EP2626409A1 - Serviette de sèche-linge - Google Patents

Serviette de sèche-linge Download PDF

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Publication number
EP2626409A1
EP2626409A1 EP12154972.9A EP12154972A EP2626409A1 EP 2626409 A1 EP2626409 A1 EP 2626409A1 EP 12154972 A EP12154972 A EP 12154972A EP 2626409 A1 EP2626409 A1 EP 2626409A1
Authority
EP
European Patent Office
Prior art keywords
drying
cloth
dryer
textiles
range
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP12154972.9A
Other languages
German (de)
English (en)
Inventor
Carsten Otte
Lothar Hentz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Twe Vliesstoffwerke & Co KG GmbH
Original Assignee
Twe Vliesstoffwerke & Co KG GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Twe Vliesstoffwerke & Co KG GmbH filed Critical Twe Vliesstoffwerke & Co KG GmbH
Priority to EP12154972.9A priority Critical patent/EP2626409A1/fr
Publication of EP2626409A1 publication Critical patent/EP2626409A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C11D17/047—Arrangements specially adapted for dry cleaning or laundry dryer related applications
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones

Definitions

  • the invention relates to a dryer fabric containing a silicone compound and a silver compound, a process for its preparation, a process for drying textiles and the use of the dryer fabric for drying textiles.
  • US20070006391A1 describes fibers in whose polymeric material even metal complexes are incorporated so that the fibers are antimicrobial.
  • the object of the present invention is to improve the ironability, the hydrophilicity, the softness and the fresh fragrance of the textiles treated during the drying and for long-lasting freshness of the treated textiles. Furthermore, the static charge of the treated textiles should not be worsened.
  • the object underlying the invention is achieved by a dryer cloth impregnated with a silicone compound and a silver compound.
  • silicone compounds To improve the rewettability and to prevent increased static charge of the treated fabrics and to facilitate the ironing of the treated fabrics so silicone compounds are used.
  • the dryer cloth is impregnated with the silicone compound in a range of 0.5 to 20 g / m 2 .
  • the softness of the laundry is only slightly improved.
  • this range there is a risk that this hydrophobic component is transferred to the textiles and makes the textiles hydrophobic.
  • the dryer sheet is impregnated with the silver compound in a range of 9 x 10 -7 to 9 x 10 -5 mole, more preferably in a range of 4 x 10 -6 to 4 x 10 -5 mole Ag + ions per gram of the dryer sheet.
  • the silver compound in a range of 9 x 10 -7 to 9 x 10 -5 mole, more preferably in a range of 4 x 10 -6 to 4 x 10 -5 mole Ag + ions per gram of the dryer sheet.
  • this range little improvement in the freshness of the laundry is observed. Above this range, on the one hand, an economic disadvantage arises and, on the other hand, no longer-lasting freshness seems to be achievable with even more silver ions.
  • the dryer cloth is additionally impregnated with 0.5 to 20 g / m 2 of a polyalkylene.
  • This polalkylene is particularly preferably one Polyethylene.
  • the dryer sheet according to the invention is impregnated with more polyalkylene than with the silicone compound.
  • the proportion by weight of polyalkylene is therefore preferably higher than the weight proportion of the silicone compound. This has the advantage that the dry knitter angle of the treated textiles becomes higher and thus better and, moreover, the hydrophilicity of the textiles is reduced less than in the known solutions.
  • Preferred silicone compounds or silicone derivatives are, for example, polydialkyl or alkylaryl siloxanes in which the alkyl groups have one to five carbon atoms and are completely or partially fluorinated.
  • Preferred silicones are polydimethylsiloxanes, which may optionally be derivatized and are then amino-functional or quaternized or have Si-OH, Si-H and / or Si-Cl bonds.
  • the viscosities of the preferred silicones are advantageously at 25 ° C in the range between 100 and 100,000 mPas.
  • the silicone compound is at least functionalized with a group containing nitrogen, in particular amino-functionalized. This functionality apparently makes this softener component less likely to be transferred to the fabrics.
  • the silver compound is represented by the following formula: Ag (I) nLm where n> m, n and m are integers and n is in a range of 2 to 4, and wherein L is an organic ligand, in particular derived from a polybasic organic acids.
  • the ligand is preferably derived from oxalic, tartaric, citric, oxalacetic, malonic, maleic, glutaric, succinic, malic, adipic, aconitic and / or aspartic acid.
  • N is particularly preferably 3.
  • m is preferably 1. These compounds have proven to be particularly suitable. To introduce silver ions into the dryer cloths and then to transfer them to the laundry as uniformly as possible.
  • the dryer cloth comprises a thermoplastic nonwoven having a basis weight in a range of 30 to 100 g / m 2 , in particular in a range of 40 to 80 g / m 2 .
  • thermoplastic non-woven is preferably a non-woven of polyester.
  • the fibers in the nonwoven are particularly preferably a mixture of customary polyester fibers and polyester melt fibers. Particularly preferred is the weight ratio of these fibers to each other in a range of 2: 1 to 1: 2.
  • the fleece preferably consists of at least two layers, which are particularly preferably needled together.
  • the layers are advantageously crossed.
  • the thickness of the dryer cloth is preferably in a range of 0.1 to 0.5 mm.
  • the surface of the dryer cloth is preferably in a range of 50 to 250 cm 2 .
  • the object underlying the invention is achieved by a method for producing a dryer sheet according to the invention, characterized in that providing a nonwoven web during nonwoven production with an aqueous composition containing at least one silicone compound dispersed therein, and Either during the nonwoven production or subsequently a silver compound is introduced into the dryer cloth.
  • composition preferably contains from 1 to 9% by weight of polyalkylene in dispersed form.
  • the composition preferably contains 1 to 9, in particular 4 to 6,% by weight of the silicone compound.
  • the silver compound is preferably an organic silver salt.
  • the silver salt is included in an amount in the composition such that the content of complexed and free silver ions in the composition is in a range of 7 x 10 -5 to 7 x 10 -4 mol / l of the composition.
  • the silver compound is advantageously equipped as described above.
  • the composition may contain from 0.25 to 0.6% by weight of an ammonium compound.
  • an ammonium compound products of the reaction of alkylamine compounds and polyalkyleneamine compounds with epichlorohydrin may be used, which may be open-chain or ring-shaped, such as ethylenediamine, diethylaminopropylamine, tetraethylenepentamine, polyethyleneamine, imidazole or hexamethylenetetramine.
  • ammonium compounds are products of the reaction of alkylamino and polyalkyleneamino compounds with C8 to C22 chain fatty acids or aliphatic dicarboxylic acids of 2 to 6 carbon atoms in open chain or ring form such as fatty acid amidoalkyl compounds, fatty acid imidazolinium compounds such as fatty acid imidazolinium acetate, coconut fatty acid dimethylamidopropyl betaine compounds, polyamidoamine resin formate; also products of ethoxylation and propoxylation of mono-, di- and polyamine compounds such as stearylamine ethoxylate, and ammonium compounds of urea, guanidine and hydrazine and their derivatives.
  • anions of the ammonium compounds according to the invention are preferably chloride, bromide, sulfate, phosphate, formate, acetate or hydroxide, but other anions are basically usable.
  • the nonwoven is provided with the aqueous composition by foam application, padding, spraying, kissroll or paddling.
  • the aqueous composition is applied after needling and before drying and fixing. As a result, a particularly good impregnation is achieved.
  • the object underlying the invention is achieved by a method for drying textiles, characterized in that adding a dryer cloth according to the invention to the textiles to be dried.
  • the object underlying the invention is achieved by the use of a drying cloth according to the invention for drying textiles, without the hydrophilic properties of the textiles being impaired.
  • a 1 m 2 cross-cut carded web of a 1: 1 mixture of commercial staple polyester fibers and 50 g / m 2 polyester melt fibers was provided. Subsequently, a composition was applied by padding by means of two squeeze rolls. The liquor pickup was 100%.
  • the composition contained: Touch 5 MEP 250 g / l Touch Intermediate DS 250 g / l silver oxalate 27 mg / l water ad 1 liter
  • Touch 5-MEP is a product of Beyond Surface Technologies AG containing an aqueous emulsion of an amino-functionalized polydimethylsiloxane (15 to 20% by weight) and 2.5 to 5% by weight of an alkyl ethoxylate.
  • Touch Intermediate DS is a product of Beyond Surface Technologies AG containing an aqueous emulsion of a polyethylene (about 20 to 25 wt%) and 1 to 2.5 wt% stearylamine ethoxylate.
  • the antimicrobial properties were determined according to ISO 20743 / JIS L 1902 with Klebsiella pneumoniae (ATCC 4352) and Staphylococcus aureus (ATCC 6538P).
  • the number of bacteria according to the above standard was 9.9E + 1 at a reduction of 99.9998%.
  • the number of bacteria according to the above standard was 9.9E + 1 at a reduction of 99.9996%.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
EP12154972.9A 2012-02-10 2012-02-10 Serviette de sèche-linge Withdrawn EP2626409A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP12154972.9A EP2626409A1 (fr) 2012-02-10 2012-02-10 Serviette de sèche-linge

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP12154972.9A EP2626409A1 (fr) 2012-02-10 2012-02-10 Serviette de sèche-linge

Publications (1)

Publication Number Publication Date
EP2626409A1 true EP2626409A1 (fr) 2013-08-14

Family

ID=45592220

Family Applications (1)

Application Number Title Priority Date Filing Date
EP12154972.9A Withdrawn EP2626409A1 (fr) 2012-02-10 2012-02-10 Serviette de sèche-linge

Country Status (1)

Country Link
EP (1) EP2626409A1 (fr)

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69116737T2 (de) 1990-06-01 1996-06-05 Unilever Nv Konditionierungsblatt für Gewebetrockner, enthaltend kompatible Silikone
WO2001088081A1 (fr) * 2000-05-17 2001-11-22 Milliken & Company Substrats de transfert antimicrobien et leurs methodes d'utilisation
US20040167056A1 (en) 2002-04-10 2004-08-26 Lentsch Steven E. Fabric treatment compositions and methods for treating fabric in a dryer
DE69925601T2 (de) 1998-07-28 2006-04-27 Neg Micon A/S Windturbinenflügel mit u-förmigen schwingungsdämpfer
WO2006103076A2 (fr) * 2005-03-30 2006-10-05 Momentive Performance Materials Gmbh Composition contenant des compose polyamino-polysiloxane et/ou polyammonium-polysiloxane sur un substrat
US20070006391A1 (en) 2005-07-07 2007-01-11 Tirthankar Ghosh Fiber containing an antimicrobial composition
US20080004204A1 (en) 2002-04-10 2008-01-03 Tindel-Koukal Monica P Solid fabric conditioning compositions and treatment in a dryer
WO2011110550A1 (fr) * 2010-03-09 2011-09-15 Polymers Crc Ltd Procédé de préparation d'un article antimicrobien
EP2458083A2 (fr) * 2010-11-23 2012-05-30 Rohm and Haas Company Procédé pour le traitement antimicrobien durable de tissus

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69116737T2 (de) 1990-06-01 1996-06-05 Unilever Nv Konditionierungsblatt für Gewebetrockner, enthaltend kompatible Silikone
DE69925601T2 (de) 1998-07-28 2006-04-27 Neg Micon A/S Windturbinenflügel mit u-förmigen schwingungsdämpfer
WO2001088081A1 (fr) * 2000-05-17 2001-11-22 Milliken & Company Substrats de transfert antimicrobien et leurs methodes d'utilisation
US20040167056A1 (en) 2002-04-10 2004-08-26 Lentsch Steven E. Fabric treatment compositions and methods for treating fabric in a dryer
US7087572B2 (en) 2002-04-10 2006-08-08 Ecolab Inc. Fabric treatment compositions and methods for treating fabric in a dryer
US20080004204A1 (en) 2002-04-10 2008-01-03 Tindel-Koukal Monica P Solid fabric conditioning compositions and treatment in a dryer
WO2005026432A1 (fr) 2003-09-04 2005-03-24 Ecolab Inc. Compositions de traitement d'etoffe et procedes de traitement d'une etoffe dans un seche-linge
WO2006103076A2 (fr) * 2005-03-30 2006-10-05 Momentive Performance Materials Gmbh Composition contenant des compose polyamino-polysiloxane et/ou polyammonium-polysiloxane sur un substrat
US20070006391A1 (en) 2005-07-07 2007-01-11 Tirthankar Ghosh Fiber containing an antimicrobial composition
WO2011110550A1 (fr) * 2010-03-09 2011-09-15 Polymers Crc Ltd Procédé de préparation d'un article antimicrobien
EP2458083A2 (fr) * 2010-11-23 2012-05-30 Rohm and Haas Company Procédé pour le traitement antimicrobien durable de tissus

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