EP2728046B1 - Matériau composite pour la fabrication de systèmes d'étanchéité et procédé correspondant - Google Patents

Matériau composite pour la fabrication de systèmes d'étanchéité et procédé correspondant Download PDF

Info

Publication number
EP2728046B1
EP2728046B1 EP20120191325 EP12191325A EP2728046B1 EP 2728046 B1 EP2728046 B1 EP 2728046B1 EP 20120191325 EP20120191325 EP 20120191325 EP 12191325 A EP12191325 A EP 12191325A EP 2728046 B1 EP2728046 B1 EP 2728046B1
Authority
EP
European Patent Office
Prior art keywords
biosoluble
composite material
ceramics
solution
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Not-in-force
Application number
EP20120191325
Other languages
German (de)
English (en)
Other versions
EP2728046A1 (fr
Inventor
Franco Rossi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
F M I SpA
Original Assignee
F M I SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by F M I SpA filed Critical F M I SpA
Priority to EP20120191325 priority Critical patent/EP2728046B1/fr
Publication of EP2728046A1 publication Critical patent/EP2728046A1/fr
Application granted granted Critical
Publication of EP2728046B1 publication Critical patent/EP2728046B1/fr
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4209—Inorganic fibres

Definitions

  • the present invention relates to a composite material for making sealing systems and a method therefor.
  • biosoluble ceramics fibers which will be hereinbelow referred to as "A" composite are exclusively used.
  • B composites comprise: muscovite and phlogophite mica, bentonite, montmorilonite, laponite, hydrotalcite, kaolin, lamellar structure silicates, phyllosilicates, thermally, ultrasonically and/or chemically foamed phlogophite mica.
  • Said B composites may also be used in any combinations and rates.
  • the A composite may be used as a fibrous reinforcement agent for composite materials, owing to its good mechanical and chemical properties; however, in the sealing or gasket system field it cannot be used per se, because of its poor sealing capability.
  • the B composites may be used in the sealing system field, since they provide good sealing capabilities, but cannot be used per se, because of their poor mechanical characteristics.
  • the aim of the present invention is to provide a combined composite material the A composite of which is chemically bound to the B composite, through an organosilane based chemical process.
  • the end product appears as consisting of an uneven weave of biosoluble ceramics fibers operating as structural support for inorganic compounds having a layered lamellar structure.
  • the invention also relates to a method for making plates, films and sheets even coupled to other materials such as metal and non-metal fiber fabrics, smooth, perforated and/or diamond shaped metal laminates, which will be hereinbelow referred to as "supports".
  • the method according to the present invention comprises the following method steps:
  • the A composite is processed with vinyltriethoxysilane in an aqueous or organic solution and with a concentration from 0.1 to 30% by weight, in which vinyltriethoxysilane is present starting from a rate from 0.5% up to 30% by weight, based on the A composite.
  • the B composite is processed with bis(triethoxy-silylpropyl)polysulfide in an aqueous or organic solution at a concentration from 0.1 to 60% by weight, wherein said bis(triethoxysilylpropyl)polysulfide is present from a rate of 0.5% to 30% by weight based on the B composite.
  • the A and B composites, as pre-processed in said step 1) are mixed with a solution polymer based binding system such as: NBR, chloroprene, SBR, polyisoprene, polybutadiene, butyl, silicone, fluorurated and urethane rubbers.
  • a solution polymer based binding system such as: NBR, chloroprene, SBR, polyisoprene, polybutadiene, butyl, silicone, fluorurated and urethane rubbers.
  • the following solvents are herein used: toluene, xylene, dimethylketone methylethylketone, saturated C6-C10 linear and cyclic hydrocarbons.
  • the solutions contain the polymer in a rate up to 30% by weight.
  • the preferred mixing system comprises a "Z branch" or a planetary system.
  • the mixing time is preferably from 30 to 45 minutes, depending on the desired end viscosity.
  • the A composite may be introduced into the mixture in a rate up to 80% by weight.
  • the B composite may be introduced into the mixture in a rate up to 90% by weight.
  • the process aid is introduced into the mixture in a rate up to 7% by weight.
  • step 3) the mixture of step 2) may be processed through calendaring or spreading and optionally coupled to a support, if either plates or continuous films are to be achieved.
  • step 4 the half-finished articles of step 3) are subjected to a thermal cycle up to 250°C depending on the used process aid polymer and solvent, with a heating rate from 1°C/minute.
  • the invention has provided a method of making a composite material, particularly suitable for making sealing systems, comprising a combination of biosoluble ceramics fibers and mineral filers.
  • the method according to the present invention provides an end product consisting of an uneven weave of biosoluble ceramics fibers, operating as a structural support for inorganic composites having a lamellar layered structure.
  • the sealing system composite material according to the present invention comprises a biosoluble fiber matrix having a thermal resistance up to 1000°C, with lamellar layered structure inorganic composites having a particle size from 1 ⁇ m.
  • organosilanes in the subject method provides a mechanically continuous phase between the biosoluble fiber structure and the lamellar structure inorganic composites.
  • the method according to the present invention provides semifinished sheets, plates, films or sheet elements coupled to other materials such as metal and non-metal fiber fabrics, smooth, perforated and/or diamond shaped metal laminates and other articles.
  • the composite material made by the present invention may be used at high temperatures up to 1,000°C, even in the presence of strongly oxidizing agents.
  • inventive composite material may also be used for high temperature sealing systems.
  • inventive composite material may also be used as a protective film coated on surfaces of the sheet elements.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Sealing Material Composition (AREA)

Claims (7)

  1. Procédé de fabrication d'un matériau composite pour des systèmes d'étanchéité, ledit matériau composite comprenant une matrice de fibres de céramique biosolubles fonctionnant comme un support structurel pour les composites inorganiques ayant une structure stratifiée lamellaire, ledit procédé comprenant les étapes de :
    prétraitement chimique de fibres de céramique biosolubles dans une solution aqueuse avec du vinyltriéthoxysilane et de charges minérales avec du polysulfure de bis(triéthoxysilylpropyle) ou inversement ;
    mélange lentement des fibres de céramique biosolubles et des charges minérales chimiquement prétraitées par une solution de matériau élastomère ;
    formation d'une plaque et/ou d'une structure lamellaire avec ledit support structurel ;
    durcissement thermique de ladite plaque et/ou de ladite structure stratifiée ; et
    revêtement à chaud, par calandrage à vide, sur une surface de ladite plaque et/ou de ladite structure stratifiée, d'un film protecteur antiadhésif ayant une épaisseur supérieure à 5 µm, basé sur une silice à température élevée et du PET.
  2. Procédé selon la revendication 1, caractérisé en ce que lesdites charges minérales comprennent un ou plusieurs éléments choisis parmi le mica, la muscovite et la phlogopite, la bentonite, la montmorilonite, la laponite, l'hydrotalcite, le kaolin, les silicates de structure lamellaire, les phyllosilicates et un mica phlogopite expansé thermiquement, par ultrasons et/ou chimiquement.
  3. Procédé selon la revendication 1, caractérisé en ce que ledit vinyltriéthoxysilane est sous la forme d'une solution aqueuse ou organique à une concentration de 0,1 à 30 % en poids, ledit vinyltriéthoxysilane étant appliqué en une quantité de 0,5 % à 30 % en poids par rapport aux fibres de céramique biosolubles, ledit polysulfure de bis(triéthoxysilylpropyle) étant sous la forme d'une solution aqueuse ou organique à une concentration de 0,1 à 60 % en poids, ledit polysulfure de bis(triéthoxysilylpropyle) étant appliqué en une quantité de 0,5 % à 30 % en poids par rapport auxdites charges minérales, ledit prétraitement étant réalisé de manière séparée dans un récipient de prétraitement fermé et sous agitation à une température de 25 °C à 80 °C pendant 24 heures.
  4. Procédé selon la revendication 1, caractérisé en ce que ladite solution de matériau élastomère est une solution d'un matériau polymère choisi parmi un ou plusieurs de NBR, chloroprène, SBR, polyisoprène, polybutadiène, butyle, silicone et caoutchoucs d'uréthane et fluorés.
  5. Procédé selon la revendication 1, caractérisé en ce que lesdits solvants du procédé choisis parmi le toluène, le xylène, la diméthylcétone, la méthyléthylcétone, les hydrocarbures en C6-C10 linéaires et cycliques saturés sont utilisés.
  6. Matériau composite pour la préparation de systèmes d'étanchéité par un procédé selon la revendication 1, caractérisé en ce que ladite matrice de fibres de céramique biosolubles se compose d'un arrangement tissé irrégulier de fibres biosolubles.
  7. Matériau composite selon la revendication 6, caractérisé en ce que ladite matrice de fibres de céramique biosolubles a une résistance thermique inférieure à 1 000 °C et lesdits composites inorganiques de la structure stratifiée lamellaire ont une granulométrie supérieure à 1 µm.
EP20120191325 2012-11-05 2012-11-05 Matériau composite pour la fabrication de systèmes d'étanchéité et procédé correspondant Not-in-force EP2728046B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP20120191325 EP2728046B1 (fr) 2012-11-05 2012-11-05 Matériau composite pour la fabrication de systèmes d'étanchéité et procédé correspondant

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP20120191325 EP2728046B1 (fr) 2012-11-05 2012-11-05 Matériau composite pour la fabrication de systèmes d'étanchéité et procédé correspondant

Publications (2)

Publication Number Publication Date
EP2728046A1 EP2728046A1 (fr) 2014-05-07
EP2728046B1 true EP2728046B1 (fr) 2015-02-25

Family

ID=47115604

Family Applications (1)

Application Number Title Priority Date Filing Date
EP20120191325 Not-in-force EP2728046B1 (fr) 2012-11-05 2012-11-05 Matériau composite pour la fabrication de systèmes d'étanchéité et procédé correspondant

Country Status (1)

Country Link
EP (1) EP2728046B1 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105885130A (zh) * 2015-01-13 2016-08-24 奉化联邦橡胶有限公司 一种耐低温、耐油橡胶密封复合材料及其制备方法
CN113171961B (zh) * 2021-04-25 2022-04-15 杭州萧山红垦保温防腐有限公司 一种岩棉毡及其生产工艺

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5814271A (en) * 1996-09-03 1998-09-29 Dow Corning Corporation Process of producing fibers from curable alk-1-enyl ether functional siloxane resins
KR100773602B1 (ko) * 2001-12-29 2007-11-07 주식회사 케이씨씨 인공체액에 대한 용해도가 우수한 고온단열재용 생분해성세라믹 섬유조성물
KR101206365B1 (ko) * 2010-02-24 2012-11-29 주식회사 케이씨씨 세라믹 섬유 제조용 조성물 및 그로부터 제조된 고온단열재용 생체용해성 세라믹 섬유

Also Published As

Publication number Publication date
EP2728046A1 (fr) 2014-05-07

Similar Documents

Publication Publication Date Title
RU2676289C1 (ru) Сегментированные гелевые композиты и жесткие панели, изготовленные из них
Signorini et al. Silica coating for interphase bond enhancement of carbon and AR-glass Textile Reinforced Mortar (TRM)
Chu et al. Construction of hierarchical natural fabric surface structure based on two-dimensional boron nitride nanosheets and its application for preparing biobased toughened unsaturated polyester resin composites
US20110306255A1 (en) Strong Materials of Construction and Coatings Comprising Inorganic Binders with Fibre Reinforcement
CN104532551B (zh) 一种碳纤维表面原位制备硅硼碳氮陶瓷涂层的方法
DE102010046684A1 (de) Stabilisierter Wärmedämmformkörper mit hydrophoben, mikroporösem Dämmstoffkern und hydrophiler Oberfläche
KR20130048748A (ko) 액상 경화성 조성물
AU2013263748B2 (en) Building board and method for producing building board
Jung et al. The effect of aqueous polyimide sizing agent on PEEK based carbon fiber composites using experimental techniques and molecular dynamics simulations
Ostapiuk et al. Interlaminar shear strength study of Mg and carbon fiber-based hybrid laminates with self-healing microcapsules
EP2728046B1 (fr) Matériau composite pour la fabrication de systèmes d'étanchéité et procédé correspondant
KR101427061B1 (ko) 폐섬유를 이용한 내열성 조인트 시트의 제조방법
Liu et al. High strength, high toughness, low thermal conductivity, and appropriate expansion capacity of hybrid organic/inorganic nanocomposites used for thermal protection
Wu et al. Polyhedral oligomeric silsesquioxane encountering tannic acid: a mild and efficient strategy for interface modification on carbon fiber composites
US8333867B2 (en) Method for bonding fibrous silicone-coated supports
Zhang et al. Tea‐polyphenols mediated interfacial modifier to integrate reinforcement, reprocessability, and shape memory properties into rubber/carbon black composites via coordination bonds
CN1803963A (zh) 非石棉类片状垫片
CN107323020B (zh) 一种硅橡胶聚合物耐候性皮革及其制备方法
KR101872450B1 (ko) 아라미드직물을 사용한 자동차용 다이어프램용 원단의 제조방법
EP1836271B1 (fr) Materiau pour joint et procede de fabrication
KR100948355B1 (ko) 차열 및 방수 구조물, 차열 및 방수시트 및 이를 이용한차열 및 방수공법
CN120923928A (zh) 一种耐磨密封胶条及其制备方法
Aziz et al. Calcium-reinforced graphene oxide-biopolymer nanocomposite: A novel and sustainable sizing agent for enhancing E-glass fibers strength and adhesion in cement composites
Li et al. Mechanism of CFF/PPS interface strength enhancement via infrared heating desizing‐assisted plasma treatment
Sun et al. Self-Healing Polyurethane/Fabric Composite with Puncture Resistance Enabled by Phase Regulation and Matrix-Fiber Strengthening

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20121105

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

AX Request for extension of the european patent

Extension state: BA ME

17P Request for examination filed

Effective date: 20140609

17Q First examination report despatched

Effective date: 20140721

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

INTG Intention to grant announced

Effective date: 20141114

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 602012005425

Country of ref document: DE

Effective date: 20150409

REG Reference to a national code

Ref country code: AT

Ref legal event code: REF

Ref document number: 712104

Country of ref document: AT

Kind code of ref document: T

Effective date: 20150415

REG Reference to a national code

Ref country code: NL

Ref legal event code: VDEP

Effective date: 20150225

REG Reference to a national code

Ref country code: AT

Ref legal event code: MK05

Ref document number: 712104

Country of ref document: AT

Kind code of ref document: T

Effective date: 20150225

REG Reference to a national code

Ref country code: LT

Ref legal event code: MG4D

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150225

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150225

Ref country code: NO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150525

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150225

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150225

Ref country code: HR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150225

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150625

Ref country code: AT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150225

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150526

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150225

Ref country code: RS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150225

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150225

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150225

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150225

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150225

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150225

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150225

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 602012005425

Country of ref document: DE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150225

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed

Effective date: 20151126

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150225

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150225

REG Reference to a national code

Ref country code: DE

Ref legal event code: R119

Ref document number: 602012005425

Country of ref document: DE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150225

Ref country code: LU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20151105

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20151130

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20151130

REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

Effective date: 20160729

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20151105

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20160601

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20151130

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO

Effective date: 20121105

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150225

Ref country code: SM

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150225

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150225

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20161105

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150225

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20161105

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150225

Ref country code: MK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150225

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150225

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150225

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IT

Payment date: 20191121

Year of fee payment: 8

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20201105