or nitrogen gas may be injected thereinto.
  • the metal alloys for dental porcelain fusing prepared according to Experimental Examples III-1 to III-17 may be completely or partially constituted of Group 1 to Group VIII elements.
  • the Group 1 element platinum may be further added in addition to gold.
  • the Group V element in addition to the elements presented above, tin (Sn), selenium (Se), carbon (C), antimony (Sb), or copper (Cu) may be added as having similar functions as those of the elements presented above.
  • the Group VII element the elements presented above, vanadium (V) or tungsten (W) may be added as having similar functions as those of the elements presented above.
  • rhenium (Re), rhodium (Rh), lanthanum (La), osmium (Os), or bismuth (Bi) may be added as having similar functions as those of the elements presented above.
  • the first adding element may be selected from Group VI elements
  • the second adding element may be selected from Group VII elements
  • the third adding element may be selected from Group V elements
  • the fourth adding element may be selected from Group VIII elements.
  • Table 4 shows mechanical/physical properties of the alloys prepared according to Experimental Examples shown in Table 3. Such results were obtained by dissolving the alloys prepared according to Experimental Examples shown in Table 3 with an electric furnace used in technology laboratories or an oxygen-propane gas torch, and carrying out tests according to ISO9693 standard.
  • the alloys of Experimental Examples III-1 to III-17 were all yellow. Melting points of the alloys were in a range of 945 to 1047°C, and thermal expansion coefficient thereof were in a range of 12.1 to 17.2 10 -6 K -1 . Accordingly, it was confirmed that the alloys were suitable for low temperature or high temperature calcination.
  • palladium (Pd) was added in a content of 39 to 45 weight% for illustrative purpose. However, the Pd content may increase if contents of gold (Au) and silver (Ag) decrease.
  • the gold (Au) content may be in a range of about 2 to 20 weight%, and the silver (Ag) content may be in a range of about 13 to 31 weight%.
  • the gold and silver contents may be outside the ranges as described above.
  • the melting point and the thermal expansion coefficient of the alloys may, first of all, significantly depend on the indium (In) content. Such effects of indium may be weakened or enhanced by other alloy elements.
  • In the case of an alloy for fusing with porcelain for low temperature calcination a low melting point is required although a thermal expansion coefficient is relatively high.
  • a relatively low thermal expansion coefficient is required although a melting point is relatively high.
  • a melting point of the alloy for low temperature calcination may be in a range of 920 to 1040°C, and a thermal expansion coefficient thereof may be in a range of 15.5 x 10 -6 to 17.5 x 10 -6 K -1 .
  • the alloys of Experimental Examples III-1 to III-9 may be used for low temperature calcination.
  • the indium content may be in a range of about 20.3 to 30.0 weight%, and for example, 20.5 to 29.5 weight%.
  • the indium content when the melting point is restricted to 1000°C or lower, as in the case of Experimental Example III-6 to III-9, the indium content may be in a range of about 23.0 to 30.0 weight%. Furthermore, under strict conditions, for example, when a melting point is restricted to 1000°C or lower and a thermal expansion coefficient is restricted to a range of 16.0 x 10 -6 to 17.2 x 10 -6 K -1 , the indium content may be in a range of about 24 to 30 weight%.
  • Experimental Examples III-8 and III-9 compared to Experimental Examples III-1 to III-7, further include a Group VII element (second adding element), and accordingly, although the indium content is relatively low, a melting point is relatively low compared to those in Experimental Examples III-1 to III-7. From this point, it is confirmed that the Group VII element may contribute to a wider indium content range in an alloy for low temperature calcination and a lower melting point of the alloy.
  • a Group VII element second adding element
  • An alloy for high temperature calcination may have a melting point of 1030 to 1200 °C, for example, 1030 to 1050 °C, and a thermal expansion coefficient of 12.0 x 10 -6 to 16.0 x 10 -6 K -1 , for example, 13.0 x 10 -6 to 15.5 x 10 -6 K -1 , and for example, 13.9 x 10 -6 to 15.5 x 10 -6 K -1 .
  • the alloys of Experimental Examples III-10 to III-17 may be used for high temperature calcination, and in this case, the indium content may be in a range of about 12.0 to 26 weight%.
  • the indium content in the alloys for high temperature calcination may be increased by increasing contents of other adding elements, for example, gold, platinum, or the Group VII element (second adding element).
  • Gold, silver, or platinum may contribute to an increase in the melting point of the alloy.
  • the Group VII element may contribute to a decrease in the melting point of the alloy and a reduction in deformation of an alloy due to increased indium content.
  • the third adding element (Group V element) was added, as described above, in a content of 10 weight% or lower, for example, 7 weight% or lower in consideration of rigidity and corrosion resistance characteristics of an alloy.
  • the fourth adding element (Group VIII element) was added, as described above, in a content of 2 weight% or lower, for example, 0.5 weight% or lower in consideration of grain refinement of an alloy.
  • the samples were prepared in powder, and suspended at various concentrations in water-soluble methyl cellulose, and then orally administered into Albino rat. For 2 weeks, toxicity effects of the samples were recorded every day. As a result, LD50 was 8 g/kg, which means high in vivo stability.
  • Fibroblast L-929 cells of Albino rat were inoculated into Eagle MEM culture (10% FBS) at a cell concentration of 5105 per 1 mL cell, and then cultured at a temperature of 37°C for 24 hours. After the culturing, a liquid component of a culture plate was removed by suctioning, and about 12 mL of Eagle culture supplemented with 1.0% w/v agar was placed in the culture plate. 3 mL of 0.02% w/v neutral red phosphate buffer saline solution injection liquid was added to the agar plane, and then the cells were incubated with a 5% carbon dioxide apparatus at a temperature of 37°C for 2 to 3 hours.
  • Table 5 shows compositions (weight%) and physical characteristics of metal alloys of Experimental Example V.
  • Experimental Example IV Group 1 Group 2 Group 3 Group 4 Group 5 Group 6 Group 7 Physical Properties Pd Au Pt Ag In Zn Cu Ga Ge Si Co Thermal Expansion Coefficient (10 -6 K -1 ) Melting point (°C) Calcination range Yellow level Calcination deformation 1 50 2 23 21 2 17.03 1030 Low temperature Low X 2 40 2 25 30 3 18.05 943 X Middle X 3 40 2 24.6 30 3 0.4 16.20 945 Low temperature Middle X 4 40 2 24 30 3 1 16.40 943 Low temperature Middle X 5 45 15 16.5 21 2 0.5 14.4 1070 High temperature Middle O 6 43.8 10 0.8 15.7 24 0.7 0.6 3.2 13.90 1180 High temperature Low X 7 38 10 1 16.6 28 0.5 0.5 2.5 14.90 1100 High temperature Lower middle X 8 45 15 14.5 21 2 0.5 2 14.1 1180 High temperature Lower middle X 9 21.8 40 1 15.4 18 0.5 1 1 0.6 1.5 14.14 11.5
  • the first adding element may be selected from Group VI elements
  • the second adding element may be selected from Group VII elements
  • the third adding element may be selected from Group V elements.
  • Experimental Examples V-5 to IV-19 in which the indium content is about 30 weight%, of Group VI elements (first adding element), the content of silicon is 0.5 weight% or more, are suitable for high temperature calcination.
  • the metal alloys of these Experimental Examples used for high temperature calcination may be suitable for fusing with porcelain.
  • the alloy of Experimental Example V-5 that does not include cobalt, a Group VII element (second adding element) experienced calciantion deformation due to the flowing down of indium during fusing with porcelain. Accordingly, to perform high temperature calcination, a metal alloy needs to include an appropriate content of the Group VI element, and furthermore, to prevent calcination deformation during high temperature calcination, a metal alloy needs to include an appropriate content of the Group VII element.
  • the cobalt content may be controlled to be 5 weight% or lower.
  • the yellow expression level of the metal alloy was downgraded to lower middle or low.
  • the Group II element and the Group V element in particular, copper (Cu) was added or a content thereof was increased, so as to upgrade the yellow expression level of the metal alloy to middle.
  • the metal alloy of Experimental Example V-17 including a relatively low gold content showed a middle of the yellow expression level.
  • the copper content may be controlled to be 5 weight% or lower.
  • the dental metal alloys prepared according to the above Experimental Examples may be fused with ceramic porcelain for use in dental prosthetic appliances.
  • the dental metal alloys may have a stronger binding force with ceramic porcelain during binding by experiencing a pretreatment.
  • excess oxidation films may be interposed therebetween to prevent the binding between ceramic porcelain and a metal alloy.
  • indium in the metal alloy may be oxidized during high temperature calcination.
  • the metal alloy by pretreating, prior to high temperature calcination, the metal alloy to remove a metal oxide on a surface of the metal alloy, formation of excess oxide between ceramic porcelain and the metal alloy is prevented to increase their chemical binding.
  • surface-etching by performing surface-etching to form pores in the surface of the metal alloy, a physical binding between the metal alloy and the ceramic porcelain is induced to increase a binding force.
  • the pretreatment may include wet-etching for the removal of the metal oxide.
  • wet-etching may be performed with an aqueous solution of a fluoric acid and a nitric acid.
  • An etching time may be appropriately controlled to be a few to several minutes according to the metal oxide content in the metal alloy.
  • FIG. 1 shows a picture of a dental prosthetic appliance prepared by calcination without a pretreatment according to Comparative Example.
  • FIG. 2 is a picture of a dental prosthetic appliance that is prepared by clacination with a pretreatment according to Experimental Example.
  • the metal alloy prepared according to Experimental Example was molded in a tooth shape, and its calcination temperature with respect to ceramic porcelain may be in a range of about 900 to 980 °C.
  • the ceramic porcelain when a pretreatment was not performed, the ceramic porcelain was substantially separated from the tooth-shaped metal alloy. However, as shown in FIG. 2 , when a pretreatment was performed for an appropriate period of time, the ceramic porcelain was not separated from the tooth-shaped metal alloy or was not broken

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EP11786922.2A 2010-05-27 2011-05-26 Metalllegierung zur fusion zahnärztlicher keramikartikel und zahnprothese Withdrawn EP2578202A2 (de)

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KR1020100049599A KR101191987B1 (ko) 2010-05-27 2010-05-27 치과 도재소부용 금속 합금 및 치과 보철물
KR1020100117307A KR101254289B1 (ko) 2010-11-24 2010-11-24 치과 도재소부용 금속 합금 및 치과 보철물
PCT/KR2011/003875 WO2011149290A2 (ko) 2010-05-27 2011-05-26 치과 도재소부용 금속 합금 및 치과 보철물

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RU2481095C1 (ru) * 2012-04-04 2013-05-10 Открытое акционерное общество "Научно-производственный комплекс "Суперметалл" имени Е.И. Рытвина" Сплав на основе палладия для изготовления зубных протезов
JP6142347B2 (ja) * 2012-09-28 2017-06-07 株式会社徳力本店 電気・電子機器用途のＡｇ‐Ｐｄ‐Ｃｕ‐Ｃｏ合金
CN103205594B (zh) * 2013-05-07 2015-06-17 四川奇和贵金属有限公司 牙科用钯银合金材料
EP3070182B1 (de) * 2015-03-17 2017-08-30 The Swatch Group Research and Development Ltd. Weissgoldlegierung
CN104962773A (zh) * 2015-06-02 2015-10-07 张亚南 一种用于齿科修复的铸造合金及其应用
CH714785B1 (it) * 2018-03-15 2022-05-13 Argor Heraeus Sa Lega d'oro resistente alla decolorazione e metodo di produzione della medesima.
EP3783124B1 (de) * 2019-08-23 2024-08-07 Omega SA Uhr, schmuck- oder juwelierartikel aus gold
CN115896527B (zh) * 2022-12-16 2024-05-03 深圳市华悦珠宝科技有限公司 一种16k金、弹簧的制作方法、弹簧及首饰

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WO2011149290A2 (ko) 2011-12-01

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