EP2586073A2 - Transducteur électromécanique, procédé de production et utilisation - Google Patents

Transducteur électromécanique, procédé de production et utilisation

Info

Publication number
EP2586073A2
EP2586073A2 EP11735818.4A EP11735818A EP2586073A2 EP 2586073 A2 EP2586073 A2 EP 2586073A2 EP 11735818 A EP11735818 A EP 11735818A EP 2586073 A2 EP2586073 A2 EP 2586073A2
Authority
EP
European Patent Office
Prior art keywords
layer
electret
dielectric elastomer
electrode
electromechanical transducer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP11735818.4A
Other languages
German (de)
English (en)
Inventor
Werner Jenninger
Joachim Wagner
Deliani Lovera-Prieto
Dirk Schapeler
Philippe Jean
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer Intellectual Property GmbH
Original Assignee
Bayer Intellectual Property GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer Intellectual Property GmbH filed Critical Bayer Intellectual Property GmbH
Priority to EP11735818.4A priority Critical patent/EP2586073A2/fr
Publication of EP2586073A2 publication Critical patent/EP2586073A2/fr
Withdrawn legal-status Critical Current

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Classifications

    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N30/00—Piezoelectric or electrostrictive devices
    • H—ELECTRICITY
    • H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02N—ELECTRIC MACHINES NOT OTHERWISE PROVIDED FOR
    • H02N1/00—Electrostatic generators or motors using a solid moving electrostatic charge carrier
    • H02N1/06—Influence generators
    • H02N1/08—Influence generators with conductive charge carrier, i.e. capacitor machines
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N30/00—Piezoelectric or electrostrictive devices
    • H10N30/01—Manufacture or treatment
    • H10N30/09—Forming piezoelectric or electrostrictive materials
    • H10N30/098—Forming organic materials
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N30/00—Piezoelectric or electrostrictive devices
    • H10N30/30—Piezoelectric or electrostrictive devices with mechanical input and electrical output, e.g. functioning as generators or sensors
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N30/00—Piezoelectric or electrostrictive devices
    • H10N30/80—Constructional details
    • H10N30/85—Piezoelectric or electrostrictive active materials
    • H10N30/857—Macromolecular compositions
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00—Metal working
    • Y10T29/49—Method of mechanical manufacture
    • Y10T29/49002—Electrical device making
    • Y10T29/49117—Conductor or circuit manufacturing

Definitions

  • Electromechanical transducer process for its manufacture and use
  • the present invention relates to an electromechanical transducer. It further relates to a process for its preparation and its use. Furthermore, the invention relates to a method for obtaining electrical energy, in which the converter according to the invention can be used.
  • Electromechanical converters convert electrical energy into mechanical energy and vice versa. They can be used as part of sensors, actuators and generators.
  • WO 2001/06575 A1 discloses an energy converter, its use and its production. The energy converter converts mechanical energy into electrical energy. Some of the energy converters shown have biased polymers. The bias improves the conversion between electrical and mechanical energy.
  • a device is disclosed which comprises an electroactive polymer for converting electrical energy into mechanical energy.
  • electrodes are disclosed which are adapted to the shape of the polymer in the energy converter. Also disclosed are methods for making an electromechanical device comprising one or more electroactive polymers.
  • the cavities After charging the upper and lower FEP layers of positive and negative polarity, respectively, the cavities form large dipoles that can be deformed by mechanical or electrical action. As a result, the three-layer sandwich shows direct and inverse piezoelectricity.
  • the continuous method of bonding the layers involves a press with heated cylindrical rollers, which are operated at temperatures of up to 310 ° C. This allows the production of cost-effective transducer materials on a large scale.
  • the conference paper covers the concept, processing, charging and electromechanical properties of the three-layer ferroelectrete. Layered composites of dielectric elastomers and other materials for electromechanical
  • Transducers are disclosed in US 2009/0169829 Al.
  • This patent application is concerned with a multi-layer composite comprising a film, a first electrically conductive layer and at least one intermediate layer, which is arranged between the film and the first electrically conductive layer.
  • the film is made of a dielectric material and has first and second surfaces. At least the first surface comprises a surface pattern with peaks and valleys.
  • the first electrically conductive layer is mounted on the surface pattern and has a waveform formed by the surface pattern of the film.
  • the intermediate layer can be obtained by plasma treatment of the film surface.
  • the intermediate layer serves to improve the adhesion between the electrically conductive layer and the film.
  • the sensor actuator comprises an actuator part made of an ionic polymer-metal composite, a sensor part made of a piezoelectric material and an insulating part between the actuator part and the sensor part.
  • the sensor-actuator may further comprise a compensation circuit for receiving a sensor signal from the sensor part and an actuator signal from the actuator part, which compensates the received signal for coupling between the actuator part and the sensor part.
  • the structure disclosed here is not suitable for energy-gaining operation in the plane direction of the element.
  • the present invention has for its object to provide an electromechanical transducer of the type mentioned above, which is characterized by the possibility of operation at higher strains especially in the surface direction.
  • the converter comprises at least one dielectric elastomer layer, electrodes and at least one electret layer, wherein the dielectric elastomer layer is contacted by the at least one electret layer, wherein the at least an electret layer carries an electrical charge and is contacted by a first electrode, and wherein a second electrode is disposed on the side of the dielectric elastomer layer opposite the first electrode.
  • the electromechanical converter according to the invention is based initially on the general knowledge that the relevant for the operation of such a converter dielectric displacement (electrical flux density) can be changed by the variation of two parameters.
  • the dielectric shift can be expressed as the sum of the polarization and the product of the electric field strength with the electric field constant:
  • the second electrode is arranged on the side of the dielectric elastomer layer opposite the first electrode may mean that the elastomer layer is in contact with this electrode. However, it is also possible that an electret layer or other layers are located between the electrode and the elastomer layer.
  • the transducer according to the invention can be operated at much greater strains.
  • maximum strains during operation of> 10%,> 20%,> 30% or even> 50% are conceivable. In this way, for example, you win new ones
  • the dielectric elastomer may, for example, have a maximum stress of> 0.2 MPa and a maximum elongation of> 100%.
  • the stress can range from> 0.1 MPa to ⁇ 50 MPa (determined according to ASTM D 412).
  • the elastomer may have a Young's modulus at an elongation of 100% of> 0.1 MPa to ⁇ 100 MPa (determined according to ASTM D 412).
  • the elastomer layer and / or the electret layer or electret layers are made compact.
  • this is to be understood as meaning that the proportion of cavities within the respective layers is> 0% by volume to ⁇ 5% by volume and in particular> 0% by volume to ⁇ 1% by volume.
  • the elastomer layer and the electret layer or electret layers are connected to one another in a flat manner.
  • the type of connection may in particular be a cohesive connection.
  • the type of contacting of the electret layer or electret layers with their associated electrodes is initially not specified and may for example be made laterally or flat.
  • the dielectric elastomer layer is contacted on opposite sides by an electret layer, faces of that electret layer facing and facing away from the dielectric elastomer layer are respectively formed.
  • the first electret layer is contacted on its side facing away from the dielectric elastomer layer from the first electrode.
  • the electrodes can furthermore be structured.
  • a patterned electrode may be configured as a conductive coating in stripes or in lattice form. In this way, in addition, the sensitivity of the electromechanical transducer can be influenced and adapted to specific applications.
  • the electrodes may be structured such that the transducer has active and passive regions.
  • the electrodes can be structured in such a way that signals can be detected with local resolution or active areas can be controlled in a targeted manner. This can be achieved by providing the active regions with electrodes, whereas the passive regions have no electrodes.
  • the thickness of the dielectric elastomer layer may, for example, in a range of> 10 ⁇ to ⁇ 500 ⁇ and preferably> 20 ⁇ to ⁇ 200 ⁇ lie.
  • the thickness of the first and / or further electret layers may be, for example, in a range of> 1 ⁇ to ⁇ 200 ⁇ and preferably> 2 ⁇ to ⁇ 100 ⁇ .
  • the dielectric elastomer layer is contacted on opposite sides by a first electret layer and a second electret layer, wherein the first electret layer and the second electret layer carry opposite electrical charges and wherein the first electret layer is from the first electrode and the second electret layer is contacted by the second electrode.
  • At least one of the sides of the dielectric elastomer layer along at least one direction has a wave-shaped cross-sectional profile with elevations and depressions.
  • these are at least one of the first and / or, if present, second electret layer contacted sides of the dielectric elastomer layer, which along at least one direction has a wave-shaped cross-sectional profile with elevations and depressions.
  • “Wavy” here is to be understood as a regular or irregular sequence of elevations and depressions. Preference is given here to a regular sequence.
  • the distance from one survey to the adjacent survey for example,> 1 ⁇ to ⁇ 5000 ⁇ and preferably> 5 ⁇ to ⁇ 2000 ⁇ amount.
  • the vertical distance between the lowest point of a depression and the highest point of an adjacent increase may, for example, be> 0.3 ⁇ m to ⁇ 5000 ⁇ m and preferably> 5 ⁇ m to ⁇ 2000 ⁇ m.
  • An example of a wavy profile along one direction is when, in an elastomer layer having a thickness direction, a longitudinal direction and a transverse direction, the undulating profile is formed only in the longitudinal direction. Another example is the case that this profile occurs in the longitudinal and in the transverse direction.
  • the advantage of a wave-shaped profile is that more material is available for expansion when the elastomer layer is stretched in the direction of the waves.
  • the wavy profile of the side of the dielectric elastomer layer is a sine wave profile or a triangular wave profile.
  • These waveforms are to be understood here as meaning that any sinusoidal or triangular waves scaled in height and / or width can be used.
  • the side contacted by the at least one electret layer and the side of the dielectric elastomer layer opposite this side have a wave-shaped path along the same direction
  • Cross-sectional profile with elevations and depressions on and surveys continue and Recesses of the profile of the one side parallel to protrusions and depressions of the profile of the other side of the dielectric elastomer layer. Then, even with a large elongation, the thickness of the elastomer layer in the running direction of the waves remain as uniform as possible.
  • the at least one electret layer and / or at least the first electrode has a wave-shaped cross-sectional profile along at least one direction, which is adapted to the wavy cross-sectional profile of the contacted side of the dielectric elastomer.
  • electret and / or electrode layers can also adapt well to the stretching of the elastomer layer.
  • the dielectric elastomer layer comprises a polyurethane polymer, silicone polymer and / or acrylate polymer. Preference is given here polyurethane elastomers.
  • Suitable polyisocyanates A) are, for example, 1,4-butylene diisocyanate, 1,6-hexamethylene diisocyanate (HDI), isophorone diisocyanate (IPDI), 2,2,4 and / or 2,4,4-trimethylhexamethylene diisocyanate, the isomeric bis (4, 4'-isocyanatocyclohexyl) methanes or mixtures thereof of any isomer content, 1,4-cyclohexylene diisocyanate, 4-isocyanatomethyl-1,9-octane diisocyanate (nonane triisocyanate), 1,4-phenylene diisocyanate, 2,4- and / or 2,6-toluene diisocyanate, 1,5-naphthylene diisocyanate, 2,2'- and / or 2,4'- and / or 4,4'-diphenylmethane diisocyanate, 1,3- and / or 1,4-
  • Component A) may preferably be a polyisocyanate or a polyisocyanate mixture having an average NCO functionality of 2 to 4 with exclusively aliphatically or cycloaliphatically bonded isocyanate groups.
  • the polyisocyanate prepolymers which can be used as component B) can be obtained by reacting one or more diisocyanates with one or more hydroxy-functional, in particular polymeric, polyols, if appropriate with addition of catalysts and auxiliaries and additives.
  • components for chain extension such as, for example, with primary and / or secondary amino groups (NH 2 and / or NH-functional components) for the formation of the polyisocyanate prepolymer.
  • the polyisocyanate prepolymer as component B) may preferably be obtainable from the reaction of polymeric polyols and aliphatic diisocyanates.
  • Hydroxy-functional, polymeric polyols for the conversion to the polyisocyanate prepolymer B) can be, for example, polyesterpolyols, polyacrylatepolyols, polyurethanepolyols, polycarbonatepolyols, polyetherpolyols, polyesterpolyacrylatepolyols, polyurethanepolyacrylatepolyols, polyurethanepolyesterpolyols, pol y urethane-polyetherpolyols, polypyrrolepolypolypolyols and d / o of the polyester polycarbonate polyols. These can be used to prepare the polyisocyanate prepolymer individually or in any mixtures with each other. Suitable polyester polyols for the preparation of the polyisocyanate prepolymers B
  • Polycondensates of di- and optionally tri- and tetraols and di- and optionally tri- and tetracarboxylic acids or hydroxycarboxylic acids or lactones instead of the free polycarboxylic acids, it is also possible to use the corresponding polycarboxylic acid anhydrides or corresponding polycarboxylic acid esters of lower alcohols for the preparation of the polyesters.
  • diols examples include ethylene glycol, butylene glycol, diethylene glycol, triethylene glycol, polyalkylene glycols such as polyethylene glycol, furthermore 1,2-propanediol, 1,3-propanediol, butanediol (1,3), butanediol (1,4), hexanediol (1,6) and isomers, neopentyl glycol or hydroxypivalic acid neopentyl glycol esters or mixtures thereof, with hexanediol (1,6) and isomers, butanediol (1,4), neopentyl glycol and neopentyl glycol hydroxypivalate being preferred.
  • polyols such as trimethylolpropane, glycerol, erythritol, pentaerythritol,
  • Trimethylolbenzene or Trishydroxyethylisocyanurat or mixtures thereof are used.
  • dicarboxylic acids may include phthalic acid, isophthalic acid, terephthalic acid, tetrahydrophthalic acid, hexahydrophthalic acid, cyclohexanedicarboxylic acid, adipic acid, azelaic acid, sebacic acid, glutaric acid, tetrachlorophthalic acid, maleic acid, fumaric acid, itaconic acid, malonic acid, suberic acid, 2-methyl succinic acid, 3,3-diethylglutaric acid and / or 2 , 2-dimethylsuccinic acid are used.
  • the acid source used may also be the corresponding anhydrides. If the mean functionality of the polyol to be esterified is> 2, monocarboxylic acids, such as benzoic acid and hexanecarboxylic acid may additionally be used.
  • Preferred acids are aliphatic or aromatic acids of the abovementioned type. Particular preference is given to adipic acid, isophthalic acid and phthalic acid.
  • Hydroxycarboxylic acids which may be co-used as reactants in the preparation of a hydroxyl-terminated polyester polyol include hydroxycaproic acid, hydroxybutyric acid, hydroxydecanoic acid or hydroxystearic acid, or mixtures thereof.
  • Suitable lactones are caprolactone, butyrolactone or homologs or mixtures thereof. Preference is given to caprolactone.
  • hydroxyl-containing polycarbonates for example polycarbonate, preferably polycarbonate, can be used.
  • M n a number-average molecular weight of from 400 g / mol to 8000 g mol, preferably from 600 g / mol to 3000 g / mol.
  • carbonic acid derivatives such as diphenyl carbonate, dimethyl carbonate or phosgene
  • polyols preferably diols.
  • diols examples include ethylene glycol, 1,2- and 1,3-propanediol, 1,3- and 1,4-butanediol, 1,6-hexanediol, 1,8-octanediol, neopentyl glycol, 1, 4-bishydroxymethylcyclohexane, 2 - Methyl-l, 3-propanediol, 2,2,4-Trimethylpentandiol-l, 3, dipropylene glycol, polypropylene glycols, dibutylene glycol, polybutylene glycols, bisphenol A or lactone-modified diols of the type mentioned above or mixtures thereof.
  • the diol component then preferably contains from 40 percent by weight to 100 percent by weight of hexanediol, preferably 1,6-hexanediol and / or hexanediol derivatives.
  • hexanediol derivatives are based on hexanediol and may have ester or ether groups in addition to terminal OH groups.
  • Such derivatives are obtainable, for example, by reaction of hexanediol with excess caprolactone or by etherification of hexanediol with itself to give di- or trihexylenglycol.
  • the amount of these and other components are chosen such that the sum does not exceed 100 weight percent, especially 100 weight percent.
  • Hydroxyl-containing polycarbonates are preferably linearly constructed.
  • polyether polyols can be used to prepare the polyisocyanate prepolymers B).
  • polytetramethylene glycol polyethers as by polymerization are suitable of tetrahydrofuran are obtainable by cationic ring opening.
  • suitable polyether polyols may be the addition products of styrene oxide, ethylene oxide, propylene oxide, butylene oxide and / or epichlorohydrin to di- or polyfunctional starter molecules.
  • Suitable starter molecules for example, water, butyl diglycol, glycerol, diethylene glycol, trimethylolpropane, propylene glycol, sorbitol, ethylenediamine, triethanolamine, or 1, 4-butanediol or mixtures thereof can be used.
  • Preferred components for the preparation of the polyisocyanate prepolymers B) are polypropylene glycol, polytetramethylene glycol polyethers and polycarbonate polyols or mixtures thereof, with polypropylene glycol being particularly preferred.
  • polymeric polyols having a number average molecular weight M n of from 400 g / mol to 8000 g of mol, preferably from 400 g / mol to 6000 g / mol and more preferably from 600 g / mol to 3000 g / mol. These preferably have an OH functionality of from 1.5 to 6, particularly preferably from 1.8 to 3, very particularly preferably from 1.9 to 2.1.
  • short-chain polyols can also be used in the preparation of the polyisocyanate prepolymers B).
  • ester diols of the stated molecular weight range, such as ⁇ -hydroxybutyl- ⁇ -hydroxycaproic acid ester, ro-hydroxyhexyl-Y-hydroxybutyric acid ester, adipic acid ( ⁇ -hydroxyethyl) ester or terephthalic acid bis ( ⁇ -hydroxyethyl) ester.
  • monofunctional isocyanate-reactive hydroxyl-containing compounds for the preparation of the polyisocyanate prepolymers B).
  • monofunctional compounds are ethanol, n-butanol, ethylene glycol monobutyl ether, diethylene glycol monomethyl ether, diethylene glycol monobutyl ether, propylene glycol monomethyl ether, dipropylene glycol monomethyl ether, tripropylene glycol monomethyl ether, dipropylene glycol monopropyl ether, propylene glycol monobutyl ether, dipropylene glycol monobutyl ether, tripropylene glycol monobutyl ether, 2-ethylhexanol, 1-octanol, 1-dodecanol or 1-hexadecanol or mixtures thereof.
  • polyisocyanate prepolymers B it is possible to react diisocyanates with the polyols at a ratio of the isocyanate groups to hydroxyl groups (NCO / OH ratio) of 2: 1 to 20: 1, for example 8: 1.
  • NCO / OH ratio ratio of the isocyanate groups to hydroxyl groups
  • urethane and / or allophanate structures can be formed.
  • a proportion of unreacted polyisocyanates can then be separated off.
  • a thin-film distillation is used, with residual monomer low products with residual monomer contents of, for example, ⁇ 1 weight percent, preferably ⁇ 0.5 weight percent, more preferably ⁇ 0, 1 weight percent, are obtained.
  • the reaction temperature may be from 20 ° C to 120 ° C, preferably from 60 ° C to 100 ° C, amount.
  • stabilizers such as benzoyl chloride, isophthaloyl chloride, dibutyl phosphate, 3-chloropropionic acid or methyl tosylate may be added during the preparation.
  • NH 2 - and / or NH-functional components can be used in addition to the chain extension in the preparation of the polyisocyanate prepolymers B).
  • Suitable components for chain extension are organic di- or polyamines.
  • organic di- or polyamines For example, ethylenediamine, 1,2-diaminopropane, 1, 3-diaminopropane, 1,4-diaminobutane, 1,6-diaminohexane, isophoronediamine, isomer mixtures of 2,2,4- and 2,4,4-trimethylhexamethylenediamine, 2-methylpentamethylenediamine , Diethylenetriamine,
  • Diaminodicyclohexylmethan or dimethylethylenediamine or mixtures thereof are diminodicyclohexylmethan or dimethylethylenediamine or mixtures thereof.
  • Alkanolamines such as N-aminoethylethanolamine, ethanolamine, 3-aminopropanol, neopentanolamine.
  • chain termination are usually amines having an isocyanate-reactive group such as methylamine, ethylamine, propylamine, butylamine, octylamine, laurylamine, stearylamine, isononyloxypropylamine, dimethylamine, diethylamine, dipropylamine, dibutylamine, N-methylaminopropylamine, diethyl (methyl) aminopropylamine, morpholine, piperidine, or suitable substituted derivatives thereof, amide amines from diprimary amines and monocarboxylic acids, monoketim of diprimary amines, primary / tertiary amines, such as N, N-dimethylaminopropylamine.
  • Component C) is a compound having at least two isocyanate-reactive functional groups.
  • component C) may be a polyamine or a polyol having at least two isocyanate-reactive hydroxy groups.
  • component C it is possible to use hydroxy-functional, in particular polymeric, polyols, for example polyether polyols or polyester polyols.
  • Suitable polyols have already been described above in connection with the preparation of the prepolymer B), so that reference is made to avoid repetition thereof.
  • component C) is a polymer having 2 to 4 hydroxy groups per molecule, most preferably a polypropylene glycol having 2 to 3 hydroxy groups per molecule.
  • polyether polyols preferably have a polydispersity of 1.0 to 1.5 and an OH functionality of greater than 1.9, and particularly preferably greater than or equal to 1.95.
  • Such polyether polyols can be prepared in a manner known per se by alkoxylation of suitable starter molecules, in particular using double metal cyanide catalysts (DMC catalysis). This method is described, for example, in the patent US Pat. No. 5,158,922 and the published patent application EP 0 654 302 A1.
  • DMC catalysis double metal cyanide catalysts
  • the reaction mixture for the polyurethane can be obtained by mixing components A) and / or B) and C).
  • the ratio of isocyanate-reactive hydroxy groups to free isocyanate groups is preferably from 1: 1.5 to 1.5: 1, more preferably from 1: 1.02 to 1: 0.95.
  • at least one of components A), B) or C) has a functionality of> 2.0, preferably> 2.5 preferably> 3.0 to introduce branching or crosslinking into the polymer element.
  • the term "functionality" in component A) and B) refers to the average number of NCO groups per molecule and in component C) to the average number of OH groups per molecule. This branching or crosslinking brings about better mechanical properties and better elastomeric properties, in particular also better elongation properties.
  • the obtained polyurethane polymer may preferably have a maximum Stress of> 0.2 MPa, in particular from 0.4 MPa to 50 MPa, and a maximum elongation of> 100%, in particular of> 120%.
  • the polyurethane may have a Young's modulus at an elongation of 100% from 0.1 MPa to 100 MPa, for example, from 1 MPa to 80 MPa (determined according to ASTM D 412).
  • the polyurethane polymer obtained is a dielectric elastomer having a volume resistivity according to ASTM D 257 of> 10 12 to ⁇ 10 17 ohm cm. It is further preferred that the polyurethane polymer has a dielectric breakdown field strength according to ASTM 149-97a of> 50 V / ⁇ to ⁇ 200 V / ⁇ .
  • the reaction mixture for the preparation of the polyurethane in addition to the components A), B), C) and D) additionally contain auxiliaries and additives.
  • auxiliaries and additives are crosslinkers, thickeners, solvents, thixotropic agents, stabilizers, antioxidants, light stabilizers, emulsifiers, surfactants, adhesives, plasticizers, water repellents, pigments, fillers and leveling agents.
  • Preferred solvents are methoxypropyl acetate and ethoxypropyl acetate.
  • Preferred flow control agents are polyacrylates, in particular amine resin-modified acrylic copolymers.
  • fillers can regulate the dielectric constant of the polymer element.
  • the reaction mixture comprises fillers to increase the dielectric constants, such as fillers with a high dielectric constant.
  • these are ceramic fillers, in particular barium titanate, titanium dioxide and piezoelectric ceramics such as quartz or lead zirconium titanate, as well as organic fillers, in particular those having a high electrical polarizability, for example phthalocyanines.
  • a high dielectric constant can also be achieved by introducing electrically conductive fillers below the percolation threshold.
  • Examples of these are carbon black, graphite, single-walled or multi-walled carbon nanotubes, electrically conductive polymers such as polythiophenes, polyanilines or polypyrroles, or mixtures thereof.
  • electrically conductive polymers such as polythiophenes, polyanilines or polypyrroles, or mixtures thereof.
  • carbon black which have a surface passivation and therefore at higher concentrations below the percolation threshold increase the dielectric constant and nevertheless do not lead to an increase in the conductivity of the polymer.
  • the terms "a” and “an” in the context of the present invention and in particular with the components A), B) and C) are not used as number words, but as an indefinite article, unless the context clearly different Statement results.
  • the material of the dielectric elastomer layer has a dielectric constant ⁇ ⁇ of> 2.
  • This dielectric constant may also be in a range from> 2 to ⁇ 2000 or from> 3 to ⁇ 1000. The determination of this constant can be done according to ASTM 150-98.
  • At least one electret layer comprises a polymer selected from the group comprising polycarbonates, perfluorinated or partially fluorinated polymers and copolymers, polytetrafluoroethylene (PTFE), fluorinated ethylene propylene (FEP), perfluoroalkoxyethylene (PFA), polyester, Polyethylene terephthalate (PET), polyethylene naphthalate (PEN), polyimide, polyetherimide, polyether, polymethyl (meth) acrylate, cyclo-olefin polymers, cyclo-olefin copolymers (COC), polyolefins, polypropylene, and mixtures of these polymers. If more than one electret layer is present, this also applies accordingly for this layer. Preferred material here is FEP.
  • the material of at least the first electrode is selected from the group comprising metals, metal alloys, conductive oligo- or polymers, conductive oxides and / or polymers filled with conductive fillers. If a second electrode is present, this also applies to them accordingly.
  • a second electrode is present, this also applies to them accordingly.
  • polythiophenes, polyanilines or polypyrroles can be used as conductive oligo- or polymers.
  • fillers for polymers filled with conductive fillers for example metals, conductive carbon-based materials such as carbon black, carbon nanotubes (CNT) or conductive oligo- or polymers can be used.
  • the filler content of the polymers is preferably above the percolation threshold, so that the conductive fillers continuously form electrically conductive paths within the polymers filled with conductive fillers.
  • the thickness ratio between the dielectric elastomer layer and the at least one electret layer is in a range of> 1: 1 to ⁇ 100: 1.
  • the thickness ratios are given in each case for the thickness of the elastomer layer and an electret layer and can also be in a range of> 2: 1 to ⁇ 50: 1.
  • the present invention further relates to a method for producing an electromechanical transducer according to the invention, comprising the steps:
  • the provision of the dielectric elastomer layer may conveniently be done directly from a roll, thus enabling a roll-to-roll process. From the same considerations, this can also be done for the electret layers.
  • the contacting of the elastomer layer with the electret layers can be achieved, for example, by lamination at elevated temperatures. In this way, a firm connection between the individual layers can be established.
  • solvent-based or extrusion and coextrusion processes may be used in the steps described above.
  • the two electret layers are charged so that they carry opposite electrical charges. This can be done for example by means of tribocharging, electron beam bombardment, applying an electrical voltage to existing electrodes or corona discharge.
  • the charging can be carried out by a two-electron corona arrangement.
  • the needle voltage can be> 20 kV,> 25 kV and in particular> 30 kV.
  • the charging time can be> 20 s,> 25 s and in particular> 30 s.
  • a corona treatment is also advantageously usable on an industrial scale.
  • the electret layers can be contacted with the electrodes by conventional methods such as sputtering, spraying, vapor deposition, chemical vapor deposition (CVD), printing, knife coating and spin coating.
  • the second electrode When arranging the second electrode on the opposite side of the first electrode of the dielectric elastomer layer can basically proceed as well. It is possible that the elastomeric layer is contacted with the second electrode. But it is also possible that between the second electrode and the elastomer layer, for example, still an electret layer is, which is then contacted accordingly.
  • Another object of the present invention is the use of an inventive electromechanical transducer as an actuator, sensor or generator.
  • the use can be made, for example, in the electromechanical and / or electroacoustic area.
  • electromechanical transducer according to the invention in the field of energy from mechanical vibrations ("energy harvesting"), acoustics, ultrasound, medical diagnostics, acoustic microscopy, mechanical sensors, in particular pressure, force and / or strain sensors, the Robotics and / or communication technology, in particular in speakers, vibration transducers, light deflectors, membranes, modulators for optical fiber optics, pyroelectric detectors, capacitors and control systems can be used.
  • the present invention also relates to an actuator, sensor or generator comprising an electromechanical transducer according to the invention. To avoid unnecessary lengths, reference is made to the above explanations regarding the converter with regard to details and specific embodiments.
  • Also provided in the context of the present invention is a method for obtaining electrical energy, comprising the steps of: (a2) providing a generator element, the generator element having a longitudinal direction and a thickness direction and at least one longitudinally arranged electret layer or a plurality of longitudinally arranged ones opposite electret layers comprises, wherein there is an electrical charge separation within an electret layer in the thickness direction of the generator element and this electret layer is contacted on opposite sides of electrodes in the thickness direction, or wherein an electret layer carries an electric charge and this electret layer is contacted on opposite sides of electrodes or an electret layer carries an electric charge and another electret layer carries a different or equal electric charge and these electret layers are each contacted by an electrode;
  • the inventive method for obtaining electrical energy is based on the knowledge that a generator element in the planar mode (d 3 i-mode) is operated.
  • the generator element is a sufficiently thick electret layer in which a macroscopic electrical charge separation prevails along its thickness and which can be connected by means of electrodes with a suitable electrical circuit. It is also possible that an electrically charged, on both sides contacted with electrodes electret layer is present.
  • Another simple case is that there are two equally or differently charged and spatially separated, superimposed electret layers.
  • the generator element is stretched along its longitudinal direction. This can also be stretched generally in the area direction. During stretching, the distance between the electrodes preferably changes, which results in a charge displacement in the case of an asymmetrical design of the generator. However, it is also possible for the symmetrical case that the surface of opposing electret layers changes and this leads to a dielectric shift. The resulting electrical voltage is derived from the electrodes and can be used. When relaxing the generator element, the reverse process takes place.
  • the generator element is an inventive electromechanical converter as described above.
  • the converter With regard to details and specific embodiments.
  • the invention will be further elucidated with reference to the following drawings without, however, being limited thereto. Show it:
  • FIG. 1 an electromechanical transducer
  • FIG. 2 shows another electromechanical converter
  • FIG. 3 shows another electromechanical converter
  • FIG. 4 shows another electromechanical converter
  • FIG. 5 shows another electromechanical converter
  • FIG. 1 shows an electromechanical transducer in cross-sectional view. It may be the cross-sectional view of a laminate film. The thickness direction of this arrangement is vertical in the drawing and the longitudinal direction is horizontal.
  • a dielectric elastomer layer 1 is contacted on its upper side by a first electret layer 4. Schematically represented by the symbol "+" is the electric charge of these electret layers. This can be achieved during the manufacture of the transducer in a corona discharge process.
  • the first electrode 2 is arranged on the side facing away from the dielectric elastomer layer 1 side of the electret layer 4.
  • the second electrode 3 is located on the side facing away from the electret layer 4 of the dielectric elastomer layer.
  • the thickness is reduced. Because the distance between the electret layer 4 and the first electrode 2 remains constant during stretching, but the distance between this electret layer 4 and the second electrode 3 changes, a piezoelectric effect occurs. The occurring electrical voltage can be tapped by means of the electrodes 2 and 3.
  • FIG. 2 another electromechanical transducer is shown in cross-sectional view.
  • this may also be the cross-sectional view of a laminate film.
  • the thickness direction of this arrangement is vertical in the drawing and the longitudinal direction is horizontal.
  • a dielectric elastomer layer 1 is contacted on its upper side and on the opposite underside by first electret layer 4 and second electret layer 5.
  • first electret layer 4 and second electret layer 5 Schematically represented by the symbols "+” and "-" are the opposite electrical charges of both electret layers 4, 5. This can be achieved during the manufacture of the transducer in a corona discharge process by means of suitable positioning of the electrodes.
  • the sides of the electret layers 4, 5 facing and facing away from the dielectric elastomer layer 1 are formed.
  • the first electrode 2 is located on the side of the first electret layer 4 facing away from the elastomer layer 1.
  • the second electrode 3 is located on the side of the second electret layer 5 facing away from the elastomer layer 1.
  • the electrical voltage occurring due to the piezoelectric effect can be picked up by means of the electrodes 2 and 3.
  • FIG. 3 shows a variation of the embodiment shown in FIG. 2 illustrated electromechanical transducer.
  • the two electret layers 4, 5 now have the same, positive electrical charge. Of course, these layers can both be negatively charged.
  • a piezoelectric effect also occurs here due to the change in the size of the opposing surfaces.
  • FIG. 4 shows a further variation of the embodiment shown in FIG. 2 illustrated electromechanical transducer.
  • the dielectric elastomer layer 1 now has a wave-shaped cross-sectional profile along the longitudinal direction.
  • the wave-shaped cross section is formed on both sides of the electret layers 4, 5 contacted sides of the elastomer chicht 1.
  • the wave-shaped cross-sectional profile has elevations 6 and depressions 7.
  • the elevations 6 and depressions 7 of the upper and the lower side of the elastomer layer 1 run parallel here. This has the advantage that with a large elongation in the longitudinal direction, the thickness of the elastomer layer 1 remains as uniform as possible in the course of the longitudinal direction.
  • the electret layers 4, 5 also each have a wave-shaped cross-sectional profile on both sides, which is adapted to the profile of the elastomer chicht 1. Again, the behavior is advantageous for large strains in the longitudinal direction.
  • the electret layers 4, 5 contacting sides of the electrodes 2, 3 are adapted in their cross-sectional profile of the wave-shaped profile of the electret layers 4, 5.
  • FIG. 5 shows a variation of the embodiment shown in FIG. 4 illustrated electromechanical transducer.
  • the electret layers 4, 5 contacting electrodes 2, 3 now have at their respective upper and Bottom sides of an as the electret layers 4, 5 adapted wave-shaped profile.
  • the cross-sectional profile of the entire transducer has been optimized for the thickness behavior at high strains.

Landscapes

  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Power Engineering (AREA)
  • Laminated Bodies (AREA)
  • General Electrical Machinery Utilizing Piezoelectricity, Electrostriction Or Magnetostriction (AREA)
  • Electrostatic, Electromagnetic, Magneto- Strictive, And Variable-Resistance Transducers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

L'invention concerne un transducteur électromécanique comprenant au moins une couche d'élastomère (1) diélectrique, des couches d'électret (4, 5) et des électrodes (2, 3), la couche d'élastomère (1) diélectrique est mise en contact électrique avec ladite au moins une couche d'électret (4), ladite au moins une couche d'électret (4) portant une charge électrique et étant mise en contact avec une première électrode (2) et une deuxième électrode étant disposée sur la face de la couche d'élastomère (1) diélectrique, laquelle étant opposée à la première électrode (2). L'invention concerne également un procédé de production et l'utilisation dudit transducteur électromécanique ainsi que la production d'énergie électrique pouvant faire intervenir le transducteur selon l'invention. Un fonctionnement du transducteur permet la production d'énergie en mode planaire (mode d31).
EP11735818.4A 2010-06-23 2011-06-20 Transducteur électromécanique, procédé de production et utilisation Withdrawn EP2586073A2 (fr)

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EP10167012A EP2400573A1 (fr) 2010-06-23 2010-06-23 Convertisseur électromécanique, son procédé de fabrication et d'utilisation
EP11735818.4A EP2586073A2 (fr) 2010-06-23 2011-06-20 Transducteur électromécanique, procédé de production et utilisation
PCT/EP2011/060225 WO2011161052A2 (fr) 2010-06-23 2011-06-20 Transducteur électromécanique, procédé de production et utilisation

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EP (2) EP2400573A1 (fr)
JP (1) JP2013529884A (fr)
KR (1) KR20130069717A (fr)
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WO (1) WO2011161052A2 (fr)

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CN103069601A (zh) 2013-04-24
US20130307370A1 (en) 2013-11-21
WO2011161052A2 (fr) 2011-12-29
EP2400573A1 (fr) 2011-12-28
KR20130069717A (ko) 2013-06-26
WO2011161052A3 (fr) 2012-06-28

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