EP2688924A4 - Vinylterminierte höhere olefinpolymere und herstellungsverfahren dafür - Google Patents

Vinylterminierte höhere olefinpolymere und herstellungsverfahren dafür

Info

Publication number
EP2688924A4
EP2688924A4 EP12764747.7A EP12764747A EP2688924A4 EP 2688924 A4 EP2688924 A4 EP 2688924A4 EP 12764747 A EP12764747 A EP 12764747A EP 2688924 A4 EP2688924 A4 EP 2688924A4
Authority
EP
European Patent Office
Prior art keywords
produce
methods
olefin polymers
vinyl terminated
higher olefin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
EP12764747.7A
Other languages
English (en)
French (fr)
Other versions
EP2688924A2 (de
Inventor
Matthew W Holtcamp
Charles J Ruff
Donna J Crowther
John R Hagadorn
Patrick Brant
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
ExxonMobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US13/072,288 external-priority patent/US8426659B2/en
Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc
Priority to EP12764747.7A priority Critical patent/EP2688924A4/de
Publication of EP2688924A2 publication Critical patent/EP2688924A2/de
Publication of EP2688924A4 publication Critical patent/EP2688924A4/de
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
EP12764747.7A 2011-03-25 2012-03-05 Vinylterminierte höhere olefinpolymere und herstellungsverfahren dafür Ceased EP2688924A4 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP12764747.7A EP2688924A4 (de) 2011-03-25 2012-03-05 Vinylterminierte höhere olefinpolymere und herstellungsverfahren dafür

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US13/072,288 US8426659B2 (en) 2011-03-25 2011-03-25 Vinyl terminated higher olefin polymers and methods to produce thereof
EP11167033 2011-05-23
PCT/US2012/027690 WO2012134721A2 (en) 2011-03-25 2012-03-05 Vinyl terminated higher olefin polymers and methods to produce thereof
EP12764747.7A EP2688924A4 (de) 2011-03-25 2012-03-05 Vinylterminierte höhere olefinpolymere und herstellungsverfahren dafür

Publications (2)

Publication Number Publication Date
EP2688924A2 EP2688924A2 (de) 2014-01-29
EP2688924A4 true EP2688924A4 (de) 2015-02-25

Family

ID=46932228

Family Applications (1)

Application Number Title Priority Date Filing Date
EP12764747.7A Ceased EP2688924A4 (de) 2011-03-25 2012-03-05 Vinylterminierte höhere olefinpolymere und herstellungsverfahren dafür

Country Status (5)

Country Link
EP (1) EP2688924A4 (de)
JP (1) JP5826913B2 (de)
CN (1) CN103443139B (de)
TW (1) TWI460193B (de)
WO (1) WO2012134721A2 (de)

Families Citing this family (10)

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Publication number Priority date Publication date Assignee Title
CN104968693B (zh) * 2013-01-30 2017-10-17 埃克森美孚化学专利公司 含乙烯基封端的大分子单体作为共聚单体的聚乙烯共聚物
KR101757370B1 (ko) 2015-06-01 2017-07-12 주식회사 엘지화학 1-옥텐 조성물
WO2017097571A1 (en) * 2015-12-09 2017-06-15 Sabic Global Technologies B.V. Process for the preparation of polyolefin-based graft copolymers comprising a first functionalized short chain branched polyolefin block and one or multiple polymer side chains
EP3523337A4 (de) * 2016-10-05 2020-08-05 ExxonMobil Chemical Patents Inc. Sterisch gehinderte metallocene, synthese und verwendung
US10882932B2 (en) 2016-10-05 2021-01-05 Exxonmobil Chemical Patents Inc. Sterically hindered metallocenes, synthesis and use
US10927203B2 (en) * 2017-11-13 2021-02-23 Exxonmobil Chemical Patents Inc. Polyethylene compositions and articles made therefrom
WO2020060690A1 (en) * 2018-09-17 2020-03-26 Exxonmobil Chemical Patents Inc. Metallocene dimer selective catalysts and processes to produce poly alpha-olefin dimers
EP4051656A1 (de) * 2019-10-28 2022-09-07 ExxonMobil Chemical Patents Inc. Dimer-selektive metallocen-katalysatoren, nicht-aromatische kohlenwasserstoff-lösliche aktivatoren und verfahren zum produzieren von poly-alpha-olefin-oligmeren mit ihnen
CN116194494B (zh) * 2020-09-30 2025-04-08 博里利斯股份公司 改善性能特征的乙烯-辛烯共聚物
JP2025075105A (ja) * 2022-03-30 2025-05-15 三井化学株式会社 オレフィン重合体の製造方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004031250A1 (en) * 2002-10-02 2004-04-15 Dow Global Technologies Inc. Liquid and gel-like low molecular weight ethylene polymers

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DE3772331D1 (de) 1986-11-13 1991-09-26 Idemitsu Kosan Co Verfahren zur oligomerisierung von propen.
US5198401A (en) 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5153157A (en) 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5384299A (en) 1987-01-30 1995-01-24 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
PL276385A1 (en) 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
IL85097A (en) 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
US5241025A (en) 1987-01-30 1993-08-31 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5066741A (en) 1990-03-22 1991-11-19 The Dow Chemical Company Process for preparation of syndiotactic vinyl aromatic polymers
US5763549A (en) 1989-10-10 1998-06-09 Fina Technology, Inc. Cationic metallocene catalysts based on organoaluminum anions
US5387568A (en) 1989-10-30 1995-02-07 Fina Technology, Inc. Preparation of metallocene catalysts for polymerization of olefins
EP0426637B2 (de) 1989-10-30 2001-09-26 Fina Technology, Inc. Herstellung von Metallocenkatalysatoren für Olefinpolymerisation
DE69130320T2 (de) 1990-07-24 1999-04-08 Mitsui Chemicals Inc Katalysator für alpha-olefinpolymerisation und herstellung von poly(alpha)olefinen damit
US5189192A (en) 1991-01-16 1993-02-23 The Dow Chemical Company Process for preparing addition polymerization catalysts via metal center oxidation
US5206197A (en) 1991-03-04 1993-04-27 The Dow Chemical Company Catalyst composition for preparation of syndiotactic vinyl aromatic polymers
US5721185A (en) 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
US5434115A (en) 1992-05-22 1995-07-18 Tosoh Corporation Process for producing olefin polymer
WO1994001471A1 (en) 1992-07-01 1994-01-20 Exxon Chemical Patents Inc. Transition metal olefin polymerization catalysts
US5447895A (en) 1994-03-10 1995-09-05 Northwestern University Sterically shielded diboron-containing metallocene olefin polymerization catalysts
BR9507915A (pt) * 1994-06-09 1997-08-12 Exxon Chemical Patents Inc Processo contínuo para a produção de polimero não etileno compreendendo unidades monoméricas derivadas de pelo menos uma olefina na presença de um sistema catalisador de metaloceno e numa zona de reação contendo fase liquida
EP0728773B1 (de) 1995-02-21 1998-11-04 Mitsubishi Chemical Corporation Katalysatoren für Olefinpolymerisation und Verfahren zur Herstellung von damit erhaltenen Olefinpolymeren
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US7589160B2 (en) * 2002-12-04 2009-09-15 Basell Polyolefine Gmbh Process for preparing 1-butene polymers
WO2006028169A1 (ja) * 2004-09-10 2006-03-16 Mitsui Chemicals, Inc. 潤滑油用粘度調整剤、潤滑油用添加剤組成物および潤滑油組成物
US8372930B2 (en) * 2008-06-20 2013-02-12 Exxonmobil Chemical Patents Inc. High vinyl terminated propylene based oligomers
SG193137A1 (en) 2008-06-20 2013-09-30 Exxonmobil Chem Patents Inc High vinyl terminated propylene based oligomers

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WO2004031250A1 (en) * 2002-10-02 2004-04-15 Dow Global Technologies Inc. Liquid and gel-like low molecular weight ethylene polymers

Non-Patent Citations (3)

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Title
See also references of WO2012134721A2 *
XU G ET AL: "ETHYLENE COPOLYMERIZATION WITH 1-OCTENE USING A 2-METHYLBENZÚE 3/4 INDENYL-BASED ANSA-MONOCYCLOPENTADIENYLAMIDO COMPLEX AND METHYLALUMINOXANES CATALYST", MACROMOLECULES, AMERICAN CHEMICAL SOCIETY, US, vol. 31, no. 15, 28 July 1998 (1998-07-28), pages 4724 - 4729, XP000769970, ISSN: 0024-9297, DOI: 10.1021/MA980498D *
ZHIXIAN LIU ET AL: "Kinetics of Initiation, Propagation, and Termination for the [ rac -(C 2 H 4 (1-indenyl) 2 )ZrMe][MeB(C 6 F 5 ) 3 ]-Catalyzed Polymerization of 1-Hexene", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 123, no. 45, 1 November 2001 (2001-11-01), pages 11193 - 11207, XP055125935, ISSN: 0002-7863, DOI: 10.1021/ja016072n *

Also Published As

Publication number Publication date
JP2014511912A (ja) 2014-05-19
EP2688924A2 (de) 2014-01-29
CN103443139A (zh) 2013-12-11
TW201300431A (zh) 2013-01-01
TWI460193B (zh) 2014-11-11
JP5826913B2 (ja) 2015-12-02
WO2012134721A2 (en) 2012-10-04
WO2012134721A3 (en) 2012-11-29
CN103443139B (zh) 2016-10-12

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